JP2014504308A - 膨張発泡断熱材による壁空洞の充填方法 - Google Patents
膨張発泡断熱材による壁空洞の充填方法 Download PDFInfo
- Publication number
- JP2014504308A JP2014504308A JP2013540005A JP2013540005A JP2014504308A JP 2014504308 A JP2014504308 A JP 2014504308A JP 2013540005 A JP2013540005 A JP 2013540005A JP 2013540005 A JP2013540005 A JP 2013540005A JP 2014504308 A JP2014504308 A JP 2014504308A
- Authority
- JP
- Japan
- Prior art keywords
- blowing agent
- independently selected
- foam
- cavity
- hfc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006260 foam Substances 0.000 title claims abstract description 92
- 238000011049 filling Methods 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims description 33
- 238000009413 insulation Methods 0.000 title description 22
- 239000004604 Blowing Agent Substances 0.000 claims abstract description 101
- 239000004814 polyurethane Substances 0.000 claims abstract description 40
- 229920000582 polyisocyanurate Polymers 0.000 claims abstract description 33
- 239000011495 polyisocyanurate Substances 0.000 claims abstract description 32
- 229920002635 polyurethane Polymers 0.000 claims abstract description 32
- 238000009835 boiling Methods 0.000 claims abstract description 30
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims description 69
- 229920005862 polyol Polymers 0.000 claims description 53
- 150000003077 polyols Chemical class 0.000 claims description 49
- 238000006243 chemical reaction Methods 0.000 claims description 28
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims description 28
- 238000005187 foaming Methods 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- 239000003054 catalyst Substances 0.000 claims description 19
- 239000012948 isocyanate Substances 0.000 claims description 18
- -1 halogenated aromatic polyol Chemical class 0.000 claims description 17
- 239000004088 foaming agent Substances 0.000 claims description 15
- 150000002513 isocyanates Chemical class 0.000 claims description 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- 229910052731 fluorine Inorganic materials 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 229910052801 chlorine Inorganic materials 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 6
- 229930006000 Sucrose Natural products 0.000 claims description 6
- 239000005720 sucrose Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 20
- 210000004027 cell Anatomy 0.000 description 19
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 15
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 13
- 239000005056 polyisocyanate Substances 0.000 description 13
- 229920001228 polyisocyanate Polymers 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 229920002396 Polyurea Polymers 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229920005830 Polyurethane Foam Polymers 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000011496 polyurethane foam Substances 0.000 description 6
- 239000003380 propellant Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical class FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000011152 fibreglass Substances 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 4
- AQUOXSKXTDCRCV-UHFFFAOYSA-N 1,1,1,3,3-pentafluoropentane Chemical compound CCC(F)(F)CC(F)(F)F AQUOXSKXTDCRCV-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000012774 insulation material Substances 0.000 description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 3
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- NLOLSXYRJFEOTA-OWOJBTEDSA-N (e)-1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)\C=C\C(F)(F)F NLOLSXYRJFEOTA-OWOJBTEDSA-N 0.000 description 2
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 description 2
- NVSXSBBVEDNGPY-UHFFFAOYSA-N 1,1,1,2,2-pentafluorobutane Chemical class CCC(F)(F)C(F)(F)F NVSXSBBVEDNGPY-UHFFFAOYSA-N 0.000 description 2
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 description 2
- FYIRUPZTYPILDH-UHFFFAOYSA-N 1,1,1,2,3,3-hexafluoropropane Chemical compound FC(F)C(F)C(F)(F)F FYIRUPZTYPILDH-UHFFFAOYSA-N 0.000 description 2
- INEMUVRCEAELBK-UHFFFAOYSA-N 1,1,1,2-tetrafluoropropane Chemical class CC(F)C(F)(F)F INEMUVRCEAELBK-UHFFFAOYSA-N 0.000 description 2
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 description 2
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 2
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 2
- BOUGCJDAQLKBQH-UHFFFAOYSA-N 1-chloro-1,2,2,2-tetrafluoroethane Chemical compound FC(Cl)C(F)(F)F BOUGCJDAQLKBQH-UHFFFAOYSA-N 0.000 description 2
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical class O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 description 2
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 description 2
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229920005372 Plexiglas® Polymers 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 2
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000006261 foam material Substances 0.000 description 2
- 229920001821 foam rubber Polymers 0.000 description 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- UKACHOXRXFQJFN-UHFFFAOYSA-N heptafluoropropane Chemical class FC(F)C(F)(F)C(F)(F)F UKACHOXRXFQJFN-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 229920005906 polyester polyol Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 description 1
- CXIGIYYQHHRBJC-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluorobutane Chemical class FC(F)(F)CCC(F)(F)F CXIGIYYQHHRBJC-UHFFFAOYSA-N 0.000 description 1
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
- NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical class FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 description 1
- DMUPYMORYHFFCT-UHFFFAOYSA-N 1,2,3,3,3-pentafluoroprop-1-ene Chemical compound FC=C(F)C(F)(F)F DMUPYMORYHFFCT-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- GIWQSPITLQVMSG-UHFFFAOYSA-N 1,2-dimethylimidazole Chemical compound CC1=NC=CN1C GIWQSPITLQVMSG-UHFFFAOYSA-N 0.000 description 1
- IKYNWXNXXHWHLL-UHFFFAOYSA-N 1,3-diisocyanatopropane Chemical compound O=C=NCCCN=C=O IKYNWXNXXHWHLL-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 description 1
- LDTMPQQAWUMPKS-UHFFFAOYSA-N 1-chloro-3,3,3-trifluoroprop-1-ene Chemical class FC(F)(F)C=CCl LDTMPQQAWUMPKS-UHFFFAOYSA-N 0.000 description 1
- DTZHXCBUWSTOPO-UHFFFAOYSA-N 1-isocyanato-4-[(4-isocyanato-3-methylphenyl)methyl]-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(CC=2C=C(C)C(N=C=O)=CC=2)=C1 DTZHXCBUWSTOPO-UHFFFAOYSA-N 0.000 description 1
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- MELCWEWUZODSIS-UHFFFAOYSA-N 2-[2-(diethylamino)ethoxy]-n,n-diethylethanamine Chemical compound CCN(CC)CCOCCN(CC)CC MELCWEWUZODSIS-UHFFFAOYSA-N 0.000 description 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- ZWXQPERWRDHCMZ-UHFFFAOYSA-N 2-methyl-n-propan-2-ylpropan-2-amine Chemical compound CC(C)NC(C)(C)C ZWXQPERWRDHCMZ-UHFFFAOYSA-N 0.000 description 1
- QZWKEPYTBWZJJA-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine-4,4'-diisocyanate Chemical compound C1=C(N=C=O)C(OC)=CC(C=2C=C(OC)C(N=C=O)=CC=2)=C1 QZWKEPYTBWZJJA-UHFFFAOYSA-N 0.000 description 1
- NGRYSBPZIYVTHZ-UHFFFAOYSA-N 3-[3-(dimethylamino)propoxy]-n,n-dimethylpropan-1-amine Chemical compound CN(C)CCCOCCCN(C)C NGRYSBPZIYVTHZ-UHFFFAOYSA-N 0.000 description 1
- JLEIRAYWBMNMKU-UHFFFAOYSA-N 3-ethylpentan-3-amine Chemical compound CCC(N)(CC)CC JLEIRAYWBMNMKU-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ZMSQJSMSLXVTKN-UHFFFAOYSA-N 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine Chemical compound C1COCCN1CCOCCN1CCOCC1 ZMSQJSMSLXVTKN-UHFFFAOYSA-N 0.000 description 1
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
- KMFMBVVSSUECBW-UHFFFAOYSA-N 4-isocyanato-1-[(4-isocyanato-2-methylphenyl)methyl]-2-methylbenzene Chemical compound CC1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1C KMFMBVVSSUECBW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- JZUFKLXOESDKRF-UHFFFAOYSA-N Chlorothiazide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC2=C1NCNS2(=O)=O JZUFKLXOESDKRF-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- KEJFAGMNOBNFJR-QMTHXVAHSA-N Isophorene Natural products S=C(NC[C@]1(C)C[C@H](NC(=S)NC)CC(C)(C)C1)NC KEJFAGMNOBNFJR-QMTHXVAHSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 1
- IXQBIOPGDNZYNA-UHFFFAOYSA-N N=C=O.N=C=O.CC1=CC=CC=C1C1=CC=CC=C1C Chemical compound N=C=O.N=C=O.CC1=CC=CC=C1C1=CC=CC=C1C IXQBIOPGDNZYNA-UHFFFAOYSA-N 0.000 description 1
- SPTUBPSDCZNVSI-UHFFFAOYSA-N N=C=O.N=C=O.COC1=CC=CC=C1C1=CC=CC=C1OC Chemical compound N=C=O.N=C=O.COC1=CC=CC=C1C1=CC=CC=C1OC SPTUBPSDCZNVSI-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 239000005662 Paraffin oil Chemical class 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical class CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- 229950005499 carbon tetrachloride Drugs 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 125000004773 chlorofluoromethyl group Chemical group [H]C(F)(Cl)* 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 239000012973 diazabicyclooctane Substances 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- QVQGTNFYPJQJNM-UHFFFAOYSA-N dicyclohexylmethanamine Chemical compound C1CCCCC1C(N)C1CCCCC1 QVQGTNFYPJQJNM-UHFFFAOYSA-N 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 description 1
- 210000000497 foam cell Anatomy 0.000 description 1
- 239000011494 foam glass Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 229960002003 hydrochlorothiazide Drugs 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 239000004620 low density foam Substances 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- VMOWKUTXPNPTEN-UHFFFAOYSA-N n,n-dimethylpropan-2-amine Chemical compound CC(C)N(C)C VMOWKUTXPNPTEN-UHFFFAOYSA-N 0.000 description 1
- ASKYIFBXGFWCBG-UHFFFAOYSA-N n-benzyl-n-methylcyclopentanamine Chemical compound C1CCCC1N(C)CC1=CC=CC=C1 ASKYIFBXGFWCBG-UHFFFAOYSA-N 0.000 description 1
- WFMUJLWWGDJDBF-UHFFFAOYSA-N n-benzyl-n-methylpropan-2-amine Chemical compound CC(C)N(C)CC1=CC=CC=C1 WFMUJLWWGDJDBF-UHFFFAOYSA-N 0.000 description 1
- OBYVIBDTOCAXSN-UHFFFAOYSA-N n-butan-2-ylbutan-2-amine Chemical compound CCC(C)NC(C)CC OBYVIBDTOCAXSN-UHFFFAOYSA-N 0.000 description 1
- FUUUBHCENZGYJA-UHFFFAOYSA-N n-cyclopentylcyclopentanamine Chemical compound C1CCCC1NC1CCCC1 FUUUBHCENZGYJA-UHFFFAOYSA-N 0.000 description 1
- BBPKSHICVYBPRR-UHFFFAOYSA-N n-propan-2-yl-n-(2,2,2-trifluoroethyl)butan-2-amine Chemical compound CCC(C)N(C(C)C)CC(F)(F)F BBPKSHICVYBPRR-UHFFFAOYSA-N 0.000 description 1
- CATWEXRJGNBIJD-UHFFFAOYSA-N n-tert-butyl-2-methylpropan-2-amine Chemical compound CC(C)(C)NC(C)(C)C CATWEXRJGNBIJD-UHFFFAOYSA-N 0.000 description 1
- MTEWAFVECQBILW-UHFFFAOYSA-N n-tert-butylcyclohexanamine Chemical compound CC(C)(C)NC1CCCCC1 MTEWAFVECQBILW-UHFFFAOYSA-N 0.000 description 1
- 125000004957 naphthylene group Chemical group 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000013849 propane Nutrition 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000012048 reactive intermediate Substances 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 238000009436 residential construction Methods 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical class CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000002937 thermal insulation foam Substances 0.000 description 1
- 239000006269 thermoset foam Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- BZVJOYBTLHNRDW-UHFFFAOYSA-N triphenylmethanamine Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(N)C1=CC=CC=C1 BZVJOYBTLHNRDW-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 239000004639 urea-formaldehyde foam Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/22—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
- C08G18/3804—Polyhydroxy compounds
- C08G18/3806—Polyhydroxy compounds having chlorine and/or bromine atoms
- C08G18/381—Polyhydroxy compounds having chlorine and/or bromine atoms having bromine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Refrigerator Housings (AREA)
Abstract
Description
前記空洞に二成分のポリウレタンまたはポリイソシアヌレート発泡体を加える工程であって、前記発泡体が、有効量の少なくとも1つの発泡剤、およびその混和性混合物および共沸混合物等を含み、前記発泡剤が以下の式(I)を含む:
[CVa]m - A - [CXb]n - B - [CYc]o - D - [CZd]p
式中、
Cは、炭素原子であり;
V、X、YおよびZは、独立して、H、FおよびClよりなる群から選択され、従って、上記で使用した通り、上記のマーカッシュの式の第一の成分として許容される部分、即ち[CVa]は、CF3-、CHF2-、CH2F-、CCl3-、CHCl2-、CH2Cl-、CH3-、CHClF-、CCl2F-、CF2Cl-、CH=、C≡、CF=、CCl=等であってもよく;
aおよびdは、独立して、0から3までの範囲の整数値から選択され;
bおよびcは、独立して、0から2までの範囲の整数値から選択され;
o、pおよびnは、1に等しく;
mは、0から1までの範囲の整数値から選択され;
A、BおよびDは、隣接する炭素原子が存在する場合、そのような炭素原子の利用可能な結合部位を充分に満たす共有結合であり;
前記発泡剤は、沸点が約5〜50℃の間であり、オゾン層破壊係数が0.05以下であり;
前記発泡系は、反応プロフィールのゲルおよび粘着時間(a reation profile gel and tack time)が約90秒未満である。
[CUe]q - E - [CWf]r - F - [CVa]m - A - [CXb]n - B - [CYc]o - D - [CZd]p
式中、
Cは、炭素原子であり;
U、W、V、X、YおよびZは、独立して、H、FおよびClよりなる群から選択され、式(I)に示される通り、マーカッシュの式の要素に類似の構造を配置し;
dおよびeは、独立して、0から3までの範囲の整数値から選択され;
a、b、cおよびfは、独立して、0から2までの範囲の整数値から選択され;
o、pおよびnは、1に等しく;
m、qおよびrは、独立して、0から1までの範囲の整数値から選択され;
A、B、D、EおよびFは、隣接する炭素原子が存在する場合、そのような炭素原子の利用可能な結合部位を充分に満たす共有結合であり;
前記発泡剤は、沸点が約5〜50℃の間であり、オゾン層破壊係数が0.05以下であり;
前記発泡系は、反応プロフィールのゲルおよび粘着時間が約90秒未満であり;
前記発泡剤は、不燃性である。
R(NCO)z
実施例10
[CVa]m - A - [CXb]n - B - [CYc]o - D - [CZd]p
式中、
Cは、炭素原子であり;
V、X、YおよびZは、独立して、H、FおよびClよりなる群から選択され(前記と同様の定義を適用する);
aおよびdは、独立して、0から3までの範囲の整数値から選択され;
bおよびcは、独立して、0から2までの範囲の整数値から選択され;
o、pおよびnは、1に等しく;
mは、0から1までの範囲の整数値から選択され;
A、BおよびDは、隣接する炭素原子が存在する場合、そのような炭素原子の利用可能な結合部位を満たすに充分な共有結合であり;
前記発泡剤、およびその混和性混合物および共沸混合物は、沸点が約5〜50℃の間であり、オゾン層破壊係数が実質的にゼロであり;
前記発泡系は、反応プロフィールのゲルおよび粘着時間が約90秒未満であり、より好ましくは約60秒未満であり、最も好ましくは約45秒未満であり;および
好ましい態様において、前記発泡剤は不燃性であり、共発泡剤は可燃性であってもよいと認められる。
[CUe]q - E - [CWf]r - F - [CVa]m - A - [CXb]n - B - [CYc]o - D - [CZd]p
式中、
Cは、炭素原子であり;
U、W、V、X、YおよびZは、独立して、H、FおよびClよりなる群から選択され、(前記と同様の定義を適用する);
dおよびeは、独立して、0から3までの範囲の整数値から選択され;
a、b、cおよびfは、独立して、0から2までの範囲の整数値から選択され;
o、pおよびnは、1に等しく;
m、qおよびrは、独立して、0から1までの範囲の整数値から選択され;
A、B、D、EおよびFは、隣接する炭素原子が存在する場合、そのような炭素原子の利用可能な結合部位を満たすに充分な共有結合であり;
前記発泡剤は、沸点が約5〜50℃の間であり、オゾン層破壊係数が0.05以下であり;
前記発泡系は、反応プロフィールのゲルおよび粘着時間が約90秒未満であり、より好ましくは約60秒未満であり、最も好ましくは約45秒未満であり;および
好ましい態様において、前記発泡剤は不燃性であり、共発泡剤は可燃性であってもよいと認められる。
Claims (22)
- 空洞を発泡性ポリウレタンまたはポリイソシアヌレート発泡体系で充填する方法であって、前記空洞の内壁を湾曲させたり、発泡前に前記空間の底部の亀裂から滲出することのない方法であり、以下の工程を含む、方法:
前記空洞に二成分のポリウレタンまたはポリイソシアヌレート発泡体を加える工程であって、前記発泡体が、有効量の少なくとも1つの発泡剤(その混和性混合物および共沸混合物を含む)、前記発泡剤が以下の式(I)を含む:
[CVa]m - A - [CXb]n - B - [CYc]o - D - [CZd]p
式中、
Cは、炭素原子であり;
V、X、YおよびZは、独立して、H、FおよびClよりなる群から選択され;
aおよびdは、独立して、0から3までの範囲の整数値から選択され;
bおよびcは、独立して、0から2までの範囲の整数値から選択され;
o、pおよびnは、1に等しく;
mは、0から1までの範囲の整数値から選択され;
A、BおよびDは、隣接する炭素原子が存在する場合、そのような炭素原子の利用可能な結合部位を満たすに充分な共有結合であり;
前記少なくとも1つの発泡剤は、沸点が約5〜50℃の間であり、オゾン層破壊係数が0.05以下であり;
前記発泡系は、反応プロフィールのゲルおよび粘着時間が約90秒未満である。 - 請求項1の方法であって、前記共有結合A、BおよびDが、独立して、一重、二重および三重共有結合よりなる群から選択される、方法。
- 請求項1の方法であって、式(I)が、HFC-245fa、HFC-365mfc、HBA-2、FEA-1100、AFA-L1、AFA-L2、それらの混和性混合物および共沸混合物よりなる群から選択され、さらに式(I)が前記発泡剤の主要量である、方法。
- 請求項3の方法であって、前記発泡剤の沸点が約10〜40℃の間である、方法。
- 請求項4の方法であって、前記反応プロフィールのゲルおよび粘着時間が約60秒未満である、方法。
- 請求項5の方法であって、前記反応プロフィールのゲルおよび粘着時間が約45秒未満である、方法。
- 請求項6の方法であって、前記ポリオール成分が、ハロゲン化芳香族ポリオールを含む、方法。
- 請求項7の方法であって、前記ポリオール成分が、さらに、少なくとも4つの官能基を有するスクロースポリエーテルポリオールを含む、方法。
- 請求項8の方法であって、前記ポリオール成分が、さらに、少なくとも3つの異なる触媒を含む、方法。
- 請求項9の方法であって、前記発泡剤の蒸気圧が、75°F(24℃)で約5 psi(34.5 kPa)〜30 psi(206.9 kPa)である、方法。
- 空洞を発泡性ポリウレタンまたはポリイソシアヌレート発泡体系で充填する方法であって、前記空洞の内壁を湾曲させたり、発泡前に前記空間の底部の亀裂から滲出することのない方法であり、以下の工程を含む、方法:
前記空洞に二成分のポリウレタンまたはポリイソシアヌレート発泡体を加える工程であって、前記発泡体が、有効量の少なくとも1つの発泡剤(その混和性混合物および共沸混合物を含む)、前記発泡剤が以下の式(II)を含む:
[CUe]q - E - [CWf]r - F - [CVa]m - A - [CXb]n - B - [CYc]o - D - [CZd]p
式中、
Cは、炭素原子であり;
U、W、V、X、YおよびZは、独立して、H、FおよびClよりなる群から選択され;
dおよびeは、独立して、0から3までの範囲の整数値から選択され;
a、b、cおよびfは、独立して、0から2までの範囲の整数値から選択され;
o、pおよびnは、1に等しく;
m、qおよびrは、独立して、0から1までの範囲の整数値から選択され;
A、B、D、EおよびFは、隣接する炭素原子が存在する場合、そのような炭素原子の利用可能な結合部位を満たすに充分な共有結合であり;
前記発泡剤は、沸点が約5〜50℃の間であり、オゾン層破壊係数が0.05以下であり;
前記発泡系は、反応プロフィールのゲルおよび粘着時間が約90秒未満であり;
前記発泡剤は、不燃性である。 - 請求項11の方法であって、前記共有結合A、B、D、EおよびFが、独立して、一重、二重および三重共有結合よりなる群から選択される、方法。
- 請求項11の方法であって、式(II)が、HFC-245fa、HBA-2、FEA-1100、AFA-L1、AFA-L2、それらの混和性混合物および共沸混合物よりなる群から選択され、さらに式(II)が前記発泡剤の主要量である、方法。
- 請求項13の方法であって、前記発泡剤の沸点が約10〜40℃の間である、方法。
- 請求項14の方法であって、前記反応プロフィールのゲルおよび粘着時間が約60秒未満である、方法。
- 請求項15の方法であって、前記反応プロフィールのゲルおよび粘着時間が約45秒未満である、方法。
- 請求項16の方法であって、前記ポリオール成分が、ハロゲン化芳香族ポリオールを含む、方法。
- 請求項17の方法であって、前記ポリオール成分が、さらに、少なくとも4つの官能基を有するスクロースポリエーテルポリオールを含む、方法。
- 請求項18の方法であって、前記ポリオール成分が、さらに、少なくとも3つの異なる触媒を含む、方法。
- 請求項19の方法であって、前記発泡剤の蒸気圧が、75°F(24℃)で約5 psi(34.5 kPa)〜30 psi(206.9 kPa)である、方法。
- 発泡性の二成分のポリウレタンまたはポリイソシアヌレート発泡体系であって:
有効量の少なくとも1つの発泡剤(それらの混和性混合物および共沸混合物を含む)であって、前記発泡剤が以下の式(II)を含み:
[CUe]q - E - [CWf]r - F - [CVa]m - A - [CXb]n - B - [CYc]o - D - [CZd]p
式中、
Cは、炭素原子であり;
U、W、V、X、YおよびZは、独立して、H、FおよびClよりなる群から選択され;
dおよびeは、独立して、0から3までの範囲の整数値から選択され;
a、b、cおよびfは、独立して、0から2までの範囲の整数値から選択され;
o、pおよびnは、1に等しく;
m、qおよびrは、独立して、0から1までの範囲の整数値から選択され;
A、B、D、EおよびFは、隣接する炭素原子が存在する場合、そのような炭素原子の利用可能な結合部位を満たすに充分な共有結合であり;
前記発泡剤は、沸点が約5〜50℃の間であり、オゾン層破壊係数が0.05以下であり;
前記発泡剤は、不燃性である、発泡剤;
イソシアネート;
ハロゲン化芳香族ポリオール;
少なくとも4つの官能基を有するスクロースポリエーテルポリオール;および
少なくとも3つの異なる触媒
を含む、発泡体系。 - 請求項21の発泡体系であって、前記少なくとも3つの異なる触媒が、2つのアミン系触媒および1つのスズ系触媒を含む、発泡体系。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US57227710P | 2010-11-17 | 2010-11-17 | |
US61/572,277 | 2010-11-17 | ||
US201161535162P | 2011-09-15 | 2011-09-15 | |
US61/535,162 | 2011-09-15 | ||
PCT/US2011/061153 WO2012068351A2 (en) | 2010-11-17 | 2011-11-17 | Method for filling wall cavities with expanding foam insulation |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014504308A true JP2014504308A (ja) | 2014-02-20 |
JP5731008B2 JP5731008B2 (ja) | 2015-06-10 |
Family
ID=46047998
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013540005A Active JP5731008B2 (ja) | 2010-11-17 | 2011-11-17 | 膨張発泡断熱材による壁空洞の充填方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US8680168B2 (ja) |
JP (1) | JP5731008B2 (ja) |
CA (1) | CA2817556C (ja) |
GB (1) | GB2498694B (ja) |
WO (1) | WO2012068351A2 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016516106A (ja) * | 2013-03-06 | 2016-06-02 | ハネウェル・インターナショナル・インコーポレーテッド | 1,1,1,4,4,4−ヘキサフルオロ−2−ブテンを含む保存安定性発泡性組成物 |
JP7509950B2 (ja) | 2016-12-20 | 2024-07-02 | 日清紡ケミカル株式会社 | 2液型プレミックス組成物、及び裏込め注入用硬質ポリイソシアヌレートフォーム |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX350555B (es) * | 2011-12-09 | 2017-09-11 | Honeywell Int Inc | Espumas y articulos hechos a partir de espumas que contienen agentes de soplado hcfo o hfo. |
EP2692501A1 (de) * | 2012-07-31 | 2014-02-05 | Bayer MaterialScience AG | Verfahren zur Vakuum-unterstützten Herstellung eines PUR/PIR-Schaumkörpers |
US9481790B2 (en) | 2012-10-08 | 2016-11-01 | Icp Adhesives And Sealants, Inc. | Marine foam |
US9062168B2 (en) * | 2012-10-08 | 2015-06-23 | Fomo Products, Inc. | Method for filling concrete block cavities with expanding foam insulation |
US9593222B2 (en) * | 2013-05-14 | 2017-03-14 | Icp Adhesives And Sealants, Inc. | Method and composition for filling elongated channels with expanding foam insulation |
RU2016114439A (ru) | 2013-09-19 | 2017-10-24 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Осуществляемый с помощью вакуума способ изготовления закрытопористых жестких пенополиуретанов с использованием смешанных порообразователей |
EP3110546B1 (en) | 2014-02-26 | 2022-03-30 | Evonik Operations GmbH | Method for making a polyisocyanurate/polyurethane foam |
MX2017003329A (es) * | 2014-09-19 | 2017-06-21 | Honeywell Int Inc | Espumas termoendurecibles, flexibles, de celdas abiertas, y agentes de soplado, y metodos para elaborarlos. |
WO2016115021A1 (en) * | 2015-01-12 | 2016-07-21 | Fomo Products, Inc. | Process for extending the shelf life of gaseous olefinic propellants in polyurethane foams |
US10669727B2 (en) | 2015-09-16 | 2020-06-02 | Owens Corning Intellectual Capital, Llc | Loosefill insulation blowing machine |
US20170080614A1 (en) * | 2015-09-23 | 2017-03-23 | Douglas Lamm | System and method for minimally invasive injection foam |
PL415002A1 (pl) * | 2015-12-01 | 2017-06-05 | Selena Labs Spółka Z Ograniczoną Odpowiedzialnością | Pianka montażowa oraz jej zastosowanie jako kleju, szczeliwa, do wytwarzania powłok albo do wypełniania wewnątrz pustych struktur |
DE102016108538A1 (de) * | 2016-05-09 | 2017-11-09 | Tremco Illbruck Produktion Gmbh | Brandschutzband |
WO2021076435A1 (en) | 2019-10-15 | 2021-04-22 | Icp Construction, Inc. | Sprayable marine foam |
US11767394B2 (en) * | 2021-12-09 | 2023-09-26 | Covestro Llc | HCFO-containing polyurethane foam-forming compositions, related foams and methods for their production |
US11767407B1 (en) * | 2022-04-21 | 2023-09-26 | Covestro Llc | HCFO-containing polyurethane foam-forming compositions, related foams and methods for their production |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0782405A (ja) * | 1993-09-16 | 1995-03-28 | Matsushita Electric Ind Co Ltd | 断熱発泡体 |
JP2000507636A (ja) * | 1996-04-10 | 2000-06-20 | アライドシグナル・インコーポレーテッド | 1,1,1,3,3―ペンタフルオロプロパンと炭化水素との共沸混合物様組成物 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US30099A (en) * | 1860-09-18 | Grain-cleaning- machine | ||
US82478A (en) * | 1868-09-29 | Improved surgical splffit | ||
US69175A (en) * | 1867-09-24 | Improvement in land-eollees | ||
US4425446A (en) | 1982-06-23 | 1984-01-10 | Sealed Air Corporation | Urea-modified isocyanurate foam, composition and method |
US4430840A (en) | 1982-06-23 | 1984-02-14 | Sealed Air Corporation | Foam, composition and method useful for retrofit insulation |
US4417998A (en) | 1982-11-23 | 1983-11-29 | Patrick James Crehan | Polyurethane foams and processes for preparation |
US5640451A (en) * | 1996-04-10 | 1997-06-17 | Advanced Micro Devices Inc. | Power cross detection using loop current and voltage |
AU764900B2 (en) | 2000-11-28 | 2003-09-04 | Evonik Goldschmidt Gmbh | Use of mixtures of organofunctionally modified polysiloxanes with branched alcohols in the production of flexible polyurethane foams |
US20060069175A1 (en) * | 2003-07-15 | 2006-03-30 | E. I. Du Pont De Nemours And Company | Aromatic polyester polyols |
JP4040669B2 (ja) * | 2005-02-24 | 2008-01-30 | 横浜ゴム株式会社 | 発泡体用組成物および発泡体 |
US7717357B2 (en) | 2006-01-09 | 2010-05-18 | Fomo Products, Inc. | Method for rapid insulation of expanses |
FR2899234B1 (fr) | 2006-03-31 | 2017-02-17 | Arkema | Composition d'agent d'expansion |
FR2899233B1 (fr) | 2006-03-31 | 2010-03-12 | Arkema | Composition d'agent d'expansion |
US20100113629A1 (en) | 2007-03-29 | 2010-05-06 | Arkema Inc. | hydrofluoropropene blowing agents for thermoplastics |
CN101652412B (zh) | 2007-03-29 | 2012-07-25 | 阿科玛股份有限公司 | 氢氟丙烯与氢氯氟烯烃的发泡剂组合物 |
KR101477485B1 (ko) | 2007-06-27 | 2014-12-30 | 알케마 인코포레이티드 | 안정화된 하이드로클로로플루오로올레핀과 하이드로플루오로올레핀 |
US20100016457A1 (en) | 2008-07-16 | 2010-01-21 | Bowman James M | Hfo-1234ze mixed isomers with hfc-245fa as a blowing agent, aerosol, and solvent |
CA2743842C (en) | 2008-11-19 | 2016-02-09 | Arkema Inc. | Process for the manufacture of hydrofluoroolefins |
WO2011077191A1 (en) | 2009-12-23 | 2011-06-30 | Arkema France | Catalytic gas phase fluorination of 1230xa to 1234yf |
-
2011
- 2011-11-17 CA CA2817556A patent/CA2817556C/en active Active
- 2011-11-17 WO PCT/US2011/061153 patent/WO2012068351A2/en active Application Filing
- 2011-11-17 JP JP2013540005A patent/JP5731008B2/ja active Active
- 2011-11-17 GB GB1309591.4A patent/GB2498694B/en active Active
- 2011-11-17 US US13/298,751 patent/US8680168B2/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0782405A (ja) * | 1993-09-16 | 1995-03-28 | Matsushita Electric Ind Co Ltd | 断熱発泡体 |
JP2000507636A (ja) * | 1996-04-10 | 2000-06-20 | アライドシグナル・インコーポレーテッド | 1,1,1,3,3―ペンタフルオロプロパンと炭化水素との共沸混合物様組成物 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016516106A (ja) * | 2013-03-06 | 2016-06-02 | ハネウェル・インターナショナル・インコーポレーテッド | 1,1,1,4,4,4−ヘキサフルオロ−2−ブテンを含む保存安定性発泡性組成物 |
JP7509950B2 (ja) | 2016-12-20 | 2024-07-02 | 日清紡ケミカル株式会社 | 2液型プレミックス組成物、及び裏込め注入用硬質ポリイソシアヌレートフォーム |
Also Published As
Publication number | Publication date |
---|---|
WO2012068351A2 (en) | 2012-05-24 |
US20120121805A1 (en) | 2012-05-17 |
GB201309591D0 (en) | 2013-07-10 |
CA2817556C (en) | 2014-12-30 |
US8680168B2 (en) | 2014-03-25 |
GB2498694A (en) | 2013-07-24 |
CA2817556A1 (en) | 2012-05-24 |
WO2012068351A8 (en) | 2014-04-17 |
WO2012068351A3 (en) | 2013-11-21 |
JP5731008B2 (ja) | 2015-06-10 |
GB2498694B (en) | 2017-04-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5731008B2 (ja) | 膨張発泡断熱材による壁空洞の充填方法 | |
JP6004939B2 (ja) | ハロゲン化オレフィン発泡剤を含むフォーム及び発泡性組成物 | |
US9701782B2 (en) | Foams and articles made from foams containing 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd) | |
JP2017197768A (ja) | 発泡体、およびhcfoまたはhfo発泡剤を含む発泡体から作られる物品 | |
JP2017141465A (ja) | 1−クロロ−3,3,3−トリフルオロプロペン(1233zd)を含むフォーム、及びフォームから製造される耐炎性物品 | |
CA2829380C (en) | Method for filling concrete block cavities with expanding foam insulation | |
CN102015852A (zh) | 聚合物泡沫用发泡剂 | |
CA2851303C (en) | Method and composition for filling elongated channels with expanding foam insulation | |
EP3360922A1 (en) | Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene | |
US20170158834A1 (en) | Foams and articles made from foams containing hcfo or hfo blowing agents | |
US20240150536A1 (en) | Blowing agents comprising z-1-chloro-2,3,3,3-tetrafluoropentene (hcfo-1224yd(z)) | |
US20220033607A1 (en) | Compositions comprising 1,2-dichloro-1,2-difluoroethylene for use in foam blowing applications | |
JP2000094467A (ja) | 難燃性硬質ウレタンフォームの製造方法および難燃性硬質ウレタンフォームの製造装置 | |
JP2000095890A (ja) | 難燃性発泡剤、難燃性硬質ウレタンフォームおよびそれを用いた冷凍装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140620 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140708 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141007 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150317 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150408 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5731008 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |