JP2013528829A - 金属フレーク含有トナー - Google Patents
金属フレーク含有トナー Download PDFInfo
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- JP2013528829A JP2013528829A JP2013508038A JP2013508038A JP2013528829A JP 2013528829 A JP2013528829 A JP 2013528829A JP 2013508038 A JP2013508038 A JP 2013508038A JP 2013508038 A JP2013508038 A JP 2013508038A JP 2013528829 A JP2013528829 A JP 2013528829A
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Abstract
Description
本発明のさらなる目的は、印刷法、例えば、電子写真法(electrophotography)または電位記録法(electrography)により、受像用支持体へのトナー粒子の融着で、金属色相を効果的に作り出すことができる、封入された金属フレークを含有した多孔質トナー粒子を提供することである。
本発明のまた別の目的は、電子写真法または電位記録法などの方法を用いて回路板を印刷するための、導電性金属フレークが封入された多孔質ポリマー粒子を提供することである。
本発明のさらなる目的は、上記トナー粒子を製造するための、拡張性があり、かつ効果的な方法を提供することである。
本発明のさらなる目的は、電子写真法により、金属色相が改善され、かつ光沢またはきらめき効果のあるトナー画像を製造する方法を提供することである。
本発明のまた別の目的は、このような粒子および方法において、市販の金属フレークを、さらなる表面変性処理が必要とされることなく、直接的に利用することである。
上記した蒸発限定凝集(evaporative limited coalescence)(ELC)法を併用する多段階エマルション法を用いて、本実施例の多孔質トナーを製造した。4重量%カルボキシメチルセルロース水溶液37.5gを、水34.6gおよびOBRON SF121アルミニウムフレーク2.5gとSYNFAC8337 5gの予備混合ペーストとともに用いて第1水性相(W1)を製造した。花王N樹脂の29.6%酢酸エチル溶液141.7g、ワックスに対して20重量%のP2000分散剤を含有するWE−3ワックスの24.4%酢酸エチル分散液16.4g、帯電制御剤FCA2508N 0.75gおよび酢酸エチル88.5gを用いて、油性相を製造した。この油性相にW1相を添加した後、大型孔式解砕用ヘッド(large holed disintegrating head)を備えたシルバーソンL4Rミキサー(Silverson L4R Mixer)により混合した。得られたウォーター・イン・オイル(W1/O)型エマルションの一部(326g)を、pH4シトレート/ホスフェート緩衝液中にNALCO1060 10.4gを含有する水性相(W2)544gに電磁撹拌により穏やかに撹拌した。ブッチ・ロタ・ベーパー RE120(Buchi ROTA VAPOR RE120)を用いて減圧下、30℃で酢酸エチルを蒸発させ、粒子中に離散した細孔および多数の金属フレーク領域を有する多孔質粒子を得た。このような多段階エマルション法により製造された粒子の内部細孔構造は米国特許出願公開2008/0176157号公報、2008/0176164号公報および2010/0021838号公報の図面に示されている。トナー表面のシリカを、1N水酸化カリウムを15分間用いてpH12で除去した。その後、粒子を洗浄および乾燥した。ホリバLA−920を用いて測定したメジアン粒径(median particle size)は56マイクロメーターであった。
花王N樹脂を酢酸エチルに溶解させ、29.6%溶液として、OBRON SF121アルミニウムフレーク2.5gとSYNFAC8337 5gの予備混合ペーストに添加した。これに、ワックスに対して20重量%のP2000分散剤を含有するWE−3ワックスの24.4%酢酸エチル分散液16.4gを添加および混合した後、帯電制御剤FCA2508N 0.75gを添加および混合した。得られたこの油性相を、NALCO1060 10.5gを含有するpH4シトレート/ホスフェート緩衝液534gに分散させた後、電磁撹拌した。ブッチ・ロタ・ベーパー RE120を用いて減圧下、30℃で酢酸エチルを蒸発させ、金属フレークを含有する花王Nの中実粒子を得た。トナー表面のシリカを、水酸化カリウムを用いてpH12.5で15分間撹拌することにより除去した。その後、粒子を洗浄および乾燥した。ホリバLA−920を用いて測定したメジアン粒径は67マイクロメーターであった。
融着時における金属フレークの光反射能を測定するために、まず、常套のステンレススチール被覆ブロック(conventional stainless steel coating block)および10mil間隙のドクターブレードを用いて、過剰量の粒子を118gsmラストログロス支持体(118 gsm Lustrogloss substrate)の表面に散布することにより、多孔質試料(実施例1)および中実試料(実施例2)を調製した。ドクターブレードの使用により、各支持体上での粒子均一層の形成を確保した。試料の製造後、両方の試料を、内部加熱式オフライン融着台(internally-heated offline fuser breadboard)のニップに185Cで通過させた。このような融着台は、スプレー塗布されたフッ素ポリマー被膜を有する内部加熱式上部融着ローラおよびステンレススチール製下部加圧ローラからなるものであった。融着精度(fusing consistency)のために、上部融着ローラは市販のギヤモーターにより駆動させ、スチール製加圧ローラは回転自由であった。このような融着工程の後、両方の試料を反射光光学顕微鏡法により試験した。融着領域内での金属フレークの配向について特別に注意を払った。図1および図2はそれぞれ、比較用中実トナー粒子(実施例2)および本発明の金属フレーク含有多孔質トナー粒子(実施例1)から形成された融着トナー粒子の反射光学画像である。このような反射光学画像から明らかなように、本発明のトナー粒子は、支持体表面に対する金属フレークの整列度が高いために、より大きな反射率を示した。その結果として、このようなトナー粒子で形成される画像の金属的な外観は改善される。
Claims (20)
- 外部粒子表面を有し、ポリマーバインダー相および該相の中に封入された金属フレークを含有するトナー粒子であって、該トナー粒子が該トナー粒子内に形成された離散した細孔をさらに含有し、少なくとも10体積%の内部多孔度を有するトナー粒子。
- ポリマーバインダー相が固体状の組成的に連続した相を含有し、該固体状の組成的に連続した相内で離散した細孔が分散されている請求項1に記載のトナー粒子。
- 金属フレークが主として離散した細孔内に存在している請求項2に記載のトナー粒子。
- 細孔安定化用親水性コロイドをさらに含有する請求項2に記載のトナー粒子。
- 帯電制御剤をさらに含有する請求項1に記載のトナー粒子。
- ワックスおよび帯電制御剤をさらに含有する請求項1に記載のトナー粒子。
- 金属フレークが、相対的に小さな厚み寸法により区別される対向する主表面を有した実質的に二次元の粒子であり、主表面の相当円の直径が本来的に2ミクロン〜20ミクロンの範囲内であり、アスペクト比が少なくとも2である請求項1に記載のトナー粒子。
- 金属フレークのアスペクト比が少なくとも5である請求項7に記載のトナー粒子。
- 金属フレークがポリマーバインダーの重量に対して3〜30重量%の濃度で存在している請求項1に記載のトナー粒子。
- 金属フレークが銅またはアルミニウムを含有する請求項1に記載のトナー粒子。
- 粒子の内部多孔度が20〜90%である請求項1に記載のトナー粒子。
- 以下の工程を含む請求項1に記載のトナー粒子の製造方法:
分散された金属フレークを含有する第1水性相を供給する工程;
ポリマーバインダーを含有する有機溶液に該第1水性相を分散させて、第1エマルションを形成する工程;
第2水性相に該第1エマルションを分散させて、第2エマルションを形成する工程;
該第2エマルションを粒状安定化剤の存在下、剪断して、第2水性相中で第1エマルションの液滴を形成する工程;および
該液滴から有機溶液を蒸発させて、金属フレークが封入された多孔質トナー粒子を形成する工程。 - 第1水性相がさらに細孔安定化用ヒドロコロイドを含有する請求項12に記載の方法。
- 以下の工程を含むトナー画像の形成方法:
金属フレークが封入された多孔質トナー粒子からなる請求項1に記載のトナー粒子を含むトナー画像を支持体上に形成する工程;および
熱の適用によりトナー粒子を支持体に融着させて、トナー粒子を支持体に定着させる工程において、トナー粒子内の細孔が金属フレークに空間を提供し、該金属フレークが、融着により受像用支持体表面と相対的により平行になるように、トナー粒子バインダー相内で再配向する工程。 - トナー粒子を支持体に定着させて、金属色相を示す融着トナー画像を提供する請求項14に記載の方法。
- トナー粒子を支持体に定着させて、相対的に導電性のあるパターンの形態で融着トナー画像を提供する請求項14に記載の方法。
- トナー画像を接触式融着法により支持体に定着させる請求項14に記載の方法。
- 加熱式融着ローラを用いてトナー画像を支持体に定着させる請求項17に記載の方法。
- トナー画像をオーブン融着法、熱気融着法、輻射融着法、フラッシュ融着法、溶剤融着法、またはマイクロ波融着法により支持体に定着させる請求項14に記載の方法。
- トナー画像を以下の工程により支持体上に形成する請求項14に記載の方法:
静電潜像を一次画像形成体上に形成する工程;
該静電潜像を、封入された金属フレークを含有する請求項1に記載のトナー粒子と近接近させることにより現像し、トナー粒子を含む現像画像を形成する工程;
該現像画像を受像用支持体に静電的に転写させる工程;および
熱の適用によりトナー粒子を支持体に融着させて、現像画像を支持体に定着させる工程。
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US12/766,939 US8614039B2 (en) | 2010-04-26 | 2010-04-26 | Toner containing metallic flakes and method of forming metallic image |
US12/766,939 | 2010-04-26 | ||
PCT/US2011/033155 WO2011136997A1 (en) | 2010-04-26 | 2011-04-20 | Toner containing metallic flakes |
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EP (1) | EP2564274B1 (ja) |
JP (1) | JP5717843B2 (ja) |
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US20180094112A1 (en) | 2016-10-03 | 2018-04-05 | Eastman Kodak Company | Method and system for making light-blocking articles |
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US10920032B2 (en) | 2018-11-29 | 2021-02-16 | Eastman Kodak Company | Light-blocking articles with spacer functional composition |
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US20230129906A1 (en) * | 2021-10-21 | 2023-04-27 | Viavi Solutions Inc. | Electrostatic printing method |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62100769A (ja) * | 1985-10-29 | 1987-05-11 | Mita Ind Co Ltd | 電子写真用銀色トナ− |
JPS62100770A (ja) * | 1985-10-29 | 1987-05-11 | Mita Ind Co Ltd | 電子写真用金色トナ− |
JP2003207941A (ja) * | 2002-01-10 | 2003-07-25 | Casio Electronics Co Ltd | 静電潜像現像用金色トナー |
JP2005134738A (ja) * | 2003-10-31 | 2005-05-26 | Toyo Aluminium Kk | 電子写真用トナー |
JP2007519982A (ja) * | 2004-01-30 | 2007-07-19 | イーストマン コダック カンパニー | 金属色相トナーおよびその製造 |
WO2008088697A1 (en) * | 2007-01-18 | 2008-07-24 | Eastman Kodak Company | Toner manufacturing method |
WO2008088700A1 (en) * | 2007-01-18 | 2008-07-24 | Eastman Kodak Company | Toner porous particles containing hydrocolloids |
JP2009501349A (ja) * | 2005-07-13 | 2009-01-15 | イーストマン コダック カンパニー | トナーを調製するための方法およびそのトナー |
WO2010011297A1 (en) * | 2008-07-24 | 2010-01-28 | Eastman Kodak Company | Polymer particles with additives encapsulated in microvoids |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2934530A (en) | 1955-03-28 | 1960-04-26 | Dow Chemical Co | Suspension polymerization |
US2932629A (en) | 1955-03-28 | 1960-04-12 | Dow Chemical Co | Quiescent suspension polymerization |
US3615972A (en) | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
US3893935A (en) | 1972-05-30 | 1975-07-08 | Eastman Kodak Co | Electrographic toner and developer composition |
CA995953A (en) | 1972-05-30 | 1976-08-31 | Eastman Kodak Company | Electrographic toner and developer composition |
USRE31072E (en) | 1973-07-18 | 1982-11-02 | Eastman Kodak Company | Electrographic developing composition and process |
CA1060696A (en) | 1975-07-09 | 1979-08-21 | Eastman Kodak Company | Electrographic toner and developer composition |
US4323634A (en) | 1975-07-09 | 1982-04-06 | Eastman Kodak Company | Electrographic toner and developer composition containing quaternary ammonium salt charge control agent |
US4079014A (en) | 1976-07-21 | 1978-03-14 | Eastman Kodak Company | Electrographic toner and developer composition containing a 4-aza-1-azoniabicyclo(2.2.2) octane salt as a charge control agent |
US4160644A (en) | 1977-06-13 | 1979-07-10 | Streck Laboratories, Inc. | Platelet reference control and method of preparation |
CA1124916A (en) | 1978-07-07 | 1982-06-01 | Saburo Wakimoto | Fine spherical polymer particles containing inorganic pigment and/or coloring agent and process for the preparation thereof |
US4229513A (en) | 1979-05-29 | 1980-10-21 | Eastman Kodak Company | Liquid electrographic developers containing polymeric quaternary salts |
US4394430A (en) | 1981-04-14 | 1983-07-19 | Eastman Kodak Company | Electrophotographic dry toner and developer compositions |
US4414152A (en) | 1981-05-18 | 1983-11-08 | Eastman Kodak Company | Bis aryl-azo derivatives of 2,3-naphthalenediol |
US4430408A (en) | 1982-06-25 | 1984-02-07 | Minnesota Mining And Manufacturing Company | Developing powder composition containing a fluorine-modified alkyl siloxane |
US4416965A (en) | 1982-07-14 | 1983-11-22 | Eastman Kodak Company | Electrostatographic developers comprising toners containing a polyester having p-hydroxybenzoic acid recurring units |
EP0180655B1 (en) | 1984-11-05 | 1988-04-06 | Hodogaya Chemical Co., Ltd. | Electrophotographic toner |
JPS6253944A (ja) | 1985-05-28 | 1987-03-09 | Hodogaya Chem Co Ltd | 電子写真用トナー |
US4683188A (en) | 1985-05-28 | 1987-07-28 | Hodogaya Chemical Co., Ltd. | Electrophotographic toner containing metal complex charge control agent |
US4814250A (en) | 1987-03-17 | 1989-03-21 | Eastman Kodak Company | Electrophotographic toner and developer compositions containing dioctylsulfosuccinate and sodium benzoate charge control agents |
US4834920A (en) | 1987-12-17 | 1989-05-30 | Eastman Kodak Company | New quaternary ammonium salts |
US4840864A (en) | 1987-12-17 | 1989-06-20 | Eastman Kodak Company | New electrostatographic toners and developers containing new charge-control agents |
US4965131A (en) | 1988-03-21 | 1990-10-23 | Eastman Kodak Company | Colloidally stabilized suspension process |
US4833060A (en) | 1988-03-21 | 1989-05-23 | Eastman Kodak Company | Polymeric powders having a predetermined and controlled size and size distribution |
JP2704756B2 (ja) | 1989-04-25 | 1998-01-26 | キヤノン株式会社 | カラートナー |
US5180650A (en) | 1992-01-31 | 1993-01-19 | Xerox Corporation | Toner compositions with conductive colored magnetic particles |
US6342273B1 (en) | 1994-11-16 | 2002-01-29 | Dsm N.V. | Process for coating a substrate with a powder paint composition |
IL113302A0 (en) | 1995-04-07 | 1995-07-31 | Indigo Nv | Printing on transparent film |
US5714295A (en) | 1997-03-14 | 1998-02-03 | Eastman Kodak Company | Electrostatographic toners and developers containing (1,2-benzisothiazol-3(2H)-ylidene 1,1-dioxide)acetate charge-control agents |
US20030151028A1 (en) * | 2002-02-14 | 2003-08-14 | Lawrence Daniel P. | Conductive flexographic and gravure ink |
DE102007010986A1 (de) * | 2007-03-05 | 2008-09-11 | Merck Patent Gmbh | Übergangsmetallhaltige Effektpigmente |
US8039183B2 (en) * | 2007-10-25 | 2011-10-18 | Xerox Corporation | Resin-coated pearlescent or metallic pigment for special effect images |
US8758969B2 (en) | 2007-12-22 | 2014-06-24 | Eastman Kodak Company | Method for producing an antenna structure for an RFID device, and dry toner for use in producing such antenna structure |
US20110262654A1 (en) | 2010-04-26 | 2011-10-27 | Yates Mathew Z | Process for preparing polymer particles containing metallic flakes |
-
2010
- 2010-04-26 US US12/766,939 patent/US8614039B2/en active Active
-
2011
- 2011-04-20 BR BR112012024510-4A patent/BR112012024510A2/pt not_active Application Discontinuation
- 2011-04-20 EP EP11717135.5A patent/EP2564274B1/en active Active
- 2011-04-20 CN CN2011800207618A patent/CN102859446A/zh active Pending
- 2011-04-20 WO PCT/US2011/033155 patent/WO2011136997A1/en active Application Filing
- 2011-04-20 JP JP2013508038A patent/JP5717843B2/ja active Active
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62100769A (ja) * | 1985-10-29 | 1987-05-11 | Mita Ind Co Ltd | 電子写真用銀色トナ− |
JPS62100770A (ja) * | 1985-10-29 | 1987-05-11 | Mita Ind Co Ltd | 電子写真用金色トナ− |
JP2003207941A (ja) * | 2002-01-10 | 2003-07-25 | Casio Electronics Co Ltd | 静電潜像現像用金色トナー |
JP2005134738A (ja) * | 2003-10-31 | 2005-05-26 | Toyo Aluminium Kk | 電子写真用トナー |
JP2007519982A (ja) * | 2004-01-30 | 2007-07-19 | イーストマン コダック カンパニー | 金属色相トナーおよびその製造 |
JP2009501349A (ja) * | 2005-07-13 | 2009-01-15 | イーストマン コダック カンパニー | トナーを調製するための方法およびそのトナー |
WO2008088697A1 (en) * | 2007-01-18 | 2008-07-24 | Eastman Kodak Company | Toner manufacturing method |
WO2008088700A1 (en) * | 2007-01-18 | 2008-07-24 | Eastman Kodak Company | Toner porous particles containing hydrocolloids |
JP2010517074A (ja) * | 2007-01-18 | 2010-05-20 | イーストマン コダック カンパニー | 親水コロイドを含有するトナー多孔質粒子 |
JP2010517073A (ja) * | 2007-01-18 | 2010-05-20 | イーストマン コダック カンパニー | トナー製造方法 |
WO2010011297A1 (en) * | 2008-07-24 | 2010-01-28 | Eastman Kodak Company | Polymer particles with additives encapsulated in microvoids |
JP2011529203A (ja) * | 2008-07-24 | 2011-12-01 | イーストマン コダック カンパニー | 微小空洞中に封入された添加剤を具有するポリマー粒子 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013117697A (ja) * | 2011-12-05 | 2013-06-13 | Fuji Xerox Co Ltd | 静電荷像現像用トナー、静電荷像現像剤、トナーカートリッジ、プロセスカートリッジ、及び、画像形成装置 |
JP2013134314A (ja) * | 2011-12-26 | 2013-07-08 | Fuji Xerox Co Ltd | 光輝性トナー、現像剤、トナーカートリッジ、プロセスカートリッジ、画像形成装置、及び、光輝性トナーの製造方法 |
JP2013156343A (ja) * | 2012-01-27 | 2013-08-15 | Fuji Xerox Co Ltd | 静電荷像現像用トナー、現像剤、トナーカートリッジ、プロセスカートリッジ、及び、画像形成装置 |
JP2015184595A (ja) * | 2014-03-25 | 2015-10-22 | 富士ゼロックス株式会社 | 光輝性トナー、静電荷像現像剤、現像剤カートリッジ、プロセスカートリッジ、画像形成装置、及び、画像形成方法 |
JP2017537990A (ja) * | 2014-10-09 | 2017-12-21 | コロプラスト アクティーゼルスカブ | ポリマーと切替開始剤とを含んでなる組成物 |
US11045576B2 (en) | 2014-10-09 | 2021-06-29 | Coloplast A/S | Composition comprising a polymer and a switch initiator |
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BR112012024510A2 (pt) | 2020-07-28 |
JP5717843B2 (ja) | 2015-05-13 |
CN102859446A (zh) | 2013-01-02 |
US20110262858A1 (en) | 2011-10-27 |
US8614039B2 (en) | 2013-12-24 |
EP2564274B1 (en) | 2017-05-17 |
EP2564274A1 (en) | 2013-03-06 |
WO2011136997A1 (en) | 2011-11-03 |
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