JP2013160863A - 偏光子保護フィルム、偏光板及び液晶表示素子 - Google Patents
偏光子保護フィルム、偏光板及び液晶表示素子 Download PDFInfo
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- JP2013160863A JP2013160863A JP2012021357A JP2012021357A JP2013160863A JP 2013160863 A JP2013160863 A JP 2013160863A JP 2012021357 A JP2012021357 A JP 2012021357A JP 2012021357 A JP2012021357 A JP 2012021357A JP 2013160863 A JP2013160863 A JP 2013160863A
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- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
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Abstract
【解決手段】本発明の偏光子保護フィルムは、液晶表示パネルの偏光子に接着される偏光子保護フィルムであって、アクリル系樹脂を主成分とする基材層と、この基材層の一方の面側に積層され、透湿性をコントロールするための第一コントロール層と、第一コントロール層の一方の面側に積層される易接着層と、基材層の他方の面側に積層され、透湿性をコントロールするための第二コントロール層とを備え、第一コントロール層と第二コントロール層とが主成分として同一の樹脂を含有することを特徴としている。
【選択図】図1
Description
液晶表示パネルの偏光子に接着される偏光子保護フィルムであって、
アクリル系樹脂を主成分とする基材層と、
この基材層の一方の面側に積層され、透湿性をコントロールするための第一コントロール層と、
第一コントロール層の一方の面側に積層される易接着層と、
基材層の他方の面側に積層され、透湿性をコントロールするための第二コントロール層と
を備え、
第一コントロール層と第二コントロール層とが主成分として同一の樹脂を含有することを特徴とする偏光子保護フィルムである。
当該偏光子保護フィルムと、
この偏光子保護フィルムの易接着層に水溶性接着剤によって接着される偏光子と
を備える偏光板である。
液晶セルと、
この液晶セルの一方の面側に積層される当該偏光板と
を備える液晶表示素子である。
Δn=n1−n2
(式中、n1は伸張応力と平行な方向の屈折率であり、n2は伸張方向と垂直な方向の屈折率である。)
図1の偏光子保護フィルム1は、アクリル系樹脂を主成分とする基材層2と、透湿性をコントロールするための第一コントロール層3と、易接着層4と、透湿性をコントロールするための第二コントロール層5とを有している。偏光子保護フィルム1は、第二コントロール層5、基材層2、第一コントロール層3及び易接着層4がこの順で配設された積層体として形成されている。偏光子保護フィルム1は、液晶表示素子の偏光子に易接着層4側から接着され、この偏光子の耐衝撃性及び取扱性を向上させるための保護フィルムである。
基材層2の主成分としては、液晶表示素子の偏光子保護フィルムとして要求される高い透明性を保持し、かつ一定の透湿性を有する合成樹脂であるアクリル系樹脂が用いられる。基材層2は、透明性及び所望の強度を損なわない限り他の任意成分を含んでよいが、アクリル系樹脂を好ましくは90質量%以上含み、さらに好ましくは98質量%以上含む。ここでの任意成分の例として、紫外線吸収剤、安定剤、滑剤、加工助剤、可塑剤、耐衝撃助剤、位相差低減剤、艶消し剤、抗菌剤、防かび等が挙げられる。
第一コントロール層3は、基材層2の一方の面側に積層される。第一コントロール層3の主成分としては、親水性樹脂が好適に用いられる。この親水性樹脂としては、基材層2及び易接着層4との化学的親和性を有する樹脂である限り特に限定されないが、側鎖が親水性を有する基によって変性されているものが好ましい。親水性樹脂の親水化変性の方法としては、予め親水性の官能基を有するモノマーを(共)重合させてもよいし、あるいは、主鎖となるモノマーを(共)重合させた後、親水性基を有するモノマーをグラフト重合させて側鎖を形成してもよい。また、この親水性樹脂は、ポリエステル系樹脂、アクリル系樹脂、ウレタン系樹脂及びエポキシ系樹脂からなる群から選択されるものから形成されていることが好ましい。これらの樹脂は、単独で重合あるいは2種以上を共重合させたものであってもよい。親水性樹脂としては、例えば、重量平均分子量が300以上30000以下のものを用いることができる。
易接着層4は、第一コントロール層3の一方の面側に積層される。易接着層4の主成分としては、第一コントロール層3の主成分として含まれる親水性樹脂及び偏光子を構成するポリビニルアルコールとの化学的親和性を有する樹脂である限りは特に限定されるものではないが、セルロースエステル系樹脂が好適に用いられる。易接着層4が主成分としてセルロースエステル系樹脂を有することによって、親水性樹脂であるポリビニルアルコールからなる偏光子と易接着層4との接着性が飛躍的に改善される。すなわち、セルロースエステル系樹脂を主成分として含む易接着層4をアルカリでケン化することによって親水性基である水酸基が生じ、これによって親水性樹脂であるポリビニルアルコールとの接着性が効果的に向上する。従って、当該偏光子保護フィルム1は、水溶性接着剤を用いて、易接着層4と偏光子とを容易かつ確実に接着することができる。
第二コントロール層5は、基材層2の他方の面側に積層される。第二コントロール層5は、第一コントロール層3と主成分として同一の樹脂を含有している。第二コントロール層5の主成分としては、第一コントロール層3と同一の樹脂を含有している限り特に限定されないが、第一コントロール層3の主成分と同一の形成材料であることが好ましい。第二コントロール層5の主成分の形成材料が第一コントロール層3の主成分の形成材料と同一である場合、第二コントロール層5と第一コントロール層3の透湿度をさらに近づけることができ、偏光子保護フィルム1全体の透湿性をより確実にコントロールすることができる。また、第二コントロール層5の主成分の形成材料が第一コントロール層3の主成分の形成材料と同一である場合、当該偏光子保護フィルム1の製造容易性を向上させることができる。
偏光子保護フィルム1の透湿度としては、1g/m2・24h以上250g/m2・24h以下であることが好ましい。偏光子保護フィルム1の透湿度の上限値は、150g/m2・24h以下がより好ましく、100g/m2・24hがさらに好ましい。一方、偏光子保護フィルム1の透湿度の下限値は、10g/m2・24hがより好ましく、20g/m2・24hがさらに好ましい。偏光子保護フィルム1の透湿度が上記上限値を超える場合、外部から浸透する水分の割合が高くなり基材層2等の寸法変化を生じるおそれが高くなる。逆に、偏光子保護フィルム1の透湿度が上記下限値未満である場合、易接着層4と偏光子とを水溶性接着剤によって接着させた場合にこの水溶性接着剤に含有される水分を蒸発させるのに長時間を要するおそれがある。
図2の偏光板11は、ポリビニルアルコールからなる偏光子12の一方の面に、図1の偏光子保護フィルム1を備え、偏光子12の他方の面に、従来から用いられているセルロースエステルからなる偏光子保護フィルム13を備えた構造を有している。偏光子12と偏光子護フィルム1との間、及び偏光子12と偏光子保護フィルム13との間は、接着剤(図示せず)によって接合されている。
図4の液晶表示素子31は、液晶層34が透明媒体層33(例えばガラス)で挟持された液晶セル32の両面に対して、接着剤層35を介し、本発明による図2の偏光板11を貼り合わせることによって構成されている。本発明による偏光子保護フィルム1(基材層2、第一コントロール層3、易接着層4及び第二コントロール層5)は、偏光子12の外面側(液晶セル32の配設方向の反対側)に配置され、従来から用いられているセルロースエステルからなる偏光子保護フィルム13が偏光子12の内面側(液晶セル32の配設方向側)に配置される。液晶セル32の液晶層34及び透明媒体層33並びに接着剤層35を構成する材料は、特に限定されず公知のものを用いることができる。
なお、本発明の偏光子保護フィルム、偏光板及び液晶表示素子は、上記態様の他、種々の変更、改良を施した態様で実施することができる。例えば、偏光子保護フィルムの第二コントロール層を、第一コントロール層よりも実質的に厚くなるように形成してもよい。このように、当該偏光子保護フィルムは、第二コントロール層を第一コントロール層よりも実質的に厚くすることによって、易接着層側を内側として丸まろうとする力に対するカール防止機能を付与することができ、当該偏光子保護フィルム全体としてのカールの発生を防止することがでる。その結果、当該偏光子保護フィルムは、寸法安定性を向上することができる。
2 基材層
3 第一コントロール層
4 易接着層
5 第二コントロール層
11 偏光板
12 偏光子
13 セルロースエステルからなる偏光子保護フィルム
21 偏光板を製造するための装置
22 ニップ
23 ニップ
24 接着剤供給手段
25 ニップ
31 液晶表示素子
32 液晶セル
33 透明媒体層
34 液晶層
35 接着剤層
41 液晶表示素子
42 液晶セル
43 透明媒体層
44 液晶層
45 偏光板
46 偏光子保護フィルム
47 偏光子
48 接着剤層
Claims (12)
- 液晶表示パネルの偏光子に接着される偏光子保護フィルムであって、
アクリル系樹脂を主成分とする基材層と、
この基材層の一方の面側に積層され、透湿性をコントロールするための第一コントロール層と、
第一コントロール層の一方の面側に積層される易接着層と、
基材層の他方の面側に積層され、透湿性をコントロールするための第二コントロール層と
を備え、
第一コントロール層と第二コントロール層とが主成分として同一の樹脂を含有することを特徴とする偏光子保護フィルム。 - 上記第一コントロール層が、第二コントロール層と実質的に同一厚さである請求項1に記載の偏光子保護フィルム。
- 上記第二コントロール層が、第一コントロール層よりも実質的に厚い請求項1に記載の偏光子保護フィルム。
- 上記アクリル系樹脂の光弾性係数が、−5×10−12/Pa以上5×10−12/Pa以下である請求項1、請求項2又は請求項3に記載の偏光子保護フィルム。
- 上記易接着層が、主成分としてセルロースエステル系樹脂を含む請求項1から請求項4のいずれか1項に記載の偏光子保護フィルム。
- 上記セルロースエステル系樹脂の数平均分子量(Mn)が、40000以上100000以下である請求項5に記載の偏光子保護フィルム。
- 上記第一コントロール層及び第二コントロール層が、主成分としてアクリル変性ポリエステル系樹脂を含む請求項1から請求項6のいずれか1項に記載の偏光子保護フィルム。
- 上記第一コントロール層及び第二コントロール層が、さらにウレタン系樹脂を含有する請求項7に記載の偏光子保護フィルム。
- 透湿度が1g/m2・24h以上250g/m2・24h以下である請求項1から請求項8のいずれか1項に記載の偏光子保護フィルム。
- 上記基材層のリタデーション値(Re)が、−15nm以上15nm以下である請求項1から請求項9のいずれか1項に記載の偏光子保護フィルム。
- 請求項1から10のいずれか1項に記載の偏光子保護フィルムと、
この偏光子保護フィルムの易接着層に水溶性接着剤によって接着される偏光子と
を備える偏光板。 - 液晶セルと、
この液晶セルの一方の面側に積層される請求項11に記載の偏光板と
を備える液晶表示素子。
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JP2012021357A JP2013160863A (ja) | 2012-02-02 | 2012-02-02 | 偏光子保護フィルム、偏光板及び液晶表示素子 |
KR1020130011846A KR101461147B1 (ko) | 2012-02-02 | 2013-02-01 | 편광자 보호 필름, 편광판 및 액정 표시 소자 |
TW102103948A TWI498610B (zh) | 2012-02-02 | 2013-02-01 | A polarizing plate protective film, a polarizing plate and a liquid crystal display element |
CN201310044212.5A CN103246000B (zh) | 2012-02-02 | 2013-02-04 | 偏振片保护膜、偏光板和液晶显示元件 |
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KR (1) | KR101461147B1 (ja) |
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WO2015046010A1 (ja) * | 2013-09-27 | 2015-04-02 | Dic株式会社 | 光学材料用樹脂組成物、光学フィルム及び液晶表示装置 |
JP6500204B2 (ja) * | 2015-04-14 | 2019-04-17 | 株式会社ブイ・テクノロジー | 偏光光照射装置 |
KR101960477B1 (ko) | 2016-09-20 | 2019-03-20 | 주식회사 엘지화학 | 슬립성 및 자외선 차단 기능이 우수한 광학 필름, 및 이를 포함하는 편광판 |
FR3059675B1 (fr) * | 2016-12-02 | 2019-05-10 | Axon Cable | Vernis antifongique pour gaine thermoretractable de harnais bus |
JP7169160B2 (ja) * | 2018-10-26 | 2022-11-10 | 住友化学株式会社 | 液晶層積層体 |
KR102531339B1 (ko) * | 2019-09-03 | 2023-05-10 | 주식회사 엘지화학 | 편광판 적층체 및 이를 포함하는 화상 표시 장치 |
KR102459161B1 (ko) * | 2022-08-05 | 2022-10-27 | (주)재성글로벌 | 수용성 점착층 형성용 조성물을 포함하는 점착 테이프 |
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KR20130089605A (ko) | 2013-08-12 |
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TW201333556A (zh) | 2013-08-16 |
TWI498610B (zh) | 2015-09-01 |
CN103246000B (zh) | 2016-02-17 |
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