JP2013051385A - 光電変換素子の製造方法、固体撮像素子、撮像装置 - Google Patents
光電変換素子の製造方法、固体撮像素子、撮像装置 Download PDFInfo
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- GVIJJXMXTUZIOD-UHFFFAOYSA-N thianthrene Chemical group C1=CC=C2SC3=CC=CC=C3SC2=C1 GVIJJXMXTUZIOD-UHFFFAOYSA-N 0.000 description 1
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- 125000004149 thio group Chemical group *S* 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
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- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 125000001834 xanthenyl group Chemical group C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 description 1
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
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Abstract
【解決手段】絶縁層102上に複数の画素電極104を形成する第一の工程と、複数の画素電極104の上に有機材料を含む受光層107を形成する第二の工程と、受光層107上に対向電極108を形成する第三の工程とを備え、第一の工程は、絶縁層102上に画素電極材料を成膜する工程と、成膜した前記画素電極材料の膜をパターニングする工程と、前記パターニング後の前記基板を270℃以上で加熱する工程とで構成される。
【選択図】図1
Description
Ar2、Ar3が表すアリール基としては、それぞれ独立に、好ましくは炭素数6〜30のアリール基であり、より好ましくは炭素数6〜18のアリール基である。該アリール基は、置換基を有していてもよく、好ましくは炭素数1〜4のアルキル基又は炭素数6〜18のアリール基を有していてもよい炭素数6〜18のアリール基である。例えば、フェニル基、ナフチル基、トリル基、アンスリル基、ジメチルフェニル基、ビフェニル基等が挙げられ、フェニル基又はナフチル基が好ましく、フェニル基がより好ましい。nは0又は1が好ましい。
nは0又は1が好ましい。
縮合環としては、ベンゾフラン環、イソベンゾフラン環、ベンゾチオフェン環、インドール環、インドリン環、イソインドール環、ベンゾオキサゾール環、ベンゾチアゾール環、インダゾール環、ベンゾイミダゾール環、キノリン環、イソキノリン環、シンノリン環、フタラジン環、キナゾリン環、キノキサリン環、ジベンゾフラン環、カルバゾール環、キサンテン環、アクリジン環、フェナントリジン環、フェナントロリン環、フェナジン環、フェノキサジン環、チアントレン環、チエノチオフェン環、インドリジン環、キノリジン環、キヌクリジン環、ナフチリジン環、プリン環、プテリジン環等が挙げられる。
Lがアルキレン基、アルケニレン基、シクロアルキレン基、シクロアルケニレン基、アリーレン基、2価の複素環基、又はイミノ基を表す場合、これらは更に置換基を有していてもよい。該更なる置換基としては、アルキル基、ハロゲン原子、アリール基、ヘテロ環が挙げられる。
アルキル基としては、好ましくは炭素数1〜4のアルキル基であり、例えば、メチル基、エチル基、n−プロピル基、イゾプロピル基、又はt−ブチル基が挙げられ、メチル基であることがより好ましい。
アリール基としては、好ましくは炭素数6〜20のアリール基である。該アリール基は、アルキル基を有していてもよく、好ましくは炭素数1〜4のアルキル基を有していてもよい炭素数6〜15のアリール基である。例えば、フェニル基、ナフチル基、アントラセニル基、9−ジメチルフルオレニル基、メチルフェニル基、ジメチルフェニル基等が挙げられ、フェニル基、ナフチル基、アントラセニル基、9−ジメチルフルオレニル基が好ましい。
信号読み出し回路を有し、表面にSiO2による絶縁膜(接続部を含む)が形成されたCMOS基板上にスパッタ法により酸化窒化チタン(TiON)を15nm成膜し、この膜をフォトリソグラフィ及びドライエッチング法によりパターニングして画素電極を形成した。ここまでは真空中で行った。なお、画素電極は絶縁膜内の接続部を通して基板内の信号読み出し回路と電気的に接続されている。その後、この基板を300℃30分大気中で加熱した(基板加熱工程)。
電子ブロッキング層の材料と、光電変換層の材料と、基板加熱工程時の加熱温度と、画素電極の材料とを表1に示すとおりにした(実施例3,4は、実施例1に対して画素電極の材料をITOにしている点も異なる)以外は、実施例1と同様に固体撮像素子を作製した。表1の受光層構成の欄に示した“**/***”の表記は、**が電子ブロッキング層を示し、***が光電変換層を示す。
基板加熱工程を省略した以外は、実施例1と同様にして固体撮像素子を作製した。
電子ブロッキング層の材料と、光電変換層の材料と、画素電極の材料とを表1に示すとおりに変更した(比較例2は、比較例1に対して画素電極の材料をITOにしている点も異なる)以外は、比較例1と同様に固体撮像素子を作製した。
基板加熱工程における加熱温度を250℃に変更した以外は、実施例1と同様に固体撮像素子を作製した。
基板加熱工程における加熱温度を260℃に変更した以外は、実施例1と同様に固体撮像素子を作製した。
101 基板
102 絶縁層
104 画素電極
107 受光層
108 対向電極
Claims (9)
- 基板上に酸化膜で構成された絶縁膜が形成され、当該絶縁膜上に形成された導電性材料からなる第一の電極と、前記第一の電極の上に形成された有機材料を含む受光層と、前記受光層上に形成された第二の電極とを有する光電変換素子の製造方法であって、
前記絶縁膜上に前記第一の電極を形成する第一の工程と、
前記第一の電極の上に前記受光層を形成する第二の工程と、
前記受光層上に前記第二の電極を形成する第三の工程と、
前記第一の工程後、前記第二の工程前に、前記基板を270℃以上で加熱する工程とを備える光電変換素子の製造方法。 - 請求項1記載の光電変換素子の製造方法であって、
前記第一の工程は、前記絶縁膜上に導電性材料を成膜する工程と、成膜した前記導電性材料の膜をパターニングする工程とを含む光電変換素子の製造方法。 - 請求項2記載の光電変換素子の製造方法であって、
前記パターニングする工程では、前記パターニングを真空中で行う光電変換素子の製造方法。 - 請求項2又は3記載の光電変換素子の製造方法であって、
前記パターニングする工程では、フォトリソ及びエッチングで前記パターニングを行う光電変換素子の製造方法。 - 請求項1〜4のいずれか1項記載の光電変換素子の製造方法であって、
前記受光層は、有機材料を含む電荷ブロッキング層と、有機材料を含む光電変換層とを含む光電変換素子の製造方法。 - 請求項1〜5のいずれか1項記載の光電変換素子の製造方法であって、
前記導電性材料がITO又はTiONである光電変換素子の製造方法。 - 請求項6記載の光電変換素子の製造方法であって、
前記導電性材料がTiONであり、
前記第一の電極に含まれる酸素量のチタン量に対するatm%を、前記加熱する工程の前後で10%以上上昇させる光電変換素子の製造方法。 - 請求項1〜7のいずれか1項記載の光電変換素子の製造方法で製造した光電変換素子と、
前記受光層内で発生し前記第一の電極で捕集された電荷の電荷量に応じた信号を読み出す前記基板に形成された信号読み出し回路とを備える固体撮像素子。 - 請求項8記載の固体撮像素子を備える撮像装置。
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WO2014157216A1 (ja) * | 2013-03-28 | 2014-10-02 | 富士フイルム株式会社 | 光電変換材料、光電変換素子およびその使用方法、光センサ、撮像素子 |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006106223A (ja) * | 2004-10-01 | 2006-04-20 | Konica Minolta Business Technologies Inc | 供給回収装置及び画像形成装置 |
JP2006127782A (ja) * | 2004-10-26 | 2006-05-18 | Nippon Oil Corp | 金属−金属酸化物複合電極、その製造方法及び光電変換素子 |
JP2008072589A (ja) * | 2006-09-15 | 2008-03-27 | Matsushita Electric Ind Co Ltd | カラーイメージセンサ |
JP2008252004A (ja) * | 2007-03-30 | 2008-10-16 | Fujifilm Corp | 固体撮像素子、固体撮像素子の製造方法 |
JP2008258421A (ja) * | 2007-04-05 | 2008-10-23 | Nippon Hoso Kyokai <Nhk> | 有機光電変換素子及びその製造方法 |
JP2009105336A (ja) * | 2007-10-25 | 2009-05-14 | Mitsubishi Chemicals Corp | 膜の製造方法、有機電子素子の製造方法及びナフタロシアニン膜 |
WO2012043070A1 (ja) * | 2010-09-27 | 2012-04-05 | 富士フイルム株式会社 | 光電変換素子の製造方法、固体撮像素子、撮像装置 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000106223A (ja) * | 1998-09-29 | 2000-04-11 | Fuji Photo Film Co Ltd | 光電変換素子 |
JP4126810B2 (ja) | 1999-06-25 | 2008-07-30 | 富士電機ホールディングス株式会社 | 薄膜太陽電池の製造装置 |
JP2005085933A (ja) | 2003-09-08 | 2005-03-31 | Matsushita Electric Ind Co Ltd | 光センサ及びそれを用いた光論理素子並びに電子デバイス |
EP1933388A1 (en) * | 2005-10-03 | 2008-06-18 | Sharp Kabushiki Kaisha | Silicon-based thin film photoelectric converter, and method and apparatus for manufacturing same |
US20120037787A1 (en) | 2006-09-07 | 2012-02-16 | Matsushita Electric Industrial Co., Ltd. | Image sensor |
JP2008072435A (ja) | 2006-09-14 | 2008-03-27 | Matsushita Electric Ind Co Ltd | イメージセンサ |
JP4637196B2 (ja) | 2007-03-16 | 2011-02-23 | 富士フイルム株式会社 | 固体撮像素子 |
US8871565B2 (en) * | 2010-09-13 | 2014-10-28 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing semiconductor device |
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Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006106223A (ja) * | 2004-10-01 | 2006-04-20 | Konica Minolta Business Technologies Inc | 供給回収装置及び画像形成装置 |
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Also Published As
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US9123858B2 (en) | 2015-09-01 |
JP5572611B2 (ja) | 2014-08-13 |
WO2012043070A1 (ja) | 2012-04-05 |
KR20130101036A (ko) | 2013-09-12 |
US20130206966A1 (en) | 2013-08-15 |
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