JP2011510156A - エポキシ樹脂硬化剤組成物及び前記硬化剤組成物を含むエポキシ樹脂組成物 - Google Patents
エポキシ樹脂硬化剤組成物及び前記硬化剤組成物を含むエポキシ樹脂組成物 Download PDFInfo
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Abstract
Description
エポキシ樹脂硬化剤組成物の成分(i)は、任意の周知エポキシ樹脂であることができる。本明細書中で使用する用語「エポキシ樹脂」は、分子当たり1つ又はそれ以上の隣接エポキシ基、即ち分子当たり少なくとも1つの1,2−エポキシ基を有する組成物を意味する。一般に、エポキシ樹脂化合物は、少なくとも1つの1,2−エポキシ基を有する飽和又は不飽和脂肪族、脂環式、芳香族又は複素環式化合物であることができる。このような化合物は、所望ならばハロゲン原子、ヒドロキシ基、エーテル基、低級アルキル基などのような1つ又はそれ以上の非干渉性置換基で置換されることができる。
を有するエポキシ樹脂である。
によって示されるような、炭素環中の2つの隣接原子にエポキシ酸素が結合した飽和炭素環からなる。
一般に、典型的なエポキシ樹脂組成物は、1種又はそれ以上のエポキシ樹脂とエポキシ樹脂硬化剤を含む。エポキシ樹脂硬化剤はエポキシ樹脂と反応して(しばしば高温で)、硬化エポキシ樹脂を生成する。先行技術のエポキシ樹脂硬化剤には、例えば脂肪族及び芳香族アミン系硬化剤並びにフェノール系硬化剤などがある。エポキシ樹脂組成物は、任意の所定の温度においてエポキシ樹脂組成物とエポキシ樹脂硬化剤との反応の速度を増加させるために、触媒又は「反応促進剤」、例えば2−メチルイミダゾールを含むことも多い。
を有する化合物、成分(i)は、エポキシ樹脂硬化剤組成物に関して前述したエポキシ樹脂のいずれかであることができる。
本発明の別の関連態様において、本発明は、(a)(i)少なくとも1つの隣接エポキシ基を有する化合物及び(ii)アミノアルコールの反応生成物の粒子;並びに(b)少なくとも1つの隣接エポキシ基を有する化合物の粒子を含んでなるエポキシ樹脂粉体コーティング組成物である。
反応器中の2−アミノ−2−ヒドロキシメチル−1,3−プロパンジオール(THMAM)101.4gに、滴下漏斗を用いて市販のビスフェノールAジグリシジルエーテル(DER330銘柄エポキシ樹脂;The Dow Chemical Company)40gをゆっくり加えてスラリーとし、これを168℃に加熱することによって反応させる。得られた撹拌均質混合物に、30分間にわたってDER330銘柄エポキシ樹脂60gを加える。その間、反応器の温度を160℃(設定温度)〜177℃(反応熱による)の間に保持する。その後、温度160℃で更に30分間撹拌して、より完全な反応を確実にする。得られた生成物のガラス転移点は37℃である。この生成物の150℃における溶融粘度は2.1Pa・sである。この生成物の軟化点は81℃である。
温度172℃の反応器中の2−アミノ−2−ヒドロキシメチル−1,3−プロパンジオール(THMAM)324.5gに、滴下漏斗を用いて市販のビスフェノールAジグリシジルエーテル(DER330銘柄エポキシ樹脂;The Dow Chemical Company)480gをゆっくり加える。その間、反応器の温度を153〜172℃に保持する。その後、温度150℃で更に30分間撹拌して、より完全な反応を確実にする。得られた生成物のガラス転移点は56℃である。この生成物の150℃における溶融粘度は2.7Pa・sである。この生成物の軟化点は96℃である。13C NMRによって未反応エポキシ基は観察されない。13C NMRによる概算質量分布はBAB 84モル%;B 10モル%; BABAB 6モル%[AはDER330であり、BはTHMAMである]である。
温度175℃の反応器中の2−アミノ−2−ヒドロキシメチル−1,3−プロパンジオール(THMAM)167.3gに、滴下漏斗を用いて市販のビスフェノールAジグリシジルエーテル(DER330銘柄エポキシ樹脂;The Dow Chemical Company)333gをゆっくり加える。その間、反応器の温度を156〜178℃に保持する。その後、温度175℃で更に60分間撹拌して、より完全な反応を確実にする。得られた生成物のガラス転移点は78℃である。この生成物の150℃における溶融粘度は131Pa・sである。この生成物の軟化点は134℃である。
温度172℃の反応器中の2−アミノ−2−ヒドロキシメチル−1,3−プロパンジオール(THMAM)145gに、滴下漏斗を用いて最初にポリグリコールジグリシジルエーテルを基材とする液体エポキシ樹脂18.5gを、次いで市販のビスフェノールAジグリシジルエーテル(DER330銘柄エポキシ樹脂;The Dow Chemical Company)204.5gをゆっくり加える。その間、反応器の温度を168〜182℃に保持する。その後、温度175℃で更に30分間撹拌して、より完全な反応を確実にする。得られた生成物のガラス転移点は40℃である。この生成物の150℃における溶融粘度は2.4Pa・sである。この生成物の軟化点は91℃である。
温度165℃の反応器中の2−アミノ−2−ヒドロキシメチル−1,3−プロパンジオール(THMAM)142gに、滴下漏斗を用いて最初にポリグリコールジグリシジルエーテルを基材とする液体エポキシ樹脂23gを、次いで市販のビスフェノールAジグリシジルエーテル(DER330銘柄エポキシ樹脂;The Dow Chemical Company)200gをゆっくり加える。その間、反応器の温度を160〜181℃に保持する。その後、温度170℃で更に30分間撹拌して、より完全な反応を確実にする。得られた生成物のガラス転移点は49℃である。この生成物の150℃における溶融粘度は4.0Pa・sである。この生成物の軟化点は98℃である。
下記表Iに示した成分粉末をブレンドすることによって、3種の粉体コーティング組成物を調製する。
Claims (16)
- (i)少なくとも1つの隣接エポキシ基を有する化合物並びに(ii)少なくとも1つのアミノ基及び少なくとも1つのアルコール基を有するアミノアルコールの反応生成物を含んでなる硬化剤組成物。
- 前記の少なくとも1つの隣接エポキシ基を有する化合物のエポキシ基に対する前記アミノアルコールのアミン基のモル比が25:1〜1:1の範囲である請求項1に記載の硬化剤組成物。
- 前記アミノアルコールのアミン基が第一アミン基である請求項1に記載の硬化剤組成物。
- 前記アミノアルコールがアミノポリオールである請求項1に記載の硬化剤組成物。
- 前記アミノアルコールがモノエタノールアミン、2−アミノー2−ヒドロキシメチル−1,3−プロパンジオール及び2−アミノ−2−メチル−1,3−プロパンジオールからなる群から選ばれる請求項1に記載の硬化剤組成物。
- 前記の少なくとも1つの隣接エポキシ基を有する化合物が、2つの隣接エポキシ基を有する化合物を含む請求項1に記載の硬化剤組成物。
- エポキシ−、イソシアネート−、カルボン酸−、ビニル−及びアクリル酸−官能性樹脂から選ばれた1種又はそれ以上の化合物に対する硬化剤として有用な請求項1に記載の硬化剤組成物。
- 前記アルカノールアミンの分子量が約150〜約10,000Daである請求項1に記載の硬化剤組成物。
- 前記組成物が水分散性である請求項1に記載の硬化剤組成物。
- 前記組成物が約30〜約150℃の軟化点を有する請求項1に記載の硬化剤組成物。
- (a)請求項1に記載の反応生成物及び(b)少なくとも1つの隣接エポキシ基を有する化合物を含んでなるエポキシ樹脂組成物。
- 前記組成物が共硬化剤として固体イソシアネート又はブロックト固体イソシアネートを含む請求項12に記載のエポキシ樹脂組成物。
- (a)請求項1に記載の反応生成物の粒子及び(b)少なくとも1つの隣接エポキシ基を有する化合物の粒子を含んでなる粉体コーティング組成物。
- (a)請求項1に記載の反応生成物及び(b)少なくとも1つの隣接イソシアネート基を有する化合物を含んでなるイソシアネート樹脂溶剤非含有組成物。
- 前記化合物(b)がイソシアネート、ブロックトイソシアネート又はそれらの混合物である請求項15に記載のイソシアネート樹脂溶剤非含有組成物。
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PCT/US2009/030170 WO2009094235A1 (en) | 2008-01-23 | 2009-01-06 | Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8389652B2 (en) * | 2008-01-23 | 2013-03-05 | Dow Global Technologies Llc | Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions |
KR101178725B1 (ko) | 2010-04-05 | 2012-08-31 | 제일모직주식회사 | 고내열성 투명 에폭시 경화수지 및 이의 제조방법 |
US20120095132A1 (en) * | 2010-10-19 | 2012-04-19 | Chung-Hao Chang | Halogen- and phosphorus-free thermosetting resin composition |
RU2506291C2 (ru) * | 2011-12-28 | 2014-02-10 | Татьяна Валентиновна Лапицкая | Полимерная композиция |
KR101415015B1 (ko) * | 2012-07-04 | 2014-07-04 | 주식회사 케이씨씨 | 우수한 내식성을 갖는 파이프 피복용 에폭시 수지 분체 도료 조성물 |
CN105209536B (zh) | 2013-05-14 | 2018-01-09 | 3M创新有限公司 | 包含含吡嗪化合物的环氧树脂 |
CN103601871A (zh) * | 2013-11-19 | 2014-02-26 | 湖南神力实业有限公司 | 一种新型环氧固化剂及其合成方法 |
EP3122846B1 (en) | 2014-03-27 | 2018-12-12 | Dow Global Technologies LLC | Dispersant suitable for lubricant formulations |
US20180201825A1 (en) * | 2015-06-30 | 2018-07-19 | Dow Global Technologies Llc | Coating for capturing sulfides |
EP3317362A1 (en) * | 2015-06-30 | 2018-05-09 | Dow Global Technologies LLC | Permeable liner |
MX2017017014A (es) * | 2015-06-30 | 2018-04-13 | Dow Global Technologies Llc | Revestimiento para capturar sulfuros. |
CA2990829A1 (en) * | 2015-06-30 | 2017-01-05 | Dow Global Technologies Llc | Coating for controlled release |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5716068A (en) * | 1980-05-22 | 1982-01-27 | Shell Int Research | Coating powder suspension , production and use thereof |
JPS57100127A (en) * | 1980-12-12 | 1982-06-22 | Taoka Chem Co Ltd | Curable composition |
JPS61500499A (ja) * | 1984-04-13 | 1986-03-20 | ザ・ダウ・ケミカル・カンパニ− | 硬化性の被覆組成物及びその組成物を基体に被覆する方法 |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1141859A (fr) * | 1963-01-28 | 1957-09-11 | Support en tôle assemblée plus spécialement pour les constructions des couvertures et procédés de fabrication | |
NL128100C (ja) * | 1964-04-16 | |||
BE758385A (fr) * | 1969-11-03 | 1971-04-16 | Resyn Corp | Nouveaux agents d'emulsionnement et de durcissement de resines epoxyde |
US3686359A (en) * | 1969-12-19 | 1972-08-22 | Union Carbide Corp | Curable polyepoxide compositions |
US4066628A (en) * | 1976-08-02 | 1978-01-03 | Mitsubishi Chemical Industries Ltd. | Oxazolidone catalyst |
US4113684A (en) * | 1976-12-10 | 1978-09-12 | Westinghouse Electric Corp. | Low temperature cure epoxy-amine adhesive compositions |
DE2738270A1 (de) * | 1977-08-25 | 1979-03-01 | Veba Chemie Ag | Pulverfoermige ueberzugsmittel und deren anwendung |
US4163815A (en) * | 1977-09-19 | 1979-08-07 | Ford Motor Company | Catalyzed polyisocyanate coating compositions |
US4360649A (en) | 1980-04-30 | 1982-11-23 | Sumitomo Chemical Company, Limited | Curable composition |
US4310695A (en) * | 1980-11-17 | 1982-01-12 | Shell Oil Company | Stable epoxy-amine curing agent adducts |
JPS5924762A (ja) | 1982-07-31 | 1984-02-08 | Toto Kasei Kk | 速硬化性粉体塗料組成物 |
CA1243040A (en) | 1982-08-12 | 1988-10-11 | Paul D. Mclean | Epoxy resin fortifiers based on aromatic amides |
US4438254A (en) | 1983-02-28 | 1984-03-20 | The Dow Chemical Company | Process for producing epoxy resins |
FR2550044B1 (fr) | 1983-07-05 | 1986-11-21 | Parrens Pierre | Appareil de traitement par plasma de substrats en forme de plaquettes |
US4609685A (en) * | 1985-05-06 | 1986-09-02 | Texaco Inc. | Polyether polyols modified with amino alcohol-epoxy resin adducts |
JPH02105817A (ja) | 1988-10-14 | 1990-04-18 | Koei Chem Co Ltd | 硬化性エポキシ樹脂組成物 |
GB8825315D0 (en) * | 1988-10-28 | 1988-11-30 | Ici Plc | Coating compositions |
US5115075A (en) * | 1990-05-08 | 1992-05-19 | The Dow Chemical Company | Amide and hydroxymethyl functionalized polyethers as thermoplastic barrier resins |
US5089588A (en) | 1990-10-17 | 1992-02-18 | The Dow Chemical Company | Hydroxy-functional poly(amide ethers) as thermoplastic barrier resins |
US5171820A (en) | 1991-05-13 | 1992-12-15 | The Dow Chemical Company | Hydroxy-functional polyesters as thermoplastic barrier resins |
JPH05295076A (ja) * | 1992-04-23 | 1993-11-09 | Dainippon Ink & Chem Inc | ポリウレタン水性分散液の製造方法 |
US5246751A (en) | 1992-05-18 | 1993-09-21 | The Dow Chemical Company | Poly(hydroxy ether imides) as barrier packaging materials |
DE19935325A1 (de) * | 1999-07-28 | 2001-02-01 | Bayer Ag | Lösemittelfreie, raumtemperaturhärtende Reaktivsysteme und ihre Verwendung zur Herstellung von Klebstoffen, Dichtungsmassen, Vergußmassen, Formteilen oder Beschichtungen |
JP5485487B2 (ja) | 1999-12-13 | 2014-05-07 | ダウ グローバル テクノロジーズ エルエルシー | 難燃性リン元素含有エポキシ樹脂組成物 |
EP1576026A1 (en) | 2002-12-17 | 2005-09-21 | Dow Global Technologies Inc. | Amine-epoxy autocatalytic polymers and polyurethane products made therefrom |
US7622541B2 (en) * | 2003-01-17 | 2009-11-24 | The United States Of America As Represented By The Secretary Of The Navy | Polyurethane coating |
US7615604B2 (en) * | 2003-01-17 | 2009-11-10 | The United States Of America As Represented By The Secretary Of The Navy | Diols formed by ring-opening of epoxies |
US7001938B2 (en) * | 2003-01-27 | 2006-02-21 | Resolution Performance Products Llc | Epoxy resin curing compositions and resin compositions including same |
DE102004050955A1 (de) * | 2004-10-20 | 2006-04-27 | Byk-Chemie Gmbh | Alkoxylierte Epoxyd-Amin-Addukte und deren Verwendung |
US8389652B2 (en) * | 2008-01-23 | 2013-03-05 | Dow Global Technologies Llc | Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions |
-
2009
- 2009-01-06 US US12/812,534 patent/US8389652B2/en active Active
- 2009-01-06 CN CN2009801028143A patent/CN101925627A/zh active Pending
- 2009-01-06 JP JP2010544364A patent/JP5603256B2/ja not_active Expired - Fee Related
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- 2009-01-06 WO PCT/US2009/030170 patent/WO2009094235A1/en active Application Filing
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- 2009-01-22 TW TW098102532A patent/TWI485177B/zh not_active IP Right Cessation
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-
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- 2016-05-23 US US15/162,132 patent/US9527951B2/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5716068A (en) * | 1980-05-22 | 1982-01-27 | Shell Int Research | Coating powder suspension , production and use thereof |
JPS57100127A (en) * | 1980-12-12 | 1982-06-22 | Taoka Chem Co Ltd | Curable composition |
JPS61500499A (ja) * | 1984-04-13 | 1986-03-20 | ザ・ダウ・ケミカル・カンパニ− | 硬化性の被覆組成物及びその組成物を基体に被覆する方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20200027828A (ko) * | 2018-09-05 | 2020-03-13 | 주식회사 케이씨씨 | 분체도료 조성물 |
KR102173748B1 (ko) * | 2018-09-05 | 2020-11-03 | 주식회사 케이씨씨 | 분체도료 조성물 |
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EP2824127A1 (en) | 2015-01-14 |
US9133301B2 (en) | 2015-09-15 |
US8927663B2 (en) | 2015-01-06 |
US20130184378A1 (en) | 2013-07-18 |
US20150353674A1 (en) | 2015-12-10 |
TWI485177B (zh) | 2015-05-21 |
US8389652B2 (en) | 2013-03-05 |
CN105255312A (zh) | 2016-01-20 |
BRPI0905711A2 (pt) | 2015-07-14 |
TW200936630A (en) | 2009-09-01 |
US20100317768A1 (en) | 2010-12-16 |
JP5603256B2 (ja) | 2014-10-08 |
US20160264719A1 (en) | 2016-09-15 |
EP2235087A1 (en) | 2010-10-06 |
WO2009094235A1 (en) | 2009-07-30 |
US20150105523A1 (en) | 2015-04-16 |
US9371415B2 (en) | 2016-06-21 |
EP2235087B1 (en) | 2014-10-01 |
KR20100126698A (ko) | 2010-12-02 |
KR101512623B1 (ko) | 2015-04-21 |
US9527951B2 (en) | 2016-12-27 |
CN101925627A (zh) | 2010-12-22 |
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