JP2011014411A5 - - Google Patents
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- JP2011014411A5 JP2011014411A5 JP2009158216A JP2009158216A JP2011014411A5 JP 2011014411 A5 JP2011014411 A5 JP 2011014411A5 JP 2009158216 A JP2009158216 A JP 2009158216A JP 2009158216 A JP2009158216 A JP 2009158216A JP 2011014411 A5 JP2011014411 A5 JP 2011014411A5
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- carbon nanotube
- photoelectric conversion
- working electrode
- conversion element
- conductive layer
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前記課題を解決するために、本発明の第一は、基材上に形成された導電性層の少なくとも一部に色素担持された酸化物半導体多孔質膜層を有した作用極と、該作用極に対向して配置されて基材上に導電性層が形成された対極と、前記作用極と前記対極の間に電解質層とを備えてなる光電変換素子であって、前記作用極及び／又は対極の導電性層が、スルホン酸基及び／又はカルボキシ基を有する水溶性導電性ポリマー（Ａ）、並びにカーボンナノチューブ（Ｂ）を含む組成物から形成されるカーボンナノチューブ含有層を有する光電変換素子に関する。 In order to solve the above problems, the first of the present invention is a working electrode having an oxide semiconductor porous film layer carrying a dye supported on at least a part of a conductive layer formed on a substrate, and the action A photoelectric conversion element comprising a counter electrode disposed opposite to an electrode and having a conductive layer formed on a substrate, and an electrolyte layer between the working electrode and the counter electrode, wherein the working electrode and / or or counter electrode conductive layer, water-soluble electroconductive polymer having a sulfonic acid group and / or carboxy group (a), and a photoelectric conversion device having a carbon nanotube-containing layer formed from a composition comprising a carbon nanotube (B) About.
本発明の第二は、基材上に形成された導電性層の少なくとも一部に色素担持された酸化物半導体多孔質膜層を有した作用極と、該作用極に対向して配置されて基材上に導電性層が形成された対極と、前記作用極と前記対極の間に電解質層とを備えてなる光電変換素子であって、前記作用極、前記対極及び前記電解質層から選ばれた少なくとも一つの面上に、スルホン酸基及び／又はカルボキシ基を有する水溶性導電性ポリマー（Ａ）、カーボンナノチューブ（Ｂ）、並びに溶媒（Ｃ）を含有するカーボンナノチューブ含有組成物を塗工してカーボンナノチューブ含有層を形成する光電変換素子の製造方法である。 A second aspect of the present invention is a working electrode having an oxide semiconductor porous membrane layer carrying a dye supported on at least a part of a conductive layer formed on a substrate, and disposed opposite to the working electrode. A photoelectric conversion element comprising a counter electrode having a conductive layer formed on a substrate, and an electrolyte layer between the working electrode and the counter electrode, the photoelectric conversion element being selected from the working electrode, the counter electrode, and the electrolyte layer Further, a carbon nanotube-containing composition containing a water-soluble conductive polymer (A) having a sulfonic acid group and / or a carboxy group, a carbon nanotube (B) , and a solvent (C) is applied on at least one surface. This is a method for producing a photoelectric conversion element for forming a carbon nanotube-containing layer.
Claims (6)
前記作用極及び／又は対極の導電性層が、スルホン酸基及び／又はカルボキシ基を有する水溶性導電性ポリマー（Ａ）、並びにカーボンナノチューブ（Ｂ）を含む組成物から形成されるカーボンナノチューブ含有層を有する光電変換素子。 A working electrode having an oxide semiconductor porous membrane layer carrying a dye supported on at least a part of the conductive layer formed on the substrate, and the conductive layer disposed on the substrate so as to face the working electrode A photoelectric conversion element comprising: a counter electrode formed of; and an electrolyte layer between the working electrode and the counter electrode,
Conductive layer of the working electrode and / or counter electrode, a water-soluble electroconductive polymer having a sulfonic acid group and / or carboxy group (A), and a carbon nanotube-containing layer formed from a composition comprising a carbon nanotube (B) A photoelectric conversion element having
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009158216A JP5377120B2 (en) | 2009-07-02 | 2009-07-02 | Photoelectric conversion element and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009158216A JP5377120B2 (en) | 2009-07-02 | 2009-07-02 | Photoelectric conversion element and manufacturing method thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011014411A JP2011014411A (en) | 2011-01-20 |
| JP2011014411A5 true JP2011014411A5 (en) | 2012-07-19 |
| JP5377120B2 JP5377120B2 (en) | 2013-12-25 |
Family
ID=43593090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009158216A Active JP5377120B2 (en) | 2009-07-02 | 2009-07-02 | Photoelectric conversion element and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5377120B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011023282A (en) * | 2009-07-17 | 2011-02-03 | Mitsubishi Rayon Co Ltd | Method of manufacturing conductor |
| JP5786286B2 (en) * | 2010-06-24 | 2015-09-30 | Tdk株式会社 | Counter electrode for dye-sensitized solar cell, dye-sensitized solar cell, and method for manufacturing counter electrode |
| JP5591156B2 (en) * | 2011-03-04 | 2014-09-17 | 大阪瓦斯株式会社 | Electrolytic solution and photoelectric conversion element |
| JP5740063B2 (en) | 2012-12-14 | 2015-06-24 | 積水化学工業株式会社 | Electrode substrate and dye-sensitized solar cell |
| CN105164775A (en) * | 2013-03-21 | 2015-12-16 | 日本瑞翁株式会社 | Dye-sensitized solar-cell element |
| WO2015045396A1 (en) * | 2013-09-30 | 2015-04-02 | 日本ゼオン株式会社 | Dye-sensitized solar cell and solar cell module |
| US11753553B2 (en) * | 2019-11-28 | 2023-09-12 | Zeon Corporation | Carbon nanotube water dispersion, conductive film, electrode, and solar cell |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7645400B2 (en) * | 2002-11-01 | 2010-01-12 | Mitsubishi Rayon Co., Ltd. | Composition containing carbon nanotubes having a coating |
| JP4767498B2 (en) * | 2004-02-04 | 2011-09-07 | 信越ポリマー株式会社 | Photoelectric conversion element and manufacturing method thereof |
| JP4915785B2 (en) * | 2006-09-14 | 2012-04-11 | 日本カーリット株式会社 | Counter electrode for dye-sensitized solar cell and dye-sensitized solar cell including the same |
| JP5088863B2 (en) * | 2007-03-05 | 2012-12-05 | 日本カーリット株式会社 | Counter electrode for dye-sensitized solar cell and dye-sensitized solar cell including the same |
| JPWO2009113342A1 (en) * | 2008-03-14 | 2011-07-21 | コニカミノルタホールディングス株式会社 | Dye-sensitized solar cell |
| JP5339756B2 (en) * | 2008-03-25 | 2013-11-13 | 日立造船株式会社 | Method for manufacturing photoelectric conversion element |
-
2009
- 2009-07-02 JP JP2009158216A patent/JP5377120B2/en active Active
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