JP2010522248A - 水性塗料組成物及び複層塗膜形成方法 - Google Patents
水性塗料組成物及び複層塗膜形成方法 Download PDFInfo
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- JP2010522248A JP2010522248A JP2009537832A JP2009537832A JP2010522248A JP 2010522248 A JP2010522248 A JP 2010522248A JP 2009537832 A JP2009537832 A JP 2009537832A JP 2009537832 A JP2009537832 A JP 2009537832A JP 2010522248 A JP2010522248 A JP 2010522248A
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- water
- coating composition
- acrylic polymer
- polymer particles
- dispersible acrylic
- Prior art date
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- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000001370 static light scattering Methods 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical class O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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Abstract
【選択図】 なし
Description
VOC削減の観点から、中塗塗料及び上塗塗料においても水性化が進められている。
成方法を提供することである。
重合体粒子(A)、水酸基含有樹脂(B)及び硬化剤(C)を含んでなるものである。
本塗料における水分散性アクリル重合体粒子(A)は、1,100,000以上の重量平均分子量を有し、且つ1,4−ジオキサン溶媒中の質量濃度が1.35%の分散液の状態での分光光度計による波長330nmにおける吸光度の値が0.2以下である水分散性アクリル重合体粒子である。
ることができる。該モノマーとしては、アクリル酸又はメタクリル酸と炭素数2〜10の2価アルコールとのモノエステル化物が好適であり、例えば、2−ヒドロキシエチルアクリレート、2−ヒドロキシプロピルアクリレート、3−ヒドロキシプロピルアクリレート、4−ヒドロキシブチルアクリレート等の水酸基含有アクリレートモノマー;2−ヒドロキシエチルメタクリレート、2−ヒドロキシプロピルメタクリレート、3−ヒドロキシプロピルメタクリレート、4−ヒドロキシブチルメタクリレート等の水酸基含有メタクリレートモノマー;N−メチロールアクリルアミド、N−メチロールメタクリルアミドなどを挙げることができる。
(1)アクリル酸又はメタクリル酸と炭素数1〜20の1価アルコールとのモノエステル化物: 例えば、メチルアクリレート、メチルメタクリレート、エチルアクリレート、エチルメタクリレート、プロピルアクリレート、プロピルメタクリレート、ブチルアクリレート、ブチルメタクリレート、2−エチルヘキシルアクリレート、2−エチルヘキシルメタクリレート、シクロヘキシルアクリレート、シクロヘキシルメタクリレート、ラウリルアクリレート、ラウリルメタクリレート、ステアリルアクリレート、ステアリルメタクリレート等。
(2)芳香族系ビニルモノマー: 例えば、スチレン、α−メチルスチレン、ビニルトルエン等。
(3)グリシジル基含有ビニルモノマー: 1分子中に少なくとも1個のグリシジル基と1個の重合性不飽和結合とを有する化合物、例えば、グリシジルアクリレート、グリシジルメタクリレート等。
(4)含窒素アルキル(炭素数1〜20)(メタ)アクリレート: 例えばジメチルアミノエチルアクリレート、ジメチルアミノエチルメタクリレート等。
(5)重合性不飽和基含有アミド系化合物: 1分子中に少なくとも1個のアミド基と1個の重合性不飽和結合とを有する化合物、例えば、アクリルアミド、メタクリルアミド、ジメチルアクリルアミド、N,N−ジメチルプロピルアクリルアミド、N−ブトキシメチルアクリルアミド、ジアセトンアクリルアミド等。
(6)重合性不飽和基含有ニトリル系化合物: 例えば、アクリロニトリル、メタクリロニトリル等。
(7)ジエン系化合物: 例えばブタジエン、イソプレン等。
(8)ビニル化合物: 例えば酢酸ビニル、プロピオン酸ビニル、塩化ビニル等。
(メタ)アクリルアミド、エチレンビス(メタ)アクリルアミド等を挙げることができる。なお、多ビニル化合物(M−4)には前記ジエン系化合物は含まれない。
、ANTOX MS−60(以上商品名、日本乳化剤社製)等を挙げることができる。
Kc/R(θ)=1/MwP(θ)+2A2c+・・・ (1)
R(θ)=角度θにおける散乱光(レイリー係数)の還元強度、
c=サンプル濃度、
Mw=重量平均分子量、
A2=第2ビリアル係数、
K=光学パラメーター、
P(θ)=角度散乱関数、
が用いられるが、本発明における重量平均分子量は、サイズ排除クロマトグラフに多角度光散乱検出器を接続したSEC−MALLS法と同様、上記式(1)において、第2ビリアル係数とサンプル濃度との積である第2項以降を無視した式から求めた値である。
ミン、エチレンジアミン、プロピレンジアミン、メチルエタノールアミン、ジメチルエタノールアミン、ジエチルエタノールアミン、2−アミノ−2−メチルプロパノール、ジエタノールアミン、モルホリン等を好適に使用することができる。
本塗料において使用される水酸基含有樹脂(B)の樹脂種には、特に制限はなく、例えば、アクリル樹脂、ポリエステル樹脂、ウレタン変性ポリエステル樹脂、エポキシ樹脂などを挙げることができる。
ビニルモノマーに代表される重合性不飽和モノマーをそれ自体既知の方法で(共)重合することによって合成することができる、前述の水分散性アクリル重合体粒子(A)以外のアクリル樹脂である。合成は乳化重合又は溶液重合のいずれの方法で行ってもよく、両者を併用することもできる。溶液重合により合成する場合、反応に使用する有機溶剤としては、例えば、プロピレングリコールエーテル系、ジプロピレングリコールエーテル系等の親水性有機溶剤を使用することが好ましい。また、該アクリル樹脂は、水分散性の観点から、水酸基に加えてカルボキシル基等の酸基を有していることが好ましい。
多塩基酸と多価アルコ−ルとを常法に従いエステル化反応させることによって合成することができるポリエステル樹脂である。該ポリエステル樹脂としては、水分散性の観点から、水酸基に加えてカルボキシル基等の酸基を有しているものが好ましい。
本塗料において使用される硬化剤(C)は、特に制限されるものではなく、塗料分野で通常使用されているものが同様に使用可能であり、例えば、以下に挙げるメラミン樹脂、ブロック化ポリイソシアネート化合物などを好適に用いることができる。これらの硬化剤は、それぞれ単独で又は2種以上組み合わせて使用することができる。
ルホン酸;該スルホン酸とアミンとの中和塩;リン酸エステル化合物とアミンとの中和塩などを使用することができる。
本発明の水性塗料組成物は、以上に述べた水分散性アクリル重合体粒子(A)、水酸基含有樹脂(B)及び硬化剤(C)をそれ自体既知の方法で塗料化することにより調製することができる。
本発明によれば、被塗物に、カチオン電着塗料(a)を塗装し加熱硬化させ、次いで中塗塗料(b)を塗装し加熱硬化させた後、上塗塗料(c)を塗装し硬化させることを含んでなる複層塗膜形成方法において、中塗塗料(b)及び/又は上塗塗料(c)として、本発明の水性塗料組成物を塗装することを特徴とする複層塗膜形成方法(以下、「本方法」ということがある)が提供される。
80℃の温度で10〜40分間程度加熱することにより硬化させることができる。
として、本発明の水性塗料組成物が使用される。
製造例1
温度計、サーモスタット、撹拌器、還流冷却器及び滴下装置を備えた反応容器に、脱イオン水82部及びアデカリアソープSR−1025(注1)1.0部を仕込み、窒素気流中で撹拌混合し、75℃に昇温した。次いで、下記のモノマーと開始剤の乳化物(注2)全量のうちの3%量及び0.5%過硫酸アンモニウム水溶液10部とを反応容器内に導入し75℃で2時間保持した。その後、残りのモノマーと開始剤の乳化物を5時間かけて反応容器内に滴下し、滴下終了後6時間熟成を行なった。その後、30℃まで冷却し、5.0%ジメチルエタノールアミン水溶液と脱イオン水を用いて固形分40%、pHが6.8となるように調整した。次いで、200メッシュのナイロンクロスで濾過しながら排出し、平均粒子径140nm(サブミクロン粒度分布測定装置「COULTER N4型」(ベックマン・コールター社製、商品名)を用いて、脱イオン水で希釈し、20℃で測定した)、酸価11mgKOH/g、水酸基価24mgKOH/gの水分散性アクリル重合体粒子1(固形分40wt%)を得た。
チル−2−(2−プロペニルオキシ)エトキシ)−ポリ(オキシ−1,2−エタン
ジイル)のアンモニウム塩、アデカ社製、商品名、有効成分25%。
(注2)モノマーと開始剤の乳化物: 脱イオン水55部、ラテムルE−118B(ポリ
オキシエチレンアルキルエーテル硫酸ナトリウム、花王社製、商品名、有効成分2
6%)4部、スチレン10部、メチルメタクリレート53.5部、n−ブチルアク
リレート30部、2−ヒドロキシエチルアクリレート5部及びアクリル酸1.5部
、2,2′−アゾビス〔2−(2−イミダゾリン−2−イル)プロパン〕0.2部
を混合攪拌して、モノマーと開始剤の乳化物を得た。
モノマーと開始剤の乳化物を下記表1に示す配合とする以外、製造例1と同様に処理して、水分散性アクリル重合体粒子2〜8を得た。なお、製造例6〜8においては、開始剤として、上記(注2)中の2,2′−アゾビス〔2−(2−イミダゾリン−2−イル)プロパン〕にかえて、過硫酸アンモニウムを使用した。
−2−(2−プロペニルオキシ)エトキシ)−ポリ(オキシ−1,2−エタンジイ
ル)、アデカ社製、商品名、有効成分60%。
製造例9
加熱装置、攪拌装置、温度計、還流冷却器及び精留塔を備えた4つ口フラスコに、1,3−シクロヘキサンジカルボン酸243.7部、アジピン酸275.9部、トリメチロールプロパン247.2部、ネオペンチルグリコール95.1部及び1,4−シクロヘキサンジメタノール175.7部を入れ、160℃から230℃まで3時間かけて昇温させた後、230℃で2時間保持し、生成した縮合水を精留塔を用いて溜去した。
温度計、サーモスタット、撹拌器、還流冷却器及び滴下装置を備えた反応容器に、脱イオン水145部及びNewcol562SF(注4)1.2部を仕込み、窒素気流中で撹拌混合し、80℃に昇温した。次いで、下記のモノマー乳化物(1)の全量のうちの5%
量及び3%過硫酸アンモニウム水溶液5.2部とを反応容器内に導入し80℃で20分間保持した。
キルベンゼンスルホン酸アンモニウム、有効成分60%。
温度計、サーモスタット、撹拌器、還流冷却器及び滴下装置を備えた反応容器に、ブチルセロソルブ50部を入れ、120℃に加温した後、さらに単量体としてスチレン10部、メチルメタクリレート25部、n−ブチルメタクリレート20部、n−ブチルアクリレート25部、2−ヒドロキシエチルメタクリレート15部、アクリル酸5部及びラジカル重合開始剤として2,2−アゾビス(2−メチルブチロニトリル)6部を混合した混合物を5時間かけて滴下した。次いで、2時間熟成させた後、N,N−ジメチルエタノールアミン(アミンによるカルボキシル基の中和当量が1.0となる量)を添加して中和し、ブチルセロソルブで希釈することにより、固形分65%の水酸基含有アクリル樹脂(B−3)を得た。得られた水酸基含有樹脂(B−3)は、水酸基価が72.5mgKOH/g、酸価が39mgKOH/g、そして数平均分子量が5500であった。
攪拌機、還流冷却器、水分離器及び温度計を備えた反応器に、トリメチロールプロパン273部、無水コハク酸200部及びカージュラE10P(ジャパンエポキシレジン社製、商品名、ネオデカン酸モノグリシジルエステル)490部を仕込み、100〜230℃で3時間反応させた(この時点でサンプリングを行なったところ水酸基価は350mgKOH/gで、数平均分子量は580であった)後、さらに、無水トリメリット酸192部を加え、180℃で縮合反応させることにより、水酸基含有ポリエステル樹脂(B−4)を得た。得られた水酸基含有樹脂(B−4)は、酸価が49mgKOH/g、水酸基価が195mgKOH/g、そして数平均分子量が1500であった。
加熱装置、攪拌装置、温度計、還流冷却器及び精留塔を備えた4つ口フラスコに、ネオペンチルグリコール81.3部、トリメチロールプロパン211.3部、ヘキサヒドロ無水フタル酸298.1部、アジピン酸180.8部及び2−ブチル−2−エチル−1,3−プロパンジオール247.7部を入れ、加熱を開始した。160℃から230℃まで5
時間かけて昇温させた後、230℃で2時間保持し生成した縮合水を、精留塔を用いて溜去した。次に、精留塔を水分離器に付け替え、トルエンを適宜加え、230℃で還流状態を保ち、縮合水を水分離器で分離しながら縮合反応を進め、樹脂酸価が5となった時点でトルエンを減圧下で溜去した。
温度計、サーモスタット、撹拌器、還流冷却器及び滴下装置を備えた反応容器に、ブチルセロソルブ50部を入れ、120℃に加熱し、さらに単量体としてスチレン10部、メチルメタアクリレート60部、n−ブチルアクリレート13.7部、2−ヒドロキシエチルアクリレート10部、アクリル酸6.3部及びアゾイソブチロニトリル3部の混合物を5時間かけて摘下し、1時間熟成を行った。次いで、N,N−ジメチルエタノールアミン(アミンによるカルボキシル基の中和当量が1.0となる量)を添加して中和することにより、固形分65%の水酸基含有アクリル樹脂(B−6)を得た。得られた水酸基含有樹脂(B−6)は、酸価が50mgKOH/g、水酸基価が50mgKOH/g、そして数平均分子量が10000であった。
実施例1
製造例9で得た水酸基含有樹脂(B−1)50部、カーボンMA100(カーボンブラック、三菱化学社製、商品名)1部、JR806(チタン白、テイカ社製、商品名)70部及びMICRO ACE S−3(微粉タルク、日本タルク社製、商品名)10部を混合し、ペイントシェーカーで30分間分散し、顔料分散ペースト1を得た。
下記表2に示す配合で、実施例1と同様にして混合攪拌を行なうことにより、水性塗料組成物1−2〜1−11を得た。
)を膜厚20μmとなるように電着塗装し、170℃で30分間加熱して硬化させた。
◎:キズの大きさは小さく、水性中塗塗料(本塗料組成物)の塗膜が少し露出してい
る程度。
○:キズの大きさは小さく、水性中塗塗料の塗膜と一部電着塗膜が少し露出している
程度。
△:キズの大きさは小さいが、電着塗膜面や素地の鋼板が少し露出している程度。
×:キズの大きさはかなり大きく、素地の鋼板も大きく露出している程度。
○:ツヤ感が良好、
△:ツヤ感が劣る、
×:ツヤ感が劣り、塗面が白く濁っている。
実施例8
製造例10で得た水酸基含有樹脂(B−2)100部に、攪拌しながら順に、製造例11で得た水酸基含有樹脂(B−3)30.8部、製造例12で得た水酸基含有樹脂(B−4)20部、製造例1で得た水分散性アクリル重合体粒子1 25部及びサイメル325(三井サイテック社製、商品名、メトキシ・ブトキシ混合アルキル化メラミン樹脂)31.3部を加えて混合攪拌した。その後、アルミニウム顔料分として20部となる量のアルミペーストGX180A(旭化成社製、商品名、アルミニウムフレークペースト)を攪拌しながら添加して混合分散し、さらに、ジメチルエタノールアミン及び脱イオン水を添加してpH8.0、フォードカップNo.4による測定で20℃にて40秒の粘度となるように調製し、水性塗料組成物2−1を得た。
下記表3に示す配合で、実施例8と同様にして混合攪拌を行なうことにより、水性塗料組成物2−2〜2−11を得た。
○:ゴバン目残存個数 100個/100個
△:ゴバン目残存個数 95〜99個/100個
×:ゴバン目残存個数 95個未満 /100個
実施例15
製造例14で得た水酸基含有樹脂(B−6)15.4部、ブチルセロソルブ10部及びJR806(チタン白、テイカ社製、商品名)80部を混合し、ペイントシェーカーで30分間分散し、顔料分散ペースト2を得た。
下記表4に示す配合で、実施例15と同様にして混合攪拌を行なうことにより、水性塗料組成物3−2〜3−10を得た。
パルボンド#3020(日本パーカライジング社製、商品名、りん酸亜鉛処理)を施した冷延鋼板に、エレクロンGT−10(関西ペイント社製、商品名、カチオン電着塗料)を膜厚が20μmとなるように電着塗装し、170℃で30分間加熱して硬化させた。
Claims (14)
- 水分散性アクリル重合体粒子(A)、水酸基含有樹脂(B)及び硬化剤(C)を含有する水性塗料組成物であって、該水分散性アクリル重合体粒子(A)が、1,100,000以上の重量平均分子量を有し且つ1,4−ジオキサン溶媒中の質量濃度が1.35%の分散液の状態での分光光度計による波長330nmにおける吸光度の値が0.2以下であることを特徴とする水性塗料組成物。
- 水分散性アクリル重合体粒子(A)が1,100,000〜10,000,000の範囲内の重量平均分子量を有するものである請求項1に記載の水性塗料組成物。
- 水分散性アクリル重合体粒子(A)が、重合性不飽和モノマーの総量を基準にして、0.1〜25質量%のメタクリル酸を含んでなる重合性不飽和モノマー混合物を共重合することにより得られるものである請求項1に記載の水性塗料組成物。
- 水分散性アクリル重合体粒子(A)が、重合性不飽和モノマーの総量を基準にして、0.1〜40質量%の水酸基含有メタクリレートモノマーを含んでなる重合性不飽和モノマー混合物を共重合することにより得られるものである請求項1に記載の水性塗料組成物。
- 水分散性アクリル重合体粒子(A)が、重合性不飽和モノマーの総量を基準にして、アクリレートモノマー及びスチレンを合計で20〜80質量%含んでなる重合性不飽和モノマー混合物を共重合することにより得られるものである請求項1に記載の水性塗料組成物。
- 水分散性アクリル重合体粒子(A)が、重合性不飽和モノマーを、1分子中に−(CH2CH2O)n−[ここでnは5〜60の整数である]で表わされるポリオキシエチレン基及び重合性不飽和基を有する反応性乳化剤の存在下に共重合することにより得られるものである請求項1に記載の水性塗料組成物。
- 水分散性アクリル重合体粒子(A)が、0〜150mgKOH/gの範囲内の水酸基価及び0.1〜100mgKOH/gの範囲内の酸価を有するものである請求項1に記載の水性塗料組成物。
- 水分散性アクリル重合体粒子(A)が、10〜500nmの範囲内の平均粒子径を有するものである請求項1に記載の水性塗料組成物。
- 水分散性アクリル重合体粒子(A)が、1,4−ジオキサン溶媒中の質量濃度が1.35%の分散液の状態での分光光度計による波長330nmにおける吸光度の値が0.15以下である請求項1に記載の水性塗料組成物。
- 水酸基含有樹脂(B)が、水酸基含有アクリル樹脂又は水酸基含有ポリエステル樹脂である請求項1に記載の水性塗料組成物。
- 硬化剤(C)が、メラミン樹脂又はブロック化ポリイソシアネート化合物である請求項1に記載の水性塗料組成物。
- 水分散性アクリル重合体粒子(A)、水酸基含有樹脂(B)及び硬化剤(C)の合計樹脂固形分を基準にして、固形分として、水分散性アクリル重合体粒子(A)を1〜80質量%、水酸基含有樹脂(B)を1〜90質量%、そして硬化剤(C)を5〜60質量%の範囲内で含有する請求項1に記載の水性塗料組成物。
- 被塗物に、カチオン電着塗料(a)を塗装し加熱硬化させ、次いで中塗塗料(b)を塗装し加熱硬化させた後、上塗塗料(c)を塗装し硬化させることを含んでなる複層塗膜形成方法において、中塗塗料(b)及び/又は上塗塗料(c)として、請求項1〜12のいずれかに記載の水性塗料組成物を塗装することを特徴とする複層塗膜形成方法。
- 請求項1〜12のいずれかに記載の水性塗料組成物が塗装された物品。
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Also Published As
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US20100093914A1 (en) | 2010-04-15 |
WO2008123387A3 (en) | 2009-05-14 |
GB2460564B (en) | 2012-02-01 |
JP5491865B2 (ja) | 2014-05-14 |
US8299163B2 (en) | 2012-10-30 |
GB0916342D0 (en) | 2009-10-28 |
CN101636457B (zh) | 2012-07-25 |
GB2460564A (en) | 2009-12-09 |
CN101636457A (zh) | 2010-01-27 |
WO2008123387A2 (en) | 2008-10-16 |
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