JP2010502549A - 貴金属製ガラス供給システムのための溶射耐火性酸化物コーティング - Google Patents
貴金属製ガラス供給システムのための溶射耐火性酸化物コーティング Download PDFInfo
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- JP2010502549A JP2010502549A JP2009526716A JP2009526716A JP2010502549A JP 2010502549 A JP2010502549 A JP 2010502549A JP 2009526716 A JP2009526716 A JP 2009526716A JP 2009526716 A JP2009526716 A JP 2009526716A JP 2010502549 A JP2010502549 A JP 2010502549A
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- JP
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- Prior art keywords
- noble metal
- supply system
- refractory oxide
- glass supply
- metal glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011521 glass Substances 0.000 title claims abstract description 58
- 239000007921 spray Substances 0.000 title abstract description 12
- 238000000576 coating method Methods 0.000 title description 21
- 239000011248 coating agent Substances 0.000 title description 19
- 239000010970 precious metal Substances 0.000 title description 6
- 229910000510 noble metal Inorganic materials 0.000 claims abstract description 64
- 238000000034 method Methods 0.000 claims abstract description 54
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 53
- 230000003647 oxidation Effects 0.000 claims abstract description 30
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 20
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000008569 process Effects 0.000 claims abstract description 14
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 14
- 238000005507 spraying Methods 0.000 claims description 9
- 238000007751 thermal spraying Methods 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000010285 flame spraying Methods 0.000 claims description 6
- 229910002078 fully stabilized zirconia Inorganic materials 0.000 claims description 6
- 239000002360 explosive Substances 0.000 claims description 4
- 238000007750 plasma spraying Methods 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 18
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 16
- 239000000203 mixture Substances 0.000 description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 229910052697 platinum Inorganic materials 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 239000000956 alloy Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000007749 high velocity oxygen fuel spraying Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000011253 protective coating Substances 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- -1 HVOF Substances 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005816 glass manufacturing process Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 238000000879 optical micrograph Methods 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/42—Details of construction of furnace walls, e.g. to prevent corrosion; Use of materials for furnace walls
- C03B5/43—Use of materials for furnace walls, e.g. fire-bricks
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/02—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating
- C03B5/027—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating by passing an electric current between electrodes immersed in the glass bath, i.e. by direct resistance heating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/42—Details of construction of furnace walls, e.g. to prevent corrosion; Use of materials for furnace walls
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
- C23C4/11—Oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Coating By Spraying Or Casting (AREA)
- Joining Of Glass To Other Materials (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
Description
未被覆のPt−20Rh供給システム材料、フレーム溶射「Rokide」被覆、および2つの異なるコーティング厚のプラズマ溶射ジルコニア(PSZ)を用いて、1670℃での40日後の酸化速度を比較した。その比較の結果が、以下の表1に示されている。図1も参照のこと。
Claims (10)
- 貴金属製ガラス供給システムの酸化を減少させる方法であって、溶射プロセスによって、前記貴金属製ガラス供給システムの外面に接触して、耐火性酸化物を含む材料を十分な量だけ施し、それによって、該貴金属製ガラス供給システムの酸化を減少させる工程を有してなり、ただし、フレーム溶射されたアルミナを含む耐火性酸化物は含まないことを特徴とする方法。
- 前記溶射プロセスがプラズマ溶射であることを特徴とする請求項1記載の方法。
- 前記耐火性酸化物がジルコニアを含むことを特徴とする請求項2記載の方法。
- 前記耐火性酸化物がアルミナを含むことを特徴とする請求項2記載の方法。
- 前記溶射プロセスがフレーム溶射であり、前記耐火性酸化物がジルコニアを含むことを特徴とする請求項1記載の方法。
- 前記溶射プロセスが高速フレーム溶射または爆発溶射であることを特徴とする請求項1記載の方法。
- 前記耐火性酸化物がジルコニアを含むことを特徴とする請求項6記載の方法。
- 前記ジルコニアが、完全安定化ジルコニアであり、Ca化合物により安定化されていることを特徴とする請求項3、5または7記載の方法。
- 前記ジルコニアが、完全安定化ジルコニアであり、Mgおよび/またはY化合物により安定化されていることを特徴とする請求項3、5または7記載の方法。
- 貴金属製ガラス供給システムの酸化を減少させる方法であって、溶射プロセスによって、前記貴金属製ガラス供給システムの外面に接触して、MgO、TiO2、またはZrO2を含む耐火性酸化物を含む材料を十分な量だけ施し、それによって、該貴金属製ガラス供給システムの酸化を減少させる工程を有してなる方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/513,869 US20080057275A1 (en) | 2006-08-31 | 2006-08-31 | Method and apparatus for minimizing oxidation pitting of refractory metal vessels |
PCT/US2007/019080 WO2008027480A2 (en) | 2006-08-31 | 2007-08-30 | Thermally sprayed refractory oxide coating for precious metal glass delivery systems |
Publications (1)
Publication Number | Publication Date |
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JP2010502549A true JP2010502549A (ja) | 2010-01-28 |
Family
ID=39136591
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009526717A Pending JP2010502550A (ja) | 2006-08-31 | 2007-08-30 | 耐熱金属槽の酸化孔食を最少化するための方法および装置 |
JP2009526716A Pending JP2010502549A (ja) | 2006-08-31 | 2007-08-30 | 貴金属製ガラス供給システムのための溶射耐火性酸化物コーティング |
JP2013014517A Abandoned JP2013100228A (ja) | 2006-08-31 | 2013-01-29 | 耐熱金属槽の酸化孔食を最少化するための方法および装置 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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JP2009526717A Pending JP2010502550A (ja) | 2006-08-31 | 2007-08-30 | 耐熱金属槽の酸化孔食を最少化するための方法および装置 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013014517A Abandoned JP2013100228A (ja) | 2006-08-31 | 2013-01-29 | 耐熱金属槽の酸化孔食を最少化するための方法および装置 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20080057275A1 (ja) |
JP (3) | JP2010502550A (ja) |
KR (2) | KR20090052887A (ja) |
CN (2) | CN101668875B (ja) |
TW (2) | TWI359117B (ja) |
WO (2) | WO2008027482A2 (ja) |
Cited By (4)
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JP2012132071A (ja) * | 2010-12-22 | 2012-07-12 | Tanaka Kikinzoku Kogyo Kk | 高温装置の揮発損失防止方法 |
JP2012184147A (ja) * | 2011-03-08 | 2012-09-27 | Nippon Electric Glass Co Ltd | ガラス製造用容器 |
US8375748B2 (en) | 2009-08-26 | 2013-02-19 | Nippon Electric Glass Co., Ltd. | Glass manufacturing container, glass manufacturing apparatus with the same and glass manufacturing method using glass manufacturing apparatus |
JP2014084253A (ja) * | 2012-10-24 | 2014-05-12 | Avanstrate Inc | ガラス板製造装置、およびこの装置を用いたガラス板の製造方法 |
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US8256951B2 (en) | 2006-12-21 | 2012-09-04 | Corning Incorporated | Stirrers for minimizing erosion of refractory metal vessels in a glass making system |
WO2010024940A2 (en) * | 2008-08-29 | 2010-03-04 | Corning Incorporated | Protective coating and method |
US20100126225A1 (en) * | 2008-11-25 | 2010-05-27 | Josh Ding | Method for homogenizing a glass melt |
JP5655425B2 (ja) * | 2009-08-26 | 2015-01-21 | 日本電気硝子株式会社 | ガラス製造用容器、それを備えるガラス製造装置及びそれを用いたガラスの製造方法 |
TW201210967A (en) * | 2010-06-29 | 2012-03-16 | Avanstrate Inc | Production device of glass panel and production method using the same |
US10421681B2 (en) * | 2010-07-12 | 2019-09-24 | Corning Incorporated | Alumina isopipes for use with tin-containing glasses |
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WO2012017963A1 (ja) * | 2010-08-04 | 2012-02-09 | 旭硝子株式会社 | 溶融ガラスの導管構造とそれを備えた減圧脱泡装置および溶融ガラスの減圧脱泡方法とガラス製品の製造方法 |
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WO2012133107A1 (ja) * | 2011-03-28 | 2012-10-04 | 旭硝子株式会社 | 溶融ガラス保持用耐火物、および、溶融ガラス保持用耐火物を用いたガラス製造装置、ならびに、該ガラス製造装置を用いたガラス製造方法 |
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- 2007-08-30 TW TW96132350A patent/TWI363810B/zh not_active IP Right Cessation
- 2007-08-30 KR KR1020097006559A patent/KR20090052887A/ko active IP Right Grant
- 2007-08-30 JP JP2009526717A patent/JP2010502550A/ja active Pending
- 2007-08-30 WO PCT/US2007/019080 patent/WO2008027480A2/en active Application Filing
- 2007-08-30 JP JP2009526716A patent/JP2010502549A/ja active Pending
- 2007-08-30 CN CN2007800363253A patent/CN101668875B/zh not_active Expired - Fee Related
- 2007-08-30 KR KR1020097006177A patent/KR20090043597A/ko not_active Application Discontinuation
- 2007-08-30 CN CN2007800323896A patent/CN101511743B/zh not_active Expired - Fee Related
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2013
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US8375748B2 (en) | 2009-08-26 | 2013-02-19 | Nippon Electric Glass Co., Ltd. | Glass manufacturing container, glass manufacturing apparatus with the same and glass manufacturing method using glass manufacturing apparatus |
JP2012132071A (ja) * | 2010-12-22 | 2012-07-12 | Tanaka Kikinzoku Kogyo Kk | 高温装置の揮発損失防止方法 |
JP2012184147A (ja) * | 2011-03-08 | 2012-09-27 | Nippon Electric Glass Co Ltd | ガラス製造用容器 |
JP2014084253A (ja) * | 2012-10-24 | 2014-05-12 | Avanstrate Inc | ガラス板製造装置、およびこの装置を用いたガラス板の製造方法 |
Also Published As
Publication number | Publication date |
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WO2008027482A3 (en) | 2008-05-08 |
CN101511743A (zh) | 2009-08-19 |
KR20090052887A (ko) | 2009-05-26 |
TWI359117B (en) | 2012-03-01 |
CN101668875A (zh) | 2010-03-10 |
CN101668875B (zh) | 2011-11-16 |
WO2008027480A2 (en) | 2008-03-06 |
WO2008027482A2 (en) | 2008-03-06 |
JP2013100228A (ja) | 2013-05-23 |
WO2008027480A3 (en) | 2009-10-22 |
KR20090043597A (ko) | 2009-05-06 |
TWI363810B (en) | 2012-05-11 |
CN101511743B (zh) | 2012-06-13 |
TW200902457A (en) | 2009-01-16 |
US20080057275A1 (en) | 2008-03-06 |
TW200835814A (en) | 2008-09-01 |
JP2010502550A (ja) | 2010-01-28 |
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