JP2010254773A - 電子線硬化型または紫外線硬化型インキ用バインダー - Google Patents
電子線硬化型または紫外線硬化型インキ用バインダー Download PDFInfo
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- JP2010254773A JP2010254773A JP2009104711A JP2009104711A JP2010254773A JP 2010254773 A JP2010254773 A JP 2010254773A JP 2009104711 A JP2009104711 A JP 2009104711A JP 2009104711 A JP2009104711 A JP 2009104711A JP 2010254773 A JP2010254773 A JP 2010254773A
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Abstract
【解決手段】分子内に水酸基とアルカリ可溶性基とを両有する化合物(a)と、分子内に水酸基とビニル基とを両有する化合物(b)と、ポリカーボネート系ポリオール(c)と、ポリイソシアネート(d)とを反応させて得られるウレタン系樹脂を被膜形成成分として含有する光硬化型インキ用バインダー。
【選択図】なし
Description
(5)ポリエーテルポリオール、例えば、アルキレンオキサイド(エチレンオキサイド、プロピレンオキサイド、ブチレンオキサイドなど)および/または複素環式エーテル(テトラヒドロフランなど)を重合または共重合して得られるものが例示され、具体的にはポリエチレングリコール、ポリプロピレングリコール、ポリエチレングリコール−ポリテトラメチレングリコール(ブロックまたはランダム)、ポリテトラメチレンエーテルグリコールおよびポリヘキサメチレングリコールなど、
(8)ポリオレフィンポリオール、例えば、ポリブタジエングリコールおよびポリイソプレングリコール、または、その水素化物など、
(9)ポリメタクリレートジオール、例えば、α,ω−ポリメチルメタクリレートジオールおよびα,ω−ポリブチルメタクリレートジオールなどが挙げられる。
攪拌機、還流冷却管、温度計、窒素吹き込み管およびマンホールを備えた反応容器を窒素ガスで置換した後、アルカリ可溶基(アニオン性基)含有化合物(化合物a)、不飽和基含有化合物(化合物b)、カーボネートジオール(化合物c)、およびシクロヘキサノンを所定量加え、均一に溶解させ、溶液濃度を調節した。続いてポリイソシアネート化合物(化合物d)を所定量(NCO/OH=1.0)の当量比で加えて80℃で反応を行い、NCO基がなくなるまで反応を行った。上記ポリウレタン系樹脂の原料組成配合を表1に示す。
化合物a:
・a−1:ジメチロールブタン酸
・a−2:ジメチロールプロパン酸
・GMAE:グリセリンモノアリルエーテル(ダイソー社製)
・GMA:グリセリンモノメタクリレート(日本油脂社製)
化合物c:
・PCD(1):プラクセルCD220、ポリカーボネートジオール(ダイセル化学工業社製、平均分子量2,000)
・PCD(2):PCDL T4672、ポリカーボネートジオール(旭化成ケミカルズ社製、平均分子量2,000)
・PCD(3):PCDL T5652、ポリカーボネートジオール(旭化成ケミカルズ社製、平均分子量2,000)
・HDI:ヘキサメチレンジイソシアネート
・H12MDI:水素添加MDI(ノンホスゲン製法)
・IPDI:イソホロンジイソシアネート(ノンホスゲン製法)
・重合開始剤;イルガキュアー184(チバ・スペシャリティ・ケミカルズ社製)
・オリゴマー2:変性ビスフェノールA・エポキシアクリレート、2官能、Tg=60
1.スクリーン印刷機にて全面に直接塗工(固型分厚み40μm)した後、
2.プレキュア(80℃、20分間)し、ネガフィルムを通して露光(200mJ/cm2)し、
3.アルカリ現像液(Na2CO3、1質量%水溶液、30℃、60秒)にて未硬化部分を洗浄し、
4.ポストキュア(150℃前後、60分間)しソルダーレジストを形成させる。
<現像性>
前記したNo3工程でのアルカリ現像液(Na2CO3、1質量%水溶液、スプレー圧0.2MPa、30℃、60秒)にて未硬化部分の洗浄性を確認した。
○:上記条件で合格。
×:60秒以上を必要とする。
前記試験基板に、フローはんだ(260℃のはんだ槽に10秒間)浸漬後、セロハン粘着テープによる密着性試験を行い硬化被膜の状態を確認した。
○:硬化被膜に変化がなかったもの。
×:硬化被膜が剥離したもの。
ポリイミドフィルム(厚さ25μm)に、上記実施例1〜4および比較例1で作製したソルダーレジストインキを塗布(固型分厚み;25μm)し、露光(200mJ/cm2)したものを、7cm×7cmの試験片に作製し、室温で24時間放置した後の反りを確認した。
○:試験片に反りが見られない。
×:試験片に反りが見られる。
上記試験で作製した試験片を、硬化被膜が外側になるように180°折り曲げ、折り曲げ部を顕微鏡で観察した。
○:硬化被膜にクラック発生がないもの。
×:硬化被膜にクラック発生があるもの。
上記試験で作製した試験片を、−65℃/30分間⇔125℃/30分間を1サイクルとして、100サイクル行った際の外観変化を観察した。
○:外観に変化がない。
×:外観に異常がある。
上記試験で作製した試験片を、塩酸溶液に25℃/5分間浸漬した後の外観変化を観察した。
○:外観に変化がない。
×:外観に異常がある。
Claims (6)
- 分子内に少なくとも1個の活性水素含有基と少なくとも1個のアルカリ可溶性基(アニオン性基)とを両有する化合物(a)と、分子内に少なくとも1個の活性水素含有基とビニル基(不飽和結合基)とを両有する化合物(b)と、ポリカーボネート系ポリオール(c)と、ポリイソシアネート(d)とを、化合物(a)〜(c)の合計の全活性水素と化合物(d)のイソシアネート基とをNCO/OH=0.8〜1.1モルで反応させて得られる、同一分子内に少なくともアルカリ可溶性基およびビニル基を有するウレタン系樹脂を被膜形成成分として含有することを特徴とする電子線硬化型または紫外線硬化型インキ用バインダー。
- 前記化合物(a)が、ジメチロールブタン酸および/またはジメチロールプロパン酸である請求項1に記載の電子線硬化型または紫外線硬化型インキ用バインダー。
- 前記化合物(a)の使用量が0.01〜30質量%、前記化合物(b)の使用量が0.01〜30質量%、前記化合物(c)の使用量が10〜80質量%、前記化合物(d)の使用量が、化合物(a)〜(c)の合計の全活性水素と化合物(d)のイソシアネート基との当量比が0.8〜1.1になる量であり、数平均分子量が2,000〜500,000である請求項1に記載の電子線硬化型または紫外線硬化型インキ用バインダー。
- さらに電子線硬化性、紫外線硬化性または熱硬化性単官能モノマー、多官能モノマーまたはオリゴマーを含む請求項1に記載の電子線硬化型または紫外線硬化型インキ用バインダー。
- 請求項1に記載の電子線硬化型または紫外線硬化型インキ用バインダーの硬化物。
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KR20140018311A (ko) * | 2011-03-25 | 2014-02-12 | 후지필름 가부시키가이샤 | 감광성 조성물, 감광성 필름, 감광성 적층체, 영구 패턴 형성 방법, 및 프린트 기판 |
WO2012132580A1 (ja) * | 2011-03-25 | 2012-10-04 | 富士フイルム株式会社 | 感光性組成物、感光性フィルム、感光性積層体、永久パターン形成方法、及びプリント基板 |
JP2012215804A (ja) * | 2011-03-25 | 2012-11-08 | Fujifilm Corp | 感光性組成物、感光性フィルム、感光性積層体、永久パターン形成方法、及びプリント基板 |
KR101660574B1 (ko) * | 2011-03-25 | 2016-09-27 | 후지필름 가부시키가이샤 | 감광성 조성물, 감광성 필름, 감광성 적층체, 영구 패턴 형성 방법, 및 프린트 기판 |
CN103403619A (zh) * | 2011-03-25 | 2013-11-20 | 富士胶片株式会社 | 感光性组成物、感光性膜、感光性积层体、永久图案形成方法及印刷基板 |
WO2012132741A1 (ja) * | 2011-03-30 | 2012-10-04 | 富士フイルム株式会社 | 感光性組成物、感光性フィルム、感光性積層体、永久パターン形成方法、及びプリント基板 |
JP2013020047A (ja) * | 2011-07-11 | 2013-01-31 | Fujifilm Corp | 感光性組成物 |
WO2013008631A1 (ja) * | 2011-07-11 | 2013-01-17 | 富士フイルム株式会社 | 感光性組成物 |
CN114591648A (zh) * | 2020-12-07 | 2022-06-07 | 深圳光启高端装备技术研发有限公司 | 油墨组合物、油墨涂层及在印刷领域中的应用 |
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