JP2009543890A - ガス化システム及びその使用法 - Google Patents
ガス化システム及びその使用法 Download PDFInfo
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- JP2009543890A JP2009543890A JP2009508305A JP2009508305A JP2009543890A JP 2009543890 A JP2009543890 A JP 2009543890A JP 2009508305 A JP2009508305 A JP 2009508305A JP 2009508305 A JP2009508305 A JP 2009508305A JP 2009543890 A JP2009543890 A JP 2009543890A
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- 238000002309 gasification Methods 0.000 title claims abstract description 81
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 94
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 94
- 238000001816 cooling Methods 0.000 claims abstract description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 27
- 239000002893 slag Substances 0.000 claims abstract description 18
- 239000012530 fluid Substances 0.000 claims abstract description 8
- 238000004891 communication Methods 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 144
- 239000003595 mist Substances 0.000 claims description 34
- 238000002347 injection Methods 0.000 claims description 20
- 239000007924 injection Substances 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
- 239000001301 oxygen Substances 0.000 claims description 17
- 229910052760 oxygen Inorganic materials 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 10
- 238000002485 combustion reaction Methods 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 230000036961 partial effect Effects 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000002826 coolant Substances 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 239000003575 carbonaceous material Substances 0.000 claims description 2
- 239000012528 membrane Substances 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 238000010791 quenching Methods 0.000 description 13
- 230000000171 quenching effect Effects 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000003245 coal Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 238000000151 deposition Methods 0.000 description 3
- 239000003077 lignite Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 239000010866 blackwater Substances 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000002663 nebulization Methods 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000003476 subbituminous coal Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/485—Entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/78—High-pressure apparatus
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/16—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/09—Mechanical details of gasifiers not otherwise provided for, e.g. sealing means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Industrial Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
【選択図】図2
Description
ガス化反応器と合成ガス冷却容器とを備えたガス化システムであって、ガス化反応器が、
- 大気圧より高い圧力を維持するための圧力シェルと;
- 圧力シェルの下部に配置されたスラグ槽と;
- 圧力シェルの内部に配置されガス化室を形成するガス化装置壁と、
を備え、運転中はガス化室において合成ガスを生成でき、ガス化装置壁の開放下部がスラグ槽に流体連通しており、ガス化装置壁の開放上端部が連結導管を介して合成ガス冷却容器に流体連通しており;
合成ガス冷却容器が高温合成ガスの入口と、冷却された合成ガスの出口と、使用時に液体の水をガス化反応器において生成された高温合成ガスと直接接触させる手段とを備える、前記ガス化システム。
本発明のガス化反応器又は本発明のシステムにおいて固体炭素系原料の部分酸化により一酸化炭素と水素とを含んだ混合物を製造するため、本発明のガス化反応器を使用するのが適している。このようなプロセスでは、ガス化室内で酸素含有ガスを用いて固体炭素系原料を部分酸化させ、温度が1200〜1800℃、好ましくは1400〜1800℃の上向きに移動するガス混合物を形成する。好ましくは、この混合物は冷却工程において冷却する。別の冷却容器において、このガスを好ましくは500℃未満に更に冷却する。
「ミスト」なる用語は、液体が小さな液滴の形にて注入されることを意味する。液体として水が使用される場合には、好ましくは80%より多くの水、より好ましくは90%より多くの水が液体状態にある。
高温の合成ガスの急冷を促進するために、30〜90m/s、好ましくは40〜60m/sの速度でミストを注入させるのが好ましい。
以下、限定するものではないが例として添付の図面を参照して本発明を詳しく説明する。以下で用いられる同じ参照番号は同様の構造要素を示す。
2 ガス化反応器
3 管路
4 管路
5 連結導管
9 冷却容器
11 湿性ガススクラバー
13 シフトコンバータ
15 熱交換器
19 間接熱交換器
43 ガス化反応器
44 冷却容器
45 移送ダクト
46 液体の水の添加手段
47 ガス化室
48 ミストの注入手段
50 バーナー
51 連結導管
53 冷却容器
54 ディップ管
55 水槽
56 環状空間
58 ポンプ
Claims (18)
- ガス化反応器と合成ガス冷却容器とを備えたガス化システムであって、ガス化反応器が、
- 大気圧より高い圧力を維持するための圧力シェルと;
- 圧力シェルの下部に配置されたスラグ槽と;
- 圧力シェルの内部に配置されガス化室を形成するガス化装置壁と、
を備え、運転中はガス化室において合成ガスを生成でき、ガス化装置壁の開放下部がスラグ槽に流体連通しており、ガス化装置壁の開放上端部が連結導管を介して合成ガス冷却容器に流体連通しており;
合成ガス冷却容器が高温合成ガスの入口と、冷却された合成ガスの出口と、使用時に液体の水をガス化反応器において生成された高温合成ガスと直接接触させる手段とを備える、前記ガス化システム。 - 合成ガス冷却容器は、使用時に合成ガスの実質的に下向きの流路が生じるように、上端部にて高温合成ガスを受け入れるための入口と、下端部にて冷却された合成ガス用の出口とを有し、また、水のミストを注入する注入手段が前記下向きの流路中に設けられる、請求項1に記載のシステム。
- 合成ガス冷却容器が、上端部にて高温合成ガスを受け入れるための開口部と、冷却された合成ガスの出口とを有し、前記入口と出口との間に合成ガスの流路を形成し、また、前記合成ガスの流路中に水槽が設けられる、請求項1又は2に記載のシステム。
- 液体又はガス状の冷却媒体を合成ガスに注入するための注入手段が前記連結導管中に設けられる、請求項1〜3のいずれか一項に記載のシステム。
- 前記注入手段が、液体冷却媒体を水滴のミストの形にて注入するための注入手段である、請求項4に記載のシステム。
- 燃焼室の壁と前記連結導管の壁が冷却手段を備える、請求項1〜5のいずれか一項に記載のシステム。
- 前記冷却手段が水冷管の構造を有し、好ましくはメンブレンウォールの形をなしている、請求項6に記載のシステム。
- 前記ガス化室が1対又は複数対の部分酸化バーナーを備え、前記バーナーが固体炭素系原料の供給手段と酸素含有ガスの供給手段とを備える、請求項1〜7のいずれか一項に記載のシステム。
- 冷却された合成ガスの前記出口が、湿性ガススクラバーの入口に流体連結されている、請求項3〜8のいずれか一項に記載のシステム。
- 湿性ガススクラバーのガス出口が水シフトコンバータの入口に流体連結されている、請求項9に記載のシステム。
- 一酸化炭素と水素とを含む混合物を請求項1〜10のいずれか一項に記載のガス化システムにおいて固体炭素系原料の部分酸化によって製造する方法であって、ガス化室内において、固体炭素系原料を酸素含有ガスにより部分酸化させ、温度が1200〜1800℃で圧力が20〜100バールの上向きに移動するガス混合物を形成し、ガス又は液体状の冷却媒体を注入することにより連結導管中の前記ガス混合物を500〜900℃の温度に冷却し、次に合成ガス冷却容器中のガスを水と接触させることにより500℃未満に更に冷却する、前記方法。
- 水滴のミストをガス流中に注入することにより、連結導管及び/又は合成ガス冷却容器における前記冷却を実行する、請求項11に記載の方法。
- 注入される水ミストの温度が高温合成ガスの圧力での水の泡立ち点より最大で50℃低い、請求項12に記載の方法。
- 前記ミストが50〜200μmの直径を有する液滴からなる、請求項12又は13に記載の方法。
- 前記ミストを30〜100m/sの速度で注入する、請求項12〜14のいずれか一項に記載の方法。
- 前記ミストを40〜60m/sの速度で注入する、請求項15に記載の方法。
- 生の合成ガスの圧力より5〜20バール高い注入圧力の霧化ガスを用いて、前記ミストを注入する、請求項12〜16のいずれか一項に記載の方法。
- 前記連結導管又は冷却容器の縦軸に垂直な平面に対して30〜60°の角度で前記連結導管又は冷却容器の壁から高温合成ガスの流れの方向に前記ミストを注入する、請求項12〜17のいずれか一項に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EPPCT/EP2006/061951 | 2006-05-01 | ||
PCT/EP2006/061951 WO2006117355A1 (en) | 2005-05-02 | 2006-05-01 | Method and system for producing synthesis gas |
EP06123313.6 | 2006-11-01 | ||
EP06123313 | 2006-11-01 | ||
PCT/EP2007/053869 WO2007125046A1 (en) | 2006-05-01 | 2007-04-27 | Gasification system and its use |
Publications (2)
Publication Number | Publication Date |
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JP2009543890A true JP2009543890A (ja) | 2009-12-10 |
JP5559532B2 JP5559532B2 (ja) | 2014-07-23 |
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- 2007-04-27 EP EP07728328A patent/EP2013317A1/en not_active Withdrawn
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2012531499A (ja) * | 2009-06-30 | 2012-12-10 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 水素に富む気体混合物を製造する方法 |
KR20140111308A (ko) * | 2011-12-29 | 2014-09-18 | 우한 카이디 엔지니어링 테크놀로지 리서치 인스티튜트 코오퍼레이션 엘티디. | 바이오매스 합성가스 냉각 및 세정 방법 및 그 시스템 |
JP2015503642A (ja) * | 2011-12-29 | 2015-02-02 | 武▲漢凱▼迪工程技▲術▼研究▲総▼院有限公司 | バイオマス合成ガスの冷却・洗浄方法およびそのシステム |
JP2015503640A (ja) * | 2011-12-29 | 2015-02-02 | 武▲漢凱▼迪工程技▲術▼研究▲総▼院有限公司 | 油製造のための負圧下でのバイオマス合成ガス精製方法およびそのシステム構造 |
JP2015506390A (ja) * | 2011-12-29 | 2015-03-02 | 武▲漢凱▼迪工程技▲術▼研究▲総▼院有限公司 | 油製造のための正圧下でのバイオマス合成ガス精製方法およびそのシステム構造 |
KR101609815B1 (ko) * | 2011-12-29 | 2016-04-06 | 우한 카이디 엔지니어링 테크놀로지 리서치 인스티튜트 코오퍼레이션 엘티디. | 오일 제조용 부압하의 바이오매스 합성가스 정화 방법 및 그 구성 시스템 |
KR101609817B1 (ko) * | 2011-12-29 | 2016-04-06 | 우한 카이디 엔지니어링 테크놀로지 리서치 인스티튜트 코오퍼레이션 엘티디. | 오일 제조용 정압하의 바이오매스 합성가스 정화 방법 및 그 구성 시스템 |
KR101616527B1 (ko) * | 2011-12-29 | 2016-04-28 | 우한 카이디 엔지니어링 테크놀로지 리서치 인스티튜트 코오퍼레이션 엘티디. | 바이오매스 합성가스 냉각 및 세정 방법 및 그 시스템 |
Also Published As
Publication number | Publication date |
---|---|
EP2013317A1 (en) | 2009-01-14 |
CN101432401B (zh) | 2012-11-14 |
KR20090012255A (ko) | 2009-02-02 |
KR101367691B1 (ko) | 2014-02-27 |
CA2650604C (en) | 2015-04-07 |
WO2007125046A1 (en) | 2007-11-08 |
AU2007245731B2 (en) | 2010-08-12 |
CN101432400A (zh) | 2009-05-13 |
JP5559532B2 (ja) | 2014-07-23 |
CA2650604A1 (en) | 2007-11-08 |
CN101432401A (zh) | 2009-05-13 |
BRPI0710627A2 (pt) | 2011-08-23 |
RU2441900C2 (ru) | 2012-02-10 |
CN101432400B (zh) | 2012-11-14 |
AU2007245731A1 (en) | 2007-11-08 |
RU2008147138A (ru) | 2010-06-10 |
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