JP2006307160A - 重油回収のための煙道ガス噴射 - Google Patents
重油回収のための煙道ガス噴射 Download PDFInfo
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 239000003546 flue gas Substances 0.000 title claims abstract description 53
- 239000000295 fuel oil Substances 0.000 title claims description 40
- 239000010426 asphalt Substances 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 48
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000003345 natural gas Substances 0.000 claims abstract description 23
- 238000011084 recovery Methods 0.000 claims abstract description 15
- 239000000446 fuel Substances 0.000 claims description 48
- 230000015572 biosynthetic process Effects 0.000 claims description 41
- 238000005755 formation reaction Methods 0.000 claims description 39
- 239000007789 gas Substances 0.000 claims description 32
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 239000001569 carbon dioxide Substances 0.000 claims description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- 239000005431 greenhouse gas Substances 0.000 claims description 7
- 239000006227 byproduct Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 5
- 239000000571 coke Substances 0.000 claims description 5
- 238000010977 unit operation Methods 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 239000002006 petroleum coke Substances 0.000 claims description 4
- 238000007906 compression Methods 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- -1 residue Substances 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims 2
- 229910052815 sulfur oxide Inorganic materials 0.000 claims 2
- 238000001816 cooling Methods 0.000 claims 1
- 239000010419 fine particle Substances 0.000 claims 1
- 239000002803 fossil fuel Substances 0.000 claims 1
- 238000010796 Steam-assisted gravity drainage Methods 0.000 abstract description 13
- 238000005516 engineering process Methods 0.000 abstract description 7
- 239000012530 fluid Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000006200 vaporizer Substances 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 8
- 238000012545 processing Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000008186 active pharmaceutical agent Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000010793 Steam injection (oil industry) Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004924 electrostatic deposition Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000010689 synthetic lubricating oil Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/166—Injecting a gaseous medium; Injecting a gaseous medium and a liquid medium
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/164—Injecting CO2 or carbonated water
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B41/00—Equipment or details not covered by groups E21B15/00 - E21B40/00
- E21B41/005—Waste disposal systems
- E21B41/0057—Disposal of a fluid by injection into a subterranean formation
- E21B41/0064—Carbon dioxide sequestration
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/166—Injecting a gaseous medium; Injecting a gaseous medium and a liquid medium
- E21B43/168—Injecting a gaseous medium
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/18—Repressuring or vacuum methods
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
- E21B43/2406—Steam assisted gravity drainage [SAGD]
- E21B43/2408—SAGD in combination with other methods
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B33/00—Steam-generation plants, e.g. comprising steam boilers of different types in mutual association
- F22B33/18—Combinations of steam boilers with other apparatus
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
- Y02P90/70—Combining sequestration of CO2 and exploitation of hydrocarbons by injecting CO2 or carbonated water in oil wells
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Abstract
【解決手段】ビチューメンを含む地下形成物からの天然ガス及びビチューメンの熱回収のための方法。この方法は一連の既存ではあるが、以前に組み合わせられていない技術を含む。SAGD回収運転で慣用的に使用された蒸気生成器からの改変された煙道ガスは生じた流体の回収を向上させるために形成物内に噴射される。天然ガス、ビチューメン等は更に処理される。煙道ガスの噴射は、さもなければ、天然ガスを使い尽くした時に減圧したようになる地下形成物を再加圧するように更に作用する。従って、環境及び経済的な利点はこの方法によって現実化される。
【選択図】図1
Description
i)中間重油
25°>°API>18°
100cPs>μ>10cPs,容器で可動という条件
ii)過剰重油
20°>°API>12°、熱又は水/溶剤氾濫のような容器刺激を含む生産向上技術が要求される。
10,000cPs>μ>100cPs、
iii)オイルサンド及びビチューメン
12°>°API>6°、採掘されるか又は熱刺激が要求される。
μ>10,000cPs、熱又は水/溶剤氾濫のような容器刺激を含む生産向上技術が要求される。
これらは、
i)有害な煙道ガスの効率的且つ環境上安全な処分;
ii)地下形成物からの改善されたガス回収;
iii)単位蒸気毎により多くのビチューメンを作り出すために向上された熱回収運転;
iv)GHG放射を減じるために離隔する二酸化炭素;
v)層の内の容積測定の置換;及び
vi)これらの特徴の何れかの組合せ、を含む。
14 煙道ガス処理ユニット
18 重油形成物
28 水処理ユニット
62 中央処理プラント
70 エマルジョン燃料ユニット
76 ビチューメン・アップグレーダ
260 圧縮器
560 ガスタービン
610 発電機
Claims (25)
- 重油及びビチューメンを含む地下形成物から重油及びビチューメン回収する方法であって、
燃料を供給する段階と、
前記地下形成物内に噴射するための煙道ガスを作り出す煙道ガス再循環サーキットで前記燃料を燃やす段階と、
前記重油及び前記ビチューメンを移動させるために前記煙道ガスを前記地下形成物内に噴射する段階と、を備える方法。 - 前記燃料は化石燃料である、請求項1に記載の方法。
- 前記燃料は、天然ガス、燃料油、重油、ビチューメン、残留物、エマルジョン燃料、多相の微細に霧化された残留物、アスファルテン、石油コークス、コークス及びこれらの組合せから成る群から選択される、請求項2に記載の方法。
- 前記燃料は酸素と空気を有する蒸気発生器で燃焼される、請求項1から請求項3までの何れか1項に記載の方法。
- 前記地下形成物内への噴射に先立つ前記煙道ガスを改変する段階を更に含む、請求項1から請求項4までの何れか1項に記載の方法。
- 煙道ガスを改変する前記段階の間に生成される副生成物ガスを除去することを含む、請求項5に記載の方法。
- 前記副生成物ガスは、水素、一酸化炭素、窒素、窒素酸化物、硫黄酸化物及び二酸化炭素の少なくとも1つを含む、請求項6に記載の方法。
- 微粒子灰を除去することを含む、請求項5から請求項7までの何れか1項に記載の方法。
- 前記煙道ガスを改変する前記段階は脱微粒子化、冷却、圧縮及び脱水を含むユニット運転を備える、請求項5から請求項8までの何れか1項に記載の方法。
- 改変された煙道ガスは前記地下形成物を加圧し、かつ天然ガスを前記地下形成物内で解放するために該地下形成物内に噴射される、請求項5から請求項9までの何れか1項に記載の方法。
- 重油は再加圧中に前記地下形成物から移動される、請求項10に記載の方法。
- アップグレード・ユニット運転で移動された前記重油を改変する段階を更に含む、請求項11に記載の方法。
- 前記アップグレード・ユニット運転は前記地下形成物から移動された油からの水除去を含む、請求項12に記載の方法。
- 除去された水の少なくとも一部は前記蒸気生成器内に再循環される、請求項13に記載の方法。
- アップグレードされた前記重油からの前記残留物の少なくとも一部は燃焼燃料として使用するための多相の微細に霧化された残留物に変換される、請求項12から請求項14までの何れか1項に記載の方法。
- 前記地下層の体積内のビチューメン上のガスを含む蒸気で支援された重力排出地下層の少なくとも1つ,及び地質的に近接した地下層から、ガス及びビチューメンを回収する方法であって、
改変された煙道ガスを作り出すために煙道ガス再循環サーキットを設ける段階と、
前記ビチューメン上に前記煙道ガスを移動させるために十分な圧力で前記体積内で部分変更された該煙道ガスを注入する段階と、
移動されたガス及びビチューメンを回収する段階と、
改変された前記煙道ガスの注入より以前の圧力に実質的に類似する圧力まで改変された前記煙道ガスを有する前記体積の圧力を再加圧及び維持する段階と、を備える方法。 - 移動された前記ガスは、前記ビチューメンと直に地質接触しない天然ガスを備える、
請求項16に記載の方法。 - 移動されたガスの体積を最大化するために改変された前記煙道ガスの成分を構成する段階を更に備える、請求項16または請求項17に記載の方法。
- 移動されたガス回収に引き続いて、改変された煙道ガス噴射がグリーン・ハウス・ガスGHGの更なる離隔のために元々の地質学的圧力に実質的に類似した圧力まで続けられる、請求項16から請求項18までの何れか1項に記載の方法。
- 改変された前記煙道ガスの成分を構成する前記段階は、過度の、化学量論的な及び副化学量論的から成る郡から選択された改変された煙道ガスの酸素濃度を維持することを含む、請求項18または請求項19に記載の方法。
- 改変された前記煙道ガスの前記成分は体積で0%〜79%の窒素を備える、請求項13に記載の方法。
- 改変された前記煙道ガスから副生成物ガスを生成する段階を更に含む、請求項13に記載の方法。
- 前記副生成物ガスは、水素、一酸化炭素、窒素酸化物、硫黄酸化物及び二酸化炭素の少なくとも1つを含む、請求項13に記載の方法。
- 前記煙道ガス再循環サーキットには、天然ガス、燃料油、重油、ビチューメン、残留物、真空残留物、エマルジョン燃料、多相の微細に霧化された残留アスファルテン、石油コークス、コークス及びこれらの組合せから成る群から選択された炭化水素燃料が供給される、請求項16から請求項23までの何れか1項に記載の方法。
- ガス及びビチューメンを前記地下形成物の容積内のビチューメン上のガスを含む蒸気支援重力排出形態の少なくとも1つから、かつ地質的に近接した形成物からガス及びビチューメンを回収する方法であって、
前記地下形成物内に噴射する蒸気を生成するための蒸気生成フェーズと、
前記地下形成物内に噴射する煙道ガスを改変するための煙道ガス再循環フェーズと、
前記ビチューメン上のガスを移動させ、かつ前記地下形成物の圧力を維持するか又は該地下形成物を再加圧するように改変された煙道ガスを前記地下形成物内に噴射するための噴射フェーズと、
生成され移動されたガス及び前記噴射フェーズから遊離した液体を処理するための処理フェーズと、を備える方法。
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BRPI0607657A2 (pt) | 2009-09-22 |
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CA2505449A1 (en) | 2006-02-07 |
MX2007013439A (es) | 2008-01-14 |
CN1932237A (zh) | 2007-03-21 |
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GB2425550B (en) | 2010-06-02 |
GB0602343D0 (en) | 2006-03-15 |
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NO20060582L (no) | 2006-10-30 |
EA200602090A1 (ru) | 2008-06-30 |
AU2006200466B2 (en) | 2010-02-18 |
WO2006113982A1 (en) | 2006-11-02 |
GB2425550A (en) | 2006-11-01 |
FR2885133B1 (fr) | 2010-12-31 |
NZ545119A (en) | 2007-09-28 |
EA013019B1 (ru) | 2010-02-26 |
CA2505449C (en) | 2007-03-13 |
DE102006005277A1 (de) | 2006-11-09 |
FR2885133A1 (fr) | 2006-11-03 |
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