JP2006282614A - 毛髪洗浄剤 - Google Patents
毛髪洗浄剤 Download PDFInfo
- Publication number
- JP2006282614A JP2006282614A JP2005106451A JP2005106451A JP2006282614A JP 2006282614 A JP2006282614 A JP 2006282614A JP 2005106451 A JP2005106451 A JP 2005106451A JP 2005106451 A JP2005106451 A JP 2005106451A JP 2006282614 A JP2006282614 A JP 2006282614A
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- JP
- Japan
- Prior art keywords
- weight
- hair
- acid
- group
- sulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 93
- 239000002453 shampoo Substances 0.000 title abstract description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 38
- 150000003839 salts Chemical class 0.000 claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 18
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 13
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 12
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 7
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims abstract description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 3
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 3
- 239000011734 sodium Substances 0.000 claims abstract description 3
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 3
- -1 alkylene carbonate Chemical compound 0.000 claims description 29
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 23
- 239000003599 detergent Substances 0.000 claims description 23
- 239000000194 fatty acid Substances 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000005406 washing Methods 0.000 claims description 16
- 125000003118 aryl group Chemical group 0.000 claims description 15
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 10
- 239000012459 cleaning agent Substances 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 150000007524 organic acids Chemical class 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
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- 239000002280 amphoteric surfactant Substances 0.000 claims description 4
- 150000002596 lactones Chemical class 0.000 claims description 4
- 150000003997 cyclic ketones Chemical class 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 3
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims description 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 230000037308 hair color Effects 0.000 abstract description 7
- 238000009825 accumulation Methods 0.000 abstract description 5
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- 238000011156 evaluation Methods 0.000 description 8
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 8
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- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 239000004166 Lanolin Substances 0.000 description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 7
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 7
- 229960003237 betaine Drugs 0.000 description 7
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- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 6
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 239000001630 malic acid Substances 0.000 description 6
- 235000011090 malic acid Nutrition 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 5
- 239000003093 cationic surfactant Substances 0.000 description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 5
- 238000005342 ion exchange Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 5
- 239000011049 pearl Substances 0.000 description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- OPVLOHUACNWTQT-UHFFFAOYSA-N azane;2-dodecoxyethyl hydrogen sulfate Chemical compound N.CCCCCCCCCCCCOCCOS(O)(=O)=O OPVLOHUACNWTQT-UHFFFAOYSA-N 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 3
- WGVGLSURTKMQQC-UHFFFAOYSA-N 3-aminopropyl-ethyl-dimethylazanium Chemical compound CC[N+](C)(C)CCCN WGVGLSURTKMQQC-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 3
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229920006322 acrylamide copolymer Polymers 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
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- 239000004310 lactic acid Substances 0.000 description 3
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- 229940043348 myristyl alcohol Drugs 0.000 description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 3
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- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229940044654 phenolsulfonic acid Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- 235000019204 saccharin Nutrition 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 229940096501 sodium cocoamphoacetate Drugs 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000020712 soy bean extract Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- NRLLZRJXDKUVHM-UHFFFAOYSA-N tridecyl 7-methyloctanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCCCCC(C)C NRLLZRJXDKUVHM-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
【解決手段】成分(A)〜(D)を含有しpH2以上6未満である毛髪洗浄剤。
(A) 一般式(1)
R1-O-(C2H4O)n-SO3M (1)
〔R1はC10-18のアルキル又はアルケニル、nは0又は正の整数、Mはナトリウム又はアンモニウムを示す。〕
で表され、n=0が30〜45重量%、n=1が18〜27重量%、n=2が10〜20重量%、及びn=3以上が残余であり、かつn=0〜2の合計が全硫酸塩の70重量%以上である硫酸塩型界面活性剤
(B) C6-18疎水性スルホン酸又はその塩
(C) ヒドロキシカルボン酸、ジカルボン酸又は芳香族カルボン酸
(D) 有機溶剤
【選択図】なし
Description
(A) 次の一般式(1)
R1-O-(C2H4O)n-SO3M (1)
〔式中、R1は直鎖又は分岐鎖の炭素数10〜18のアルキル基又はアルケニル基を示し、nは0又は正の整数を示し、Mはナトリウム又はアンモニウムを示す。〕
で表される硫酸塩であって、n=0の硫酸塩 30〜45重量%、n=1の硫酸塩 18〜27重量%、n=2の硫酸塩 10〜20重量%、及び残余はn=3以上の硫酸塩から構成され、かつn=0〜2である硫酸塩の合計が全硫酸塩の70重量%以上である硫酸塩型界面活性剤
(B) 炭素数6〜18の疎水性スルホン酸又はその塩
(C) ヒドロキシカルボン酸、ジカルボン酸及び芳香族カルボン酸から選ばれる有機酸
(D) 次の(d1)〜(d5)から選ばれる有機溶剤
(d1) 一般式(2)で表される化合物
(d2) 窒素原子に炭素数1〜18のアルキル基が結合したN-アルキルピロリドン
(d3) 炭素数2〜4のアルキレンカーボネート
(d4) 分子量200〜5000のポリプロピレングリコール
(d5) 一般式(3)、(4)又は(5)で表されるラクトン又は環状ケトン
R1-O-(C2H4O)n-SO3M (1)
で表される。本発明においては、エチレンオキシド付加モル数が特定の分布を有し、付加モル数の少ない硫酸塩を多く含む硫酸塩型界面活性剤、すなわち、n=0が30〜45重量%、n=1が18〜27重量%、n=2が10〜20重量%、及び残余はn=3以上の硫酸塩から構成される分布を有し、かつn=0〜2の硫酸塩の合計が全硫酸塩中70重量%以上である硫酸塩型界面活性剤を採用することにより、良好な泡質、泡量、感触が得られるものである。ここで、分布を有する硫酸塩型界面活性剤は、同一アルキル鎖長を有しエチレンオキシドの付加モル数のみが異なる硫酸塩であることが好ましい。
例えば下記一般式で表されるものが挙げられる。
R11-N+(CH3)3 X-
〔式中、R11は炭素数12〜22のアルキル基を示し、X-はハロゲン化物イオン(特に塩化物イオン、臭化物イオン)を示す。〕
例えば下記一般式で表されるものが挙げられる。
R11-O-R12-N+(CH3)3 X-
〔式中、R12はエチレン基又はプロピレン基を示し、R11及びX-は前記と同じ意味を示す。〕
例えば下記一般式で表されるものが挙げられる。
(R13)2N+(CH3)2 X-
〔式中、R13は炭素数12〜22のアルキル基又はベンジル基を示し、X-は前記と同じ意味を示す。〕
例えば下記一般式で表されるもの及びその塩が挙げられる。
R11-N(CH3)2
〔式中、R11は前記と同じ意味を示す。〕
例えば下記一般式で表されるもの及びその塩が挙げられる。
R11-O-R12-N(CH3)2
〔式中、R11及びR12は前記と同じ意味を示す。〕
例えば下記一般式で表されるもの及びその塩が挙げられる。
R14-C(=O)NH-R12-N(CH3)2
〔式中、R14は炭素数11〜21のアルキル基を示し、R12は前記と同じ意味を示す。〕
例えば下記一般式で表されるものが挙げられる。
(CH3)3SiO-[(CH3)2SiO]d-Si(CH3)3
〔式中、dは3〜20000の数を示す。〕
各種のアミノ変性シリコーンが使用できるが、特に平均分子量が約3000〜100000の、アモジメチコーン(Amodimethicone)の名称でCTFA辞典(米国,Cosmetic Ingredient Dictionary)第3版中に記載されているものが好ましい。このアミノ変性シリコーンは水性乳濁液として用いるのが好ましく、市販品としては、SM 8704C(東レ・ダウコーニング・シリコーン社)、DC 929(ダウコーニング社)、KT 1989(GE東芝社)等が挙げられる。
上記以外に、ポリエーテル変性シリコーン、メチルフェニルポリシロキサン、脂肪酸変性シリコーン、アルコール変性シリコーン、アルコキシ変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、環状シリコーン、アルキル変性シリコーン等が挙げられる。
カルコール2470(花王社,ドデシルアルコール:テトラデシルアルコール=約3:1)2000g及び水酸化カリウム1.45gを耐圧密閉式反応装置に仕込み、110℃、10mmHgで30分脱水を行った後、系内を165℃まで昇温した。昇温後、酸化エチレン456gを圧入し、そのままの温度で30分間付加反応を行った。その後、80℃まで冷却し、酢酸1.3gで中和し、上記原料アルコールの酸化エチレン付加物を得た。
次に、上記操作で得た混合物1793gと硫酸ガス607gを用い、40℃で硫酸化反応を行った。反応後28重量%アンモニア水150gとイオン交換水600gで中和を行った。更に28重量%アンモニア水及びイオン交換水を用いて濃度とpHの調整を行い、表1に記載の硫酸塩1の25重量%水溶液を10000g得た。
得られた硫酸塩は、化粧品原料基準に則り、硫酸塩、アニオン及びEO鎖の確認を行った。
原料の反応比率を変えたほかは製造例1に準じ、表1に記載の硫酸塩2の25重量%水溶液を得た。
得られた硫酸塩は、化粧品原料基準に則り、硫酸塩、アニオン及びEO鎖の確認を行った。
製造例1で得た原料アルコールの酸化エチレン付加物1793gと硫酸ガス607gを用い、40℃で硫酸化反応を行った。反応後23重量%水酸化ナトリウム水溶液132gとイオン交換水556gで中和を行った。更に23重量%水酸化ナトリウム水溶液、75重量%リン酸及びイオン交換水を用いて濃度とpHの調整を行い、表1に記載の硫酸塩3の25重量%水溶液を10000g得た。
得られた硫酸塩は、化粧品原料基準に則り、ナトリウム塩、硫酸塩、アニオン及びEO鎖の確認を行った。
表1に示した硫酸塩型界面活性剤(ラウリルエーテル硫酸塩)を使用して、表2及び3に示す毛髪洗浄剤を調製し、洗髪時・すすぎ時の滑り感、乾燥後の毛髪(毛先)のうねりの取れる度合いを評価した。なお、pHは水で20重量倍希釈したときの25℃における値である。
あらかじめブリーチ処理を8回、洗髪と乾燥を720回繰り返したダメージ毛を用いて作成した、長さ20cm、幅5.5cm、重さ10.0gの毛束を40℃の温水で軽くすすいだ後、余分な水分を取り去り、0.5gの毛髪洗浄剤を用いて約30秒間十分に泡立てた。泡の付いた毛束のすべり感を官能評価し、続いて毛束を40℃のお湯ですすぎ流しながらすべり感を官能評価した。評価は5人で行い、その評価の合計値を示した。
4:よく滑る
3:やや滑る
2:あまり滑らない
1:滑らない
あらかじめブリーチ処理を8回、洗髪と乾燥を720回繰り返したダメージ毛を用いて作成した、長さ20cm、幅1.5cm、重さ1.0gの毛束を40℃の温水で軽くすすいだ後、余分な水分を取り去り、0.1gの毛髪洗浄剤を用いて約30秒間泡立て、40℃の流水(2L/min)で30秒間濯いだ後、タオルで水気を十分に拭き取りドライヤーで櫛を通しながら乾燥した。これを30回繰り返した。その後、目視により毛先のうねりの取れ具合を評価した。評価は5人のパネラーで行い、その評価の合計値を示した。
4:うねりが取れている
3:ややうねりが取れている
2:あまりうねりが取れている
1:うねりが取れていない
(重量%)
硫酸塩3(EO平均付加モル数1.0のラウリルエーテル硫酸ナトリウム) 48.0
キシレンスルホン酸ナトリウム 0.5
ココアンホ酢酸ナトリウム 0.5
ココイルモノエタノールアミド 0.3
ポリオキシエチレン(14)ラウリルエーテル 1.0
高重合メチルポリシロキサンエマルション
(シリコーンCF2450,東レ・ダウコーニング社) 4.0
ベンジルアルコール 0.5
エチレングリコールジステアレート 2.0
カチオン化ヒドロキシエチルセルロース(Polymer JR-400,Amerchol社) 0.4
アミノ変性シリコーン誘導体
(8500 CONDITIONING AGENT,ダウ・コーニング社)*2 1.0
パンテノール 0.05
シルクエキス 0.05
塩化ナトリウム 1.0
乳酸 pH5.0になる量
イオン交換水 バランス
W:75%は基−CH2CH(OH)CH2OH、25%は水素原子
(重量%)
硫酸塩1(EO平均付加モル数1.0のラウリルエーテル硫酸アンモニウム) 52.0
p-トルエンスルホン酸 0.5
イソデシルグリセリルエーテル 0.7
ラウリルアミドプロピルベタイン 2.0
ココイルモノエタノールアミド 0.5
ミリスチルアルコール 1.5
ポリオキシエチレン(16)ラウリルエーテル 1.0
エチレングリコールジステアレート 2.0
カチオン化ヒドロキシエチルセルロース(ポイズ C-80M,花王社) 0.5
ジアリル四級アンモニウム塩/アクリルアミド共重合物
(マーコート550,ONDEO NALCO社) 0.2
アミノ変性シリコーン誘導体
(8500 CONDITIONING AGENT,ダウ・コーニング社) 0.4
高重合メチルポリシロキサンエマルション
(シリコーンCF2450,東レ・ダウコーニング社) 2.0
ベンジルアルコール 0.4
ポリプロピレングリコール(Mw=400) 0.2
加水分解コンキオリン液(乾燥分3重量%) 0.05
オタネニンジンエキス(乾燥分3重量%) 0.05
ダイズエキス(乾燥分0.4重量%) 0.05
ユーカリエキス(乾燥分0.2重量%) 0.05
ツバキ油 0.05
米胚芽油 0.05
リンゴ酸 0.5
水酸化ナトリウム pH3.9になる量
イオン交換水 バランス
(重量%)
硫酸塩2(EO平均付加モル数1.3のラウリルエーテル硫酸アンモニウム) 40.0
クメンスルホン酸アンモニウム 0.8
ラウリルアミドプロピルベタイン 3.0
ポリオキシエチレン(16)ラウリルエーテル 2.0
ステアロキシプロピルジメチルアミン・リンゴ酸塩 0.5
エチレングリコールジステアレート 2.0
カチオン化グアーガム(Jaguar C-13S,Rhodia社) 0.3
ポリプロピレングリコール(Mw=400) 0.5
アミノ変性シリコーン誘導体
(8500 CONDITIONING AGENT,ダウ・コーニング社) 0.8
塩化ナトリウム 1.0
アルギニン 0.5
リンゴ酸 0.2
アジピン酸 0.5
グリコール酸 0.2
水酸化ナトリウム pH5.0になる量
イオン交換水 バランス
(重量%)
硫酸塩1(EO平均付加モル数1.0のラウリルエーテル硫酸アンモニウム) 16.0
p-トルエンスルホン酸ナトリウム 0.7
イソデシルグリセリルエーテル 1.5
ココイルアミドプロピルベタイン 1.0
ラウリルヒドロキシスルホベタイン 1.0
ラウリン酸 0.5
オレイン酸 0.7
ジステアリルエーテル 2.0
ココイルベンザルコニウムクロライド 0.5
カチオン化ヒドロキシエチルセルロース(Polymer JR-400,Amerchol社) 0.4
エタノール 0.5
アミノ変性シリコーン誘導体
(8500 CONDITIONING AGENT,ダウ・コーニング社) 0.2
高重合メチルポリシロキサンエマルション
(シリコーンCF2450、東レ・ダウコーニング社) 2.0
セラミドII(クローダジャパン株式会社) 0.05
ヒバマタエキス 0.05
リンゴ酸 0.7
水酸化ナトリウム pH5.0になる量
イオン交換水 バランス
Claims (8)
- 次の成分(A)〜(D)を含有し、水で20重量倍に希釈したときの25℃におけるpHが2以上6未満である毛髪洗浄剤。
(A) 次の一般式(1)
R1-O-(C2H4O)n-SO3M (1)
〔式中、R1は直鎖又は分岐鎖の炭素数10〜18のアルキル基又はアルケニル基を示し、nは0又は正の整数を示し、Mはナトリウム又はアンモニウムを示す。〕
で表される硫酸塩であって、n=0の硫酸塩 30〜45重量%、n=1の硫酸塩 18〜27重量%、n=2の硫酸塩 10〜20重量%、及び残余はn=3以上の硫酸塩から構成され、かつn=0〜2である硫酸塩の合計が全硫酸塩の70重量%以上である硫酸塩型界面活性剤
(B) 炭素数6〜18の疎水性スルホン酸又はその塩
(C) ヒドロキシカルボン酸、ジカルボン酸及び芳香族カルボン酸から選ばれる有機酸
(D) 次の(d1)〜(d5)から選ばれる有機溶剤
(d1) 一般式(2)で表される化合物
(d2) 窒素原子に炭素数1〜18のアルキル基が結合したN-アルキルピロリドン
(d3) 炭素数2〜4のアルキレンカーボネート
(d4) 分子量200〜5000のポリプロピレングリコール
(d5) 一般式(3)、(4)又は(5)で表されるラクトン又は環状ケトン
- 成分(A)を5〜30重量%、成分(B)を0.1〜5重量%、成分(C)を0.05〜10重量%、成分(D)を0.01〜50重量%を含有する請求項1記載の毛髪洗浄剤。
- 成分(B)が、芳香環を含む炭素数6〜18の疎水性スルホン酸若しくは芳香環を含まない炭素数6〜9の疎水性スルホン酸又はその塩である請求項1又は2記載の毛髪洗浄剤。
- 成分(B)が、芳香環を一つ含む炭素数6〜18の芳香族スルホン酸である請求項1〜3のいずれかに記載の毛髪洗浄剤。
- 成分(B)が、芳香環を2つ以上含む炭素数10〜18の芳香族スルホン酸である請求項1〜3のいずれかに記載の毛髪洗浄剤。
- 成分(B)が、炭素数6〜9の脂肪族炭化水素基を有する脂肪族スルホン酸である請求項1〜3のいずれかに記載の毛髪洗浄剤。
- 更に、両性界面活性剤を含有する請求項1〜6のいずれかに記載の毛髪洗浄剤。
- 更に、エチレングリコールモノ脂肪酸エステル又はエチレングリコールジ脂肪酸エステルを含有する請求項1〜7のいずれかに記載の毛髪洗浄剤。
Priority Applications (5)
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JP2005106451A JP4982051B2 (ja) | 2005-04-01 | 2005-04-01 | 毛髪洗浄剤 |
TW095108109A TWI383804B (zh) | 2005-04-01 | 2006-03-10 | 毛髮洗淨劑 |
CN2006100669124A CN1853600B (zh) | 2005-04-01 | 2006-03-30 | 毛发清洗剂 |
US11/393,921 US7776806B2 (en) | 2005-04-01 | 2006-03-31 | Hair cleansing composition |
EP06006960.6A EP1707239B1 (en) | 2005-04-01 | 2006-03-31 | Hair cleansing composition |
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JP2005106451A JP4982051B2 (ja) | 2005-04-01 | 2005-04-01 | 毛髪洗浄剤 |
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JP2006282614A true JP2006282614A (ja) | 2006-10-19 |
JP4982051B2 JP4982051B2 (ja) | 2012-07-25 |
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US (1) | US7776806B2 (ja) |
EP (1) | EP1707239B1 (ja) |
JP (1) | JP4982051B2 (ja) |
CN (1) | CN1853600B (ja) |
TW (1) | TWI383804B (ja) |
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JP2008184424A (ja) * | 2007-01-30 | 2008-08-14 | Kao Corp | 水性毛髪洗浄剤 |
JP2008208071A (ja) * | 2007-02-27 | 2008-09-11 | Lion Corp | 毛髪洗浄剤 |
JP2009298744A (ja) * | 2008-06-16 | 2009-12-24 | Kao Corp | 水性毛髪洗浄剤 |
JP2010168555A (ja) * | 2008-12-22 | 2010-08-05 | Kao Corp | 洗浄剤組成物 |
JP2017186287A (ja) * | 2016-04-08 | 2017-10-12 | 花王株式会社 | 毛髪化粧料組成物 |
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Also Published As
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EP1707239B1 (en) | 2016-05-04 |
EP1707239A2 (en) | 2006-10-04 |
TWI383804B (zh) | 2013-02-01 |
US20060223728A1 (en) | 2006-10-05 |
EP1707239A3 (en) | 2009-11-11 |
JP4982051B2 (ja) | 2012-07-25 |
CN1853600B (zh) | 2013-06-19 |
CN1853600A (zh) | 2006-11-01 |
US7776806B2 (en) | 2010-08-17 |
TW200719919A (en) | 2007-06-01 |
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