JP2005052692A - Processing system and processing method for using biomass resource effectively - Google Patents
Processing system and processing method for using biomass resource effectively Download PDFInfo
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- JP2005052692A JP2005052692A JP2003205755A JP2003205755A JP2005052692A JP 2005052692 A JP2005052692 A JP 2005052692A JP 2003205755 A JP2003205755 A JP 2003205755A JP 2003205755 A JP2003205755 A JP 2003205755A JP 2005052692 A JP2005052692 A JP 2005052692A
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- 239000002028 Biomass Substances 0.000 title claims abstract description 33
- 238000003672 processing method Methods 0.000 title claims abstract description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 148
- 238000000855 fermentation Methods 0.000 claims abstract description 30
- 230000004151 fermentation Effects 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 244000144972 livestock Species 0.000 claims abstract description 17
- 150000007524 organic acids Chemical class 0.000 claims abstract description 17
- 239000007864 aqueous solution Substances 0.000 claims abstract description 14
- 238000003763 carbonization Methods 0.000 claims abstract description 12
- 239000010813 municipal solid waste Substances 0.000 claims abstract description 12
- 238000011084 recovery Methods 0.000 claims abstract description 12
- 230000001079 digestive effect Effects 0.000 claims abstract description 11
- 239000002699 waste material Substances 0.000 claims abstract description 9
- 230000001590 oxidative effect Effects 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract 2
- 239000007789 gas Substances 0.000 claims description 57
- 239000003921 oil Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 150000001247 metal acetylides Chemical class 0.000 claims description 6
- 239000003225 biodiesel Substances 0.000 claims description 5
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 5
- 230000029087 digestion Effects 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 235000014102 seafood Nutrition 0.000 abstract description 7
- 239000000243 solution Substances 0.000 abstract description 2
- 235000005985 organic acids Nutrition 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 210000003608 fece Anatomy 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 239000005539 carbonized material Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
Landscapes
- Processing Of Solid Wastes (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Treatment Of Sludge (AREA)
- Coke Industry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
Description
【0001】
【発明の属する技術分野】
本発明は、植物、畜産物、魚介類またはそれらの廃棄物、あるいは生ゴミや畜産物の糞などの汚物を含むバイオマス資源を有効利用するための処理システム及び処理方法に関する。
【0002】
【従来の技術】
従来より、バイオマス資源からメタン(CH4)ガスを発生させて回収する手段としては、例えば特許文献1に記載されている。
【0003】
【特許文献1】
特開2001−170695号公報
【0004】
しかしながら、特許文献1に記載されたメタンガス精製設備は、メタンガスの回収率が低く、また、メタンガスを精製した後のバイオマス資源の大部分は、残渣を含む消化液となり、この消化液は、薬注の投入、汚泥の処理などの清浄化処理を行なう必要があり、清浄化処理するためのコストが高くなった。このため、清浄化処理するための最終的な残渣の生成量を極力少なくすることが望ましい。
【0005】
【発明が解決しようとする課題】
本発明の目的は、植物、畜産物、魚介類またはそれらの廃棄物、あるいは生ゴミや畜産物の糞などの汚物を含むバイオマス資源から、メタンガスや水素ガスを効率良く分別回収すると共に、最終的な残渣の生成量を極力少なくして、清浄化処理コストの低減を図ることができる、バイオマス資源を有効利用するための処理システム及び処理方法を提供することにある。
【0006】
【課題を解決するための手段】
上記目的を達成するため、本発明のバイオマス資源を有効利用するための処理システムは、植物、畜産物、魚介類またはそれらの廃棄物、あるいは生ゴミや畜産物の糞などの汚物を含むバイオマス資源を30〜90℃に加熱し、メタンガスと、残渣を含む消化液とを生成し、生成したメタンガスを分別回収するメタン発酵装置と、メタン発酵装置で生成した消化液を、温度を250℃超え400℃以下の温度とし、圧力を0.01〜14.7MPaとする高温高圧雰囲気下で加熱し、メタンガス、有機酸、油、及び残渣を含む水溶液を生成し、生成したメタンガス、有機酸及び油を分別回収する亜臨界装置と、メタン発酵装置で生成した消化液及び/又は亜臨界装置で生成した水溶液を、105℃以上で加熱して、水蒸気及び残渣を生成し、生成した水蒸気を分別回収する水分除去装置と、水分除去装置で生成した残渣を、非酸化性雰囲気下で320〜850℃の温度で加熱して、炭化物、及びメタンや水素を主体とするエネルギーガスを生成し、炭化物及びエネルギーガスを分別回収する炭化・エネルギーガス回収装置とを具えることにある。
【0007】
また、本発明のバイオマス資源を有効利用するための処理方法は、植物、畜産物、魚介類またはそれらの廃棄物、あるいは生ゴミや畜産物の糞などの汚物を含むバイオマス資源を30〜90℃に加熱し、メタンガスと、残渣を含む消化液とを生成し、生成したメタンガスを分別回収するメタン発酵工程と、メタン発酵工程で生成した消化液を、温度を250℃超え400℃以下の温度とし、圧力を0.01〜14.7MPaとする高温高圧雰囲気下で加熱し、メタンガス、有機酸、油、及び残渣を含む水溶液を生成し、生成したメタンガス、有機酸及び油を分別回収する亜臨界工程と、メタン発酵装置で生成した消化液及び/又は亜臨界装置で生成した水溶液を、105℃以上で加熱して、水蒸気及び残渣を生成し、生成した水蒸気を分別回収する水分除去工程と、水分除去工程で生成した残渣を、非酸化性雰囲気下で320〜850℃の温度で加熱して、炭化物、及びメタンや水素を主体とするエネルギーガスを生成し、炭化物及びエネルギーガスを分別回収する炭化・エネルギーガス回収工程とを具えることにある。
【0008】
さらに、バイオマス資源は、細かく破砕してペースト状にする破砕工程を経てからメタン発酵工程で処理することが好ましく、加えて、亜臨界工程で生成した油は、バイオディーゼル燃料油として用いることがより好適である。
【0009】
【発明の実施の形態】
本発明に従うバイオマス資源を有効利用するための処理システムを図面を参照しながら説明する。
図1は、本発明の代表的な処理システムを説明するためのフローチャートを示したものである。
【0010】
本発明の処理システム1は、主にメタン発酵装置2、亜臨界装置3、水分除去装置4及び炭化・エネルギーガス回収装置5とを具えている。
【0011】
メタン発酵装置2は、植物、畜産物、魚介類またはそれらの廃棄物、あるいは生ゴミや畜産物の糞などの汚物を含むバイオマス資源を利用し、このバイオマス資源を30〜90℃に加熱し、メタンガスと、残渣を含む消化液とを生成し、生成したメタンガスを、例えばガスホルダー6で分別回収する装置である。メタン発酵装置2で生成されるメタンガスの回収率は、投入したバイオマス資源全体の5質量%程度であり、回収されてガスホルダ6に送られ、残りの95%は残渣であり、かかる残渣は、後工程の乾燥装置3を経てから低温炭化装置4のバイオマス資源(原料)として使用するため、メタン発酵装置2の処理では、残渣は全く生じない。
【0012】
亜臨界装置3は、メタン発酵装置2で生成した消化液を、温度を250℃超え400℃以下の温度とし、圧力を0.01〜14.7MPaとする高温高圧雰囲気下で加熱し、メタンガス、有機酸、油、及び残渣を含む水溶液を生成し、生成したメタンガス、有機酸及び油を分別回収する装置である。
【0013】
本発明では、特に、亜臨界装置3の処理によって、投入した消化液全体の72質量%以上、さらには、投入したバイオマス資源全体からすると、70質量%以上のメタンガスを効率良く回収できることを主な特徴とする。
【0014】
また、亜臨界装置3から生成した有機酸は、例えば健康食品等の添加物などに広く使用することができ、また、され、亜臨界装置3から生成した油は、バス等のバイオディーゼル燃料油として使用したり、ボイラ発電装置(図示せず)の燃料油として使用することができ、バイオマス資源を有効利用することができる。
【0015】
水分除去装置4は、メタン発酵装置2で生成した消化液及び/又は亜臨界装置3で生成した水溶液を、105℃以上、好ましくは200〜700℃で加熱して、水蒸気及び残渣を生成し、生成した水蒸気を分別回収する装置である。分別回収した水蒸気は、例えば、ボイラ発電装置に使用すればよい。
【0016】
炭化・エネルギーガス回収装置5は、水分除去装置4で生成した残渣を、非酸化性雰囲気下で320〜850℃の温度で加熱して、炭化物、及びメタンや水素を主体とするエネルギーガスを生成し、炭化物及びエネルギーガスを分別回収する装置であり、残渣はほとんど生じない。しかしながら、炭化装置で残渣が生成される場合には、図示しない溶融炉、例えば残渣を1000℃以上で高温溶融させる還元ガス化溶融炉をさらに設けて、この残渣を高温溶融して無害化することが好ましく、このように構成すれば、炭化装置で残渣が生成したとしても、この残渣を溶融炉で完全無害化できるので、システムとしては残渣が全く生じないことになる。
【0017】
生成した水素ガスは、ガス改質装置(図示せず)を経てガスホルダ(図示せず)に送られた後、例えば、ボイラ発電装置の燃料や水素燃料電池(図示せず)の原料として有効利用すればよい。
【0018】
尚、バイオマス資源が大きな形状のままであるとメタン発酵等の処理を効率良く行なえない場合があるため、かかる場合には、図1に示すように、細かく破砕してペースト状にする破砕機7を経てからメタン発酵装置2で処理することが好ましい。
【0019】
次に、この発明の処理方法について説明する。
まず、前記バイオマス資源を30〜90℃に加熱し、メタンガスと、残渣を含む消化液とを生成し、生成したメタンガスを分別回収する(メタン発酵工程)。
前記温度を30℃未満では、メタン発酵菌が活動しないからであり、90℃超えでは、メタン発酵菌が死滅するからである。
【0020】
次いで、メタン発酵工程で生成した消化液を、温度を250℃超え400℃以下の温度とし、圧力を0.01〜14.7MPaとする高温高圧雰囲気下で加熱し、メタンガス、有機酸、油、及び残渣を含む水溶液を生成し、生成したメタンガス、有機酸及び油を分別回収する(亜臨界工程)。
前記雰囲気の温度が250℃以下だと、亜臨界状態にならないからであり、400℃超えにしても、それ以上の効果の向上はなく無駄にエネルギーを浪費することになるからである。また、雰囲気の圧力が0.01MPa未満だと、亜臨界状態にならないからであり、14.7MPa超えだと、それ以上の効果の向上はなく無駄にエネルギーを浪費することになるからである。尚、前記圧力は、より好適には4MPa以上8MPa未満とする。
【0021】
その後、メタン発酵装置で生成した消化液及び/又は亜臨界装置で生成した水溶液を、105℃以上、好ましくは200〜1200℃で加熱して、水蒸気及び残渣を生成し、生成した水蒸気を分別回収する(水分除去工程)。
【0022】
そして、水分除去工程で生成した残渣を、非酸化性雰囲気下で320〜850℃の温度で加熱して、炭化物及び水素ガスを生成し、炭化物及び水素ガスを分別回収する(炭化・エネルギーガス回収工程)。
前記温度を320℃未満では、炭化物が生成しないからであり、850℃超えでは、エネルギーガスの回収ができなくなるからである。また、ここでいう非酸化性雰囲気とは、N2、Ar等の不活性ガスを充填し、酸素がほとんど存在しない雰囲気を意味する。
【0023】
本発明の処理システムを用いて、魚のアラからなるバイオマス資源1kgを処理した。
この結果、本発明の処理システムで処理した場合に回収されたメタンガスの回収効率は
20〜70%であり、従来の処理装置で回収されるメタンガスの回収効率(3〜7%)に比べて格段に向上し、清浄化処理する必要のある最終的な残渣はほとんど生成しなかった。また、本発明の処理システムでは、メタンガスの生成に加えて、従来のメタン発酵装置では生成しない水素ガス、有機酸、バイオディーゼル燃料油などの有用な物質も生成することができた。
【0024】
上述したところは、この発明の実施形態の一例を示したにすぎず、請求の範囲において種々の変更を加えることができる。
【0025】
【発明の効果】
この発明によれば、植物、畜産物、魚介類またはそれらの廃棄物、あるいは生ゴミや畜産物の糞などの汚物を含むバイオマス資源の有効利用するための処理方法及び処理システムの提供が可能になった。
【0026】
しかも、この発明では、バイオマス資源を段階的に適正に処理することにより、最終的な残渣がほとんど生成することなく、低コストで、メタンガスの生成に加えて、従来のメタン発酵装置では生成しない水素ガス、有機酸、バイオディーゼル燃料油などの有用な物質も生成することができるという顕著な効果を奏する。
【図面の簡単な説明】
【図1】本発明に従う代表的なバイオマス資源を有効利用するための処理システムのフローチャートを示したものである。
【符号の説明】
1 処理システム
2 メタン発酵装置
3 亜臨界装置
4 乾燥装置
5 炭化装置
6 ガスホルダ
7 破砕機[0001]
BACKGROUND OF THE INVENTION
TECHNICAL FIELD The present invention relates to a processing system and a processing method for effectively using biomass resources including plants, livestock products, seafood, or wastes thereof, or filth such as food waste and feces of livestock products.
[0002]
[Prior art]
Conventionally, as means for generating and recovering methane (CH 4 ) gas from biomass resources, for example, Patent Document 1 describes.
[0003]
[Patent Document 1]
JP 2001-170695 A [0004]
However, the methane gas refining facility described in Patent Document 1 has a low methane gas recovery rate, and most of the biomass resources after the methane gas is purified becomes a digested liquid containing residues, and this digested liquid is a chemical injection. It is necessary to carry out a cleaning process such as charging of sludge and sludge, and the cost for the cleaning process has increased. For this reason, it is desirable to minimize the production amount of the final residue for the cleaning treatment.
[0005]
[Problems to be solved by the invention]
The object of the present invention is to efficiently separate and recover methane gas and hydrogen gas from biomass resources including filth such as plants, livestock products, seafood or wastes thereof, or garbage such as garbage and livestock excrement, and finally An object of the present invention is to provide a processing system and a processing method for effectively using biomass resources, which can reduce the amount of the residue generated as much as possible and reduce the cleaning processing cost.
[0006]
[Means for Solving the Problems]
In order to achieve the above object, the processing system for effectively using the biomass resource of the present invention is a biomass resource containing filth such as plants, livestock products, seafood or wastes thereof, or raw garbage or livestock dung. Is heated to 30 to 90 ° C. to produce methane gas and a digestive liquid containing a residue, and the methane fermentation apparatus that separates and recovers the generated methane gas, and the digested liquid generated by the methane fermentation apparatus have a temperature exceeding 250 ° C. and 400 ° C. It is heated in a high-temperature and high-pressure atmosphere with a pressure of 0.01 to 14.7 MPa, and an aqueous solution containing methane gas, organic acid, oil, and residue is generated, and the generated methane gas, organic acid, and oil are The subcritical apparatus to separate and collect, the digestive liquid produced in the methane fermentation apparatus and / or the aqueous solution produced in the subcritical apparatus are heated at 105 ° C. or higher to produce water vapor and residue, Moisture removal device that separates and collects the generated water vapor, and the residue generated by the water removal device is heated at a temperature of 320 to 850 ° C. in a non-oxidizing atmosphere, and energy gas mainly composed of carbide, methane, and hydrogen And a carbonization / energy gas recovery device that separates and recovers carbides and energy gas.
[0007]
Moreover, the processing method for effectively using the biomass resource of the present invention is a 30 to 90 ° C. biomass resource containing filth such as plants, livestock products, seafood or wastes thereof, or raw garbage or livestock excrement. The methane fermentation process for separating and recovering the generated methane gas, and the digestion liquid generated in the methane fermentation process are set to a temperature exceeding 250 ° C. and 400 ° C. or less. Subcriticality that heats in a high-temperature and high-pressure atmosphere with a pressure of 0.01 to 14.7 MPa, generates an aqueous solution containing methane gas, organic acid, oil, and residue, and separates and recovers the generated methane gas, organic acid, and oil. The process and the digestive liquid produced in the methane fermentation apparatus and / or the aqueous solution produced in the subcritical apparatus are heated at 105 ° C. or higher to produce water vapor and residue, and the produced water vapor is separated. The moisture removal step and the residue produced in the moisture removal step are heated at a temperature of 320 to 850 ° C. in a non-oxidizing atmosphere to produce carbide and energy gas mainly composed of methane and hydrogen, And a carbonization / energy gas recovery process for separately recovering energy gas.
[0008]
Furthermore, the biomass resources are preferably processed in the methane fermentation process after being crushed into a paste and then processed in the methane fermentation process. In addition, the oil produced in the subcritical process is more preferably used as biodiesel fuel oil. Is preferred.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
A processing system for effectively using biomass resources according to the present invention will be described with reference to the drawings.
FIG. 1 is a flowchart for explaining a typical processing system of the present invention.
[0010]
The processing system 1 of the present invention mainly includes a methane fermentation apparatus 2, a subcritical apparatus 3, a
[0011]
The methane fermentation apparatus 2 uses biomass resources including filth such as plants, livestock products, seafood or wastes thereof, or garbage such as garbage and feces of livestock products, and heats the biomass resources to 30 to 90 ° C. This is a device that generates methane gas and digestive juice containing residues, and separates and recovers the generated methane gas by, for example, the
[0012]
The subcritical apparatus 3 heats the digested liquid produced in the methane fermentation apparatus 2 in a high-temperature and high-pressure atmosphere in which the temperature is 250 ° C. and 400 ° C. or less and the pressure is 0.01 to 14.7 MPa. It is an apparatus for producing an aqueous solution containing an organic acid, oil, and residue, and separately collecting the produced methane gas, organic acid, and oil.
[0013]
In the present invention, in particular, by the treatment of the subcritical apparatus 3, 72 mass% or more of the entire digested liquid added, and moreover, 70 mass% or more of methane gas can be efficiently recovered from the total biomass resources input. Features.
[0014]
Moreover, the organic acid produced | generated from the subcritical apparatus 3 can be widely used for additives, such as health food, for example, and the oil produced | generated from the subcritical apparatus 3 is biodiesel fuel oil, such as a bath. Can be used as fuel oil for boiler power generation devices (not shown), and biomass resources can be used effectively.
[0015]
The
[0016]
The carbonization / energy gas recovery device 5 heats the residue generated by the
[0017]
The generated hydrogen gas is sent to a gas holder (not shown) through a gas reformer (not shown), and then effectively used as a fuel for a boiler power generation device or a raw material for a hydrogen fuel cell (not shown), for example. do it.
[0018]
In addition, since processing, such as methane fermentation, may not be performed efficiently when biomass resources remain in a large shape, in such a case, as shown in FIG. It is preferable to process with the methane fermentation apparatus 2 after passing.
[0019]
Next, the processing method of the present invention will be described.
First, the biomass resource is heated to 30 to 90 ° C. to produce methane gas and a digested liquid containing residues, and the produced methane gas is separated and recovered (methane fermentation step).
If the temperature is less than 30 ° C., the methane-fermenting bacteria will not be active, and if it exceeds 90 ° C., the methane-fermenting bacteria will be killed.
[0020]
Next, the digested liquid produced in the methane fermentation step is heated in a high-temperature and high-pressure atmosphere in which the temperature is higher than 250 ° C. and not higher than 400 ° C., and the pressure is 0.01 to 14.7 MPa, and methane gas, organic acid, oil, Then, an aqueous solution containing the residue is produced, and the produced methane gas, organic acid and oil are separated and recovered (subcritical process).
This is because if the temperature of the atmosphere is 250 ° C. or lower, the subcritical state is not obtained, and even if the temperature exceeds 400 ° C., the effect is not further improved and energy is wasted. Moreover, it is because it will not be in a subcritical state if the pressure of atmosphere is less than 0.01 MPa, and if it exceeds 14.7 MPa, there will be no further improvement in the effect and energy will be wasted. The pressure is more preferably 4 MPa or more and less than 8 MPa.
[0021]
Thereafter, the digestive juice produced in the methane fermentation device and / or the aqueous solution produced in the subcritical device is heated at 105 ° C. or higher, preferably 200 to 1200 ° C. to produce water vapor and residue, and the produced water vapor is separated and recovered. (Moisture removal step).
[0022]
And the residue produced | generated by the water | moisture-content removal process is heated at the temperature of 320-850 degreeC in non-oxidizing atmosphere, a carbide | carbonized_material and hydrogen gas are produced | generated, and a carbide | carbonized_material and hydrogen gas are fractionally collected (carbonization and energy gas collection | recovery) Process).
This is because if the temperature is less than 320 ° C., carbide is not generated, and if it exceeds 850 ° C., the energy gas cannot be recovered. In addition, the non-oxidizing atmosphere here means an atmosphere filled with an inert gas such as N 2 or Ar and containing almost no oxygen.
[0023]
Using the processing system of the present invention, 1 kg of biomass resources consisting of fish ara was processed.
As a result, the recovery efficiency of methane gas recovered when processed by the processing system of the present invention is 20 to 70%, which is much higher than the recovery efficiency (3 to 7%) of methane gas recovered by the conventional processing apparatus. And the final residue that needed to be cleaned was scarcely produced. In addition to the production of methane gas, the treatment system of the present invention was able to produce useful substances such as hydrogen gas, organic acid, and biodiesel fuel oil that are not produced by conventional methane fermentation apparatuses.
[0024]
What has been described above is merely an example of an embodiment of the present invention, and various modifications can be made within the scope of the claims.
[0025]
【The invention's effect】
According to the present invention, it is possible to provide a processing method and a processing system for effectively using biomass resources including plants, livestock products, seafood or waste thereof, or filth such as raw garbage and feces of livestock products. became.
[0026]
Moreover, in the present invention, by appropriately processing the biomass resources in stages, the final residue is hardly generated, and in addition to the generation of methane gas at a low cost, the hydrogen that is not generated by the conventional methane fermentation apparatus. There is a remarkable effect that useful substances such as gas, organic acid, and biodiesel fuel oil can be produced.
[Brief description of the drawings]
FIG. 1 is a flowchart of a processing system for effectively using a representative biomass resource according to the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Processing system 2 Methane fermentation apparatus 3
Claims (4)
メタン発酵装置で生成した消化液を、温度を250℃超え400℃以下の温度とし、圧力を0.01〜14.7MPaとする高温高圧雰囲気下で加熱し、メタンガス、有機酸、油、及び残渣を含む水溶液を生成し、生成したメタンガス、有機酸及び油を分別回収する亜臨界装置と、
メタン発酵装置で生成した消化液及び/又は亜臨界装置で生成した水溶液を、105℃以上で加熱して、水蒸気及び残渣を生成し、生成した水蒸気を分別回収する水分除去装置と、
水分除去装置で生成した残渣を、非酸化性雰囲気下で320〜850℃の温度で加熱して、炭化物、及びメタンや水素を主体とするエネルギーガスを生成し、炭化物及びエネルギーガスを分別回収する炭化・エネルギーガス回収装置と、
を具えることを特徴とするバイオマス資源を有効利用するための処理システム。Biomass resources containing filth such as plants, livestock products, fishery products or their wastes, or garbage such as garbage and livestock excrement are heated to 30-90 ° C. to produce methane gas and digestive juice containing residues, A methane fermentation apparatus for separating and recovering the generated methane gas;
The digested liquid produced in the methane fermentation apparatus is heated in a high-temperature and high-pressure atmosphere in which the temperature is higher than 250 ° C. and lower than 400 ° C. and the pressure is 0.01 to 14.7 MPa, and methane gas, organic acid, oil, and residue A subcritical device for producing an aqueous solution containing methane, separating and recovering the produced methane gas, organic acid and oil;
A water removal device that heats an aqueous solution produced by a digestive juice produced by a methane fermentation device and / or a subcritical device at 105 ° C. or higher to produce water vapor and a residue, and separately collects the produced water vapor;
The residue generated by the moisture removal device is heated at a temperature of 320 to 850 ° C. in a non-oxidizing atmosphere to generate carbides and energy gas mainly composed of methane and hydrogen, and the carbides and energy gas are separated and recovered. Carbonization and energy gas recovery equipment,
A processing system for effectively using biomass resources characterized by comprising:
メタン発酵工程で生成した消化液を、温度を250℃超え400℃以下の温度とし、圧力を0.01〜14.7MPaとする高温高圧雰囲気下で加熱し、メタンガス、有機酸、油、及び残渣を含む水溶液を生成し、生成したメタンガス、有機酸及び油を分別回収する亜臨界工程と、
メタン発酵装置で生成した消化液及び/又は亜臨界装置で生成した水溶液を、105℃以上で加熱して、水蒸気及び残渣を生成し、生成した水蒸気を分別回収する水分除去工程と、
水分除去工程で生成した残渣を、非酸化性雰囲気下で320〜850℃の温度で加熱して、炭化物、及びメタンや水素を主体とするエネルギーガスを生成し、炭化物及びエネルギーガスを分別回収する炭化・エネルギーガス回収工程と、
を具えることを特徴とするバイオマス資源を有効利用するための処理方法。Biomass resources containing filth such as plants, livestock products, fishery products or their wastes, or garbage such as garbage and livestock excrement are heated to 30-90 ° C. to produce methane gas and digestive juice containing residues, A methane fermentation process for separating and recovering the generated methane gas;
The digested liquid produced in the methane fermentation process is heated in a high-temperature and high-pressure atmosphere in which the temperature is 250 ° C. and 400 ° C. or less and the pressure is 0.01 to 14.7 MPa, and methane gas, organic acid, oil, and residue A subcritical process for producing an aqueous solution containing methane, separating and collecting the produced methane gas, organic acid and oil;
A water removal step of heating the digestion liquid produced in the methane fermentation apparatus and / or the aqueous solution produced in the subcritical apparatus at 105 ° C. or higher to produce water vapor and residue, and separately collecting the produced water vapor;
The residue generated in the moisture removal step is heated at a temperature of 320 to 850 ° C. in a non-oxidizing atmosphere to generate carbides and energy gas mainly composed of methane and hydrogen, and the carbides and energy gas are separated and recovered. Carbonization / energy gas recovery process,
A processing method for effectively using biomass resources characterized by comprising:
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