JP2004073886A - Make-up oil absorbing paper and manufacturing method thereof - Google Patents
Make-up oil absorbing paper and manufacturing method thereof Download PDFInfo
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この発明は、皮脂の吸収に応じて鋭敏に透明性が発現するとともに、皮脂の吸液性が早い特性に優れた化粧用あぶら取り紙及びその製造方法に関するものである。 {Circle over (1)} The present invention relates to a cosmetic oil-absorbing paper excellent in characteristics in which transparency is developed sharply in response to sebum absorption and sebum absorbs quickly, and a method for producing the same.
人間の顔面、特に鼻、頬、額、眉毛間等は皮脂の分泌が盛んで油っぽくなり易く、従って、その部分では化粧崩れを起こし易い。一般に皮脂が浮いたまま化粧をすると、皮膚に化粧料が馴染まないため、顔面の皮脂分を化粧用脂取り紙にて取り除いてから化粧し、効果を上げている。これは化粧直しの場合も同様である。従来の化粧用脂取り紙は古くから箔打紙が使われており、名塩紙が有名である。この紙は、西宮市名塩産で、三椏、楮、雁皮に特殊な泥、例えば、金箔打ちには東久保土と呼ぶ白色のもの、銀箔打ちには蛇豆土という茶褐色のものを混入して漉いた紙である。 The human face, especially between the nose, cheeks, forehead, and eyebrows, tends to become greasy due to the secretion of sebum, and thus the makeup tends to be lost in that part. In general, when makeup is applied while sebum is floating, the cosmetic does not fit into the skin. Therefore, makeup is applied after removing the sebum on the face with a cosmetic oil removing paper. This is the same in the case of makeup correction. Foil stamping paper has long been used as conventional fat removing paper for cosmetics, and famous salt paper is famous. This paper is made from the famous salt of Nishinomiya City, and is made of a special mixture of mitsumata, mulberry, and goose, such as a white one called Higashikubo Soil for gold foil and a brown one called Snake Bean Soil for silver foil. It is a piece of paper.
又、箔打紙は箔打ちを15回ほど使用すると、箔を打ちを延ばす働きがなくなり、これを女性の脂取り化粧紙として用いられている。上記の名塩産の紙(名塩紙)は箔打ち後は、密度が高く、これを脂取り化粧紙として用いると、顔面の皮脂分が除かれ、風呂に浴したようになるので、またの名を風呂屋紙として早くから用いられてきた。 箔 Foil stamping paper does not have the function of extending the stamping when the foil stamping is used about 15 times, and this is used as a grease-absorbing decorative paper for women. The above-mentioned paper made by Nao salt (Nao salt paper) has a high density after foiling, and if this is used as a grease-removing decorative paper, the sebum on the face will be removed and it will be like taking a bath. It has been used as a newspaper for a long time.
ところで、従来の箔打ちのみで製造した場合の密度、平滑度、不透明度、表面粗さを測定した結果を下記の表1に示す。なお、このときの箔打ち紙の抄造時の製造原料等の諸条件は、後記する実施例2の製造時のものと、スーパーキャレンダー処理を行なわない点を除いて同じである。 By the way, the results of measuring the density, smoothness, opacity, and surface roughness in the case of manufacturing only by conventional foil stamping are shown in Table 1 below. In this case, various conditions such as a raw material for producing the foil stamped paper are the same as those for the production of Example 2 described later, except that the super calender treatment is not performed.
(箔打ちの条件)
紙のサイズ:約21cm角、箔打ち機:ベルトハンマー機、槌の重量:16kg、受け台:石又は鉄、打撃速度:約500回/分、箔打ち時間:105秒
上記の条件で、上記の紙を300〜350枚を重ねた状態で箔打ちを行なう。上記の測定結果(表1)から、箔打ち時間を延長した場合、ある程度までで密度が変化しないことが確認できた。そして、箔打ち時間を従来条件(現行条件:105秒)の3倍に変更すると、衝撃の強さにより、和紙が破けてしまい、密度を0.80g/cm3以上だすことが不可能であることがわかった。
(Foiling conditions)
Paper size: about 21 cm square, foiling machine: belt hammer machine, weight of hammer: 16 kg, cradle: stone or iron, impact speed: about 500 times / minute, foiling time: 105 seconds, under the above conditions Is performed in a state where 300 to 350 sheets of paper are stacked. From the above measurement results (Table 1), it was confirmed that when the foiling time was extended, the density did not change to a certain extent. Then, the foil beating time prior conditions: Changing to 3 times (current condition 105 seconds), the magnitude of an impact, Japanese paper will be torn, it is impossible to issues a density 0.80 g / cm 3 or more I understand.
化粧用あぶら取り紙は、高密度でかつ、平滑度が低く、表面積が多く(表面が粗い)、不透明度が低いものほど皮脂を取れやすくする機能が高まる。
しかし、従来の箔打ちのみで形成した化粧用あぶら取り紙では、高密度にするには限界があることがわかった。
The oil removing paper for makeup has a higher density, a lower smoothness, a larger surface area (rough surface), and a lower opacity, the function of easily removing sebum increases.
However, it has been found that there is a limit in increasing the density of the conventional oil-absorbing paper formed only by foil stamping.
一方、高密度にするには、スーパーキャレンダー、熱キャレンダー又は高圧プレス等の高圧処理で行なうことが考えられる。
ところが、高圧処理を行なうと、紙面の平滑度が高すぎて、皮脂の取れ方が悪くなる問題がある。
On the other hand, in order to increase the density, high pressure treatment such as a super calender, a heat calender or a high pressure press may be considered.
However, when the high-pressure treatment is performed, there is a problem that the smoothness of the paper surface is too high and the method of removing sebum is deteriorated.
この発明は、単に箔打ちを行なって形成した化粧用あぶら取り紙よりも、使用後の透明性が高い特性が得られ、しかも平滑度を高圧処理で行なった場合よりも低くでき、かつ密度は箔打ち処理のみを行なった場合よりも大きくなるため、皮脂の取れ方を良くすることができる化粧用あぶら取り紙及びその製造方法を提供することにある。 The present invention provides higher transparency after use than a cosmetic oil blotting paper formed simply by foil stamping, and can achieve a lower smoothness than that obtained by high-pressure treatment, and has a lower density. An object of the present invention is to provide a cosmetic oil-absorbing paper and a method for producing the same, which can improve the method of removing sebum because the size is larger than when only the foiling treatment is performed.
上記の目的を達成するために、この請求項1の発明は、植物繊維を主成分とする原料からなり、高圧処理された後に、箔打ちされたことを特徴とする化粧用あぶら取り紙であって、前記高圧処理は、水分量16〜21%の紙に対して行なわれたことを要旨とするものである。
In order to achieve the above object, the invention of
なお、この明細書でいう「箔打ち」とは、金属箔を打ち延ばす目的の有無に関係無しに、紙面を打撃することをいう。
この発明での植物繊維は、マニラ麻(アバカ)、亜麻、黄麻、サイザル麻、ケナフ、雁皮、楮、バナナ繊維、或は三椏からなる靱皮繊維又は木材パルプから選ばれた少なくとも一種をいい、主成分とは、前記植物繊維を50重量部%以上含むことをいう。
It should be noted that the term “foil punching” in this specification refers to hitting a sheet of paper irrespective of whether or not there is a purpose to spread a metal foil.
The plant fiber in the present invention refers to at least one selected from bast fiber or wood pulp made of manila hemp (abaca), flax, jute, sisal, kenaf, ganp, mulberry, banana fiber, or mitsumata. Means that the plant fiber is contained in an amount of 50% by weight or more.
抄紙された紙は、高圧処理されていると、紙密度の高いものとなる。紙密度が高いと高吸油し、使用後に透明性が上がる利点がある。一方、高圧処理は平滑度が上がり過ぎるため、高圧処理の後に、箔打ちが行われていると、紙面の平滑度が下がる。紙面の平滑性は高くなり過ぎると、表面積が非常に小さくなるため皮脂の取れ方が悪くなるが、平滑度が下がると、皮脂の取れ方は良好となる。 The paper made has a high paper density when subjected to high pressure treatment. High paper density has the advantage of high oil absorption and increased transparency after use. On the other hand, the smoothness of the high-pressure treatment is too high, and therefore, if the foiling is performed after the high-pressure treatment, the smoothness of the paper surface decreases. If the smoothness of the paper surface is too high, the method of removing sebum will be poor because the surface area will be very small, but if the smoothness is reduced, the method of removing sebum will be good.
また、22%以上の水分量であると、高圧処理を行なったとき、紙が完全に乾燥できず、高圧処理後、たるみ並びに皺等のトラブルが発生しやすくなり、16%未満の水分量の場合は高密度とすることができなくなる。 Further, when the water content is 22% or more, the paper cannot be completely dried when subjected to the high-pressure treatment, and after the high-pressure treatment, troubles such as slack and wrinkles are likely to occur. In such a case, the density cannot be increased.
請求項2の発明は、請求項1に記載の化粧用あぶら取り紙は、紙密度が0.8〜1.2g/cm3であるとともに、不透明度が40.6〜33.6%であることを要旨とする。 紙密度が、0.8〜1.2g/cm3の範囲であると、高吸油し、更に使用後非常に透明性が上がる。紙密度が0.8g/cm3未満の場合は、使用後の透明性が悪くなり、1.2g/cm3を越えると、生産が困難となるため好ましくない。また、不透明度が低いものほど皮脂を取れやすくする機能が高まる。 According to a second aspect of the present invention, the cosmetic oil blotting paper according to the first aspect has a paper density of 0.8 to 1.2 g / cm 3 and an opacity of 40.6 to 33.6%. That is the gist. When the paper density is in the range of 0.8 to 1.2 g / cm 3 , the oil absorption is high, and the transparency is very high after use. If the paper density is less than 0.8 g / cm 3 , the transparency after use becomes poor, and if it exceeds 1.2 g / cm 3 , production becomes difficult, which is not preferable. Further, the lower the opacity, the higher the function of easily removing sebum.
請求項3の発明は、植物繊維を主成分とする原料を抄紙機にて抄紙した紙を高圧処理した後に、更に箔打ちすることを特徴とする化粧用あぶら取り紙の製造方法であって、前記高圧処理を、水分量が16〜21%の紙に対して行なうことを特徴とする化粧用あぶら取り紙の製造方法を要旨とする。
The invention according to
請求項4の発明は、植物繊維を主成分とする原料を抄紙機にて抄紙した後に高圧処理し、更に箔打ちすることにより、化粧用あぶら取り紙の紙密度を0.8〜1.2g/cm3とするとともに、不透明度を40.6〜33.6%とすることを特徴とする化粧用あぶら取り紙の製造方法を要旨とする。 The invention according to claim 4 is that the raw material mainly composed of vegetable fiber is subjected to high pressure treatment after papermaking by a paper machine and further foiling, so that the paper density of the cosmetic oil removing paper is 0.8 to 1.2 g. / Cm 3 and an opacity of 40.6 to 33.6%.
請求項5の発明は、請求項3又は4に記載の化粧用あぶら取り紙の製造方法における前記箔打ちは、前記高圧処理がなされた紙を300〜350枚重ねた状態で、槌の重量が16kgのベルトハンマー機を用い、打撃速度を約500回/分とし、箔打ち時間を10.5秒から315秒の範囲で行うことを要旨とする。 According to a fifth aspect of the present invention, in the method for manufacturing a cosmetic oil blotting paper according to the third or fourth aspect, the foil punching is performed by stacking 300 to 350 sheets of the high-pressure treated paper, and the weight of the hammer is reduced. The gist is to use a 16 kg belt hammer, set the impact speed to about 500 times / min, and perform the foiling time in the range of 10.5 seconds to 315 seconds.
請求項1又は2の発明は、単に箔打ちを行なって形成した化粧用あぶら取り紙よりも、使用後の透明性が高い特性が得られ、しかも平滑度を高圧処理で行なった場合よりも低くでき、かつ密度は箔打ち処理のみを行なった場合よりも大きくなるため、皮脂の取れ方を良くすることができる。更に、高圧処理を行なったとき良好に乾燥したものとすることができ、たるみ並びに皺等がない化粧用あぶら取り紙とすることができる。
The invention according to
請求項3〜5の発明によれば、請求項1又は2の化粧用あぶら取り紙を効率良く得ることができる。 According to the third to fifth aspects of the invention, it is possible to efficiently obtain the decorative oil removing paper of the first or second aspect.
以下に、製造方法の一例を挙げるが、これに限定されるものではない。
(製造方法)
原料は、マニラ麻(アバカ)、亜麻、黄麻、サイザル麻、ケナフ、雁皮、楮、バナナ繊維あるいは三椏から成る靭皮繊維又は木材パルプから選ばれた少なくとも一種を50重量部%以上を用いることが望ましい。50重量部%を下回ると、強度が弱く使用時に破けを生じ易くて好ましくない。
Hereinafter, an example of the manufacturing method will be described, but the present invention is not limited thereto.
(Production method)
As the raw material, it is preferable to use 50% by weight or more of at least one kind selected from manila hemp (abaka), flax, jute, sisal, kenaf, ganpi, kozo, banana fiber or bast fiber made of mitsumata or wood pulp. . If the amount is less than 50% by weight, the strength is weak, and it is easy to break when used, which is not preferable.
ビー夕ー等の叩解機にて所定の叩解度に調成し、更にタルク等の無機質填料を植物繊維等の原料100重量部に対して0.5〜40重量部%混合して均一分散する。そして、そのまま抄紙すると、繊維への填料定着が悪く、排水の問題並びに工程の汚れが発生するため、その後定着剤としてファイレックスRC104及びファイレックスM(ともに、明成化学工業株式会社製)等を用い、繊維への定着性を向上する。その後、丸網抄紙機、短網抄紙機、長網抄紙機等の抄き網で、一層のものを抄紙する。 The mixture is prepared to a predetermined degree of beating by a beating machine such as Bee-Bee, and 0.5 to 40 parts by weight of an inorganic filler such as talc is mixed and uniformly dispersed with respect to 100 parts by weight of a raw material such as vegetable fiber. . Then, if the paper is made as it is, the fixation of the filler to the fiber is poor, and the problem of drainage and the contamination of the process occur. Therefore, Filex RC104 and Filex M (both manufactured by Meisei Chemical Industry Co., Ltd.) are used as fixing agents. And improve the fixing property to the fiber. Thereafter, one layer is made with a paper net such as a round net paper machine, a short net paper machine, or a long net paper machine.
更に二層の場合は抄き漕を2本として一層と同様、表層と裏層に形成する。又、二層抄き合わせの場合は第一抄き漕は金網60〜120メッシュを使用して凹凸層のない層(平滑層)を形成し、更に第二抄き漕も金網60〜120メッシュを使用して凹凸層のない層(平滑層)を形成し坪量15〜25g/m2の紙を抄造する。 Further, in the case of two layers, two sheeting tanks are formed on the surface layer and the back layer as in the case of one layer. In the case of two-layer papermaking, the first papermaking tank uses a wire mesh of 60 to 120 mesh to form a layer (smooth layer) without an uneven layer, and the second papermaking tank also uses a wire mesh of 60 to 120 mesh. Is used to form a layer having no uneven layer (smooth layer), and paper having a basis weight of 15 to 25 g / m 2 is formed.
坪量15g/m2未満の場合、紙の強度がなく、使用時に破けを生じ易く、又、25g/m2を越えると柔軟性がなくなり、使用時肌との馴染みが悪く違和感があり、さらには、使用時の透明性にもかけるため25g/m2以下が好ましい。 When the grammage is less than 15 g / m 2 , the paper has no strength and tends to be torn during use. When the grammage exceeds 25 g / m 2 , the paper loses its flexibility, and when used it has a poor fit with the skin and gives a sense of incongruity. Is preferably 25 g / m 2 or less to increase transparency during use.
なお、一層であって、凹凸層としたい場合には、丸網抄紙機、短網抄紙機、長網抄紙機等の抄き網であって、線径0.1〜1 .0mmで5〜40メッシュのものを使用して網目模様にて一層の凹凸紙を形成する、又は抄き網に部分的に金網の目を詰めることによりその部分は原料が乗らず一層の凹凸紙を形成できる。 When a single layer is to be formed as an uneven layer, it is a net for a round net paper machine, a short net paper machine, a long net paper machine or the like, and has a wire diameter of 0.1-1. A layer of uneven paper is formed in a mesh pattern using a mesh having a mesh of 0 to 5 mm, or a mesh is partially filled with a metal mesh to form a layer of uneven paper in which the raw material does not ride. Can be formed.
更に二層の場合は抄き漕を2本として一層と同様、図1(a)に示すように表層と裏層に凹凸層20を形成する。又、二層抄き合わせの場合は第一抄き漕は金網60〜120メッシュを使用して凹凸層のない層(平滑層)22を形成し、更に第二抄き漕は線径0.1〜1 .0mmで5〜40メッシュを使用又は部分的に金網の目を詰めることにより凹凸層21を形成し、坪量15〜25g/m2の紙を抄造する(図1(b)を参照)。
Further, in the case of two layers, the
なお、使用される無機質填料はクレー、タルク、カオリン、炭酸カルシウム、酸化チタンあるいはホワイトカーボンの中から選ばれたものが使用できるが、皮脂の吸油量を多くするには、マイクロタルクを使用し平均粒子径2.5μ以下で表面積13.0 BETm2 /g以上のものが望ましい。 The inorganic filler used may be selected from clay, talc, kaolin, calcium carbonate, titanium oxide and white carbon.However, in order to increase the oil absorption of sebum, use micro talc. It is desirable that the particles have a particle diameter of 2.5 μ or less and a surface area of 13.0 BETm 2 / g or more.
使用後の透明性を上げるには密度を0.8〜1.2g/cm3と高密度化する必要があり、所定の寸法にした後、スーパーキャレンダー、熱キャレンダー又は高圧プレス等の高圧処理を行なう。そして、高圧処理によって、平滑性(平滑度)が高すぎたのを抑えるために、箔打ち工程で数百回〜数千回の処理を行う。 In order to increase the transparency after use, it is necessary to increase the density to 0.8 to 1.2 g / cm 3, and after setting to a predetermined size, use a super calender, a heat calender or a high-pressure press such as a high-pressure press. Perform processing. Then, in order to prevent the smoothness (smoothness) from being too high due to the high-pressure treatment, the foiling step is performed several hundred to several thousand times.
以下、実施例について説明する。
(実施例1)
実施例1では、下記の紙料、無機填料、及び定着剤を使用した。
Hereinafter, examples will be described.
(Example 1)
In Example 1, the following stock, inorganic filler, and fixing agent were used.
マニラ麻 叩解度SR30゜ 100部
マイクロタルク 平均粒子径 1.2μ 20部
表面積 14.5 BETm2/g
定着剤 ファィレックスRC−104 0.5%
ファイレックスM 0.3%
すなわち、マニラ麻をビーターにて所定の叩解度に調成し、マイクロタルクを20.0重量部を混合して均一分散とした。そして、その後、定着剤としてファイレックスRC−104及びファイレックスM(ともに、明成化学工業株式会社製)を用いて、繊維へ定着させ、その後、丸網抄紙機にて、1本バットにて坪量22g/m2で平滑紙を抄紙した。
Manila hemp beating degree SR30 ゜ 100 parts Microtalc Average particle size 1.2
Fixing agent Filex RC-104 0.5%
Filex M 0.3%
That is, Manila hemp was prepared to a predetermined beating degree by a beater, and 20.0 parts by weight of micro talc was mixed to obtain a uniform dispersion. After that, using Firex RC-104 and Firex M (both manufactured by Meisei Chemical Industry Co., Ltd.) as fixing agents, the fibers are fixed to the fiber, and thereafter, a single mesh vat is used in a round mesh paper machine. A smooth paper was made at an amount of 22 g / m 2 .
次工程において、水分量(割合)が14%,16%,18%,21%のものをスーパーキャレンダーにて高圧処理を行なった。その結果を表2に示す。
又、併せて比較対象のために従来品として、「(A2)生原紙」及び「(N)」のものを表2に示す。
In the next step, those having water contents (ratio) of 14%, 16%, 18% and 21% were subjected to high pressure treatment by a super calender. Table 2 shows the results.
In addition, Table 2 shows "(A2) raw paper" and "(N)" as conventional products for comparison.
(条件)
高圧処理方法:スーパーキャレンダー
スーパーキャレンダー条件:14段での13ニップ
線圧力:300kg/cm、温度:80℃
スピード:200m/分
上記表2中、「(A2)生原紙」とは、高圧処理、箔打ち処理のいずれの処理も行なっていないものである。又、「(N)」は、スーパーキャレンダー(高圧処理)の代わりに、表1の「(F)」と同様の箔打ち条件で箔打ち処理のみ行なったものである(なお、従来条件のものの水分量は7±0.5%である。)
以上のことから、スーパーキャレンダーのみで高圧処理した場合には、密度は、箔打ち品よりも高くすることができる。一方、スーパーキャレンダーのみ((I)〜(L))では、箔打ち品(F)と異なり、平滑度を100以下にすることは困難である。
(conditions)
High pressure treatment method: Super calender Super calender conditions: 13 nips at 14 stages Line pressure: 300 kg / cm, Temperature: 80 ° C
Speed: 200 m / min In Table 2 above, “(A2) raw paper” is one that has not been subjected to any of high-pressure treatment and foil stamping treatment. “(N)” is obtained by performing only the foiling treatment under the same foiling conditions as “(F)” in Table 1 in place of the super calender (high-pressure treatment) (note that the conventional condition was not applied). The water content is 7 ± 0.5%.)
From the above, when high-pressure treatment is performed only with the super calender, the density can be higher than that of the foil stamped product. On the other hand, with the super calender only ((I) to (L)), it is difficult to reduce the smoothness to 100 or less, unlike the foil stamped product (F).
なお、水分量が22%以上の場合には、紙が完全に乾燥できず、高圧処理後、たるみ並びに皺等のトラブルが発生しやすくなった。又、水分量14%では、0.80g/cm3以上の密度を得ることができないことがわかった。従って、高圧処理時の抄紙の水分量は、16%〜21%であることが望ましいことが分かった。 When the water content was 22% or more, the paper could not be completely dried, and after the high-pressure treatment, problems such as slack and wrinkles were likely to occur. Further, it was found that a density of 0.80 g / cm 3 or more could not be obtained with a water content of 14%. Therefore, it was found that the water content of the paper during the high-pressure treatment was desirably 16% to 21%.
次に、前記水分量18%のものを上記のようにスーパーキャレンダーで高圧処理を行なった後に、箔打ち処理を行なった。このときの、箔打ち処理条件は、前記従来の箔打ちの条件(従来条件)と同じである。 Next, after the high-pressure treatment of the water content of 18% by the super calender as described above, the foil stamping treatment was performed. The foiling treatment conditions at this time are the same as the conventional foiling conditions (conventional conditions).
スーパーキャレンダーによる高圧処理、及び箔打ち処理を行なったもの(実施例品)と、「(A2)生原紙」、「箔打ち品」(N)の、密度、平滑度、不透明度、表面粗さを表3に示す。 The density, smoothness, opacity, and surface roughness of the product subjected to high pressure treatment and foil stamping by a super calender (Example product) and “(A2) raw paper” and “Foil stamped product” (N) Table 3 shows the results.
この結果、実施例1の品では、平均表面粗さが2.80μmと非常に大きくなったため、非常に皮脂の吸油性がよくなり、又、取り除いた皮脂により、あぶら取り紙の透明性が高くなったことが確認できた。 As a result, the product of Example 1 had an extremely large average surface roughness of 2.80 μm, so that the oil absorbency of sebum was very good, and the oil seizure was removed, so that the transparency of the oil removing paper was high. It has been confirmed that it has become.
なお、スーパーキャレンダーのみで形成した化粧用あぶら取り紙(K)の場合には、平滑性(度)が高すぎるのに加えて、又、平均表面粗さが1.65μmと非常に小さいため、皮脂の取れ方が悪くなった。 In the case of the cosmetic oil blotting paper (K) formed only with a super calender, the smoothness (degree) is too high and the average surface roughness is extremely small at 1.65 μm. , How to remove sebum became worse.
又、箔打ち品(N)では、密度は0.8g/cm3以上のものが得られなかった。
(実施例2)
次に、実施例2では、下記の紙料、無機填料、及び定着剤を使用した。
Further, in the case of the foil stamped product (N), a product having a density of 0.8 g / cm 3 or more was not obtained.
(Example 2)
Next, in Example 2, the following stock, inorganic filler, and fixing agent were used.
マニラ麻(アバカ) 叩解度SR30゜ 100部
マイクロタルク 平均粒子径 1.2μ 20部
表面積 14.5 BETm2/g
定着剤 ファィレックスRC−104 0.5%
ファイレックスM 0.3%
すなわち、マニラ麻(アバカ)をビーターにて所定の叩解度に調成し、マイクロタルクを20.0重量部を混合して均一分散とした。そして、その後、定着剤としてファイレックスRC−104及びファイレックスM(ともに、明成化学工業株式会社製)を用いて、繊維へ定着させ、その後、丸網抄紙機にて、抄造した。
Manila hemp (abaka) Beating degree SR30SR 100 parts Microtalc Average particle size 1.2
Fixing agent Filex RC-104 0.5%
Filex M 0.3%
That is, Manila hemp (abaka) was prepared with a beater to a predetermined beating degree, and 20.0 parts by weight of micro talc was mixed to obtain a uniform dispersion. Then, using Firex RC-104 and Firex M (both manufactured by Meisei Chemical Industry Co., Ltd.) as fixing agents, the fibers were fixed to the fibers, and then the paper was formed by a round mesh paper machine.
丸網抄紙機の抄き網は線径0.2mmで16メッシュのものを使用し、1本バットにて坪量22g/m2で片面側に凹凸層を抄紙した。
次工程において、実施例1と同条件下でスーパーキャレンダーにて高圧処理を行い、その後、下記の箔打ち条件を基本に、箔打ち時間を変えて箔打ちを行なった。
The round mesh paper machine used was a mesh having a wire diameter of 0.2 mm and a mesh of 16 mesh, and an uneven layer was formed on one side with a basis weight of 22 g / m 2 using a single bat.
In the next step, high-pressure treatment was performed with a super calender under the same conditions as in Example 1, and thereafter, foiling was performed with the foiling time varied based on the following foiling conditions.
(箔打ちの条件)
紙のサイズ:約21cm角、箔打ち機:ベルトハンマー機、槌の重量:16kg、受け台:石又は鉄、打撃速度:約500回/分、箔打ち時間:105秒
上記の条件で、上記の紙を300〜350枚を重ねた状態で箔打ちを行なう。その場合の密度、平滑度、不透明度、表面粗さを測定した結果、及び生原紙(A1)、スーパーキャレンダー加工紙(M)を下記の表4に示す。
(Foiling conditions)
Paper size: about 21 cm square, foiling machine: belt hammer machine, weight of hammer: 16 kg, cradle: stone or iron, impact speed: about 500 times / minute, foiling time: 105 seconds, under the above conditions Is performed in a state where 300 to 350 sheets of paper are stacked. The results of measuring the density, smoothness, opacity and surface roughness in that case, as well as the raw paper (A1) and the super calendered paper (M) are shown in Table 4 below.
又、「(a)1/10」、「(b)1/4 」、「(c)1/2 」、「(d)3/4 」、「(e)1 」、「(f)2 」、「(g)3 」の中の数字は、上記の箔打ちの条件中の「箔打ち時間」にその数字を倍数にした時間で箔打ちを行なった場合のものを示している。 Also, "(a) 1/10", "(b) 1/4", "(c) 1/2", "(d) 3/4", "(e) 1", "(f) 2 The numbers in "" and "(g) 3" indicate the case where the foiling is performed in a time obtained by multiplying the number by the "foiling time" in the above-described foiling conditions.
そして、上記表4のものと、表1のものを図2乃至図6にて示す。図2は密度と箔打ち時間との関係を示す特性図、図3は不透明度と箔打ち時間との関係示す特性図、図4はA面における平滑度と箔打ち時間との関係を示す特性図、図5はB面における平滑度と箔打ち時間との関係を示す特性図である。 {Circle around (4)} and FIGS. 2 to 6 show those of Table 4 and Table 1. 2 is a characteristic diagram showing the relationship between the density and the foiling time, FIG. 3 is a characteristic diagram showing the relationship between the opacity and the foiling time, and FIG. 4 is a characteristic showing the relationship between the smoothness on the A-side and the foiling time. FIG. 5 and FIG. 5 are characteristic diagrams showing the relationship between the smoothness on the B side and the foiling time.
図2のことから、箔打ち時間が従来よりも長い時間(2倍、或いは3倍)であっても、密度が0.9g/cm3以上のものを得ることができることが理解できる。すなわち、生原紙、或いは箔打ちのみの(A1)〜(H)の比較例よりも(a)〜(g)の方が密度が高いものが得られる。 From FIG. 2, it can be understood that even if the foiling time is longer than the conventional one (double or triple), a density of 0.9 g / cm 3 or more can be obtained. That is, the density of (a) to (g) is higher than that of the comparative examples (A1) to (H) in which raw paper or foil stamping alone is used.
図3においては、縦軸は不透明度(%)を表しているため、低い方が透明度が高いものとなる、このことから、透明度は、実施例2の(a)〜(g)の方が生原紙、或いは箔打ちのみの(A1)〜(H)の比較例よりも高いものが得られる。 In FIG. 3, the vertical axis represents the opacity (%), so that the lower the opacity, the higher the transparency. Therefore, the transparency is higher in (a) to (g) of Example 2. A higher raw material than the comparative examples of (A1) to (H) in which raw paper or foil stamping alone is obtained.
図4及び図5は、それぞれA面及びB面の平滑度を表している。このことから、スーパーキャレンダー加工後、箔打ちを行なうと、比較的少ない箔打ち時間(1/10の(a)等)であっても、急激に平滑性を失うことが理解できる。又、スーパーキャレンダー加工後、比較的長い時間箔打ちを行なっても平滑度は、ある程度のレベルまでは下がるが、箔打ちだけを行なったものよりは、その平滑度が高いことが理解できる。 FIGS. 4 and 5 show the smoothness of the A surface and the B surface, respectively. From this, it can be understood that when foiling is performed after the super calendering, the smoothness is rapidly lost even with a relatively short foiling time (such as (a) of 1/10). Further, it can be understood that even if foiling is performed for a relatively long time after the super calendering, the smoothness is reduced to a certain level, but the smoothness is higher than that obtained by performing only foiling.
そして、図6に示すように、平均表面粗さ(A面における)は、スーパーキャレンダー加工を行なわない比較例に比較して、その平均表面粗さは小さいものの、スーパーキャレンダー加工後、箔打ち時間を長くする((f)の場合)と、比較例のものの平均表面粗さに近くなることが理解できる。 Then, as shown in FIG. 6, the average surface roughness (on the surface A) is smaller than that of the comparative example in which the super calendering is not performed. It can be understood that the longer the hitting time (in the case of (f)), the closer to the average surface roughness of the comparative example.
このように、実施例2では、スーパーキャレンダー加工を行なった後、箔打ちを行なうと、平均表面粗さが、箔打ちのみを行なった場合に近くなるとともに、密度は、明らかに、比較例よりも大きなものとすることができる。 Thus, in Example 2, when the super calendering was performed and then the foiling was performed, the average surface roughness was close to the case where only the foiling was performed, and the density was obviously higher than that of the comparative example. And larger.
この結果、実施例2の品では、平均表面粗さが1.9〜2.7μmと大きくなり、かつ密度が箔打ちのみの処理を行なった場合よりも大きくなったため、皮脂の吸油性がよくなり、又、取り除いた皮脂により、あぶら取り紙の透明性が高くなったことが確認できた。特に、スーパーキャレンダー加工後、箔打ち時間を長くした方がより良い結果が得られた。すなわち、(a)のものよりも(b)のものの方が、(b)よりも(c)のものの方が、というように箔打ち時間が長くなると、より良好な皮脂吸収効果が得られることが分かった。なお、(f)と(g)のものとでは、(f)のものの方が皮脂の吸収性は良い傾向を示すが、(g)は(e)と平均表面粗さがそれほど大きな変わりがないため、その皮脂吸収性は、(e)と同じ程度であった。 As a result, in the product of Example 2, the average surface roughness was as large as 1.9 to 2.7 μm, and the density was higher than that in the case of performing only the foil stamping. In addition, it was confirmed that the transparency of the oil removing paper was increased by the removed sebum. In particular, better results were obtained by increasing the foiling time after super calendering. In other words, when the foiling time is longer for (b) than for (a), for (c) than for (b), a better sebum absorption effect can be obtained. I understood. It should be noted that, between (f) and (g), the one with (f) shows a better tendency to absorb sebum, but the one with (g) does not show much difference in average surface roughness from (e). Therefore, the sebum absorbency was about the same as (e).
なお、この発明は、前記実施例に限定されるものではなく、この発明から逸脱しない範囲で任意に変更可能である。 The present invention is not limited to the above embodiment, and can be arbitrarily changed without departing from the present invention.
20…凹凸層、21…凹凸層、22…平滑層。 # 20: an uneven layer, 21: an uneven layer, 22: a smooth layer.
Claims (5)
前記高圧処理は、水分量が16〜21%の紙に対して行なわれたことを特徴とする化粧用あぶら取り紙。 A cosmetic oil-absorbing paper, which is made of a raw material mainly composed of vegetable fiber, is subjected to high-pressure treatment, and is characterized by being foiled,
The high-pressure treatment is performed on paper having a water content of 16% to 21%.
前記高圧処理を、水分量が16〜21%の紙に対して行なうことを特徴とする化粧用あぶら取り紙の製造方法。 A method for producing a cosmetic oil-absorbing paper, characterized in that, after high-pressure processing of paper made of a raw material mainly composed of vegetable fiber by a paper machine, further foiling is performed,
A method for producing decorative oil removing paper, wherein the high-pressure treatment is performed on paper having a water content of 16 to 21%.
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