JP2003081721A - Method for controlling flying insect pest in room - Google Patents

Method for controlling flying insect pest in room

Info

Publication number
JP2003081721A
JP2003081721A JP2001279522A JP2001279522A JP2003081721A JP 2003081721 A JP2003081721 A JP 2003081721A JP 2001279522 A JP2001279522 A JP 2001279522A JP 2001279522 A JP2001279522 A JP 2001279522A JP 2003081721 A JP2003081721 A JP 2003081721A
Authority
JP
Japan
Prior art keywords
aerosol
boiling point
solvent
formulation
room
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001279522A
Other languages
Japanese (ja)
Inventor
Tomonori Iwasaki
智則 岩崎
Tadakatsu Matsunaga
忠功 松永
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP2001279522A priority Critical patent/JP2003081721A/en
Priority to MYPI20022947A priority patent/MY134711A/en
Priority to KR1020020053270A priority patent/KR100907196B1/en
Priority to ES200202027A priority patent/ES2204309B1/en
Priority to BR0203542-1A priority patent/BR0203542A/en
Priority to ARP020103453A priority patent/AR036590A1/en
Priority to IT000795A priority patent/ITTO20020795A1/en
Priority to CNB021426066A priority patent/CN1250082C/en
Publication of JP2003081721A publication Critical patent/JP2003081721A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06—Aerosols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/20—Targets to be treated

Abstract

PROBLEM TO BE SOLVED: To provide a method for efficiently controlling flying insect pests in a room by a simple means without needing the repeated sprays of an aerosol agent and the continuous operation of an electric appliance such as an electric mosquito-killing incense matt or a liquid electric mosquito-killing incense burner. SOLUTION: This method for controlling the flying insect pests in the room is characterized by adhering a tetrafluorobenzyl ester compound represented by the general formula (1) (R is methyl or methoxymethyl) to the surface of a structure or equipment, such as curtain, furniture, ceiling, room side surface or window, in the room.

Description

【発明の詳細な説明】Detailed Description of the Invention

【０００１】[0001]

【発明の属する技術分野】本発明は、家屋内における飛
翔性害虫の駆除方法に関する。TECHNICAL FIELD The present invention relates to a method for exterminating flying pests in a house.

【０００２】[0002]

【従来の技術】家屋の室内空間を飛翔する、いわゆる飛
翔性害虫、例えば蚊類 、ハエ類、などの進入が見られ
た場合、エアゾール剤で害虫をめがけて噴霧する方法が
知られている。飛翔性害虫が次々と進入してくる場合に
は、この方法ではその都度噴霧を行う必要がある。ま
た、蚊の駆除において、電気器具により継続的に薬剤を
加熱蒸散させて駆除する方法が知られている（電気蚊取
りマット、液体電気蚊取り液など）。2. Description of the Related Art When so-called flying insects such as mosquitoes and flies that enter the indoor space of a house are invaded, it is known to spray the insects with an aerosol agent. When flying pests enter one after another, this method requires spraying each time. Further, in the control of mosquitoes, a method is known in which a drug is continuously heated and evaporated by an electric device to control the mosquito (electric mosquito repellent mat, liquid electric mosquito repellent liquid, etc.).

【０００３】[0003]

【発明が解決しようとする課題】本発明は、繰り返し噴
霧や、電気器具等の継続的な運転を必要とせず、簡便な
手段によって家屋内飛翔性害虫を効率的に駆除する方法
を提供することを課題とする。DISCLOSURE OF THE INVENTION The present invention provides a method for efficiently controlling indoor flying pests by simple means without the need for repeated spraying or continuous operation of electric appliances and the like. Is an issue.

【０００４】[0004]

【課題を解決するための手段】本発明者らは、上記課題
につき鋭意検討を重ねた結果、特定の化合物を家屋室内
の構造物または備品の表面に付着させることにより、目
的が達成されることを見出し本発明に至った。すなわち
本発明は、一般式（１） （式中、Ｒはメチル基またはメトキシメチル基を表
す。）で示されるテトラフルオロベンジルエステル化合
物（以下、本化合物と記す。）を、室内の構造物または
備品の表面に付着せしめることを特徴とする家屋室内に
おける飛翔性害虫の駆除方法（以下、本発明方法と記
す。）を提供する。Means for Solving the Problems As a result of intensive studies on the above problems, the present inventors achieved the object by attaching a specific compound to the surface of a structure or equipment in a house. This led to the present invention. That is, the present invention has the general formula (1) (In the formula, R represents a methyl group or a methoxymethyl group.) A tetrafluorobenzyl ester compound (hereinafter referred to as the present compound) is attached to the surface of an indoor structure or fixture. A method for exterminating flying pests in a house (hereinafter, referred to as the method of the present invention) is provided.

【０００５】[0005]

【発明の実施の形態】本化合物は、害虫防除活性成分と
して、特開平１２−６３３２９号公報に記載の化合物で
あり、該公報に記載の方法に準じて製造することができ
る。BEST MODE FOR CARRYING OUT THE INVENTION The present compound is a compound described in JP-A No. 12-63329 as an active ingredient for controlling pests, and can be produced according to the method described in the publication.

【０００６】本化合物には、一般式（１）の置換基Rが
メチル基である化合物と、置換基Rがメトキシメチル基
である化合物が含まれるが、本発明方法においては、そ
のそれぞれを単独で使用しても良いし、両者の混合物を
使用しても良い。The present compound includes a compound in which the substituent R in the general formula (1) is a methyl group and a compound in which the substituent R is a methoxymethyl group. In the method of the present invention, each of them is used alone. May be used, or a mixture of both may be used.

【０００７】本化合物には不斉炭素に基づく光学異性体
やシクロプロパン環に基づく幾何異性体等の立体異性体
が存在する。害虫防除活性を有する全ての光学異性体や
その混合物、害虫防除活性を有する全ての幾何異性体や
その混合物が本化合物には含まれる。The present compound has stereoisomers such as optical isomers based on asymmetric carbon and geometric isomers based on cyclopropane ring. The compound includes all optical isomers having pest control activity and mixtures thereof, and all geometric isomers having pest control activity and mixtures thereof.

【０００８】本発明方法において家屋室内の構造物と
は、天井、室内側壁面、柱、欄間、窓、扉等の家屋の１
区画（部屋）を構成する構造物を指し、家屋室内の備品
とは、カーテン、家具（箪笥、収納棚、蛍光燈、机、椅
子、掛け軸、暖簾、ブラインド、ピアノ、花瓶など）等
の通常は部屋内外へ移動可能な物品を指す。In the method of the present invention, the structure in the house is one of the houses such as the ceiling, the side wall of the room, the pillars, the rails, the windows and the doors.
This refers to the structure that composes the compartment (room), and the fixtures in the house are usually curtains, furniture (such as chests, storage shelves, fluorescent lights, desks, chairs, hanging scrolls, curtains, blinds, pianos, vases). An item that can be moved in and out of a room.

【０００９】本発明方法において、家屋室内の構造物ま
たは備品の表面に本化合物を付着せしめる具体的な方法
としては、本化合物及び噴射剤を含有するエアゾール剤
などの噴霧剤を用いて該構造物または該備品に向かって
吹き付ける方法や、刷毛やブラシにより本化合物を含有
する油剤、水性液剤等を該構造物または該備品の表面に
塗り付ける方法を挙げることができる。また、密閉した
室内で全量噴射型のエアゾール剤、燻煙剤、加熱式器具
あるいは送風式器具を用いて室内空間に本化合物を放出
させ、２−３時間内に該空間に放出された本化合物を自
然に該構造物または該備品に付着させる方法をあげるこ
ともできる。この方法は通常、人が室内にいない状態で
行われる。In the method of the present invention, as a specific method for adhering the present compound to the surface of a structure or equipment in a house, a spray agent such as an aerosol agent containing the present compound and a propellant is used to form the structure. Alternatively, there may be mentioned a method of spraying onto the equipment or a method of applying an oil solution, an aqueous liquid agent or the like containing the present compound to the surface of the structure or the equipment with a brush or a brush. Further, the present compound was released into the indoor space by using an aerosol agent, a smoke agent, a heating type device, or a blowing type device of a total injection type in a closed room, and the present compound released into the space within 2-3 hours. It is also possible to cite a method of naturally adhering to the structure or the equipment. This method is usually performed with no people in the room.

【００１０】本化合物を該構造物または該備品に付着さ
せる量は１ｍ3当たり、通常０．１〜１０００ｍｇであ
り、好ましくは１〜５００ｍｇである。例えば本化合物
及び噴射剤を含有するエアゾール剤（以下、本エアゾー
ル剤と記すことがある。）を用いて本化合物を付着せし
める場合、本エアゾール剤中の本化合物の含有量は、通
常０．００１〜２０重量％程度である。The amount of the present compound attached to the structure or the equipment is usually 0.1 to 1000 mg, preferably 1 to 500 mg per 1 m 3 . For example, when the present compound is attached using an aerosol agent containing the present compound and a propellant (hereinafter sometimes referred to as the present aerosol agent), the content of the present compound in the present aerosol agent is usually 0.001. It is about 20% by weight.

【００１１】本エアゾール剤における噴射剤としては、
エアゾール剤中の液体部分と均一に混じりうる、沸点２
５℃以下の化合物、例えば、１，１−ジフルオロエタン
（沸点−２５．０℃）、１，１，１，２−テトラフルオ
ロエタン（沸点−２６．２℃）等のフルオロカーボン、
ジメチルエーテル（沸点−２４．８℃）、プロパン（沸
点−４２．１℃）、ｎ−ブタン（沸点−０．５℃）、イ
ソブタン（沸点−１２℃）等を挙げることができ、これ
らは単独でまたは２種以上の混合物で使用することがで
きる。As the propellant in the present aerosol agent,
Boiling point 2 that can mix uniformly with the liquid part of the aerosol
Compounds having a temperature of 5 ° C. or lower, for example, fluorocarbons such as 1,1-difluoroethane (boiling point-25.0 ° C.) and 1,1,1,2-tetrafluoroethane (boiling point-26.2 ° C.),
Examples include dimethyl ether (boiling point −24.8 ° C.), propane (boiling point −42.1 ° C.), n-butane (boiling point −0.5 ° C.), isobutane (boiling point −12 ° C.), etc. Alternatively, it can be used as a mixture of two or more kinds.

【００１２】本エアゾール剤における噴射剤の量は、通
常２０〜９９．９９９９重量％である。The amount of propellant in the present aerosol is usually 20 to 99.9999% by weight.

【００１３】本エアゾール剤中には、さらに溶剤を含有
することができる。溶剤としては、沸点３０〜２１０℃
の溶剤が好ましく、沸点３０〜１２０℃の溶剤がより好
ましく、沸点３０〜１００℃の溶剤はさらに好ましい。
実用的には、溶剤として実質的に沸点３０〜２１０℃の
溶剤のみを含むエアゾール剤が好ましい。ここで沸点３
０〜２１０℃の溶剤とは、溶剤を構成する全成分の沸点
が実質的に３０〜２１０℃の範囲であることを意味し、
具体的には、単独の溶剤の場合にはその溶剤の沸点が、
また、２種以上の混合溶剤の場合には該混合溶剤の９５
重量％以上の成分の沸点が３０〜２１０℃の範囲である
ことを意味する。沸点３０〜１２０℃の溶剤及び沸点３
０〜１００℃の溶剤についても同様である。また、特に
断りのない限り、溶剤の沸点とは大気圧における沸点を
意味する。The aerosol composition of the present invention may further contain a solvent. As a solvent, boiling point is 30 to 210 ° C.
Is preferable, a solvent having a boiling point of 30 to 120 ° C. is more preferable, and a solvent having a boiling point of 30 to 100 ° C. is further preferable.
Practically, an aerosol agent containing substantially only a solvent having a boiling point of 30 to 210 ° C. as a solvent is preferable. Boiling point 3 here
A solvent of 0 to 210 ° C. means that the boiling points of all components constituting the solvent are substantially in the range of 30 to 210 ° C.,
Specifically, the boiling point of the solvent in the case of a single solvent,
Further, in the case of two or more kinds of mixed solvents, 95% of the mixed solvents
It means that the boiling point of the component of not less than wt% is in the range of 30 to 210 ° C. Solvent with a boiling point of 30 to 120 ° C and boiling point 3
The same applies to the solvent of 0 to 100 ° C. Unless otherwise specified, the boiling point of the solvent means the boiling point at atmospheric pressure.

【００１４】また、溶剤としては、本エアゾール剤全体
を均一に保ち得る溶剤が好ましい。ここで組成物全体が
均一であるとは、水層と油層で分離した状態、結晶が析
出した状態、乳濁状態、懸濁状態等の状態を実質的に示
さず、いわゆる溶液状態であることを意味する。Further, the solvent is preferably a solvent which can keep the whole aerosol composition uniformly. Here, that the entire composition is uniform means that it is in a so-called solution state, which does not substantially indicate a state in which it is separated in an aqueous layer and an oil layer, a state in which crystals are precipitated, an emulsion state, a suspension state, or the like. Means

【００１５】かかる溶剤としては、例えば、ｎ−ブチル
アルコール（沸点１１７．９℃）、sec.−ブチルアルコ
ール（沸点９９．５℃）、tert.−ブチルアルコール
（沸点８２．３℃）、ｎ−プロピルアルコール（沸点９
７．２℃）、イソプロピルアルコール（沸点８２．４
℃）、エチルアルコール（沸点７８．３℃）、ヘキサン
（沸点６９℃）、ヘプタン（沸点９８．４℃）、２−メ
チルペンタン（沸点６０℃）、２，２−ジメチルブタン
（沸点５０℃）、オクタン（沸点１２５℃）、ノナン
（沸点１４９．５℃）、デカン（沸点１７４℃）、ウン
デカン（沸点１９５．９℃）、ＩＰ１６２０（出光石油
化学株式会社製商品名、イソパラフィン系溶剤、沸点１
６６〜２０２℃）、ＩＰ１０１６（出光石油化学株式会
社製商品名、イソパラフィン系溶剤、沸点７３〜１４０
℃）等を挙げることができる。また、水（沸点１００
℃）を挙げることもできるが、前記した如く本エアゾー
ル剤全体を均一に保つという点からは、水を用いる場合
には、水と相溶性を有し、かつ本化合物及び噴射剤とも
相溶性を有する、例えばイソプロパノール等のアルコー
ル類との混合溶剤として用いることが好ましい。Examples of the solvent include n-butyl alcohol (boiling point 117.9 ° C.), sec.-butyl alcohol (boiling point 99.5 ° C.), tert.-butyl alcohol (boiling point 82.3 ° C.), n- Propyl alcohol (boiling point 9
7.2 ° C.), isopropyl alcohol (boiling point 82.4)
° C), ethyl alcohol (boiling point 78.3 ° C), hexane (boiling point 69 ° C), heptane (boiling point 98.4 ° C), 2-methylpentane (boiling point 60 ° C), 2,2-dimethylbutane (boiling point 50 ° C). , Octane (boiling point 125 ° C), nonane (boiling point 149.5 ° C), decane (boiling point 174 ° C), undecane (boiling point 195.9 ° C), IP1620 (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 1
66 to 202 ° C.), IP1016 (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 73 to 140)
℃) and the like. In addition, water (boiling point 100
However, when water is used, it is compatible with water and is also compatible with the present compound and the propellant, as described above. It is preferable to use it as a mixed solvent with alcohols such as, for example, isopropanol.

【００１６】溶剤を用いる場合の本エアゾール剤中の溶
剤の量は７９．９９９９重量％以下であり、好ましくは
５〜６０重量％である。When a solvent is used, the amount of the solvent in the present aerosol agent is 79.9999% by weight or less, preferably 5 to 60% by weight.

【００１７】本エアゾール剤中には、その他例えば、悪
臭トラップに効能のあるβ−シクロデキストリンやベタ
イン、抗バクテリア剤であるトリクロル酸やヒノキチオ
ール、悪臭のマスキングに効果のある植物精油等を含有
することができ、これらβ−シクロデキストリン、トリ
クロル酸、ヒノキチオール、植物精油等を含有する場合
の含有量は本エアゾール剤中に通常０．１〜１重量％で
ある。In addition to β-cyclodextrin and betaine, which are effective for trapping malodors, trichloric acid and hinokitiol which are antibacterial agents, and plant essential oil which is effective in masking malodors, etc. When the β-cyclodextrin, trichloric acid, hinokitiol, plant essential oil and the like are contained, the content is usually 0.1 to 1% by weight in the present aerosol.

【００１８】本エアゾール剤は例えば、以下のようにし
て得ることができる。本化合物、必要により溶剤や他の
害虫防除活性化合物、忌避剤、共力剤、安定剤等をエア
ゾール容器に充填する。該容器にエアゾールバルブを装
着し、噴射剤をステムを通して該容器中に充填し、振と
うした後、アクチュエーターを装着することにより成さ
れる。アクチュエーターとしては、例えば、ボタン式、
トリガー式のものなどが使用できる。本エアゾール剤
を、一回の噴射で容器内の全内容物を排出してしまう、
いわゆる全量噴射型エアゾール剤とする場合には、前記
アクチュエーターに代えて、全量噴射型アクチュエータ
ーを装着することにより成される。全量噴射型アクチュ
エーターは、一度押すと、押した状態が維持されるよう
な機構になっている。The present aerosol agent can be obtained, for example, as follows. The present compound, if necessary, a solvent or other active compound for controlling insect pests, a repellent, a synergist, a stabilizer and the like are filled in an aerosol container. An aerosol valve is attached to the container, a propellant is filled into the container through a stem, shaken, and then an actuator is attached. As the actuator, for example, a button type,
Trigger type can be used. This aerosol agent will eject all contents in the container with one injection.
In the case of using a so-called total injection type aerosol agent, a total injection type actuator is attached instead of the actuator. The full-quantity injection type actuator has a mechanism such that when it is pressed once, the pressed state is maintained.

【００１９】本化合物を含有する油剤については、例え
ば特開平６−３１６５０３号公報に記載の方法、水性液
剤については、例えば特開平６−９３０５号公報に記載
の方法、燻煙剤については、例えば特開平５−２９４８
０３号公報に記載の方法、加熱式器具については、例え
ば特公平２−５３３３３２号公報や特開平６−９３０５
号公報に記載の方法、送風式器具については特開平１１
−９２３０３号公報に記載の方法にそれぞれ準じて製造
することができる。For the oil agent containing the present compound, for example, the method described in JP-A-6-316503, for the aqueous liquid agent, for example, the method described in JP-A-6-9305, and for the smoke agent, for example, JP-A-5-2948
Regarding the method and heating type apparatus described in Japanese Patent Publication No. 03-033, for example, Japanese Patent Publication No. 2-533332 and Japanese Patent Laid-Open No. 6-9305
Japanese Patent Application Laid-Open No. H11-11311 for the method and blower device described in Japanese Patent
It can be manufactured according to the methods described in JP-A-92303.

【００２０】本発明方法により防除し得る飛翔性害虫と
しては、例えば以下のものがあげられる。例えば、衛生
害虫としては、イエバエ（Musca domestica）、オオイ
エバエ（Muscina stabulans）等のハエ類、アカイエカ
（Culex pipiens pallens）、コガタアカイエカ（Culex
tritaeniorhynchus）、ネッタイイエカ（Culex quinqu
efasciatus）、ヒトスジシマカ（Aedes albopictus）等
のカ類等が挙げられる。不快害虫としては、ユスリカ
類、チョウバエ類、アリ類、ハチ類等が挙げられる。The following are examples of flying pests that can be controlled by the method of the present invention. For example, as hygienic pests, flies such as house fly (Musca domestica) and house fly (Muscina stabulans), Culex pipiens pallens, Culex pipiens Culex (Culex)
tritaeniorhynchus), Culex quinqu
efasciatus), Aedes albopictus, and other mosquitoes. Examples of the unpleasant pests include chironomids, butterfly flies, ants, and bees.

【００２１】[0021]

【実施例】以下、本発明を実施例にてより詳細に説明す
るが、本発明はこれに限定されるものではない。EXAMPLES The present invention will now be described in more detail with reference to examples, but the present invention is not limited thereto.

【００２２】製剤例１ ２，３，５，６−テトラフルオロ−４−メトキシメチル
ベンジル （１Ｒ）−トランス−３−（１−プロペニル
（Ｚ／Ｅ＝８／１））−２，２−ジメチルシクロプロパ
ンカルボキシラート（以下、本化合物Ａと記す。）１ｇ
及びＩＰ１６２０（出光石油化学株式会社製商品名、イ
ソパラフィン系溶剤、沸点１６６〜２０２℃）６９ｇを
エアゾール缶に入れ、エアゾールバルブを装着した後、
３０ｇのジメチルエーテルを充填し、振とうを加え、ア
クチュエーターを装着することによりエアゾール製剤１
を得る。Formulation Example 1 2,3,5,6-tetrafluoro-4-methoxymethylbenzyl (1R) -trans-3- (1-propenyl (Z / E = 8/1))-2,2-dimethyl Cyclopropanecarboxylate (hereinafter referred to as the present compound A) 1 g
And IP1620 (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., isoparaffinic solvent, boiling point 166 to 202 ° C.) (69 g) were put in an aerosol can and equipped with an aerosol valve.
Aerosol formulation 1 by filling with 30 g of dimethyl ether, adding shaking, and mounting an actuator
To get

【００２３】製剤例２ 本化合物Ａ０．０２５ｇをエアゾール缶に入れ、エアゾ
ール缶にエアゾールバルブを装着した後、９９．９７５
ｇのジメチルエーテルを充填し、振とうを加え、アクチ
ュエーターを装着することによりエアゾール製剤２を得
た。Formulation Example 2 0.025 g of the present compound A was placed in an aerosol can, and an aerosol valve was attached to the aerosol can, and then 99.975.
Aerosol formulation 2 was obtained by filling g of dimethyl ether, adding shaking, and attaching an actuator.

【００２４】製剤例３ 本化合物Ａの量を０．０５ｇとし、ジメチルエーテルの
量を９９．９５ｇとした以外は製剤例３と同様の操作を
行うことによりエアゾール製剤３を得た。Formulation Example 3 Aerosol Formulation 3 was obtained by the same procedure as Formulation Example 3 except that the amount of the present compound A was 0.05 g and the amount of dimethyl ether was 99.95 g.

【００２５】製剤例４ 本化合物Ａの量を０．１ｇとし、ジメチルエーテルの量
を９９．９ｇとした以外は製剤例３と同様の操作を行う
ことによりエアゾール製剤４を得た。Formulation Example 4 Aerosol Formulation 4 was obtained by the same procedure as Formulation Example 3 except that the amount of the present compound A was 0.1 g and the amount of dimethyl ether was 99.9 g.

【００２６】製剤例５ 本化合物Ａの量を０．２ｇとし、ジメチルエーテルの量
を９９．８ｇとした以外は製剤例３と同様の操作を行う
ことによりエアゾール製剤５を得た。Formulation Example 5 Aerosol Formulation 5 was obtained by the same procedure as Formulation Example 3 except that the amount of the present compound A was 0.2 g and the amount of dimethyl ether was 99.8 g.

【００２７】製剤例６ 本化合物Ａの量を０．５ｇとし、ジメチルエーテルの量
を９９．５ｇとする以外は製剤例３と同様の操作を行う
ことによりエアゾール製剤６を得た。Formulation Example 6 Aerosol Formulation 6 was obtained by the same procedure as Formulation Example 3 except that the amount of the present compound A was 0.5 g and the amount of dimethyl ether was 99.5 g.

【００２８】製剤例７ 本化合物Ａの量を１ｇとし、ジメチルエーテルの量を９
９ｇとする以外は製剤例１と同様の操作を行うことによ
りエアゾール製剤７を得た。Formulation Example 7 The amount of the present compound A was 1 g, and the amount of dimethyl ether was 9 g.
Aerosol formulation 7 was obtained by performing the same operations as in formulation example 1 except that the amount was 9 g.

【００２９】製剤例８ 本化合物Ａの量を５ｇとし、ジメチルエーテルの量を９
５ｇとする以外は製剤例１と同様の操作を行うことによ
りエアゾール製剤８を得る。Formulation Example 8 The amount of the present compound A was 5 g and the amount of dimethyl ether was 9 g.
Aerosol formulation 8 is obtained by performing the same operation as in formulation example 1 except that the amount is 5 g.

【００３０】製剤例９ 本化合物Ａ０．０２５ｇ及びＩＰ１６２０（出光石油化
学株式会社製商品名、イソパラフィン系溶剤、沸点１６
６〜２０２℃）４９．９７５ｇをエアゾール缶に入れ、
エアゾールバルブを装着した後、５０ｇのジメチルエー
テルを充填し、振とうを加え、アクチュエーターを装着
することによりエアゾール製剤９を得る。Formulation Example 9 0.025 g of the present compound A and IP1620 (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 16)
(6 to 202 ° C) 49.975 g in an aerosol can,
After mounting the aerosol valve, 50 g of dimethyl ether is filled, shaken, and the actuator is mounted to obtain the aerosol preparation 9.

【００３１】製剤例１０ 本化合物Ａの量を０．０５ｇとし、ＩＰ１６２０（出光
石油化学株式会社製商品名、イソパラフィン系溶剤、沸
点１６６〜２０２℃）の量を４９．９５ｇとした以外は
製剤例９と同様の操作を行うことによりエアゾール製剤
１０を得る。Formulation Example 10 Formulation Example 10 except that the amount of Compound A was 0.05 g and the amount of IP1620 (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 166 to 202 ° C.) was 49.95 g. By performing the same operation as in 9, an aerosol preparation 10 is obtained.

【００３２】製剤例１１ 本化合物Ａの量を０．１ｇとし、ＩＰ１６２０（出光石
油化学株式会社製商品名、イソパラフィン系溶剤、沸点
１６６〜２０２℃）の量を４９．９ｇとした以外は製剤
例９と同様の操作を行うことによりエアゾール製剤１１
を得る。Formulation Example 11 Formulation Example 11 except that the amount of Compound A was 0.1 g and the amount of IP1620 (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 166 to 202 ° C.) was 49.9 g. Aerosol formulation 11 by performing the same operation as 9
To get

【００３３】製剤例１２ 本化合物Ａの量を０．２ｇとし、ＩＰ１６２０（出光石
油化学株式会社製商品名、イソパラフィン系溶剤、沸点
１６６〜２０２℃）の量を４９．８ｇとした以外は製剤
例９と同様の操作を行うことによりエアゾール製剤１２
を得る。Formulation Example 12 Formulation Example 12 except that the amount of the present compound A was 0.2 g and the amount of IP1620 (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 166 to 202 ° C.) was 49.8 g. Aerosol formulation 12 by performing the same operation as 9
To get

【００３４】製剤例１３ 本化合物Ａの量を０．５ｇとし、ＩＰ１６２０（出光石
油化学株式会社製商品名、イソパラフィン系溶剤、沸点
１６６〜２０２℃）の量を４９．５ｇとする以外は製剤
例９と同様の操作を行うことによりエアゾール製剤１３
を得る。Formulation Example 13 Formulation Example 13 except that the amount of the present compound A was 0.5 g and the amount of IP1620 (trade name of Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 166 to 202 ° C.) was 49.5 g. Aerosol formulation 13 by performing the same operation as 9
To get

【００３５】製剤例１４ 本化合物Ａの量を１ｇとし、ＩＰ１６２０（出光石油化
学株式会社製商品名、イソパラフィン系溶剤、沸点１６
６〜２０２℃）の量を４９ｇとする以外は製剤例９と同
様の操作を行うことによりエアゾール製剤１４を得る。Formulation Example 14 IP1620 (trade name of Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 16)
Aerosol formulation 14 is obtained by performing the same operation as in formulation example 9, except that the amount of (6 to 202 ° C) is 49 g.

【００３６】製剤例１５ 本化合物Ａの量を５ｇとし、ＩＰ１６２０（出光石油化
学株式会社製商品名、イソパラフィン系溶剤、沸点１６
６〜２０２℃）の量を４５ｇとする以外は製剤例９と同
様の操作を行うことによりエアゾール製剤１５を得る。Formulation Example 15 IP1620 (trade name of Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 16)
Aerosol formulation 15 is obtained by performing the same operation as in formulation example 9 except that the amount of (6 to 202 ° C) is 45 g.

【００３７】製剤例１６〜２３ ＩＰ１６２０（出光石油化学株式会社製商品名、イソパ
ラフィン系溶剤、沸点１６６〜２０２℃）に代えてＩＰ
１０１６（出光石油化学株式会社製商品名、イソパラフ
ィン系溶剤、沸点７３〜１４０℃）を用いる以外は製剤
例９〜１５と同様の操作を行うことによりエアゾール製
剤１６〜２３を得る。Formulation Examples 16 to 23 IP1620 (trade name of Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 166 to 202 ° C.) is used instead of IP.
Aerosol formulations 16 to 23 are obtained by performing the same operations as in formulation examples 9 to 15 except that 1016 (trade name of Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 73 to 140 ° C.) is used.

【００３８】製剤例２４〜３０ ＩＰ１６２０（出光石油化学株式会社製商品名、イソパ
ラフィン系溶剤、沸点１６６〜２０２℃）に代えてイソ
プロピルアルコールを用いる以外は製剤例９〜１５と同
様の操作を行うことによりエアゾール製剤２４〜３０を
得る。Formulation Examples 24 to 30 Perform the same operations as in Formulation Examples 9 to 15 except that isopropyl alcohol is used in place of IP1620 (trade name of Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 166 to 202 ° C.). To obtain aerosol formulations 24-30.

【００３９】製剤例３１〜３７ ＩＰ１６２０（出光石油化学株式会社製商品名、イソパ
ラフィン系溶剤、沸点１６６〜２０２℃）に代えてヘキ
サンを用いる以外は製剤例９〜１５と同様の操作を行う
ことによりエアゾール製剤３１〜３７を得る。Formulation Examples 31 to 37 IP1620 (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., isoparaffinic solvent, boiling point 166 to 202 ° C.) is replaced by hexane in the same manner as in Formulation Examples 9 to 15. Aerosol formulations 31-37 are obtained.

【００４０】製剤例３８〜７４ ジメチルエーテルに代えてＬＰＧを用いる以外は製剤例
１〜３７と同様の操作を行うことによりエアゾール製剤
３８〜７４を得る。Formulation Examples 38 to 74 Aerosol formulations 38 to 74 are obtained by the same operations as in Formulation Examples 1 to 37 except that LPG is used in place of dimethyl ether.

【００４１】製剤例７５ 本化合物Ａ２．６７ｇをＩＰ１６２０（出光石油化学株
式会社製商品名、イソパラフィン系溶剤、沸点１６６〜
２０２℃）９７．３３ｇに溶解させた。該油剤３．６ｇ
をエアゾール缶に入れ、エアゾールバルブを装着した
後、ＬＰＧおよびジメチルエーテルからなる液化噴射ガ
ス ８．４ｇを充填し、振とうを加え、トータルリリー
ス用アクチュエーターを装着することによりエアゾール
製剤７５を得る。Formulation Example 75 2.67 g of the present compound A was added to IP1620 (trade name, manufactured by Idemitsu Petrochemical Co., Ltd., isoparaffin solvent, boiling point 166-).
It was dissolved in 97.33 g (202 ° C.). 3.6 g of the oil solution
Is placed in an aerosol can, and after installing an aerosol valve, 8.4 g of a liquefied injection gas consisting of LPG and dimethyl ether is charged, shaken, and a total release actuator is installed to obtain an aerosol preparation 75.

【００４２】製剤例７６ 本化合物Ａ０．０２５ｇ及び水／イソプロパノール混合
溶剤（１／１（ｗｔ／ｗｔ））４９．９７５ｇをエアゾ
ール缶に入れ、エアゾールバルブを装着した後、５０ｇ
のジメチルエーテルを充填し、振とうを加え、アクチュ
エーターを装着することによりエアゾール製剤７６を得
る。Formulation Example 76 0.025 g of the present compound A and 49.975 g of water / isopropanol mixed solvent (1/1 (wt / wt)) were placed in an aerosol can, and 50 g of the aerosol valve was installed.
Then, the aerosol formulation 76 is obtained by filling it with dimethyl ether, shaking and adding an actuator.

【００４３】製剤例７７ 本化合物Ａに代えて２，３，５，６−テトラフルオロ−
４−メチルベンジル （１Ｒ）−トランス−３−（１−
プロペニル（Ｚ／Ｅ＝８／１））−２，２−ジメチルシ
クロプロパンカルボキシラート（以下、本化合物Ｂと記
す）を用いる以外は製剤例１と同様の操作を行うことに
よりエアゾール製剤７７を得る。Formulation Example 77 Instead of the present compound A, 2,3,5,6-tetrafluoro-
4-Methylbenzyl (1R) -trans-3- (1-
Aerosol formulation 77 is obtained by performing the same operation as in formulation example 1 except that propenyl (Z / E = 8/1))-2,2-dimethylcyclopropanecarboxylate (hereinafter referred to as the present compound B) is used. .

【００４４】製剤例７８〜８３ 本化合物Ａに代えて本化合物Ｂを用いる以外は製剤例２
〜７と同様の操作を行うことによりエアゾール製剤７８
〜８３を得た。Formulation Examples 78 to 83 Formulation Example 2 except that the present compound B is used in place of the present compound A
The aerosol formulation 78 can be prepared by performing the same operation as
~ 83 was obtained.

【００４５】製剤例８４〜１５２ 本化合物Ａに代えて本化合物Ｂを用いる以外は製剤例８
〜７6と同様の操作を行うことによりエアゾール製剤８
４〜１５２を得る。Formulation Examples 84 to 152 Formulation Example 8 except that the present compound B is used in place of the present compound A
~ Aerosol formulation 8 by performing the same operation as
4-152 are obtained.

【００４６】比較製剤例１ 製剤例７において本化合物Ａの代わりにエンペントリン
を用い、同様の操作により比較用エアゾール１を作製し
た。Comparative Formulation Example 1 Comparative Example Aerosol 1 was prepared in the same manner as in Formulation Example 7 except that Empentrin was used instead of the present compound A.

【００４７】比較製剤例２ 製剤例７において本化合物Ａの代わりにペルメトリンを
用い、同様の操作により比較用エアゾール２を作製し
た。Comparative Formulation Example 2 Comparative formulation aerosol 2 was prepared in the same manner as in Formulation Example 7 except that permethrin was used instead of the present compound A.

【００４８】試験例１ 約５，８ｍ3の試験室（内寸：幅１．８ｍ，奥行き１．
８ｍ，高さ１．８ｍ，４面ある壁の一面がガラス張り）
のガラス壁面に１ｍ四方のナイロンカーテン（１６メッ
シュ）を床から１４０ｃｍの高さから広げて吊るし、前
述のエアゾール製剤７をナイロンカーテンから２０ｃｍ
離してナイロンカーテン上に均一に広がるように６秒間
噴霧した。実際に何ｇ噴霧されたのかは噴霧操作前後の
エアゾール缶全体の重量を秤り減少量により確認した。
噴霧した後直ちに試験室の排気ファン作動による強制換
気を１０分間行い、入り口を締め密閉した。翌日（１日
後）、さらに１０分間の強制換気を行った後、アカイエ
カ雌雄成虫２０頭を試験室内に放った。所定経過時間毎
にノックダウン虫数を観察した。さらに、エアゾール噴
霧２日後、３日後も、１０分間の換気を行い、３日後に
ついては１日後と同様にしてアカイエカノックダウン試
験を行った。また、エアゾール製剤８３、比較用エアゾ
ール１、２についても同様の試験を行なった。結果を表
１に示す。Test Example 1 A test chamber of about 5,8 m 3 (internal dimension: width 1.8 m, depth 1.
8m, height 1.8m, one side of 4 walls is covered with glass)
A 1 m square nylon curtain (16 mesh) is hung from the floor from a height of 140 cm and hung on the glass wall of, and the above-mentioned aerosol preparation 7 is 20 cm from the nylon curtain.
Separated and sprayed for 6 seconds to spread evenly over the nylon curtain. The actual weight of the sprayed aerosol can was confirmed by measuring the weight of the entire aerosol can before and after the spraying operation and measuring the amount of decrease.
Immediately after spraying, forced ventilation was performed by operating the exhaust fan in the test room for 10 minutes, and the inlet was closed and sealed. On the next day (1 day later), forced ventilation was further performed for 10 minutes, and then 20 adult male and female Culex pipiens were released into the test room. The number of knockdown insects was observed at every predetermined elapsed time. Furthermore, ventilation for 10 minutes was performed after 2 days and 3 days after aerosol spraying, and after 3 days, the Acai caeca knockdown test was performed in the same manner as after 1 day. Further, the same test was performed on the aerosol formulation 83 and the comparative aerosols 1 and 2. The results are shown in Table 1.

【００４９】[0049]

【表１】 [Table 1]

【００５０】エアゾール製剤７、８３を処理した場合に
は、処理３日後までアカイエカに対する速効的駆除効果
が維持された。一方比較用エアゾール１を処理した場合
には、処理翌日（１日後）には駆除効果が認められた
が、処理３日後にはその効果がほとんど消失した。比較
用エアゾール２を処理した場合には、処理翌日（１日
後）における駆除効果はほとんどなく、処理３日後にお
いても駆除効果はほとんどない結果となった。When the aerosol formulations 7 and 83 were treated, the rapid-acting exterminating effect against Culex pipiens was maintained up to 3 days after the treatment. On the other hand, when Comparative Aerosol 1 was treated, an exterminating effect was recognized on the day after the treatment (1 day later), but the effect almost disappeared 3 days after the treatment. When the comparative aerosol 2 was treated, there was almost no extermination effect on the day after the treatment (1 day later), and there was almost no extermination effect 3 days after treatment.

【００５１】試験例２ エアゾール製剤１、８、１４、１５、２２、２３、２
９、３０、３６、３７、７７、８３、８９、９０、９
７、９８、１０４、１０５、１１１及び１１２について
も、試験例１と同様の方法で試験を行うことにより、こ
れらのエアゾール製剤が優れた害虫駆除効果を有するこ
とが確認できる。Test Example 2 Aerosol formulation 1, 8, 14, 15, 22, 23, 2
9, 30, 36, 37, 77, 83, 89, 90, 9
By performing the same test on 7, 98, 104, 105, 111 and 112 in the same manner as in Test Example 1, it can be confirmed that these aerosol preparations have an excellent pest control effect.

【００５２】[0052]

【発明の効果】本発明によれば、電気器具等の継続的な
使用や噴霧剤の繰り返し噴霧を行わずとも、噴霧処理な
どの一回施用で少なくとも数日間は蚊、ハエなどの飛翔
害虫駆除が可能となる。According to the present invention, it is possible to exterminate flying insect pests such as mosquitoes and flies for at least several days with a single application such as spraying treatment without continuous use of electric appliances or repeated spraying of spraying agent. Is possible.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０９Ｋ 3/30 Ａ０１Ｎ 53/00 ５０６Ｂ ５０６Ｚ Ｆターム(参考） 4D075 AA04 CA45 DC02 EA07 EB16 EC30 4H011 AC01 AC02 BA01 BB15 BC02 BC03 DA21 DD05 DD06 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) C09K 3/30 A01N 53/00 506B 506Z F term (reference) 4D075 AA04 CA45 DC02 EA07 EB16 EC30 4H011 AC01 AC02 BA01 BB15 BC02 BC03 DA21 DD05 DD06

Claims (7)

【特許請求の範囲】[Claims] 【請求項１】一般式（１） （式中、Ｒはメチル基またはメトキシメチル基を表
す。）で示されるテトラフルオロベンジルエステル化合
物を、室内の構造物または備品の表面に付着せしめるこ
とを特徴とする家屋室内における飛翔性害虫の駆除方
法。1. A general formula (1) (In the formula, R represents a methyl group or a methoxymethyl group.) A tetrafluorobenzyl ester compound is attached to the surface of an indoor structure or fixture to control a flying pest in a room. Method. 【請求項２】室内の構造物または備品が、室内のカーテ
ン、家具、天井、室内側面または窓である請求項１に記
載の方法。2. The method according to claim 1, wherein the indoor structure or equipment is an indoor curtain, furniture, ceiling, indoor side surface or window. 【請求項３】テトラフルオロベンジルエステル化合物
（１）の室内の構造物または備品の表面への付着が、テ
トラフルオロベンジルエステル化合物（１）及び噴射剤
を含有するエアゾール剤により行われる請求項１または
２に記載の方法。3. The method according to claim 1, wherein the tetrafluorobenzyl ester compound (1) is attached to the surface of an indoor structure or fixture by an aerosol agent containing the tetrafluorobenzyl ester compound (1) and a propellant. The method described in 2. 【請求項４】テトラフルオロベンジルエステル化合物
（１）及び噴射剤を含有するエアゾール剤が、さらに溶
剤を含有し、該溶剤が沸点３０〜２１０℃の溶剤である
請求項３に記載の方法。4. The method according to claim 3, wherein the aerosol agent containing the tetrafluorobenzyl ester compound (1) and the propellant further contains a solvent, and the solvent has a boiling point of 30 to 210 ° C. 【請求項５】溶剤が沸点３０〜１２０℃の溶剤である請
求項４に記載の方法。5. The method according to claim 4, wherein the solvent has a boiling point of 30 to 120 ° C. 【請求項６】溶剤が沸点３０〜１００℃の溶剤である請
求項４に記載の方法。6. The method according to claim 4, wherein the solvent has a boiling point of 30 to 100 ° C. 【請求項７】溶剤がアルコールを含有するものである請
求項４〜６のいずれかに記載の方法。7. The method according to claim 4, wherein the solvent contains alcohol.
JP2001279522A 2001-09-14 2001-09-14 Method for controlling flying insect pest in room Pending JP2003081721A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP2001279522A JP2003081721A (en) 2001-09-14 2001-09-14 Method for controlling flying insect pest in room
MYPI20022947A MY134711A (en) 2001-09-14 2002-08-07 Pesticidal methods and uses
KR1020020053270A KR100907196B1 (en) 2001-09-14 2002-09-04 Pesticidal methods and uses
ES200202027A ES2204309B1 (en) 2001-09-14 2002-09-05 METHODS AND USES PESTICIDES.
BR0203542-1A BR0203542A (en) 2001-09-14 2002-09-11 Pesticide process and its use
ARP020103453A AR036590A1 (en) 2001-09-14 2002-09-12 METHODS AND USES OF PESTICIDES
IT000795A ITTO20020795A1 (en) 2001-09-14 2002-09-12 USE OF A TETRABENZYL ESTER COMPOUND AS A PESTICIDE AND RELATED PROCEDURES FOR THE USE OF SUCH COMPOUND.
CNB021426066A CN1250082C (en) 2001-09-14 2002-09-12 Pest killing method and use

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001279522A JP2003081721A (en) 2001-09-14 2001-09-14 Method for controlling flying insect pest in room

Publications (1)

Publication Number Publication Date
JP2003081721A true JP2003081721A (en) 2003-03-19

Family

ID=19103698

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JP2001279522A Pending JP2003081721A (en) 2001-09-14 2001-09-14 Method for controlling flying insect pest in room

Country Status (8)

Country Link
JP (1) JP2003081721A (en)
KR (1) KR100907196B1 (en)
CN (1) CN1250082C (en)
AR (1) AR036590A1 (en)
BR (1) BR0203542A (en)
ES (1) ES2204309B1 (en)
IT (1) ITTO20020795A1 (en)
MY (1) MY134711A (en)

Cited By (8)

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JP2010059198A (en) * 2009-11-20 2010-03-18 Sumitomo Chemical Co Ltd Composition for controlling harmful insect and method of controlling harmful insect
JP2012149007A (en) * 2011-01-19 2012-08-09 Sumika Life Tech Co Ltd Noxious insect repellent aerosol composition for ground spraying, noxious insect repellent aerosol product for ground spraying, and method for repelling noxious insect
JP2013126959A (en) * 2011-12-17 2013-06-27 Dainippon Jochugiku Co Ltd Aerosol for controlling flying insect pest on glass surface and screen door
JP2015017083A (en) * 2013-06-11 2015-01-29 大日本除蟲菊株式会社 Aerosol for mosquito control and mosquito control method using the same
JP2015027982A (en) * 2013-07-01 2015-02-12 大日本除蟲菊株式会社 Aerosol for insect pest control, and insect pest control method using the same
JP2017095412A (en) * 2015-11-26 2017-06-01 住化エンバイロメンタルサイエンス株式会社 Aerosol composition for insect pest control, aerosol for insect pest control and pest control method
US10091989B2 (en) 2010-09-17 2018-10-09 Sumitomo Chemical Company, Limited Composition for pest control aerosol
JP2020186271A (en) * 2015-12-28 2020-11-19 大日本除蟲菊株式会社 Pest control aerosol agent

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010059198A (en) * 2009-11-20 2010-03-18 Sumitomo Chemical Co Ltd Composition for controlling harmful insect and method of controlling harmful insect
US10091989B2 (en) 2010-09-17 2018-10-09 Sumitomo Chemical Company, Limited Composition for pest control aerosol
JP2012149007A (en) * 2011-01-19 2012-08-09 Sumika Life Tech Co Ltd Noxious insect repellent aerosol composition for ground spraying, noxious insect repellent aerosol product for ground spraying, and method for repelling noxious insect
JP2013126959A (en) * 2011-12-17 2013-06-27 Dainippon Jochugiku Co Ltd Aerosol for controlling flying insect pest on glass surface and screen door
JP2015017083A (en) * 2013-06-11 2015-01-29 大日本除蟲菊株式会社 Aerosol for mosquito control and mosquito control method using the same
JP2015027982A (en) * 2013-07-01 2015-02-12 大日本除蟲菊株式会社 Aerosol for insect pest control, and insect pest control method using the same
JP2017095412A (en) * 2015-11-26 2017-06-01 住化エンバイロメンタルサイエンス株式会社 Aerosol composition for insect pest control, aerosol for insect pest control and pest control method
JP2020186271A (en) * 2015-12-28 2020-11-19 大日本除蟲菊株式会社 Pest control aerosol agent

Also Published As

Publication number Publication date
AR036590A1 (en) 2004-09-22
ITTO20020795A1 (en) 2003-03-15
KR20030023492A (en) 2003-03-19
KR100907196B1 (en) 2009-07-10
BR0203542A (en) 2003-06-03
ES2204309A1 (en) 2004-04-16
CN1250082C (en) 2006-04-12
ES2204309B1 (en) 2005-06-16
MY134711A (en) 2007-12-31
CN1408230A (en) 2003-04-09

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