JP2003055884A - Method for printing textile product comprising cellulose fiber and polyester fiber - Google Patents
Method for printing textile product comprising cellulose fiber and polyester fiberInfo
- Publication number
- JP2003055884A JP2003055884A JP2001242443A JP2001242443A JP2003055884A JP 2003055884 A JP2003055884 A JP 2003055884A JP 2001242443 A JP2001242443 A JP 2001242443A JP 2001242443 A JP2001242443 A JP 2001242443A JP 2003055884 A JP2003055884 A JP 2003055884A
- Authority
- JP
- Japan
- Prior art keywords
- dye
- fiber
- disperse dye
- fabric
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、セルロース系繊維
とポリエステル系繊維とからなる繊維製品の捺染方法に
関するものであり、さらに詳しくは、セルロース系繊維
とポリエステル系繊維とからなる繊維製品を分散染料お
よび建染染料で捺染し高堅牢度、高濃度固着、柄のシャ
ープ性に優れ、かつ風合いが柔らかく、着用快適性に優
れた捺染物を得るための方法、特に高濃度固着で柄のシ
ャープ性に優れた捺染物を得るための方法に関するもの
である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for printing a fiber product composed of a cellulosic fiber and a polyester fiber, and more particularly to a disperse dye for a fiber product composed of a cellulosic fiber and a polyester fiber. And a method to obtain a printed product that is printed with vat dye and has high fastness, high density fixation, sharpness of the pattern, soft texture, and excellent wearing comfort, especially sharpness of the pattern with high density fixation The present invention relates to a method for obtaining an excellent printed material.
【０００２】[0002]
【従来の技術】従来、綿や麻、レーヨンなどのセルロー
ス系繊維とポリエステル系繊維とからなる繊維製品の捺
染方法としては、例えば次の４つの方法が知られてい
る。2. Description of the Related Art Conventionally, for example, the following four methods have been known as textile printing methods for textiles made of cellulosic fibers such as cotton, hemp and rayon and polyester fibers.
【０００３】まず、第一の方法は、分散染料および建染
染料を捺染、乾燥、乾熱処理して、分散染料を固着させ
てから、ハイドロサルファイト、苛性ソーダ、および硫
酸ナトリウムなどの塩を含む溶液で処理した後、そのま
ま飽和水蒸気で３０〜６０秒間処理し建染染料を固着し
て、同時に、未固着の分散染料を分解させてから、ソー
ピングを行い未固着の染料を洗い落とすという方法であ
る。しかしながら、この方法によると、高堅牢度、高濃
度固着については問題がないが、ハイドロサルファイ
ト、苛性ソーダなどのアルカリおよび還元剤を水溶液の
状態で処理するために、織物の柄の周囲に染料が滲み出
したり、蒸気処理からソーピング工程の間で染料が移っ
てしまうことにより、柄のシャープ性の低下を生じてし
まうという欠点があった。First, the first method is to print a disperse dye and a vat dye, dry and heat-treat them to fix the disperse dye, and then a solution containing hydrosulfite, caustic soda, and a salt such as sodium sulfate. After the treatment, the vat dye is fixed by directly treating it with saturated steam for 30 to 60 seconds, at the same time, the unfixed disperse dye is decomposed, and then the unfixed dye is washed off by soaping. However, according to this method, although there is no problem in terms of high fastness and high-concentration fixation, a dye is applied around the handle of the fabric because the alkali and reducing agent such as hydrosulfite and caustic soda are treated in an aqueous solution. There is a drawback that the sharpness of the pattern is deteriorated due to exudation or transfer of the dye between the steam treatment and the soaping step.
【０００４】第二の方法は、分散染料および建染染料お
よびアルカリと還元剤で捺染して、乾燥、乾熱処理をし
て分散染料を固着させてから、そのまま飽和水蒸気で１
５〜２０分間処理し建染染料を固着させ、未固着の分散
染料を分解させてから、ソーピングを行い、未固着の染
料を洗い落とすという方法である。しかしながら、この
方法によると、分散染料および建染染料およびアルカリ
と還元剤の４物質を同時に存在させるため、乾燥、乾熱
処理の間に分散染料が一部分解してしまうことにより、
堅牢度、柄のシャープ性は良好であるが、高濃度固着
（高染色）ができないという欠点があった。In the second method, a disperse dye, a vat dye, an alkali and a reducing agent are printed, dried and heat-treated to fix the disperse dye, and then saturated water vapor is used to
This is a method in which the vat dye is fixed by treating for 5 to 20 minutes, the unfixed disperse dye is decomposed, and then soaping is performed to wash off the unfixed dye. However, according to this method, since the disperse dye, the vat dye, and the alkali and the reducing agent are simultaneously present, the disperse dye is partially decomposed during drying and dry heat treatment.
The fastness and the sharpness of the pattern are good, but there is a drawback that high density fixation (high dyeing) cannot be performed.
【０００５】第三の方法は、分散染料と反応性染料とア
ルカリとを用いて捺染し、乾燥させてから１６０〜１７
０℃の過熱蒸気で１０〜２０分処理して分散染料と反応
性染料を固着させてから、ソーピングを行い未固着の染
料を洗い落とす方法である。The third method is to print 160 to 17 after printing with a disperse dye, a reactive dye and an alkali, and drying.
This is a method in which the disperse dye and the reactive dye are fixed by treatment with superheated steam at 0 ° C. for 10 to 20 minutes, and then the unfixed dye is washed off by soaping.
【０００６】しかしながら、この方法によると、還元剤
を用いることができないため未固着の分散染料を分解さ
せることができず、その結果分散染料が残存するため、
堅牢度が悪い上に、柄のシャープ性が低下するという欠
点があった。However, according to this method, since the reducing agent cannot be used, the unfixed disperse dye cannot be decomposed, and as a result, the disperse dye remains.
In addition to having poor fastness, there was a drawback that the sharpness of the pattern was reduced.
【０００７】第四の方法は、織物に顔料とバインダーで
捺染して、乾熱処理する方法である。The fourth method is a method in which a woven fabric is printed with a pigment and a binder, and dry heat treatment is performed.
【０００８】しかしながら、この方法は、バインダーを
用いるために風合いが粗硬であるという欠点があった。However, this method has a drawback that the texture is coarse and hard because the binder is used.
【０００９】[0009]
【発明が解決しようとする課題】上記のように、セルロ
ース系繊維とポリエステル系繊維とから構成された布帛
を分散染料および建染染料で染色する場合、高堅牢度に
おいては、ある程度満足するものが得られたが、高濃度
固着、柄のシャープ性に優れたものを同時に得ることは
できないという問題があった。As described above, when a cloth composed of cellulosic fibers and polyester fibers is dyed with a disperse dye and a vat dye, some of the high fastnesses are satisfactory. Although it was obtained, there was a problem in that it was not possible to simultaneously obtain a product having high density fixation and an excellent pattern sharpness.
【００１０】本発明は、上記のような従来技術の欠点を
解消するためのものであり、セルロース系繊維とポリエ
ステル系繊維とからなる繊維製品を分散染料および建染
染料で捺染し高堅牢度はもとより、特に、高濃度固着、
柄のシャープ性に優れ、かつ風合いが柔らかく、着用快
適性に優れた捺染物を得るための方法を提供するもので
ある。The present invention is intended to solve the above-mentioned drawbacks of the prior art, and a textile product comprising a cellulosic fiber and a polyester fiber is printed with a disperse dye and a vat dye to achieve high fastness. Of course, especially high concentration fixation,
It is intended to provide a method for obtaining a printed material having excellent pattern sharpness, soft texture, and excellent wearing comfort.
【００１１】[0011]
【課題を解決するための手段】かかる課題は、セルロー
ス系繊維とポリエステル系繊維とから構成された布帛
を、分散染料および建染染料を含む色糊と共に捺染、乾
燥、熱処理をした後、アルカリおよび還元剤を含む糊を
付着、蒸熱処理、ソーピングをするセルロース系繊維と
ポリエステル系繊維とからなる繊維製品の捺染方法によ
って達成される。[Means for Solving the Problems] The object is to print a cloth composed of a cellulosic fiber and a polyester fiber with a color paste containing a disperse dye and a vat dye, dry and heat-treat, and then remove the alkali and This can be achieved by a method for printing a fiber product comprising cellulosic fibers and polyester fibers, in which a paste containing a reducing agent is attached, steamed, and soaped.
【００１２】この場合特に、アルカリおよび還元剤を含
む糊を付着した後に、乾燥を行い、しかる後に蒸熱処理
を行うことによって、さらに優れた効果が得られる。In this case, in particular, a further excellent effect can be obtained by applying a paste containing an alkali and a reducing agent, followed by drying and then steaming.
【００１３】[0013]
【発明の実施の形態】本発明の捺染方法は、次の２段階
の捺染方法をとるものである。すなわち、セルロース系
繊維とポリエステル系繊維とから構成された布帛を、分
散染料および建染染料を含む色糊と共に捺染、乾燥、熱
処理をする第１段階、およびアルカリおよび還元剤を含
む糊を付着、蒸熱処理、ソーピングをする第２段階であ
る。第１段階の熱処理により、分散染料がポリエステル
系繊維に固着される。第２段階のアルカリおよび還元剤
処理により、建染染料がセルロース系繊維に固着され、
かつ、未固着の分散染料が分解される。本発明で特に、
特徴的な条件は、第２段階のアルカリおよび還元剤によ
る処理を水分をおさえた条件、すなわちアルカリおよび
還元剤を糊に含有させた状態で分散染料および建染染料
に接触させる点にある。このような条件で行うことによ
って、柄のシャープ性の顕著な効果が得られるのであ
る。この効果を一層顕著になさしめるために、アルカリ
および還元剤を含む糊を付着した後に乾燥を行うこと
が、さらに有効である。この乾燥温度は、１００〜１３
０℃で行うことが好ましい。BEST MODE FOR CARRYING OUT THE INVENTION The printing method of the present invention is the following two-step printing method. That is, a cloth composed of a cellulosic fiber and a polyester fiber is printed with a color paste containing a disperse dye and a vat dye, a first step of drying, heat treatment, and a paste containing an alkali and a reducing agent is attached, This is the second stage of steaming and soaping. The disperse dye is fixed to the polyester fiber by the first stage heat treatment. The vat dye is fixed to the cellulosic fiber by the second stage alkali and reducing agent treatment,
At the same time, unfixed disperse dye is decomposed. Particularly in the present invention,
The characteristic condition is that the treatment with the alkali and the reducing agent in the second stage is carried out under the condition that the moisture is suppressed, that is, the disperse dye and the vat dye are brought into contact with the paste containing the alkali and the reducing agent. By carrying out under such conditions, a remarkable effect of the sharpness of the pattern can be obtained. In order to make this effect more remarkable, it is more effective to carry out drying after applying a paste containing an alkali and a reducing agent. The drying temperature is 100 to 13
It is preferable to carry out at 0 ° C.
【００１４】本発明におけるセルロース系繊維として
は、綿、麻、レーヨン、アセテートなどが挙げられる。Examples of the cellulosic fibers in the present invention include cotton, hemp, rayon and acetate.
【００１５】また、ポリエステル系繊維としては、ポリ
エチレンテレフタレート繊維、ポリブチレンテレフタレ
ート繊維、ポリエチレン-２，６-ナフタレンジカルボキ
シレート繊維等が挙げられるが、代表的なポリエステル
繊維としては、ポリエチレンテレフタレート繊維であ
る。これらのポリエステル繊維は、ホモポリエステルで
あってもよく、コポリエステルであってもよい。コポリ
エステルの場合、ポリエステルの繰り返し単位の２０モ
ル％以下で第３成分を共重合させたものが好ましい。Examples of the polyester fiber include polyethylene terephthalate fiber, polybutylene terephthalate fiber, polyethylene-2,6-naphthalene dicarboxylate fiber, and the like. A typical polyester fiber is polyethylene terephthalate fiber. . These polyester fibers may be homopolyesters or copolyesters. In the case of the copolyester, it is preferable that the third component is copolymerized with 20 mol% or less of the repeating unit of the polyester.
【００１６】勿論、ポリエステルに、通常用いられる添
加剤、例えば、熱安定剤、酸化防止剤、着色剤、帯電防
止剤、紫外線吸収剤等が含有されていてもよい。Of course, the polyester may contain additives usually used, for example, heat stabilizers, antioxidants, colorants, antistatic agents, ultraviolet absorbers and the like.
【００１７】セルロース系繊維とポリエステル系繊維と
から構成された布帛としては、特にポリエステル系繊
維、綿および麻からなる布帛、またはポリエステル系繊
維とレーヨンからなる布帛が汎用される。As the cloth composed of the cellulose fiber and the polyester fiber, a cloth composed of polyester fiber, cotton and hemp, or a cloth composed of polyester fiber and rayon is generally used.
【００１８】分散染料としては、たとえば、Dianix Yel
low AM-42、Dianix Red BN-SE、Dianix Blue BG-FS、Di
anix Navy Blue ER-FS（以上、Ｄｙｓｔａｒ社製）、Fo
ron Yellow Brown S-2RFL、ForonBrown S-2BL、ForonBl
ue S-BGL（以上、Ｃｌａｒｉａｎｔ社製）、Palanil Go
lden Yellow GG、Palanil Scarlet BRE、Palanil Blue
5GE（以上、三井ＢＡＳＦ社製）等が挙げられる。As the disperse dye, for example, Dianix Yel
low AM-42, Dianix Red BN-SE, Dianix Blue BG-FS, Di
anix Navy Blue ER-FS (above, made by Dystar), Fo
ron Yellow Brown S-2RFL, ForonBrown S-2BL, ForonBl
ue S-BGL (above, Clariant company), Palanil Go
lden Yellow GG, Palanil Scarlet BRE, Palanil Blue
5GE (above, manufactured by Mitsui BASF) and the like.
【００１９】建染染料としては、たとえば、Mikethrene
Yellow GCN、Mikethrene OrangeRRTS、Mikethrene Bro
wn 5RN、Mikethrene BlackVCliq、MikethreneRedFFB、M
ikethrene Blue GCD（以上、三井ＢＡＳＦ社製）等が挙
げられる。As vat dyes, for example, Mikethrene
Yellow GCN, Mikethrene OrangeRRTS, Mikethrene Bro
wn 5RN, Mikethrene BlackVCliq, MikethreneRedFFB, M
Examples include ikethrene Blue GCD (above, manufactured by Mitsui BASF).
【００２０】糊としては、たとえば、でんぷん、可溶性
でんぷん、グアーガム、ローカストビーンガム、カルボ
キシメチルでんぷん、アルギン酸ナトリウム、水溶性メ
チルセルロース等が挙げられる。Examples of the paste include starch, soluble starch, guar gum, locust bean gum, carboxymethyl starch, sodium alginate, water-soluble methyl cellulose and the like.
【００２１】第１段階での乾燥温度は、通常、１００〜
１３０℃である。また、熱処理条件は、通常、分散染料
をポリエステル系繊維に固着させるために、１５０〜２
１０℃で３０秒〜３０分間、乾熱または、過熱蒸気で処
理される。より好ましくは、乾熱で１６０〜１９０℃、
７〜２０分間処理される。The drying temperature in the first stage is usually 100 to
It is 130 ° C. The heat treatment condition is usually 150 to 2 for fixing the disperse dye to the polyester fiber.
It is treated with dry heat or superheated steam at 10 ° C. for 30 seconds to 30 minutes. More preferably, it is 160 to 190 ° C. in dry heat,
It is processed for 7 to 20 minutes.
【００２２】第２段階で用いられるアルカリとしては、
たとえば、炭酸ナトリウム、重炭酸ナトリウム、水酸化
ナトリウム、水酸化カリウム、炭酸カリウム等が挙げら
れる。As the alkali used in the second stage,
For example, sodium carbonate, sodium bicarbonate, sodium hydroxide, potassium hydroxide, potassium carbonate and the like can be mentioned.
【００２３】また、還元剤としては、たとえば、ナトリ
ウムホルムアルデヒドスルホキシレート、ハイドロサル
ファイト、二酸化チオ尿素等が挙げられる。Examples of the reducing agent include sodium formaldehyde sulfoxylate, hydrosulfite, thiourea dioxide and the like.
【００２４】第２段階の蒸熱処理の条件は、通常、アル
カリおよび還元剤によって建染染料をセルロース系繊維
に固着させ、かつ未分解の分散染料を分解させるため
に、１００〜１１０℃で１〜３０分間、より好ましく
は、１０２〜１０４℃で１０〜３０分間で処理される。The conditions of the second stage steaming treatment are usually 1 to 100 ° C. to 110 ° C. in order to fix the vat dye to the cellulosic fiber with an alkali and a reducing agent and to decompose the undecomposed disperse dye. The treatment is carried out for 30 minutes, more preferably 10 to 30 minutes at 102 to 104 ° C.
【００２５】[0025]
【実施例】以下、実施例を挙げて本発明を具体的に説明
する。なお、本発明で得られる効果は、次の基準により
判断した。
（１）Ｋ／Ｓ
Ｋ/Ｓ値の測定方法は次のようである。側色機ＣＯＬＯ
Ｒ−７ｅ２（倉敷紡績社製）により反射率を測定し、下
記のＫｕｂｅｌｃａ−Ｍｕｎｋ式にて算出した。
Ｋ/Ｓ＝（１−Ｒ）2／２Ｒ Ｒ：捺染布の最大吸収
波長における反射率
そして、この値は、大きいほど着色濃度が大であること
を示している。
（２）柄のシャープ性
目視判断で、プリントされた柄のにじみが認められない
ものを良好、判別できる程度のにじみが認められるもの
を不良とした。
（３）堅牢度
以下のＪＩＳ規格に準じて測定した。
洗濯堅牢度：ＪＩＳ．L−０８４４ Ａ−２
汗堅牢度：ＪＩＳ．L−０８４８ Ａ
耐光堅牢度：ＪＩＳ．L−０８４２
摩擦堅牢度：ＪＩＳ．L−０８４９IIEXAMPLES The present invention will be specifically described below with reference to examples. The effects obtained by the present invention were judged according to the following criteria. (1) K / S The K / S value measuring method is as follows. Side color machine COLO
The reflectance was measured by R-7e2 (manufactured by Kurashiki Spinning Co., Ltd.) and calculated by the following Kubelca-Munk formula. K / S = (1−R) 2 / 2R R: reflectance at the maximum absorption wavelength of the textile fabric. The larger this value, the higher the coloring density. (2) Sharpness of pattern A pattern in which bleeding of a printed pattern was not visually recognized was judged as good, and a pattern in which bleeding was recognizable was judged as defective. (3) Fastness Measured according to the following JIS standard. Washing fastness: JIS. L-0844 A-2 Sweat fastness: JIS. L-0848 A Light fastness: JIS. L-0842 Fastness to rubbing: JIS. L-0849II
【００２６】実施例１
ポリエステル繊維／綿（６５／３５）、４５番手（綿番
手）双糸を経糸、麻１００％２１番手（綿番手）単糸を
緯糸に用いた経密度１４４本／ｉｎ、緯密度６８本／in
で製織し、精練、晒、シルケット、ヒートセットを行っ
た織物にグアーガム３０ｇ／ｋｇ、アルギン酸ソーダ３
０ｇ／ｋｇの割合で水に溶かしたものを元糊として、元
糊を６０重量％、分散染料であるForon BrownS-2BLを４
重量％、Dianix YellowAM-42を１．３重量％、建染染料
であるMikethren Black VCliqを５．５重量％、Mikethr
en Orange RRTSを４．５重量％、Mikethren Brown5RNを
０．９重量％に水を加え１００％としたものを捺染し、
１２０℃で３分間乾燥し、１８０℃で１５分間、乾熱処
理を行った。この織物にグアーガム１２０ｇ／ｋｇ、炭
酸ナトリウム８０ｇ／ｋｇ、炭酸カリ４０ｇ／ｋｇの割
合で水に溶かしたものを元糊として、元糊を６０重量
％、ナトリウムホルムアルデヒドスルホキシレート１７
重量％、水２３重量％の糊を全面に捺染し、１２０℃で
３分間乾燥してから１０２℃の飽和蒸気で１５分間処理
を行った。その後、通常の方法でソーピング・乾燥し
た。処理された織物の洗濯堅牢度、汗堅牢度、耐光堅牢
度、摩擦堅牢度、柄のシャープ性およびＫ／Ｓを測定し
表１にまとめた。Example 1 Polyester fiber / cotton (65/35), 45 count (cotton count) twin yarn as warp yarn, 100% hemp 21 count (cotton count) single yarn as weft yarn, warp density 144 yarns / in, Weft density 68 / in
Woven fabric, scoured, bleached, mercerized, and heat-set on guar gum 30 g / kg, sodium alginate 3
Dissolved in water at a rate of 0 g / kg was used as the base paste, 60% by weight of the base paste, and 4 parts of Foron Brown S-2BL as a disperse dye.
% By weight, 1.3% by weight of Dianix Yellow AM-42, 5.5% by weight of vat dye Mikethren Black VCliq, Mikethr
4.5% by weight of en Orange RRTS and 0.9% by weight of Mikethren Brown 5RN were added to water and printed to 100%,
Drying was performed at 120 ° C. for 3 minutes, and dry heat treatment was performed at 180 ° C. for 15 minutes. Guar gum 120 g / kg, sodium carbonate 80 g / kg, potassium carbonate 40 g / kg dissolved in water was used as the original paste, and the original paste was 60% by weight, sodium formaldehyde sulfoxylate 17
A paste containing 20% by weight of water and 23% by weight of water was printed on the entire surface, dried at 120 ° C. for 3 minutes, and then treated with saturated steam at 102 ° C. for 15 minutes. Then, it was soaped and dried by a usual method. The wash fastness, sweat fastness, light fastness, rubbing fastness, pattern sharpness and K / S of the treated fabric were measured and summarized in Table 1.
【００２７】比較例１
実施例１の１８０℃で１５分間、乾熱処理までは同様の
操作を行った後、この織物の捺染面に硫酸ナトリウム６
０ｇ／ｌ、水酸化ナトリウム５０ｇ／ｌ、ハイドロサル
ファイト５０ｇ／ｌの溶液を、移しロールで付着させ１
０２℃の水蒸気で１分間処理を行った。その後、通常の
方法でソーピング・乾燥した。第２段階のアルカリおよ
び還元剤の処理を溶液の状態で行ったため、堅牢度およ
びＫ／Ｓは満足できるものであったが、柄のシャープ性
は劣るものであった。処理された織物の結果を表１にま
とめた。Comparative Example 1 The same operation as in Example 1 was carried out for 15 minutes at 180 ° C. until dry heat treatment, and then the printed surface of this woven fabric was treated with sodium sulfate 6
A solution of 0 g / l, sodium hydroxide 50 g / l and hydrosulfite 50 g / l was transferred and adhered with a roll.
It was treated with steam at 02 ° C. for 1 minute. Then, it was soaped and dried by a usual method. Since the second stage treatment with the alkali and the reducing agent was carried out in a solution state, the fastness and K / S were satisfactory, but the sharpness of the pattern was poor. The results for the treated fabrics are summarized in Table 1.
【００２８】比較例２
実施例１と同様のポリエステル繊維／綿（６５／３
５）、４５番手（綿番手）双糸を経糸、麻１００％２１
番手（綿番手）単糸を緯糸に用いた経密度１４４本／ｉ
ｎ、緯密度６８本／inで製織し、精練、晒、シルケッ
ト、ヒートセットを行った織物に、グアーガム１２０ｇ
／ｋｇ、炭酸ナトリウム８０ｇ／ｋｇ、炭酸カリ４０ｇ
／ｋｇの割合で水に溶かしたものを元糊として、元糊を
６０重量％、ナトリウムホルムアルデヒドスルホキシレ
ート１２重量％、Foron BrownS-2BLを４重量％、Dianix
YellowAM-42を１．３重量％、 Mikethren Black VCli
qを５．５重量％、Mikethren Orange RRTSを４．５重量
％、Mikethren Brown5RNを０．９重量％に水を加え１０
０％としたものを捺染し、１２０℃で３分間乾燥し、１
６０℃で１５分間、乾熱処理を行った。その後、１０２
℃の水蒸気で１５分間処理を行い、しかる後、通常の方
法でソーピング・乾燥した。分散染料、建染染料および
アルカリと還元剤の４物質を同時に存在させるため、柄
のシャープ性は良好であったがＫ／Ｓに劣るものであっ
た。処理された織物の結果を表１にまとめた。Comparative Example 2 Polyester fiber / cotton (65/3 as in Example 1)
5), 45 count (cotton count) twin yarn, warp, hemp 100% 21
Warp density using count (cotton count) single yarn for weft 144 / i
120 g of guar gum on a woven fabric that has been woven at a weft density of 68 yarns / in and has undergone scouring, bleaching, mercerizing, and heat setting.
/ Kg, sodium carbonate 80g / kg, potassium carbonate 40g
The original paste is 60% by weight of the original paste, 12% by weight of sodium formaldehyde sulfoxylate, 4% by weight of Foron Brown S-2BL, Dianix.
1.3% by weight of YellowAM-42, Mikethren Black VCli
Add q to 5.5% by weight, Mikethren Orange RRTS to 4.5% by weight, Mikethren Brown 5RN to 0.9% by weight and add water to 10
0% is printed and dried at 120 ° C for 3 minutes.
Dry heat treatment was performed at 60 ° C. for 15 minutes. Then 102
It was treated with water vapor at ℃ for 15 minutes, and then soaped and dried by a usual method. Since the disperse dye, the vat dye, and the four substances of alkali and reducing agent were present at the same time, the sharpness of the pattern was good, but the K / S was inferior. The results for the treated fabrics are summarized in Table 1.
【００２９】比較例３
実施例１と同様のポリエステル繊維／綿（６５／３
５）、４５番手（綿番手）双糸を経糸、麻１００％２１
番手（綿番手）単糸を緯糸に用いた経密度１４４本／ｉ
ｎ、緯密度６８本／inで製織し、精練、晒、シルケッ
ト、ヒートセットを行った織物に、アルギン酸ソーダ４
４ｇ／ｋｇ、尿素８０ｇ／ｋｇ、メタニトロベンゼンス
ルホン酸ソーダ１４ｇ／ｋｇの割合で水に溶かしたもの
を元糊として、元糊を７０重量％、Foron BrownS-2BLを
４重量％、Dianix YellowAM-42を１．３重量％、 KPCi
on BlackP/GNを４．２重量％、Kayacion Yellow P/N3Rl
iqを３．６重量％、Kayacion Red P・BNを１．５重量
％、重炭酸ソーダを３重量％に水を加えて１００％とし
たものを捺染し、１２０℃で３分間乾燥し、１６０℃の
過熱蒸気で１５分間、乾熱処理を行った。しかる後、通
常の方法でソーピング・乾燥した。還元剤を用いていな
いので未固着の分散染料を分解させることができず、そ
の結果、分散染料が残存するため堅牢度が悪い上に、柄
のシャープ性が低かった。処理された織物の結果を表１
にまとめた。Comparative Example 3 Polyester fiber / cotton (65/3 as in Example 1)
5), 45 count (cotton count) twin yarn, warp, hemp 100% 21
Warp density using count (cotton count) single yarn for weft 144 / i
n, weft density of 68 yarns / in, scouring, bleaching, mercerizing, heat-setting woven fabric, sodium alginate 4
4 g / kg, urea 80 g / kg, sodium metanitrobenzene sulfonate 14 g / kg dissolved in water as a base paste, the base paste is 70% by weight, Foron Brown S-2BL is 4% by weight, and Dianix YellowAM-42 1.3% by weight, KPCi
4.2% by weight of on Black P / GN, Kayacion Yellow P / N3Rl
iq was 3.6% by weight, Kayacion Red P / BN was 1.5% by weight, sodium bicarbonate was 3% by weight and water was added to make 100%, and the mixture was printed and dried at 120 ° C for 3 minutes, and then at 160 ° C. A dry heat treatment was performed with superheated steam for 15 minutes. Then, it was soaped and dried by a usual method. Since no reducing agent was used, unfixed disperse dyes could not be decomposed, and as a result, disperse dyes remained, resulting in poor fastness and poor pattern sharpness. The results of the treated fabrics are shown in Table 1.
Summarized in.
【００３０】[0030]
【表１】 [Table 1]
【００３１】[0031]
【発明の効果】本発明は、セルロース系繊維とポリエス
テル系繊維とからなる繊維製品を分散染料および建染染
料で捺染し、高堅牢度はもとより、特に、高濃度固着、
柄のシャープ性に優れ、かつ風合いが柔らかく、着用快
適性に優れた捺染物を得るための方法を提供するもので
ある。この繊維製品の捺染方法は、作業外衣、ユニフォ
ームなど高い堅牢度を要求される衣料の染色に有効に適
用される。EFFECTS OF THE INVENTION The present invention prints a fiber product consisting of a cellulosic fiber and a polyester fiber with a disperse dye and a vat dye to obtain high fastness, and in particular, high density fixation,
It is intended to provide a method for obtaining a printed material having excellent pattern sharpness, soft texture, and excellent wearing comfort. This textile printing method is effectively applied to the dyeing of clothing such as work outerwear and uniforms, which requires high fastness.
フロントページの続き (72)発明者 傳田 章 東京都中央区日本橋２丁目５番13号 帝国 繊維株式会社内 (72)発明者 小杉 和夫 静岡県浜松市木戸町２番３号 大和染工株 式会社内 Ｆターム(参考） 4H057 AA02 BA08 BA09 CA08 CA33 CC02 CC03 DA11 DA17 DA24 DA30 FA17 GA04 GA21 GA25 HA01 HA06 JA10 JB03 Continued front page (72) Inventor Akira Denda 2-5-13 Nihonbashi, Chuo-ku, Tokyo Empire Textile Co., Ltd. (72) Inventor Kazuo Kosugi 2-3 Kidocho, Hamamatsu City, Shizuoka Prefecture Daiwa Dyeing Co., Ltd. Inside the company F-term (reference) 4H057 AA02 BA08 BA09 CA08 CA33 CC02 CC03 DA11 DA17 DA24 DA30 FA17 GA04 GA21 GA25 HA01 HA06 JA10 JB03
Claims (2)
から構成された布帛を、分散染料および建染染料を含む
色糊と共に捺染、乾燥、熱処理をした後、アルカリおよ
び還元剤を含む糊を付着、蒸熱処理、ソーピングをする
セルロース系繊維とポリエステル系繊維とからなる繊維
製品の捺染方法。1. A cloth composed of a cellulose fiber and a polyester fiber is printed, dried and heat-treated with a color paste containing a disperse dye and a vat dye, and then a paste containing an alkali and a reducing agent is applied, A textile printing method comprising a cellulosic fiber and a polyester fiber, which are steam-heat treated and soaped.
を含む糊を付着した後に乾燥を行い、しかる後に蒸熱処
理を行うセルロース系繊維とポリエステル系繊維とから
なる繊維製品の捺染方法。2. A textile printing method according to claim 1, wherein a paste containing an alkali and a reducing agent is adhered, dried, and then steamed and heat treated to form a cellulose-based fiber and a polyester-based fiber.
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|---|---|---|---|
| JP2001242443A JP4767451B2 (en) | 2001-08-09 | 2001-08-09 | Method for printing fiber products comprising cellulosic fibers and polyester fibers |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001242443A JP4767451B2 (en) | 2001-08-09 | 2001-08-09 | Method for printing fiber products comprising cellulosic fibers and polyester fibers |
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| Publication Number | Publication Date |
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| JP2003055884A true JP2003055884A (en) | 2003-02-26 |
| JP4767451B2 JP4767451B2 (en) | 2011-09-07 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103757947A (en) * | 2013-12-04 | 2014-04-30 | 常熟市福亿印花炼染有限公司 | Technology for polyester-cotton blended fabric |
| US9605378B2 (en) | 2013-12-03 | 2017-03-28 | Ricoh Company, Ltd. | Textile printing method, inkjet ink for textile printing, and electrophotographic toner for textile printing |
| CN107587360A (en) * | 2017-09-30 | 2018-01-16 | 山东沃源新型面料股份有限公司 | The technique that scattered/intellectual circle's dye printing improves definition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4872485A (en) * | 1971-12-29 | 1973-09-29 | ||
| JPS55163286A (en) * | 1979-06-08 | 1980-12-19 | Mitsubishi Rayon Co | Coloring discharge style of polyester fiber and cellulosic fiber blended fabric |
| JPS5742989A (en) * | 1980-08-27 | 1982-03-10 | Sumitomo Chemical Co | Continuous dyeing of fiber material |
| JPS58104293A (en) * | 1981-12-16 | 1983-06-21 | 東洋紡績株式会社 | Resist and discharge style of polyester and cellulose fiber mixed structure |
| JPS61194284A (en) * | 1985-02-20 | 1986-08-28 | 東洋紡績株式会社 | Resist stypl fiber composite structure and its production |
-
2001
- 2001-08-09 JP JP2001242443A patent/JP4767451B2/en not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4872485A (en) * | 1971-12-29 | 1973-09-29 | ||
| JPS55163286A (en) * | 1979-06-08 | 1980-12-19 | Mitsubishi Rayon Co | Coloring discharge style of polyester fiber and cellulosic fiber blended fabric |
| JPS5742989A (en) * | 1980-08-27 | 1982-03-10 | Sumitomo Chemical Co | Continuous dyeing of fiber material |
| JPS58104293A (en) * | 1981-12-16 | 1983-06-21 | 東洋紡績株式会社 | Resist and discharge style of polyester and cellulose fiber mixed structure |
| JPS61194284A (en) * | 1985-02-20 | 1986-08-28 | 東洋紡績株式会社 | Resist stypl fiber composite structure and its production |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9605378B2 (en) | 2013-12-03 | 2017-03-28 | Ricoh Company, Ltd. | Textile printing method, inkjet ink for textile printing, and electrophotographic toner for textile printing |
| CN103757947A (en) * | 2013-12-04 | 2014-04-30 | 常熟市福亿印花炼染有限公司 | Technology for polyester-cotton blended fabric |
| CN107587360A (en) * | 2017-09-30 | 2018-01-16 | 山东沃源新型面料股份有限公司 | The technique that scattered/intellectual circle's dye printing improves definition |
| CN107587360B (en) * | 2017-09-30 | 2020-09-01 | 山东沃源新型面料股份有限公司 | Process for improving definition of disperse/threne dye printing |
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|---|---|
| JP4767451B2 (en) | 2011-09-07 |
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