JP2003026540A - Water-based manicure composition and method for producing the same - Google Patents
Water-based manicure composition and method for producing the sameInfo
- Publication number
- JP2003026540A JP2003026540A JP2001207591A JP2001207591A JP2003026540A JP 2003026540 A JP2003026540 A JP 2003026540A JP 2001207591 A JP2001207591 A JP 2001207591A JP 2001207591 A JP2001207591 A JP 2001207591A JP 2003026540 A JP2003026540 A JP 2003026540A
- Authority
- JP
- Japan
- Prior art keywords
- water
- film
- range
- polymers
- nail polish
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 59
- 239000000839 emulsion Substances 0.000 claims abstract description 30
- 239000002253 acid Substances 0.000 claims abstract description 17
- 230000009477 glass transition Effects 0.000 claims abstract description 14
- 239000002245 particle Substances 0.000 claims abstract description 9
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 8
- 239000002966 varnish Substances 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 229920000058 polyacrylate Polymers 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 238000003287 bathing Methods 0.000 abstract description 9
- 239000002932 luster Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 description 17
- 239000003960 organic solvent Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 9
- 239000000049 pigment Substances 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 229920002635 polyurethane Polymers 0.000 description 6
- 239000004814 polyurethane Substances 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 210000003298 dental enamel Anatomy 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- -1 more preferably Polymers 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- GDXHBFHOEYVPED-UHFFFAOYSA-N 1-(2-butoxyethoxy)butane Chemical compound CCCCOCCOCCCC GDXHBFHOEYVPED-UHFFFAOYSA-N 0.000 description 1
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- QBQSKYIIEGLPJT-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.OCCOC(=O)C=C QBQSKYIIEGLPJT-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- WLDHEUZGFKACJH-ZRUFZDNISA-K Amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1\N=N\C1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-ZRUFZDNISA-K 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 101000801109 Homo sapiens Transmembrane protein 131 Proteins 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- QQILFGKZUJYXGS-UHFFFAOYSA-N Indigo dye Chemical compound C1=CC=C2C(=O)C(C3=C(C4=CC=CC=C4N3)O)=NC2=C1 QQILFGKZUJYXGS-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 102100033700 Transmembrane protein 131 Human genes 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- HBHZKFOUIUMKHV-UHFFFAOYSA-N chembl1982121 Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O HBHZKFOUIUMKHV-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- 229940100539 dibutyl adipate Drugs 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 description 1
- VJHINFRRDQUWOJ-UHFFFAOYSA-N dioctyl sebacate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCC(=O)OCC(CC)CCCC VJHINFRRDQUWOJ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- CMDXMIHZUJPRHG-UHFFFAOYSA-N ethenyl decanoate Chemical compound CCCCCCCCCC(=O)OC=C CMDXMIHZUJPRHG-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、実質的に有機溶剤
を含有しない水をベースとする水系マニキュア組成物及
びその製造方法に関する。ここで、マニキュアには、ネ
イルエナメル、ネイルエナメルベースコート及びネイル
エナメルオーバーコート等が含まれる。TECHNICAL FIELD The present invention relates to a water-based water-based nail varnish composition containing substantially no organic solvent, and a method for producing the same. Here, the nail polish includes nail enamel, nail enamel base coat, nail enamel overcoat, and the like.
【従来の技術】現在、有機溶媒を使用しない様々な水性
マニキュアが提案されている。例えば、特開昭５４−２
８８３６号公報及び特公昭５５−４３４４５号公報に
は、アクリル系ポリマーエマルションをベースとするマ
ニキュアが、特開昭５６−１３１５１３号公報及び特開
昭５７−５６４１０号公報には、アクリル系ポリマーの
マイクロエマルションをベースとするマニキュアが開示
されている。2. Description of the Related Art At present, various aqueous nail polishes which do not use organic solvents have been proposed. For example, JP-A-54-2
8836 and JP-B-55-43445 disclose manicures based on acrylic polymer emulsions, and JP-A-56-131513 and JP-A-57-56410 disclose micro-based acrylic polymers. Emulsion based manicures have been disclosed.
【０００２】しかしながら、上記公報に開示された水性
マニキュアには、乳化剤や水溶性ポリマーを用いた乳化
重合により製造されたポリマーエマルションが使用され
ているため、水性マニキュアとしての特徴を失わない程
度の少量の成膜助剤の使用では、使用に十分に耐え得る
程の傷付きにくく硬いフィルムを付与することが困難で
あった。また、上記公報に開示された水性マニキュアで
得られるフィルムは耐水性に劣るため、日常生活での使
用中にすぐに剥がれてしまうという欠点があり、十分に
実用に耐えるものとは言えない。上記問題を解決するた
め、特開平４−１０３５１３号公報には、ガラス転移温
度の差が１０℃以上である２種以上のアクリル系ポリマ
ーエマルションを混合使用した水性マニキュアが提案さ
れている。この水性マニキュアは、単なるアクリル系ポ
リマーエマルションを利用した水性マニキュアに比べる
と、光沢、密着性、耐水性及び塗膜強度についてはある
程度改良されているが、入浴後の剥がれや光沢が充分で
はない。また、特開平１０−３０６０１６号公報には、
自己乳化可能なビニル系ポリマー及びセルロース誘導体
を含む水性乳化液を含有することを特徴とする水性マニ
キュアが開示されているが、これでも、入浴後の剥がれ
や光沢が充分ではなく、更なる塗膜性能の改良された水
性マニキュアが望まれている。However, since the aqueous nail polish disclosed in the above publication uses a polymer emulsion produced by emulsion polymerization using an emulsifier and a water-soluble polymer, it has a small amount so as not to lose the characteristics of the aqueous nail polish. With the use of the film-forming aid, it was difficult to provide a hard film that is hard to be scratched and can withstand the use sufficiently. In addition, since the film obtained by the aqueous nail polish disclosed in the above publication has poor water resistance, it has a drawback that it is easily peeled off during use in everyday life, and it cannot be said that it is sufficiently practical. In order to solve the above-mentioned problem, JP-A-4-103513 proposes an aqueous nail polish in which two or more kinds of acrylic polymer emulsions having a glass transition temperature difference of 10 ° C. or more are mixed and used. Although this water-based nail polish has some improvement in gloss, adhesion, water resistance and coating strength as compared with a water-based nail polish using a simple acrylic polymer emulsion, peeling and gloss after bathing are not sufficient. Further, Japanese Patent Laid-Open No. 10-306016 discloses that
Disclosed is an aqueous nail varnish characterized by containing an aqueous emulsion containing a self-emulsifiable vinyl polymer and a cellulose derivative, but even with this, peeling and gloss after bathing are not sufficient, and a further coating film is obtained. Aqueous nail polish with improved performance is desired.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、特に入浴後
に剥がれることがなく、又入浴後であっても優れた光沢
を保持できる水系マニキュア組成物を提供することを目
的とする。本発明は、又、上記水系マニキュア組成物を
効率的に製造することができる方法を提供することを目
的とする。SUMMARY OF THE INVENTION It is an object of the present invention to provide a water-based nail varnish composition which does not peel off after bathing and can maintain excellent gloss even after bathing. Another object of the present invention is to provide a method capable of efficiently producing the above water-based nail polish composition.
【０００４】[0004]
【課題を解決するための手段】本発明は、従来のように
２種のポリマーエマルジョンを混合使用するのではなく
て、同一のエマルジョン粒子内に、分子内に塩基で中和
された酸基を有しかつ特定のガラス転移温度（Ｔｇ）を
有する少なくとも２種の皮膜形成性ポリマーを含有し、
該エマルジョン粒子が水に自己乳化した形態の水性組成
物を用いると、上記課題を効率的に解決できるとの知見
に基づいてなされたのである。すなわち、本発明は、皮
膜形成性ポリマーエマルジョンを含有する水系マニキュ
ア組成物であって、同一のエマルジョン粒子内に、分子
内に塩基で中和された酸基を有しかつガラス転移温度
（Ｔｇ）が-１０℃〜９０℃の範囲にある少なくとも２
種の皮膜形成性ポリマーを含有し、該ポリマーのＴｇの
差異が５〜８０℃の範囲にあることを特徴とする水系マ
ニキュア組成物を提供する。本発明は、又、分子内に酸
基を有しかつガラス転移温度（Ｔｇ）が-１０℃〜９０
℃の範囲にある少なくとも２種の皮膜形成性ポリマー溶
液を別々に溶液重合によって調製し、ポリマーのＴｇの
差異が５〜８０℃の範囲にある該溶液重合液を混合し、
これをアルカリ剤で中和した後、水と混合して、同一の
エマルジョン粒子内にガラス転移温度（Ｔｇ）が-１０
℃〜９０℃の範囲にある少なくとも２種の皮膜形成性ポ
リマーを形成し、ついで溶液重合液中に含まれている有
機溶剤を除去することを特徴とする水系マニキュア組成
物の製造方法を提供する。The present invention does not use two kinds of polymer emulsions in a mixed manner as in the prior art, but the same emulsion particles contain an acid group neutralized with a base in a molecule. Containing at least two film-forming polymers having a specific glass transition temperature (Tg),
This was done based on the finding that the above problems can be efficiently solved by using an aqueous composition in which the emulsion particles are self-emulsified in water. That is, the present invention is a water-based nail polish composition containing a film-forming polymer emulsion, wherein the same emulsion particles have a base-neutralized acid group in the molecule and a glass transition temperature (Tg). Is at least -10 ° C to 90 ° C
Provided is a water-based nail varnish composition, characterized in that it contains a film-forming polymer of a species and the difference in Tg of the polymer is in the range of 5 to 80 ° C. The present invention also has an acid group in the molecule and has a glass transition temperature (Tg) of -10 ° C to 90 ° C.
At least two film-forming polymer solutions in the range of 0 ° C. are separately prepared by solution polymerization, and the solution polymerization solutions in which the difference in Tg of the polymers is in the range of 5 to 80 ° C. are mixed,
This is neutralized with an alkaline agent and then mixed with water so that the same emulsion particles have a glass transition temperature (Tg) of -10.
Provided is a method for producing an aqueous manicure composition, which comprises forming at least two kinds of film-forming polymers in the range of 90 ° C. to 90 ° C., and then removing the organic solvent contained in the solution polymerization liquid. .
【０００５】[0005]
【発明の実施の形態】本発明で用いる分子内に酸基を有
しかつガラス転移温度（Ｔｇ）が-１０℃〜９０℃、好
ましくは-５〜７５℃、より好ましくは５〜６０℃の範
囲にある皮膜形成性ポリマーとしては、酸基（好ましく
はカルボキシル基）及び/又はその塩を分子内に有する
共重合性モノマー（以下、酸基を有するモノマーとい
う）、好ましくは酸基を有するビニル系ポリマー、より
好ましくはα，β−不飽和カルボン酸を構成モノマーと
するポリマーがあげられる。このようなポリマーは、前
記モノマー自体又はこれと酸基及び/又はその塩を分子
内に有しないモノマー（他の共重合性モノマーという）
との共重合によって得られるポリマーであるのが好まし
い。BEST MODE FOR CARRYING OUT THE INVENTION The polymer used in the present invention has an acid group and has a glass transition temperature (Tg) of -10 ° C to 90 ° C, preferably -5 to 75 ° C, more preferably 5 to 60 ° C. The film-forming polymer in the range is a copolymerizable monomer having an acid group (preferably a carboxyl group) and / or a salt thereof in the molecule (hereinafter referred to as a monomer having an acid group), preferably a vinyl having an acid group. Polymers, more preferably, polymers having α, β-unsaturated carboxylic acid as a constituent monomer are mentioned. Such a polymer is a monomer which does not have the above-mentioned monomer itself or an acid group and / or its salt in the molecule (referred to as other copolymerizable monomer).
It is preferably a polymer obtained by copolymerization with
【０００６】酸基を有するモノマーとしては、分子内に
カルボキシル基又はスルホン酸基を有するモノマー又は
その塩を用いるのが好ましい。上記分子内にカルボキシ
ル基を有するモノマーとしては、例えば、炭素数３〜１
２（好ましくは３〜８）の不飽和カルボン酸又はその塩
が好ましく、具体的には、（メタ）アクリル酸、フマル
酸、マレイン酸及びイタコン酸及びそれらの塩等が挙げ
られる。上記分子内にスルホン酸基を有するモノマーと
しては、炭素数３〜１２（好ましくは３〜８）の不飽和
スルホン酸又はその塩が好ましく、具体的には、スチレ
ンスルホン酸、アリルスルホン酸、スルホプロピルアク
リレート及びスルホプロピルメタクリレート及びそれら
の塩等が挙げられる。これらは単独で用いてもよく、又
は２種以上を組み合わせて用いてもよい。As the monomer having an acid group, it is preferable to use a monomer having a carboxyl group or a sulfonic acid group in the molecule or a salt thereof. The monomer having a carboxyl group in the molecule has, for example, 3 to 1 carbon atoms.
2 (preferably 3 to 8) unsaturated carboxylic acids or salts thereof are preferable, and specific examples thereof include (meth) acrylic acid, fumaric acid, maleic acid, itaconic acid and salts thereof. As the monomer having a sulfonic acid group in the molecule, an unsaturated sulfonic acid having 3 to 12 carbon atoms (preferably 3 to 8) or a salt thereof is preferable, and specific examples thereof include styrene sulfonic acid, allyl sulfonic acid, and sulfo. Examples thereof include propyl acrylate, sulfopropyl methacrylate and salts thereof. These may be used alone or in combination of two or more.
【０００７】他の共重合性モノマーとしては、例えば、
（メタ）アクリル酸エステル（アクリレート）、ビニル
エステル及びビニルエーテル等が挙げられる。上記（メ
タ）アクリル酸エステルとしては、例えば、アルキル基
の炭素数が１〜１２（好ましくは１〜８）の（メタ）ア
クリル酸アルキルエステルが好ましく、具体的には、メ
チル（メタ）アクリレート、エチル（メタ）アクリレー
ト、プロピル（メタ）アクリレート、ブチル（メタ）ア
クリレート、オクチル（メタ）アクリレートヒドロキシ
エチルアクリレート、ヒドロキシエチルメタクリレー
ト、エチレンオキシド鎖長の異なる各種ポリエチレング
リコールメタクリレート及びアクリレート等等が挙げら
れる。上記ビニルエステルとしては、例えば、炭素数２
〜１４（好ましくは３〜１２）のカルボン酸のビニルエ
ステルが好ましく、具体的には、酢酸ビニル、プロピオ
ン酸ビニル、カプリン酸ビニル及びバーサチック酸ビニ
ル等が挙げられる。上記ビニルエーテルとしては、例え
ば、アルキル基の炭素数が１〜１２（好ましくは１〜
８）のアルキルビニルエーテルが好ましく、具体的に
は、メチルビニルエーテル、エチルビニルエーテル、プ
ロピルビニルエーテル及びブチルビニルエーテル等が挙
げられる。また、その他のモノマーとしては、例えば、
スチレン、アクリルニトリル、アクリルアミド、メタク
リルニトリル、塩化ビニル、塩化ビニリデン、マレイン
酸ジブチル及びマレイン酸ジオクチル等が挙げられる。
上記ポリマーを得るために、上記モノマーを単独で用い
てもよく、又は２種以上を組み合わせて用いてもよい。
酸基を有するモノマーのモル共重合率は、好ましくは１
〜３０％、更に好ましくは３〜１０％の範囲である。こ
れらのポリマーの分子量は、約１万〜約１００万である
のが好ましく、より好ましくは約５万〜約２０万の範囲
である。Other copolymerizable monomers include, for example,
Examples thereof include (meth) acrylic acid ester (acrylate), vinyl ester and vinyl ether. As the (meth) acrylic acid ester, for example, a (meth) acrylic acid alkyl ester having an alkyl group with 1 to 12 (preferably 1 to 8) carbon atoms is preferable, and specifically, methyl (meth) acrylate, Examples include ethyl (meth) acrylate, propyl (meth) acrylate, butyl (meth) acrylate, octyl (meth) acrylate hydroxyethyl acrylate, hydroxyethyl methacrylate, and various polyethylene glycol methacrylates and acrylates having different ethylene oxide chain lengths. The vinyl ester has, for example, 2 carbon atoms.
A vinyl ester of a carboxylic acid of 14 to 14 (preferably 3 to 12) is preferable, and specific examples thereof include vinyl acetate, vinyl propionate, vinyl caprate and vinyl versatate. As the vinyl ether, for example, the alkyl group has 1 to 12 carbon atoms (preferably 1 to 12 carbon atoms).
The alkyl vinyl ether of 8) is preferable, and specific examples thereof include methyl vinyl ether, ethyl vinyl ether, propyl vinyl ether and butyl vinyl ether. Further, as the other monomer, for example,
Examples thereof include styrene, acrylonitrile, acrylamide, methacrylonitrile, vinyl chloride, vinylidene chloride, dibutyl maleate and dioctyl maleate.
In order to obtain the above polymer, the above monomers may be used alone, or two or more kinds may be used in combination.
The molar copolymerization rate of the monomer having an acid group is preferably 1
-30%, more preferably 3-10%. The molecular weight of these polymers is preferably in the range of about 10,000 to about 1,000,000, more preferably in the range of about 50,000 to about 200,000.
【０００８】本発明では、又、カルボン酸、スルホン
酸、硫酸エステル、リン酸エステル等の酸基及び/又は
その塩を分子内に有するポリウレタン形成用モノマーを
構成成分とするポリウレタンを用いることができる。カ
ルボン酸基を有するポリウレタンが特に好ましく、例え
ば、ポリウレタンの中和価が１０ないし８０の範囲のも
のが好ましく、より好ましくは２０ないし５０の範囲の
ポリウレタンである。これらのポリウレタンの分子量
は、約１万ないし約１００万であるのが好ましく、より
好ましくは約１万ないし約１０万の範囲である。本発明
で用いる皮膜形成性ポリマーとしては、アクリル系ポリ
マー及び/又はウレタン系ポリマーであるのが好まし
く、２種以上のポリマーのＴｇの差異が１０〜８０℃の
範囲にあるのが好ましく、より好ましくは、差異が１５
〜７５℃、最も好ましくは、３０〜５５℃である。In the present invention, it is also possible to use a polyurethane containing a monomer for forming polyurethane having an acid group such as carboxylic acid, sulfonic acid, sulfuric acid ester, phosphoric acid ester and / or its salt in the molecule as a constituent component. . Polyurethanes having a carboxylic acid group are particularly preferable. For example, those having a neutralization value of polyurethane in the range of 10 to 80 are preferable, and polyurethane in the range of 20 to 50 is more preferable. The molecular weight of these polyurethanes is preferably from about 10,000 to about 1,000,000, and more preferably from about 10,000 to about 100,000. The film-forming polymer used in the present invention is preferably an acrylic polymer and / or a urethane polymer, and the difference in Tg between two or more polymers is preferably in the range of 10 to 80 ° C, more preferably Has a difference of 15
-75 degreeC, Most preferably, it is 30-55 degreeC.
【０００９】本発明では、皮膜形成性ポリマーとして乳
化剤を実質的に含有しない重合系で重合して得られたも
のを用いるのが好ましい。本発明の水系マニキュア組成
物は、上記皮膜形成性ポリマーがエマルジョン形態で水
中に乳化した状態で存在するものであり、乳化剤を実質
的に含有しない自己乳化型の皮膜形成性ポリマーを用い
るのが好ましい。しかしながら、本発明の水系マニキュ
ア組成物に、必要により、アニオン、ノニオン、カチオ
ン又は両性界面活性剤を含有させることができる。In the present invention, it is preferable to use, as the film-forming polymer, a polymer obtained by polymerization in a polymerization system containing substantially no emulsifier. The water-based nail polish composition of the present invention is one in which the film-forming polymer is present in an emulsion form in an emulsified state in water, and it is preferable to use a self-emulsifying film-forming polymer which does not substantially contain an emulsifier. . However, the water-based nail polish composition of the present invention may contain an anion, a nonion, a cation or an amphoteric surfactant, if necessary.
【００１０】本発明の水系マニキュア組成物は、皮膜形
成性ポリマーを固形分濃度として２０重量％以上含有す
るのが好ましく、３０重量％以上であるのが更に好まし
く、特に３０〜５０重量％であるのが好ましい。又、ガ
ラス転移温度（Ｔｇ）が-１０℃〜９０℃の範囲にある
皮膜形成性ポリマーを２種含有する場合には、それらの
含有割合を任意とすることができるが、両者を１/９〜
９/１（重量比）とするのが好ましく、低いＴｇのポリ
マー/高いＴｇのポリマーを１/９〜８/２（重量比）で
用いるのが好ましい。さらに、ガラス転移温度（Ｔｇ）
が-１０℃〜９０℃の範囲にある皮膜形成性ポリマーを
３種以上含有する場合には、１番低いＴｇのポリマーと
２番目に低いＴｇのポリマーのＴｇの差異が、１０〜８
０℃の範囲にあるのが好ましく、１番低いＴｇのポリマ
ーとそれ以外のポリマーの重量比を上記範囲とするのが
好ましい。The water-based nail varnish composition of the present invention preferably contains the film-forming polymer in a solid content concentration of 20% by weight or more, more preferably 30% by weight or more, particularly 30 to 50% by weight. Is preferred. Further, when two kinds of film-forming polymers having a glass transition temperature (Tg) in the range of -10 ° C to 90 ° C are contained, the content ratio of them may be arbitrary, but both are 1/9. ~
It is preferable to use 9/1 (weight ratio), and it is preferable to use low Tg polymer / high Tg polymer at 1/9 to 8/2 (weight ratio). Furthermore, glass transition temperature (Tg)
When three or more film-forming polymers having a temperature range of -10 ° C to 90 ° C are contained, the difference in Tg between the polymer having the lowest Tg and the polymer having the second lowest Tg is 10-8.
It is preferably in the range of 0 ° C., and the weight ratio of the polymer having the lowest Tg to the other polymers is preferably in the above range.
【００１１】本発明の水系マニキュア組成物には、その
他のアクリル樹脂系エマルション、水性ウレタン樹脂、
アルカリ可溶性レジン溶液、ポリオレフィン系ワックス
エマルションなどの樹脂エマルション、顔料分散物、可
塑剤、成膜助剤、顔料分散物、界面活性剤などを混合す
ることができる。可塑剤としては、例えば、ジブチルフ
タレート、ジ−２−エチルヘキシルフタレート、ジ−ｎ
−オクチルフタレート、ジイソデシルフタレート、ジイ
ソノニルフタレート、ブチルベンジルフタレート、ジブ
チルアジペート、ジ−２−エチルヘキシルアジペート、
ジブチルグリコールアジペート、ジブチルセバケート及
びジ−２−エチルヘキシルセバケート等が挙げられる。
可塑剤の含有量は、皮膜形成性ポリマー１００重量部に
対して０〜１５０重量部であるのが好ましく、特に５〜
１００重量部である。一方、上記成膜助剤としては、例
えば、セロソルブ、セロソルブアセテート、カルビトー
ル、ブチルカルビトール、カルビトールアセテート、ブ
チルカルビトールアセテート、ヘキシレングリコール、
ベンジルアルコール及びテキサノール等が挙げられる。
成膜助剤の含有量は、皮膜形成性ポリマー１００重量部
に対して０〜５０重量部であるのが好ましく、特に好ま
しくは５〜３０重量部である。The aqueous nail polish composition of the present invention includes other acrylic resin emulsions, aqueous urethane resins,
It is possible to mix an alkali-soluble resin solution, a resin emulsion such as a polyolefin wax emulsion, a pigment dispersion, a plasticizer, a film-forming aid, a pigment dispersion, and a surfactant. Examples of the plasticizer include dibutyl phthalate, di-2-ethylhexyl phthalate, di-n
-Octyl phthalate, diisodecyl phthalate, diisononyl phthalate, butylbenzyl phthalate, dibutyl adipate, di-2-ethylhexyl adipate,
Examples thereof include dibutyl glycol adipate, dibutyl sebacate and di-2-ethylhexyl sebacate.
The content of the plasticizer is preferably 0 to 150 parts by weight, particularly 5 to 100 parts by weight with respect to 100 parts by weight of the film-forming polymer.
It is 100 parts by weight. On the other hand, as the film forming aid, for example, cellosolve, cellosolve acetate, carbitol, butyl carbitol, carbitol acetate, butyl carbitol acetate, hexylene glycol,
Examples thereof include benzyl alcohol and texanol.
The content of the film-forming auxiliary is preferably 0 to 50 parts by weight, and particularly preferably 5 to 30 parts by weight, based on 100 parts by weight of the film-forming polymer.
【００１２】上記可塑剤及び上記成膜助剤はこのような
後添加法によってもよいが、予め溶液重合時に共存させ
て溶媒としての役割を果たさせてもよく、又はポリマー
溶液に添加してもよい。後添加するよりも、予め溶液重
合時に共存させる方がよい。本発明の水系マニキュア組
成物は、そのままでも用いることができるが、更に顔料
を添加してエナメルとして用いることができる。上記顔
料としては、例えば、赤色２０２号、赤色２０６号、赤
色２２０号、赤色２２１号、橙色２０３号、青色２０１
号及び黄色２０４号等の有機顔料、赤色２号、赤色１０
２号、緑色２号、青色１号及び紫色１号等のレーキ顔
料、黄酸化鉄、カーボンブラック、群青及び酸化チタン
等の無機顔料が挙げられる。上記顔料を使用する場合に
は、その添加量としては、皮膜形成性ポリマー１００重
量部に対して３〜１０重量部であることが好ましい。ま
た、本発明の水系マニキュア組成物には、必要に応じ
て、更に増粘剤、染料、防腐剤及び香料等の添加剤を配
合することができる。The above-mentioned plasticizer and film-forming auxiliary may be added by such a post-addition method, but they may be made to coexist in advance during solution polymerization to serve as a solvent, or they may be added to a polymer solution. Good. It is better to make them coexist at the time of solution polymerization, rather than to add them later. The water-based nail polish composition of the present invention can be used as it is, but can be used as an enamel by further adding a pigment. Examples of the pigment include Red No. 202, Red No. 206, Red No. 220, Red No. 221, Orange No. 203, Blue No. 201.
Pigments such as No. 20 and Yellow No. 204, Red No. 2, Red No. 10
Lake pigments such as No. 2, Green No. 2, Blue No. 1 and Purple No. 1 and the like, and inorganic pigments such as iron oxide yellow, carbon black, ultramarine blue, and titanium oxide. When the above-mentioned pigment is used, its addition amount is preferably 3 to 10 parts by weight with respect to 100 parts by weight of the film-forming polymer. Further, the water-based nail polish composition of the present invention may further contain additives such as a thickener, a dye, a preservative and a fragrance, if necessary.
【００１３】次に、本発明の水系マニキュア組成物の製
造方法について説明する。本発明の水系マニキュア組成
物の製造方法は、たとえば、少なくとも２種の上記の皮
膜形成性ポリマーを含有する有機溶媒溶液を水に分散
し、同一のエマルジョン粒子内にこれらの少なくとも２
種の皮膜形成性ポリマーが存在してなるエマルジョンを
形成し、次いで上記有機溶媒を除去することを含む。具
体的には、分子内に酸基の全部又は一部が塩基で中和さ
れて塩の形態となっている少なくとも２種の皮膜形成性
ポリマーを、１つの有機溶媒に溶解し、これを水に分散
させ、ついで有機溶媒を除去することを含む方法、分子
内に酸基、例えば、酸価が２０〜２００ｍｇＫＯＨ／g
（より好ましくは３０〜１３０ｍｇＫＯＨ／g）であり
かつガラス転移温度（Ｔｇ）が-１０℃〜９０℃の範囲
にある少なくとも２種の皮膜形成性ポリマー溶液を別々
に溶液重合によって調製し、ポリマーのＴｇの差異が５
〜８０℃の範囲にある該溶液重合液を混合し、これをア
ルカリ剤で中和した後、水と混合して、同一のエマルジ
ョン粒子内にガラス転移温度（Ｔｇ）が-１０℃〜９０
℃の範囲にある少なくとも２種の皮膜形成性ポリマーを
形成し、ついで溶液重合液中に含まれている有機溶剤を
留去することを含む方法があげられる。Next, a method for producing the aqueous nail polish composition of the present invention will be described. The method for producing the water-based nail polish composition of the present invention comprises, for example, dispersing an organic solvent solution containing at least two kinds of the above film-forming polymers in water, and adding at least two of them in the same emulsion particle.
Forming an emulsion in which the film-forming polymer of the species is present and then removing the organic solvent. Specifically, at least two kinds of film-forming polymers in which all or part of acid groups in the molecule are neutralized with a base to form a salt are dissolved in one organic solvent, and this is dissolved in water. And then removing the organic solvent, an acid group in the molecule, for example, an acid value of 20-200 mgKOH / g
(More preferably 30 to 130 mg KOH / g) and having a glass transition temperature (Tg) in the range of -10 ° C to 90 ° C, at least two film-forming polymer solutions are separately prepared by solution polymerization, Difference in Tg is 5
The solution polymerization liquid in the range of -80 ° C is mixed, neutralized with an alkaline agent, and then mixed with water so that the same emulsion particles have a glass transition temperature (Tg) of -10 ° C to 90 ° C.
The method includes forming at least two kinds of film-forming polymers in the range of ° C, and then distilling off the organic solvent contained in the solution polymerization liquid.
【００１４】ここで、溶液重合液は乳化剤の不存在下で
行うのが好ましく、使用するアルカリ剤としては、例え
ば、アンモニア、水酸化ナトリウム及び水酸化カリウム
等の無機アルカリ、及びジエタノールアミン、トリエタ
ノールアミン、ジメチルアミン及びジエチルアミン等の
有機アルカリが挙げられる。中和は、当量の０.４〜５
倍量で行うのが好ましい。また、溶剤量の１倍〜３倍量
の精製水を加えて乳化するのが好ましい。その後、エマ
ルジョンから有機溶媒を減圧下に除去する。有機溶媒の
除去方法に特に制限はなく、例えば、減圧除去又はスチ
ームストリッピング等により行うことができるHere, the solution polymerization solution is preferably carried out in the absence of an emulsifier, and examples of the alkaline agent used include ammonia, inorganic alkalis such as sodium hydroxide and potassium hydroxide, and diethanolamine and triethanolamine. , Organic solvents such as dimethylamine and diethylamine. Neutralization is equivalent to 0.4-5
It is preferable to carry out a double dose. Further, it is preferable to add 1 to 3 times the amount of the solvent to the purified water to emulsify. Then, the organic solvent is removed from the emulsion under reduced pressure. There is no particular limitation on the method of removing the organic solvent, and for example, it can be performed by vacuum removal or steam stripping.
【００１５】[0015]
【発明の効果】本発明によれば、特に入浴後に剥がれる
ことがなく、又入浴後であっても優れた光沢を保持でき
る水系マニキュア組成物を提供することができる。さら
に、本発明の水系マニキュア組成物は、爪に対する密着
性に優れると共に、高い硬度が得ら、皮膜形成性に優れ
る。また、乳化剤を使用しないものでは、耐水性、耐洗
剤性に優れるとともに、乾燥が早く、光沢も良好である
との利点がある。本発明では、又、このような優れた水
系マニキュア組成物を効率的に製造することができる方
法を提供することができる。次に実施例により本発明を
説明するが、本発明はこれらに限定されるものではな
い。EFFECTS OF THE INVENTION According to the present invention, it is possible to provide a water-based nail varnish composition which does not peel off after bathing and can maintain excellent gloss even after bathing. Further, the water-based nail polish composition of the present invention has excellent adhesion to nails, high hardness, and excellent film-forming property. In addition, those which do not use an emulsifier have the advantages that they are excellent in water resistance and detergent resistance, dry quickly, and have good gloss. The present invention can also provide a method capable of efficiently producing such an excellent water-based nail polish composition. Next, the present invention will be described with reference to examples, but the present invention is not limited thereto.
【００１６】[0016]
【実施例】参考例１
皮膜形成性ポリマーNo１を次に示す溶液重合法により製
造した。撹拌機、コンデンサー、温度計及び滴下装置を
取り付けた反応容器にメチルエチルケトン６９．４ｇを
仕込み、窒素雰囲気中、撹拌下、温度を７０℃に保っ
た。別途、メタクリル酸１．５ｇ、メチルメタクリレー
ト１１．０４ｇ、ブチルアクリレート１７．４６ｇにア
ゾビスイソブチロニトリル０．６ｇを加え、均一に撹拌
して混合物を調製した。この混合物を、反応容器のメチ
ルエチルケトン中に７０℃に保ちながら４時間にわたっ
て滴下した。滴下終了後、１時間熟成した。その後、常
温まで冷却した。固形分３０％の溶液重合物（皮膜形成
性ポリマーNo１）を得た。原料のモノマー組成とＴｇを
表-１に示す。溶液重合物１と同様な製造方法にて溶液
重合物（皮膜形成性ポリマーNo２〜５）を得た。これら
を調製するのに用いた原料のモノマー組成とＴｇも表-
１に示す。EXAMPLES Reference Example 1 Film-forming polymer No. 1 was produced by the solution polymerization method shown below. A reaction vessel equipped with a stirrer, a condenser, a thermometer, and a dropping device was charged with 69.4 g of methyl ethyl ketone, and the temperature was kept at 70 ° C. under stirring in a nitrogen atmosphere. Separately, 0.6 g of azobisisobutyronitrile was added to 1.5 g of methacrylic acid, 11.04 g of methyl methacrylate, and 17.46 g of butyl acrylate, and stirred uniformly to prepare a mixture. This mixture was added dropwise to methyl ethyl ketone in a reaction vessel over 4 hours while maintaining the temperature at 70 ° C. After completion of dropping, the mixture was aged for 1 hour. Then, it cooled to normal temperature. A solution polymerization product (film-forming polymer No. 1) having a solid content of 30% was obtained. Table 1 shows the monomer composition and Tg of the raw materials. Solution polymerization products (film-forming polymers No. 2 to 5) were obtained by the same production method as for the solution polymerization product 1. The monomer composition and Tg of the raw materials used to prepare these are also listed.
Shown in 1.
【００１７】実施例１及び比較例１
Ｔｇの異なった溶液重合物である皮膜形成性ポリマーNo
２とNo４のそれぞれ１５ｇと３５ｇを撹拌機で混合して
均一な溶液組成物とした後、撹拌を続けながら、中和当
量の０．５倍のアンモニア水を滴下して中和した後、４
０℃で３５．２ｇの精製水を加えてエマルジョンにし
た。このエマルジョンを、撹拌装置と減圧装置を取り付
けた脱水及び脱溶剤装置にいれ、３０℃、減圧下、５時
間かけて脱溶剤を行った後、温度を４０℃に上昇させて
脱水を行い、固形分が４０重量％の水系エマルジョンａ
を得た。組成を表-２に示す。同様にして、水系エマル
ジョンｂ〜ｈを調製した。組成を同様に表-２に示す。
このようにして調製した水系エマルジョンｂ〜ｈを用
い、可塑剤などの種々の成分を添加して水系マニキュア
組成物Ａ〜Ｈを調製した。配合組成物を表-３に示す。Example 1 and Comparative Example 1 Film-forming polymer No that is a solution polymerized product having different Tg
After mixing 15 g and 35 g of No. 2 and No. 4 with a stirrer to form a uniform solution composition, while continuing stirring, 0.5 times the neutralization equivalent of ammonia water was added dropwise to neutralize and then 4
An emulsion was prepared by adding 35.2 g of purified water at 0 ° C. This emulsion is put in a dehydrating and desolventizing device equipped with a stirrer and a depressurizing device, desolvated at 30 ° C under reduced pressure for 5 hours, and then dehydrated by raising the temperature to 40 ° C. 40% by weight of water-based emulsion a
Got The composition is shown in Table-2. Similarly, aqueous emulsions b to h were prepared. The composition is also shown in Table-2.
Using the aqueous emulsions b to h thus prepared, various components such as a plasticizer were added to prepare aqueous nail polish compositions A to H. The compounding composition is shown in Table-3.
【００１８】[0018]
【表１】 [Table 1]
【００１９】[0019]
【表２】 [Table 2]
【００２０】[0020]
【表３】 [Table 3]
【００２１】実施例及び比較例により得られた水系マニ
キュア組成物Ａ〜Ｈについて、乾燥性、密着性、耐温水
性、耐洗剤性、光沢を以下のような方法により評価し
た。試験は5名のモニターにより行い、その平均をそれ
ぞれの試料の性能評価とした。また、塗布する指を順に
換えることで評価結果に誤差が無いよう５回試験した。
結果をまとめて表-４に示す。
＜試験方法＞
爪に水系マニキュア組成物Ａ〜Ｈをネイルエナメル筆
で塗布し、乾燥時間を指触により評価した。
完全に乾燥したところでそれぞれの光沢を下記の基準
により評価した。
○・・・良い、△・・・あまり光沢がない、×・・・光沢がない
塗布後２時間経過してから入浴を行い、次のような項
目についてマニキュアの残存性を目視で評価した。
(i)どの程度剥がれたかを観察し、皮膜の状態を下記の
基準で評価した。
◎・・・全く剥がれない、○・・・少し剥がれる、△・・・半分
くらい剥がれる、×・・・全て剥がれる
(ii)つやが落ちていないか観察し、つやの状態を下記の
基準で評価した。
○・・・全くつや落ちがない、△・・・少しつや落ちする、×
・・・ほとんどつやがないThe water-based nail polish compositions A to H obtained in Examples and Comparative Examples were evaluated for dryness, adhesion, hot water resistance, detergent resistance and gloss by the following methods. The test was performed by 5 monitors, and the average was used as the performance evaluation of each sample. In addition, the finger to be applied was changed in order, and the evaluation result was tested five times so that there was no error.
The results are summarized in Table-4. <Test Method> The water-based nail polish compositions A to H were applied to the nails with a nail enamel brush, and the drying time was evaluated by touch with a finger. When completely dried, each gloss was evaluated according to the following criteria. ○: good, Δ: not very glossy, ×: not glossy, two hours after application, bathing was performed, and the nail polish persistence was visually evaluated for the following items. (i) The degree of peeling was observed and the state of the film was evaluated according to the following criteria. ◎ ・ ・ ・ No peeling, ○ ・ ・ ・ Slightly peeling, △ ・ ・ ・ Peeling about half, × ・ ・ ・ Peeling all (ii) Observing whether or not the gloss has fallen, and evaluating the gloss state according to the following criteria. . ○: No gloss, △: Slight gloss, ×
... almost matte
【００２２】[0022]
【表４】 表-４ 総合評価 [Table 4] Table-4 Overall Evaluation
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4C083 AB082 AC072 AC372 AC762 AC852 AD01 AD022 AD071 AD072 AD091 AD092 CC28 DD31 EE01 EE03 4J002 BC02W BC12W BD03W BD10W BE04W BF01W BF02W BG04W BG05W BG07W BG10W BG12W BH00W BH02W CK02X FD020 GB00 ─────────────────────────────────────────────────── ─── Continued front page F-term (reference) 4C083 AB082 AC072 AC372 AC762 AC852 AD01 AD022 AD071 AD072 AD091 AD092 CC28 DD31 EE01 EE03 4J002 BC02W BC12W BD03W BD10W BE04W BF01W BF02W BG04W BG05W BG07W BG10W BG12W BH00W BH02W CK02X FD020 GB00
Claims (5)
する水系マニキュア組成物であって、同一のエマルジョ
ン粒子内に、分子内に塩基で中和された酸基を有しかつ
ガラス転移温度（Ｔｇ）が-１０℃〜９０℃の範囲にあ
る少なくとも２種の皮膜形成性ポリマーを含有し、該ポ
リマーのＴｇの差異が５〜８０℃の範囲にあることを特
徴とする水系マニキュア組成物。1. A water-based nail varnish composition containing a film-forming polymer emulsion, wherein the same emulsion particles have acid groups neutralized with a base in the molecule and have a glass transition temperature (Tg). A water-based nail polish composition comprising at least two film-forming polymers in the range of -10 ° C to 90 ° C and having a difference in Tg of the polymers in the range of 5 to 80 ° C.
マー及び/又はウレタン系ポリマーである請求項１記載
の水系マニキュア組成物。2. The water-based nail polish composition according to claim 1, wherein the film-forming polymer is an acrylic polymer and / or a urethane polymer.
の範囲にある請求項１又は２記載の水系マニキュア組成
物。3. The difference in Tg of the polymers is 10 to 80 ° C.
The water-based nail polish composition according to claim 1, which is in the range of 1.
３のいずれか１項記載の水系マニキュア組成物。4. The method according to claim 1, which contains substantially no emulsifier.
The water-based nail polish composition according to any one of 3 above.
（Ｔｇ）が-１０℃〜９０℃の範囲にある少なくとも２
種の皮膜形成性ポリマー溶液を別々に溶液重合によって
調製し、ポリマーのＴｇの差異が５〜８０℃の範囲にあ
る該溶液重合液を混合し、これをアルカリ剤で中和した
後、水と混合して、同一のエマルジョン粒子内にガラス
転移温度（Ｔｇ）が-１０℃〜９０℃の範囲にある少な
くとも２種の皮膜形成性ポリマーを形成し、ついで溶液
重合液中に含まれている有機溶剤を除去することを特徴
とする水系マニキュア組成物の製造方法。5. At least 2 having an acid group in the molecule and having a glass transition temperature (Tg) in the range of -10 ° C to 90 ° C.
The film-forming polymer solutions of the seeds are separately prepared by solution polymerization, the solution polymerization solutions having a difference in Tg of the polymers in the range of 5 to 80 ° C. are mixed, neutralized with an alkaline agent, and then mixed with water. By mixing, at least two kinds of film-forming polymers having a glass transition temperature (Tg) in the range of -10 ° C to 90 ° C are formed in the same emulsion particle, and then the organic compound contained in the solution polymerization solution is added. A method for producing an aqueous nail polish composition, which comprises removing a solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001207591A JP2003026540A (en) | 2001-07-09 | 2001-07-09 | Water-based manicure composition and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001207591A JP2003026540A (en) | 2001-07-09 | 2001-07-09 | Water-based manicure composition and method for producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003026540A true JP2003026540A (en) | 2003-01-29 |
Family
ID=19043551
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001207591A Pending JP2003026540A (en) | 2001-07-09 | 2001-07-09 | Water-based manicure composition and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2003026540A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010077042A (en) * | 2008-09-25 | 2010-04-08 | Kao Corp | Oil-in-water type eyelash cosmetic |
| CN109316366A (en) * | 2018-10-25 | 2019-02-12 | 杭州莱凡网络科技有限公司 | A kind of quick-drying nail polish and its preparation process |
| CN109384900A (en) * | 2018-11-14 | 2019-02-26 | 广州指匠科技有限公司 | Self-drying aqueous nail polish polyaminoester emulsion, preparation method and the nail polish prepared using it as base-material |
| WO2019045251A1 (en) * | 2017-08-31 | 2019-03-07 | 코스맥스 주식회사 | Aqueous nail polish composition comprising acrylate-based copolymer |
| KR20190072839A (en) * | 2017-12-18 | 2019-06-26 | 김영욱 | Aqueous manicure composition and manufacturing method thereof |
-
2001
- 2001-07-09 JP JP2001207591A patent/JP2003026540A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010077042A (en) * | 2008-09-25 | 2010-04-08 | Kao Corp | Oil-in-water type eyelash cosmetic |
| WO2019045251A1 (en) * | 2017-08-31 | 2019-03-07 | 코스맥스 주식회사 | Aqueous nail polish composition comprising acrylate-based copolymer |
| KR20190072839A (en) * | 2017-12-18 | 2019-06-26 | 김영욱 | Aqueous manicure composition and manufacturing method thereof |
| KR102026202B1 (en) | 2017-12-18 | 2019-09-27 | 김영욱 | Aqueous manicure composition and manufacturing method thereof |
| CN109316366A (en) * | 2018-10-25 | 2019-02-12 | 杭州莱凡网络科技有限公司 | A kind of quick-drying nail polish and its preparation process |
| CN109316366B (en) * | 2018-10-25 | 2021-08-06 | 杭州莱凡网络科技有限公司 | Quick-drying nail polish and preparation process thereof |
| CN109384900A (en) * | 2018-11-14 | 2019-02-26 | 广州指匠科技有限公司 | Self-drying aqueous nail polish polyaminoester emulsion, preparation method and the nail polish prepared using it as base-material |
| CN109384900B (en) * | 2018-11-14 | 2021-03-23 | 广州凯沃科技有限公司 | Polyurethane emulsion for self-drying water-based nail polish, preparation method thereof and nail polish prepared by taking polyurethane emulsion as base material |
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