JP2002088348A - Organic hydrophilic treatment agent for aluminum- containing metal material and method for treating the same - Google Patents
Organic hydrophilic treatment agent for aluminum- containing metal material and method for treating the sameInfo
- Publication number
- JP2002088348A JP2002088348A JP2000280152A JP2000280152A JP2002088348A JP 2002088348 A JP2002088348 A JP 2002088348A JP 2000280152 A JP2000280152 A JP 2000280152A JP 2000280152 A JP2000280152 A JP 2000280152A JP 2002088348 A JP2002088348 A JP 2002088348A
- Authority
- JP
- Japan
- Prior art keywords
- aluminum
- metal material
- containing metal
- group
- hydrophilic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/56—Treatment of aluminium or alloys based thereon
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、アルミニウムまた
はアルミニウム合金材を包含するアルミニウム含有金属
材料の表面を親水性化するために用いられる有機親水性
処理剤及びその処理方法に関するものである。さらに詳
しく述べるなら、本発明は、アルミニウム含有金属材料
に優れた親水性、防臭、消臭効果を発揮する皮膜を形成
するための有機親水性処理剤及びそれを用いたアルミニ
ウム含有金属材料を処理する方法に関するものである。
特に、本発明の有機親水性処理剤及び処理方法は家電、
自動車の分野で利用され、エアコン部品として使用され
る熱交換器用アルミフィンの製造に好適なものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an organic hydrophilic treating agent used for making the surface of an aluminum-containing metal material including aluminum or an aluminum alloy material hydrophilic, and a method for treating the same. More specifically, the present invention treats an aluminum-containing metal material with an organic hydrophilic treatment agent for forming a film exhibiting excellent hydrophilicity, deodorization and deodorizing effects, and an aluminum-containing metal material using the same. It is about the method.
In particular, the organic hydrophilic treating agent and the treating method of the present invention are used for home appliances,
It is suitable for manufacturing aluminum fins for heat exchangers used in the field of automobiles and used as air conditioner parts.
【０００２】[0002]
【従来の技術】従来、熱交換器用アルミフィンの表面上
に親水性皮膜を形成するために用いられる組成物とし
て、アルカリ珪酸塩やシリカなどの無機系化合物を主成
分として含む水溶液、及び有機系高分子化合物の水溶液
またはそれに界面活性剤を配合した水溶液等が知られて
いる。これらの組成物に、アルミニウム含有金属材料を
浸漬またはロールコート処理を施した後、加熱乾燥する
ことでアルミニウム表面に親水性皮膜が形成される。一
方、省エネルギー化の一環で、熱交換器のコンパクト化
を達成するため、フィンピッチを狭め、さらに熱交換率
を向上させるために熱交換器表面に親水性、親水持続性
を付与する技術分野が発展し、その技術レベルが高くな
っている。2. Description of the Related Art Conventionally, as a composition used for forming a hydrophilic film on the surface of an aluminum fin for a heat exchanger, an aqueous solution containing an inorganic compound such as an alkali silicate or silica as a main component and an organic An aqueous solution of a polymer compound or an aqueous solution in which a surfactant is blended with the aqueous solution are known. These compositions are dipped or roll-coated with an aluminum-containing metal material, and then dried by heating to form a hydrophilic film on the aluminum surface. On the other hand, as a part of energy saving, the technical field of imparting hydrophilicity and hydrophilic persistence to the heat exchanger surface to narrow the fin pitch in order to achieve a compact heat exchanger and to further improve the heat exchange rate has been developed. It has evolved and its technical level has increased.
【０００３】エアコン部品である熱交換器に発生する臭
気についても、非常に関心が高まっている。すなわち前
記無機系化合物を主成分として形成された親水性皮膜の
場合、ほこり臭及びセメント臭などの無機臭が強く発生
し、不快感を与えるという問題がある。また、前記有機
高分子化合物を主成分として形成された親水性皮膜の場
合には、皮膜自身の臭気は少ないが、長期間使用する
と、皮膜上に黴やバクテリアなどの微生物が発生し、腐
敗臭などの不快臭が発生する。特に、高温、多湿となる
雰囲気下では不快臭の発生がさらに増進される。それを
抑制する手段として、あらかじめ親水性処理剤に防菌剤
を添加するか、防臭スプレー等で熱交換器に防菌剤を直
接吹き付ける方法が挙げられる。防菌剤は微量添加する
ことにより腐敗臭抑制効果が得られるが、それ自身が、
これを取り扱う人体に対して必ずしも毒性がないとは言
えない。臭気を抑制する物質として、臭気物質の吸着能
に優れた活性炭を親水性皮膜中に添加する方法もある。
しかしながら、吸着した臭気物質を高湿度雰囲気で再放
出したり、親水持続性が劣化するなどの問題がある。[0003] The odor generated in a heat exchanger as an air conditioner component is also of great interest. That is, in the case of a hydrophilic film formed with the above-mentioned inorganic compound as a main component, there is a problem that inorganic odors such as dust odor and cement odor are strongly generated, giving a feeling of discomfort. In the case of a hydrophilic film formed mainly of the organic polymer compound, the odor of the film itself is small, but when used for a long time, microorganisms such as molds and bacteria are generated on the film, and putrefaction odor is generated. An unpleasant odor such as occurs. In particular, the generation of unpleasant odor is further promoted under an atmosphere of high temperature and high humidity. As means for suppressing this, there is a method in which a bactericide is added to the hydrophilic treatment agent in advance, or a bactericidal agent is directly sprayed on the heat exchanger with a deodorant spray or the like. The antiseptic odor control effect can be obtained by adding a small amount of antibacterial agent, but
It is not necessarily toxic to the human body handling it. As a substance that suppresses odor, there is a method in which activated carbon having an excellent odor substance adsorption ability is added to the hydrophilic film.
However, there are problems such as re-release of the adsorbed odor substance in a high-humidity atmosphere and deterioration of hydrophilic sustainability.
【０００４】ロールコート法を用いる処理方法におい
て、アルミニウム含有金属材料表面上に親水性処理剤を
塗布、加熱乾燥した後に成形加工するプレコート方式の
場合、しごき、穴あけなど厳しい加工条件下において、
金型と皮膜との間で起こる摩擦により、不快臭を発生す
る場合がある。また、有機高分子化合物を主成分とした
皮膜は、摩擦熱による熱分解又は熱酸化分解によって、
皮膜劣化が起こり、不快臭を発生する。成形加工時に臭
気が発生しない場合でも、有機高分子皮膜の熱分解物が
皮膜表面もしくは皮膜内部に存在し、これがエアコン稼
働初期に揮散して異臭が感ぜられる場合がある。上述の
ような臭気発生に関する問題は、熱交換器製造時の作業
環境において、また、エアコン稼働時の室内環境におい
て、生起し、これにより不快を感ずる使用者が多い。こ
のような、臭気対策のため、従来からいろいろな提案が
なされている。[0004] In a treatment method using a roll coating method, in the case of a pre-coat method in which a hydrophilic treatment agent is applied to the surface of an aluminum-containing metal material, heated and dried, and then formed, the processing is performed under severe processing conditions such as ironing and drilling.
An unpleasant odor may be generated due to friction generated between the mold and the film. In addition, the film mainly composed of an organic polymer compound is thermally decomposed or thermally oxidized by frictional heat,
Deterioration of the film occurs, generating an unpleasant odor. Even when no odor is generated during the molding process, a thermal decomposition product of the organic polymer film exists on the film surface or inside the film, which may be volatilized in the early stage of the operation of the air conditioner and an unpleasant odor may be felt. The above-mentioned problems concerning the generation of odors occur in the working environment when manufacturing the heat exchanger and in the indoor environment when the air conditioner is operating, and thus many users feel uncomfortable. Various proposals have conventionally been made for such odor control.
【０００５】例えば、特開平９−２７２８１８号公報に
は、「熱交用親水性処理組成物」が開示されている。し
かしながら、この開示技術により得られた皮膜から臭気
が感じられるから、臭気防止性が完全なものではない。
特開平８−２３２０２８号公報には、アルミニウム含有
金属材料の親水性水系処理剤及び親水性処理方法」が開
示されている。この処理剤には、異臭発生防止のため必
須成分として防菌剤が含有されているが、防菌剤は化学
反応により合成されたものであり、防菌剤自体の人体に
対する、毒性は必ずしも低いとは言えない。更に、消臭
性に関する技術として、特開昭６２−９０１６８号の
「消臭フィルター」、及び、特開平２−２５１６８１号
の「消臭機能を有する繊維の加工法」が公開されている
が、これらの発明による消臭効果は認められるがその用
途、分野は本発明の技術分野及び用途と全く異なるもの
であり、本発明の用途には適当ではないものである。特
開平５−４５０８３号の「自己消臭性熱交換器用Ａｌフ
ィン材」は、プレス加工時の異臭発生は認められない
が、水分散シリカが含有されているために、これを長期
間使用すると冷房運転時の結露水が原因となりシリカが
皮膜表面に顕在化し、不快な無機臭を発生する。したが
って、現状ではアルミニウム含有金属材料表面に優れた
親水性、防臭性、消臭性を同時に付与し得る親水性皮膜
を形成させることができる組成物は得られていないので
ある。[0005] For example, JP-A-9-272818 discloses a "hydrophilic treatment composition for heat exchange". However, since the odor is felt from the film obtained by the disclosed technique, the odor prevention is not perfect.
Japanese Patent Application Laid-Open No. Hei 8-232320 discloses a hydrophilic aqueous treatment agent and a hydrophilic treatment method for an aluminum-containing metal material. This treating agent contains an antibacterial agent as an essential component for preventing the generation of an offensive odor, but the antibacterial agent is synthesized by a chemical reaction, and the toxicity of the antibacterial agent itself to the human body is not necessarily low. It can not be said. Further, as a technique relating to deodorizing properties, "Deodorizing filter" of JP-A-62-90168 and "Processing method of fiber having deodorizing function" of JP-A-2-251681 have been disclosed. Although the deodorizing effects of these inventions are recognized, their uses and fields are completely different from the technical fields and uses of the present invention, and are not suitable for the uses of the present invention. Japanese Patent Application Laid-Open No. 5-45083 discloses that “Al fin material for self-deodorizing heat exchanger” does not generate an unpleasant odor at the time of press working, but contains water-dispersed silica. Due to the dew water during the cooling operation, silica becomes apparent on the film surface, generating an unpleasant inorganic odor. Therefore, at present, a composition capable of forming a hydrophilic film capable of simultaneously imparting excellent hydrophilicity, deodorant property, and deodorant property to the surface of an aluminum-containing metal material has not been obtained.
【０００６】[0006]
【発明が解決しようとする課題】本発明は、前記従来技
術の有する上記問題点を解決するためのものであり、ア
ルミニウム含有金属材料表面に優れた親水性、防臭性、
消臭性を付与する有機親水性皮膜を形成させるための有
機親水性処理剤及びこれを用いる処理方法を提供しよう
とするものである。SUMMARY OF THE INVENTION The present invention has been made to solve the above problems of the prior art, and has excellent hydrophilicity and deodorant properties on the surface of an aluminum-containing metal material.
An object of the present invention is to provide an organic hydrophilic treating agent for forming an organic hydrophilic film imparting deodorant properties and a treatment method using the same.
【０００７】ここで、上記臭気に関わる用語で、「防
臭」とは本発明を適用して製造された親水性処理アルミ
ニウム材の表面、バルクから不快な臭気発生がないこ
と、また加工時の摩擦熱による皮膜分解物に起因する不
快な臭気発生がない効果を意味する。ただし、上記防臭
効果が得られたということは、当該臭気が人間が感知で
きるレベルより低いという意味であり、絶対無発生とい
うことではない。また、「消臭」とは、アセトアルデヒ
ド、アンモニア、トリメチルアミン、メルカプタンなど
の悪臭物質が存在する雰囲気下で、アルミニウム含有金
属材料の上に形成された有機親水性皮膜が積極的にこれ
らと反応して、これらの存在量を低減することを意味す
る。Here, in the term relating to the above-mentioned odor, "deodorization" means that no unpleasant odor is generated from the surface and bulk of the hydrophilically treated aluminum material manufactured by applying the present invention, and that friction during processing is not caused. This means that there is no unpleasant odor generated due to the film decomposition product due to heat. However, that the above-mentioned deodorizing effect is obtained means that the odor is lower than a level that can be perceived by humans, and does not mean that the odor is not generated. In addition, "deodorization" means that in an atmosphere where malodorous substances such as acetaldehyde, ammonia, trimethylamine, and mercaptan are present, an organic hydrophilic film formed on an aluminum-containing metal material actively reacts with these substances. , Means reducing their abundance.
【０００８】[0008]
【課題を解決するための手段】本発明のアルミニウム含
有金属材料用有機親水性処理剤は、カルボキシル基、ア
ミド基、ヒドロキシル基、スルホン基、ホスホン基から
選ばれた少なくとも１種が主鎖に結合している水溶性高
分子化合物（Ａ）、及び１個以上の芳香族核構造を含む
多環式構造に合計５個以上のヒドロキシル基が直接結合
しているフェノール化合物（Ｂ）を含有することを特徴
とするものである。本発明のアルミニウム含有金属材料
用有機親水性処理剤において、更に、グリシジル基含有
有機化合物（Ｃ）を含有することが好ましい。本発明の
アルミニウム含有金属材料用有機親水性処理剤におい
て、前記フェノール化合物（Ｂ）が、下記構造式（Ｉ）
により表される多ヒドロキシ化合物：According to the present invention, there is provided an organic hydrophilic treating agent for an aluminum-containing metal material, wherein at least one selected from a carboxyl group, an amide group, a hydroxyl group, a sulfone group and a phosphone group is bonded to the main chain. Water-soluble polymer compound (A), and a phenolic compound (B) in which a total of five or more hydroxyl groups are directly bonded to a polycyclic structure containing one or more aromatic core structures. It is characterized by the following. The organic hydrophilic treating agent for an aluminum-containing metal material of the present invention preferably further contains a glycidyl group-containing organic compound (C). In the organic hydrophilic treating agent for an aluminum-containing metal material of the present invention, the phenolic compound (B) is represented by the following structural formula (I)
Polyhydroxy compound represented by:
【化３】 〔但し、式（Ｉ）中、Ｘは２個以上のヒドロキシル基に
より置換された芳香族基を表し、Ｙはヒドロキシル基又
は下記式（II）：Embedded image [However, in the formula (I), X represents an aromatic group substituted by two or more hydroxyl groups, and Y represents a hydroxyl group or the following formula (II):
【化４】 により表される芳香族基を表す〕から選ばれることが好
ましい。本発明のアルミニウム含有金属材料用有機親水
性処理剤において、前記一般式（Ｉ）の多ヒドロキシ化
合物が（＋）−カテキン、（−）−エピカテキン、
（＋）−ガロカテキン、（−）−エピカテキンガレー
ト、（−）−エピカロカテキンガレート、及び（−）−
エピガロカテキンから選ばれることが好ましい。本発明
のアルミニウム含有金属材料用有機親水性処理剤におい
て、前記成分（Ａ），（Ｂ）及び（Ｃ）の固形分換算含
有重量Ａ，Ｂ及びＣが、下記関係式（１）及び（２）を
満たすことが好ましい。 Ａ／Ｃ＝９／１〜３／７ （１） Ｂ／（Ａ＋Ｃ）＝１／１０００〜１／２０ （２） 本発明のアルミニウム含有金属材料の表面親水性処理方
法は前記本発明のアルミニウム含有金属材料用有機親水
性処理剤を、アルミニウム含有金属材料の少なくとも１
表面に塗布し、これを加熱乾燥して有機親水性皮膜層を
形成することを特徴とするものである。Embedded image Represents an aromatic group represented by the following formula: In the organic hydrophilic treating agent for an aluminum-containing metal material of the present invention, the polyhydroxy compound of the general formula (I) is (+)-catechin, (−)-epicatechin,
(+)-Gallocatechin, (−)-epicatechin gallate, (−)-epicalocatechin gallate, and (−)-
It is preferably selected from epigallocatechin. In the organic hydrophilic treating agent for an aluminum-containing metal material of the present invention, the weights A, B and C in terms of solid content of the components (A), (B) and (C) are determined by the following relational formulas (1) and (2). Is preferable. A / C = 9/1 to 3/7 (1) B / (A + C) = 1/1000 to 1/20 (2) The method for treating the surface hydrophilicity of the aluminum-containing metal material of the present invention includes the aluminum-containing material of the present invention. The organic hydrophilic treatment agent for a metal material is at least one of an aluminum-containing metal material.
It is characterized in that it is applied on the surface and dried by heating to form an organic hydrophilic film layer.
【０００９】[0009]
【発明の実施の形態】以下に本発明の構成を詳細に述べ
る。DESCRIPTION OF THE PREFERRED EMBODIMENTS The configuration of the present invention will be described below in detail.
【００１０】本発明のアルミニウム含有金属材料用有機
親水性処理剤は、水溶性高分子化合物（Ａ）と、特定化
学構造を有する多ヒドロキシフェノール化合物（Ｂ）
と、必要によりグリシジル基含有有機化合物（Ｃ）とを
含有するものである。本発明に用いられる水溶性高分子
化合物（Ａ）は、アルミニウム含有金属材料に高い親水
性を付与するために処理剤中に配合され、この化合物
（Ａ）はカルボキシル基、アミド基、ヒドロキシル基、
スルホン基及びホスホン基からなる群から選ばれる少な
くとも１種の官能基を有するものである。水溶性高分子
化合物（Ａ）は、前記親水性基を有するエチレン性不飽
和結合含有モノマー、オリゴマーを用いて、加熱、加圧
及び攪拌などの特定条件下で重合して得られる重合体で
ある。The organic hydrophilic treating agent for an aluminum-containing metal material of the present invention comprises a water-soluble polymer compound (A) and a polyhydroxyphenol compound (B) having a specific chemical structure.
And, if necessary, a glycidyl group-containing organic compound (C). The water-soluble polymer compound (A) used in the present invention is blended in a treating agent in order to impart high hydrophilicity to the aluminum-containing metal material, and the compound (A) contains a carboxyl group, an amide group, a hydroxyl group,
It has at least one functional group selected from the group consisting of a sulfone group and a phosphone group. The water-soluble polymer compound (A) is a polymer obtained by polymerizing the ethylenically unsaturated bond-containing monomer or oligomer having a hydrophilic group under specific conditions such as heating, pressurizing and stirring. .
【００１１】水溶性高分子化合物（Ａ）用のカルボキシ
ル基、アミド基を含有するモノマーとしては、アクリル
酸、メタクリル酸、クロトン酸、イタコン酸、マレイン
酸、フマル酸、アクリルアミド等が挙げられ、さらにそ
のなかの塩形成性化合物の塩も包含される。その塩とし
ては、ナトリウム、カリウム等のアルカリ金属塩、マグ
ネシウム、カルシウム等のアルカリ土類金属塩が挙げら
れる。またスルホン酸基、ホスホン酸基を含有するモノ
マーとしては、ビニルスルホン酸、スルホエチルアクリ
レート、スルホエチルメタクリレート、Ｎ−メチルスル
ホン酸アクリルアミド、２−アクリルアミド−２−メチ
ルプロパンスルホン酸、スチレンスルホン酸、ビニルホ
スホン酸またはホスホノキシエチルメタクリレートなど
を用いることができる。さらにこれら塩も用いることが
でき、例えばナトリウム、カリウム等のアルカリ金属
塩、マグネシウム、カルシウム等のアルカリ土類金属塩
が挙げられる。さらに、ヒドロキシル基を含有するモノ
マーとしては、ビニルアルコール、（メタ）アクリル酸
２−ヒドロキシエチル、（メタ）アクリル酸２−ヒドロ
キシプロピル、（メタ）アクリル酸３−ヒドロキシプロ
ピル等が挙げられる。Examples of the monomer having a carboxyl group and an amide group for the water-soluble polymer compound (A) include acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid, fumaric acid and acrylamide. Among them, salts of the salt-forming compounds are also included. Examples of the salt include alkali metal salts such as sodium and potassium, and alkaline earth metal salts such as magnesium and calcium. Examples of the monomer containing a sulfonic acid group and a phosphonic acid group include vinyl sulfonic acid, sulfoethyl acrylate, sulfoethyl methacrylate, N-methylsulfonic acid acrylamide, 2-acrylamide-2-methylpropanesulfonic acid, styrenesulfonic acid, and vinyl sulfonic acid. Phosphonic acid or phosphonoxyethyl methacrylate can be used. Further, these salts can be used, and examples thereof include alkali metal salts such as sodium and potassium, and alkaline earth metal salts such as magnesium and calcium. Further, examples of the monomer having a hydroxyl group include vinyl alcohol, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, and 3-hydroxypropyl (meth) acrylate.
【００１２】次にフェノール化合物（Ｂ）は、１個以上
の芳香族核構造を含む多環構造を有するもので、この多
環構造には５個以上のヒドロキシル基が直接結合してい
る。このようなフェノール化合物（Ｂ）は、前記構造式
（Ｉ）により表される多ヒドロキシ化合物から選ばれる
ことが好ましい。式（Ｉ）において、２−位に結合する
Ｘ基は、２個以上のヒドロキシル基により置換された芳
香族基、例えば、下記式（III ）、及び（IV）により示
されるものNext, the phenol compound (B) has a polycyclic structure containing one or more aromatic nucleus structures, and five or more hydroxyl groups are directly bonded to the polycyclic structure. Such a phenol compound (B) is preferably selected from the polyhydroxy compounds represented by the structural formula (I). In the formula (I), the X group bonded to the 2-position is an aromatic group substituted by two or more hydroxyl groups, for example, those represented by the following formulas (III) and (IV)
【化５】 から選ばれ、３位に結合しているＹ基は、ヒドロキシル
基、又は、式（II）により示される３個のヒドロキシル
基を有する芳香族基を表し、例えば式（IV）により表さ
れる芳香族基であることが好ましい。本発明に用いられ
るフェノール化合物（Ｂ）は、例えば、カテキン、エピ
カテキン、ガロカテキン、エピカテキンガレート、エピ
ガロカテキン、エピガロカテキンガレートなどが挙げら
れる。フェノール化合物（Ｂ）はツバキ科植物の葉が供
給源であり、例えば、茶、ツバキ、レンギョウ、キンモ
クセイ、ドクダミ、ヒサカキなどから抽出、さらに分離
して得られた、前記カテキン類の混合物であってもよ
い。これらカテキン類の化合物は、その混合比率に関係
なく、いずれも高い防臭、消臭効果を有している。Embedded image And the Y group bonded to the 3-position represents a hydroxyl group or an aromatic group having three hydroxyl groups represented by the formula (II), for example, an aromatic group represented by the formula (IV) It is preferably a group. Examples of the phenol compound (B) used in the present invention include catechin, epicatechin, gallocatechin, epicatechin gallate, epigallocatechin, epigallocatechin gallate, and the like. The source of the phenolic compound (B) is a leaf of a camellia plant, for example, a mixture of the above catechins obtained by extracting and further separating from tea, camellia, forsythia, oats, dokudami, hisakaki etc. Is also good. All of these catechin compounds have high deodorant and deodorant effects regardless of the mixing ratio.
【００１３】また、本発明の処理剤は、必要によりグリ
シジル基含有化合物（Ｃ）を含んでいてもよい。グリシ
ジル基含有有機化合物（Ｃ）としては、水溶性高分子化
合物（Ａ）に含有されるカルボキシル基又はアミド基に
対し架橋反応性を有するようなものが用いられる。例え
ば、グリシジル基２個以上を含有する化合物として、ソ
ルビトールポリグリシジルエーテル、ポリグリセロール
ポリグリシジルエーテル、ペンタエリトリトールポリグ
リシジルエーテル、トリグリシジルトリイソシアネー
ト、グリセロールポリグリシジルエーテル、トリメチロ
ールプロパンポリグリシジルエーテル、レゾルシンジグ
リシジルエーテル、ネオペンチルグリコールジグリシジ
ルエーテル、１，６−ヘキサンジオールジグリシジルエ
ーテル、（ポリ）エチレングリコールジグリシジルエー
テル、（ポリ）プロピレングリコールジグリシジルエー
テル、（ポリ）テトラメチレングリコールジグリシジル
エーテル等を用いることができる。これらのグリシジル
基含有化合物（Ｃ）は、水溶性高分子化合物（Ａ）の反
応性基と結合してこれを不溶化し、また、フェノール成
分（Ｂ）のヒドロキシル基と反応してそれを難溶化乃至
不溶化することができる。The treating agent of the present invention may contain a glycidyl group-containing compound (C) if necessary. As the glycidyl group-containing organic compound (C), a compound having crosslinking reactivity with a carboxyl group or an amide group contained in the water-soluble polymer compound (A) is used. For example, as a compound containing two or more glycidyl groups, sorbitol polyglycidyl ether, polyglycerol polyglycidyl ether, pentaerythritol polyglycidyl ether, triglycidyl triisocyanate, glycerol polyglycidyl ether, trimethylolpropane polyglycidyl ether, resorcin diglycidyl Use of ether, neopentyl glycol diglycidyl ether, 1,6-hexanediol diglycidyl ether, (poly) ethylene glycol diglycidyl ether, (poly) propylene glycol diglycidyl ether, (poly) tetramethylene glycol diglycidyl ether, etc. Can be. These glycidyl group-containing compounds (C) bind to the reactive groups of the water-soluble polymer compound (A) to insolubilize them, and react with the hydroxyl groups of the phenol component (B) to make them hardly soluble. Or insolubilized.
【００１４】本発明の親水性処理剤に含有される水溶性
高分子化合物（Ａ）とグリシジル基含有有機化合物
（Ｃ）との固形分換算重量比Ａ／Ｃは、９／１〜３／７
であることが好ましい。この重量比Ａ／Ｃが９／１を超
えると、塗布、焼付乾燥後に親水性皮膜は形成するが、
湿潤環境下において親水持続性が若干劣化することがあ
る。ただし、それは実用上は問題ないレベルである。ま
た重量比Ａ／Ｃが３／７を超えると、得られる親水性皮
膜の親水性持続性が劣化することがあり、実用上不利と
なる場合がある。The weight ratio A / C of the water-soluble polymer compound (A) and the glycidyl group-containing organic compound (C) contained in the hydrophilic treating agent of the present invention is 9/1 to 3/7.
It is preferable that When the weight ratio A / C exceeds 9/1, a hydrophilic film is formed after coating and baking and drying,
In a humid environment, the hydrophilic durability may be slightly deteriorated. However, that is a level that is not a problem in practical use. If the weight ratio A / C exceeds 3/7, the hydrophilicity of the resulting hydrophilic film may be deteriorated, which may be disadvantageous in practical use.
【００１５】親水性処理剤中の成分（Ｂ）の含有量に関
して、固形分換算重量比、Ｂ／Ａ＋Ｃが１／１０００〜
１／２０であることが好ましい。この比が、１／１００
０未満では十分な防臭、消臭効果が得られないことがあ
る。逆に、それが１／２０を超えると効果が飽和して経
済的に不利になることがある。With respect to the content of the component (B) in the hydrophilic treatment agent, the weight ratio in terms of solid content, B / A + C, is 1 / 1000-1000.
It is preferably 1/20. This ratio is 1/100
If it is less than 0, sufficient deodorizing and deodorizing effects may not be obtained. Conversely, if it exceeds 1/20, the effect may be saturated and economically disadvantageous.
【００１６】本発明の親水性処理剤をアルミニウム含有
金属材料表面に塗布、加熱乾燥すると、得られる親水性
皮膜は、アセトアルデヒド、酢酸、アンモニア、トリエ
チルアミン、メルカプタン類などの悪臭物質が存在する
雰囲気内において、その存在量を確実に減じる効果があ
る。特に、前記臭気物質は人間の生活空間において強い
不快感をもたらすものであるため、本発明の親水性処理
剤による前記効果は実用上非常に意義あることと言え
る。When the hydrophilic treating agent of the present invention is applied to the surface of an aluminum-containing metal material and dried by heating, the resulting hydrophilic film is formed in an atmosphere where malodorous substances such as acetaldehyde, acetic acid, ammonia, triethylamine and mercaptans are present. Has the effect of reliably reducing its abundance. In particular, since the odorous substance causes strong discomfort in human living space, it can be said that the effect of the hydrophilic treatment agent of the present invention is very significant in practical use.
【００１７】アルミニウム含有金属材料表面への親水性
処理剤の塗布性向上、及び乾燥して得られた皮膜の親水
持続性向上のため、本発明の親水性処理剤に、さらに界
面活性剤を適宜添加してもよい。添加可能な界面活性剤
は大別すると、アニオン性界面活性剤、両性界面活性
剤、ノニオン性界面活性剤が挙げられる。In order to improve the coatability of the hydrophilic treatment agent on the surface of the aluminum-containing metal material and to improve the hydrophilicity of the film obtained by drying, a surfactant is further added to the hydrophilic treatment agent of the present invention. It may be added. Surfactants that can be added are roughly classified into anionic surfactants, amphoteric surfactants, and nonionic surfactants.
【００１８】アニオン性界面活性剤としては、高級アル
コール硫酸エステル塩、高級アルキルエーテル硫酸エス
テル塩、ジアルキルスルホコハク酸塩、アルキルベンゼ
ンスルホン酸塩、高級アルコールリン酸エステル塩等が
挙げられる。両性界面活性剤としては、ラウリルアミノ
プロピオン酸メチル、ラウリルアミノプロピオン酸塩、
ラウリルジメチルベタイン、ステアリルジメチルベタイ
ン、ラウリルジヒドロキシエチルベタイン等が挙げられ
る。更に、ノニオン性界面活性剤としては、（ポリ）オ
キシエチレンアルキルエーテル、（ポリ）オキシエチレ
ンアルキルフェニルエーテル、（ポリ）エチレングリコ
ール、（ポリ）エチレン（ポリ）プロピレングリコール
共重合物、（ポリ）テトラメチレングリコールなどが挙
げられる。Examples of the anionic surfactant include higher alcohol sulfates, higher alkyl ether sulfates, dialkyl sulfosuccinates, alkylbenzene sulfonates, higher alcohol phosphates, and the like. Examples of the amphoteric surfactant include methyl laurylaminopropionate, laurylaminopropionate,
Lauryl dimethyl betaine, stearyl dimethyl betaine, lauryl dihydroxyethyl betaine, and the like. Further, nonionic surfactants include (poly) oxyethylene alkyl ether, (poly) oxyethylene alkylphenyl ether, (poly) ethylene glycol, (poly) ethylene (poly) propylene glycol copolymer, (poly) tetra Methylene glycol and the like can be mentioned.
【００１９】本発明の有機親水性処理剤の固形分濃度に
は特に限定はないが、一般には３〜３０％の範囲内とあ
ることが好ましい。任意の固形分濃度を有する親水性処
理剤をアルミニウム含有金属材料の表面に塗布乾燥し
て、０．１〜２．０ｇ／ｍ2 の範囲内の乾燥皮膜を得る
ことが好ましい。皮膜量が０．１ｇ／ｍ2 未満の場合、
アルミニウム含有金属材料表面を均一に被覆できず、こ
のため湿潤雰囲気下においてアルミニウム酸化物が原因
となる無機臭が感ぜられることがある。また、皮膜量が
２ｇ／ｍ2 を超えると、効果が飽和し、従って経済的に
不利になることがある。The solid concentration of the organic hydrophilic treating agent of the present invention is not particularly limited, but is generally preferably in the range of 3 to 30%. It is preferable that a hydrophilic treatment agent having an arbitrary solid content concentration is applied to the surface of the aluminum-containing metal material and dried to obtain a dry film in the range of 0.1 to 2.0 g / m 2 . When the coating amount is less than 0.1 g / m 2 ,
The surface of the aluminum-containing metal material cannot be coated uniformly, so that an inorganic odor due to aluminum oxide may be sensed in a humid atmosphere. On the other hand, when the coating amount exceeds 2 g / m 2 , the effect is saturated, and therefore, it may be economically disadvantageous.
【００２０】本発明の親水性処理剤の塗布方法には特に
限定はないが、一般にロールコート法、又は浸漬法など
が用いられる。また、加熱乾燥温度は被塗物の到達温度
が１８０〜２６０℃の範囲内にあり、乾燥時間が１０秒
〜１分の範囲内に設定することが適当である。乾燥温度
が２６０℃を超えたり、乾燥時間が１分を超えるとフェ
ノール化合物（Ｂ）が失活して防臭効果、消臭効果が期
待できなくなることがある。一方、乾燥温度が１８０℃
未満であったり、乾燥時間が１０秒未満の場合は、親水
性皮膜の硬化が不十分となり、密着不良、親水性劣化を
引き起こすことがある。The method for applying the hydrophilic treating agent of the present invention is not particularly limited, but a roll coating method or a dipping method is generally used. The heating and drying temperature is preferably set such that the temperature of the object to be coated is in the range of 180 to 260 ° C. and the drying time is in the range of 10 seconds to 1 minute. If the drying temperature exceeds 260 ° C. or the drying time exceeds 1 minute, the phenol compound (B) may be deactivated and the deodorizing effect and the deodorizing effect may not be expected. On the other hand, the drying temperature is 180 ° C
If the drying time is less than 10 seconds, or if the drying time is less than 10 seconds, the curing of the hydrophilic film becomes insufficient, which may cause poor adhesion and deterioration of hydrophilicity.
【００２１】本発明の親水性処理剤を適用するに適した
アルミニウム含有金属材料には、その親水性処理剤との
密着性、耐食性を向上させるため、アルミニウム含有金
属材料に、予めリン酸クロメート、クロミッククロメー
ト、ジルコニウム系ノンクロメート、チタニウム系ノン
クロメートなどの化成耐食下地処理、又は塗布型耐食下
地処理を施してもよい。The aluminum-containing metal material suitable for applying the hydrophilic treatment agent of the present invention includes phosphoric acid chromate, A chemical corrosion-resistant base treatment such as chromic chromate, zirconium-based non-chromate, or titanium-based non-chromate, or a coating-type corrosion-resistant base treatment may be performed.
【００２２】本発明の親水性処理剤はそれを加熱乾燥す
ることにより、水溶性高分子化合物（Ａ）が乾燥固化し
て、固形皮膜を形成し、或は、水溶性高分子化合物
（Ａ）に含有されるカルボキシル基またはアミド基に対
して、グリシジル基含有有機化合物（Ｃ）が開環付加重
合して架橋反応が生起する。この反応により、親水性処
理剤層中に三次元的なネットワーク構造が形成され不溶
化皮膜が形成される。前記反応と同時に、或は皮膜形成
以後に継続される加熱（オーバーベーク）、又は高温加
熱乾燥により、皮膜の熱分解反応及び熱酸化分解反応が
進行することがある。しかし、フェノール化合物（Ｂ）
を含有しているため、これらの熱分解及び熱酸化分解が
軽減され、また臭気発生の一因となる低分子物質発生を
抑制することができる。また同様の作用により、本発明
により親水性処理されたアルミニウム含有金属材料を連
続プレス加工する場合、金型と材料の表面との間に発生
する摩擦熱による皮膜分解劣化が抑制されるため、臭気
の発生が防止される。When the hydrophilic treating agent of the present invention is dried by heating, the water-soluble polymer compound (A) is dried and solidified to form a solid film, or the water-soluble polymer compound (A) The glycidyl group-containing organic compound (C) undergoes ring-opening addition polymerization with respect to the carboxyl group or amide group contained in the compound (A) to cause a crosslinking reaction. By this reaction, a three-dimensional network structure is formed in the hydrophilic treatment agent layer, and an insolubilized film is formed. The thermal decomposition reaction and the thermal oxidative decomposition reaction of the film may proceed simultaneously with the above-mentioned reaction or by heating (overbaking) or high-temperature heat drying continued after the film formation. However, the phenol compound (B)
, The thermal decomposition and the thermal oxidative decomposition thereof are reduced, and the generation of low molecular substances that contribute to the generation of odor can be suppressed. Further, by the same action, when the aluminum-containing metal material subjected to the hydrophilic treatment according to the present invention is continuously pressed, the decomposition of the film due to frictional heat generated between the mold and the surface of the material is suppressed. Is prevented from occurring.
【００２３】このように、熱分解反応及び熱酸化分解反
応に起因する臭気発生を抑制する効果は、成分（Ｂ）の
骨格中に含有されているフェノール性ヒドロキシル基が
抗酸化性を有していることによるものである。つまり、
不溶化皮膜形成後の熱酸化分解及び熱分解は、高分子末
端基が加速的に切断するラジカル反応に起因している
が、フェノール化合物（Ｂ）は酸化防止剤として機能的
に、このラジカル反応を防止するのである。このような
不溶化皮膜の熱分解抑制により、不溶化皮膜が本来発揮
し得る親水性皮膜性能及び親水持続性能を最大限に引き
出すことができるのである。As described above, the effect of suppressing the generation of odor due to the thermal decomposition reaction and the thermal oxidative decomposition reaction is that the phenolic hydroxyl group contained in the skeleton of the component (B) has an antioxidant property. It is due to being. That is,
The thermal oxidative decomposition and the thermal decomposition after the formation of the insolubilized film are caused by a radical reaction in which a polymer terminal group is rapidly cut off, but the phenol compound (B) functions as an antioxidant and acts on this radical reaction. Prevent it. By suppressing such thermal decomposition of the insolubilized film, it is possible to maximize the hydrophilic film performance and the hydrophilic sustainability that the insolubilized film originally exhibits.
【００２４】さらに、不溶性皮膜内に安定して留まって
いる成分（Ｂ）の特徴についてさらに述べると、長期使
用で臭気発生がないことは当然のことながら、雰囲気中
に存在する臭気物質を化学的反応によりトラップするこ
とにより消臭効果が発揮、継続されるのである。Further, the feature of the component (B) stably staying in the insoluble film will be further described. Naturally, no odor is generated during long-term use. The deodorizing effect is exhibited and maintained by trapping through the reaction.
【００２５】[0025]
【実施例】本発明を下記実施例によりさらに説明する。The present invention will be further described with reference to the following examples.
【００２６】実施例１〜９及び比較例１ 実施例１〜９及び比較例１の各々において、予め洗浄さ
れたアルミニウム板（ＪＩＳ１０５０材、厚さ０．１mm
×幅２０mm×長さ３０mm）に、クロム付着量が２０mg／
ｍ2 になるようにりん酸クロメート処理を施した。表１
に示す組成を有する本発明の親水性処理剤の固形分濃度
１０％に調整し、この塗布液ロールコーターにより前記
アルミニウム板のクロメート処理された両面上に塗布し
た。塗布後、到達板温が２２０℃になるように加熱乾燥
し、乾燥皮膜量が１ｇ／ｍ2 の親水性皮膜を形成した。 Examples 1 to 9 and Comparative Example 1 In each of Examples 1 to 9 and Comparative Example 1, an aluminum plate (JIS1050 material, 0.1 mm thick) which had been washed beforehand was used.
× width 20 mm × length 30 mm) and the amount of chromium deposited is 20 mg /
Phosphoric acid chromate treatment was performed so as to obtain m 2 . Table 1
The hydrophilic treatment agent of the present invention having the composition shown in the following was adjusted to a solid content concentration of 10%, and was applied on both surfaces of the aluminum plate subjected to chromate treatment by this coating liquid roll coater. After the application, the coating was heated and dried so that the ultimate plate temperature became 220 ° C., to form a hydrophilic coating having a dry coating amount of 1 g / m 2 .
【００２７】得られた親水性皮膜の性能を下記試験及び
評価基準により評価した。 ＜性能評価試験方法＞（１）親水性 親水性処理された材料の皮膜表面上に５μｌ（マイクロ
リットル）の脱イオン水を滴下し、形成された水滴の接
触角を接触角計（ＦＡＣＥ ＢＡ−Ｐ型 協和界面科学
製）を用いて測定した。親水性処理直後の皮膜の初期接
触角、脱イオン水に１００時間浸漬した後の皮膜の経時
接触角を算出した。評価基準 ◎：接触角１０°未満 ○：接触角１０°以上２０°未満 △：接触角２０°以上３０°未満 ×：接触角３０°以上The performance of the obtained hydrophilic film was evaluated by the following tests and evaluation criteria. <Performance Evaluation Test Method> (1) Hydrophilicity 5 μl (microliter) of deionized water was dropped on the surface of the film of the hydrophilically treated material, and the contact angle of the formed water droplet was measured using a contact angle meter (FACE BA- P type (manufactured by Kyowa Interface Science). The initial contact angle of the film immediately after the hydrophilic treatment and the temporal contact angle of the film after immersion in deionized water for 100 hours were calculated. Evaluation criteria ◎: contact angle of less than 10 ° ○: contact angle of 10 ° or more and less than 20 ° △: contact angle of 20 ° or more and less than 30 ° ×: contact angle of 30 ° or more
【００２８】（２）臭気性 親水性処理皮膜を有する材料について、５人のパネラー
による官能試験を実施し、有機親水性処理直後の初期臭
気性、さらに脱イオン水に１００時間浸漬した後の経時
臭気性を評価した。また、電気炉を用いて３００℃×１
分加熱し、室温冷却した直後の加熱臭気性を評価した。
官能試験に際して、パネラーは親水性処理皮膜材に呼気
を吹きかけて臭気を臭いだ。評価基準 ◎：全く臭気を感じない ○：ほのかに臭気を感じるが、不快感がなく、臭気種類
の判断がつかない △：明らかに臭気を感じ、臭気種類の判断がつく ×：強烈な臭気を感じる、嫌悪感あり(2) Odor A sensory test was conducted by a panel of five persons on the material having a hydrophilic treatment film, the initial odor immediately after the organic hydrophilic treatment, and the time after immersion in deionized water for 100 hours. The odor was evaluated. 300 ° C. × 1 using an electric furnace
The heated odor was evaluated immediately after cooling to room temperature.
At the time of the sensory test, the panelists breathed on the hydrophilic coating material to smell the odor. Evaluation criteria ◎: No odor at all ○: Slight odor, but no discomfort, no judgment of odor type △: Clear odor, odor type judged ×: Strong odor Feel, dislike
【００２９】（３）消臭性 親水性処理皮膜を有する材料を１００×１００mmの寸法
に切り出し、内容積が５リットルの石英ガラス容器内に
置き密閉した。次に、前記容器内に悪臭物質ガスを注入
して、所定一定濃度に調整し、初期及び３０分後のガス
濃度を測定し経時変化を追跡した。ガス濃度はガス検知
管を用いて測定した。悪臭物質の初期濃度は、アンモニ
ア１００ppm 、トリメチルアミン５０ppm 、メチルメル
カプタン１０ppm とした。各悪臭物質の濃度について、
次に示す式に従って消臭率を算出した。 消臭率（％）＝（３０分後の濃度（ppm ））／（初期濃
度（ppm ））×１００ 評価基準 ◎：消臭率≧９０％ ○：６０％≦消臭率＜９０％ △：３０％≦消臭率＜６０％ ×：消臭率＜３０％(3) Deodorizing property A material having a hydrophilic treatment film is measured in a size of 100 × 100 mm.
Into a 5 liter quartz glass container
Placed and sealed. Next, an odorous substance gas is injected into the container.
Then, adjust the concentration to a predetermined constant, and the gas at the beginning and after 30 minutes
The concentration was measured and the change over time was followed. Gas concentration is gas detection
It was measured using a tube. The initial concentration of odorous substances is
A 100 ppm, trimethylamine 50 ppm, methylmer
Captan was 10 ppm. About the concentration of each stench substance,
The deodorization rate was calculated according to the following equation. Deodorization rate (%) = (concentration (ppm) after 30 minutes) / (initial concentration
Degree (ppm)) x 100 Evaluation criteria ：: Deodorization rate ≧ 90% ○: 60% ≦ Deodorization rate <90% Δ: 30% ≦ Deodorization rate <60% X: Deodorization rate <30%
【００３０】[0030]
【表１】 [Table 1]
【００３１】表２に実施例１〜９及び比較例１の各々に
用いられた親水性処理剤（１）〜（１０）とその処理条
件を示す。なお、実施例１〜９においては、親水性処理
剤（１）〜（９）を使用した。比較例１においては、本
発明外の組成を有する親水性処理剤（１０）を使用し
た。また表３に、実施例１〜９及び比較例１の各々の親
水性処理された材料の性能評価結果を示す。Table 2 shows the hydrophilic treating agents (1) to (10) used in Examples 1 to 9 and Comparative Example 1 and the treating conditions. In Examples 1 to 9, hydrophilic treatment agents (1) to (9) were used. In Comparative Example 1, a hydrophilic treating agent (10) having a composition outside the present invention was used. Table 3 shows the performance evaluation results of the hydrophilically-treated materials of Examples 1 to 9 and Comparative Example 1.
【００３２】[0032]
【表２】 [Table 2]
【００３３】[0033]
【表３】 [Table 3]
【００３４】表３から明らかなように、本発明の有機親
水性処理剤を用いた実施例１〜９の処理材料は、親水性
が良好であり、初期臭気及び加熱後の臭気がなく、更に
悪臭物質濃度を減じる消臭効果が認められた。しかし、
比較例１においては、フェノール化合物（Ｂ）を含有し
ないため、臭気防止性が劣化し、更に脱臭効果が全く認
められなかった。As is clear from Table 3, the treatment materials of Examples 1 to 9 using the organic hydrophilic treatment agent of the present invention have good hydrophilicity, no initial odor and no odor after heating. A deodorizing effect of reducing the concentration of offensive odor substances was observed. But,
In Comparative Example 1, since the phenol compound (B) was not contained, the odor preventing property was deteriorated, and no deodorizing effect was observed.
【００３５】[0035]
【発明の効果】本発明の親水性処理剤を用いてアルミニ
ウム含有金属材料表面に形成された親水性皮膜は、経時
後も優れた親水性を有している。さらに、初期臭がない
ことは当然ながら、通常有機物が分解するような加熱を
施した後でも、臭気発生は防止される。更に、各種悪臭
物質が存在する雰囲気下において、その量を確実に減少
させる高い消臭効果を有する。従って本発明の親水性処
理剤は実用的価値が極めて高く、エアコン部品の熱交換
器用アルミニウム材料への適応性が高く、その他の広い
用途に適用することができる。The hydrophilic film formed on the surface of the aluminum-containing metal material using the hydrophilic treating agent of the present invention has excellent hydrophilicity even after aging. Further, naturally, no odor is generated, even after heating such that organic matter is decomposed, which naturally has no initial odor. Further, it has a high deodorizing effect to surely reduce the amount in an atmosphere where various malodorous substances are present. Therefore, the hydrophilic treating agent of the present invention has a very high practical value, is highly adaptable to aluminum materials for heat exchangers of air conditioners, and can be applied to other wide applications.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０９Ｄ 201/02 Ｃ０９Ｄ 201/02 Ｃ２３Ｃ 22/56 Ｃ２３Ｃ 22/56 (72)発明者 森田 良治 東京都中央区日本橋１−15−１ 日本パー カライジング株式会社内 Ｆターム(参考） 4D075 BB24Z CA37 DA23 DB07 DC11 DC16 DC18 EA06 4H020 AA04 AA05 AB02 4J038 CC091 CE021 CG021 CG141 CG171 CH121 CH261 CL001 CR071 DB022 GA03 GA06 GA09 GA13 GA14 HA066 JA73 KA02 KA03 MA08 MA09 NA06 NA27 PA19 PB06 PC02 4K026 AA09 AA22 BA01 BA07 BA12 BB02 BB10 CA16 CA37 CA39 DA02 DA11 EA06 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C09D 201/02 C09D 201/02 C23C 22/56 C23C 22/56 (72) Inventor Ryoji Morita Chuo-ku, Tokyo 1-15-1 Nihonbashi F-term in Nippon Parkerizing Co., Ltd. (Reference) 4D075 BB24Z CA37 DA23 DB07 DC11 DC16 DC18 EA06 4H020 AA04 AA05 AB02 4J038 CC091 CE021 CG021 CG141 CG171 CH121 CH261 CL001 CR071 DB022 GA03 GA06 GA09 GA13 GA02 GA73 KA03 MA08 MA09 NA06 NA27 PA19 PB06 PC02 4K026 AA09 AA22 BA01 BA07 BA12 BB02 BB10 CA16 CA37 CA39 DA02 DA11 EA06
Claims (6)
ル基、スルホン基、ホスホン基から選ばれた少なくとも
１種が主鎖に結合している水溶性高分子化合物（Ａ）、
及び１個以上の芳香族核構造を含む多環式構造に合計５
個以上のヒドロキシル基が直接結合しているフェノール
化合物（Ｂ）を含有することを特徴とするアルミニウム
含有金属材料用有機親水性処理剤。1. A water-soluble polymer compound (A) in which at least one selected from a carboxyl group, an amide group, a hydroxyl group, a sulfone group and a phosphone group is bonded to a main chain.
And a polycyclic structure containing one or more aromatic nuclei
An organic hydrophilic treating agent for an aluminum-containing metal material, comprising a phenol compound (B) having at least two hydroxyl groups directly bonded thereto.
（Ｃ）を含有する、請求項１に記載のアルミニウム含有
金属材料用有機親水性処理剤。2. The organic hydrophilic treatment agent for an aluminum-containing metal material according to claim 1, further comprising a glycidyl group-containing organic compound (C).
造式（Ｉ）により表される多ヒドロキシ化合物： 【化１】 〔但し、式（Ｉ）中、Ｘは２個以上のヒドロキシル基に
より置換された芳香族基を表し、Ｙはヒドロキシル基又
は下記式（II）： 【化２】 により表される芳香族基を表す〕から選ばれる、請求項
１に記載のアルミニウム含有金属材料用有機親水性処理
剤。3. The polyhydroxy compound wherein the phenol compound (B) is represented by the following structural formula (I): [Wherein, in the formula (I), X represents an aromatic group substituted by two or more hydroxyl groups, and Y represents a hydroxyl group or the following formula (II): The organic hydrophilic treating agent for an aluminum-containing metal material according to claim 1, which represents an aromatic group represented by
が（＋）−カテキン、（−）−エピカテキン、（＋）−
ガロカテキン、（−）−エピカテキンガレート、（−）
−エピカロカテキンガレート、及び（−）−エピガロカ
テキンから選ばれる、請求項３に記載のアルミニウム含
有金属材料用有機親水性処理剤。4. The polyhydroxy compound of the general formula (I) is (+)-catechin, (−)-epicatechin, (+)-
Gallocatechin, (-)-epicatechin gallate, (-)
The organic hydrophilic treating agent for an aluminum-containing metal material according to claim 3, which is selected from -epicalocatechin gallate and (-)-epigallocatechin.
形分換算含有重量Ａ，Ｂ及びＣが、下記関係式（１）及
び（２）を満たす、 Ａ／Ｃ＝９／１〜３／７ （１） Ｂ／（Ａ＋Ｃ）＝１／１０００〜１／２０ （２） 請求項２に記載のアルミニウム含有金属材料用有機親水
性処理剤。5. The solid content equivalent weights A, B and C of the components (A), (B) and (C) satisfy the following relational expressions (1) and (2): A / C = 9 / 1 to 3/7 (1) B / (A + C) = 1/1000 to 1/20 (2) The organic hydrophilic treating agent for an aluminum-containing metal material according to claim 2.
ルミニウム含有金属材料用有機親水性処理剤を、アルミ
ニウム含有金属材料の少なくとも１表面に塗布し、これ
を加熱乾燥して有機親水性皮膜層を形成することを特徴
とするアルミニウム含有金属材料の表面親水性処理方
法。6. The organic hydrophilic treating agent for an aluminum-containing metal material according to claim 1 is applied to at least one surface of the aluminum-containing metal material, and is dried by heating. A method for treating a surface hydrophilicity of an aluminum-containing metal material, comprising forming a hydrophilic coating layer.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000280152A JP3838856B2 (en) | 2000-09-11 | 2000-09-11 | Organic hydrophilic treatment agent for aluminum-containing metal material and treatment method thereof |
| TW090119429A TW592839B (en) | 2000-09-11 | 2001-08-16 | Organic hydrophilic agent for aluminiferous metals and method of treatment using the same |
| KR1020010051375A KR20020020837A (en) | 2000-09-11 | 2001-08-24 | Hydrophilic treatment chemical for metal materials containing aluminum and process therefor |
| CN01131245A CN1344766A (en) | 2000-09-11 | 2001-09-04 | Organic hydrophilicity processing agent for material containing aluminium metal and processing method thereof |
| AU2001288867A AU2001288867A1 (en) | 2000-09-11 | 2001-09-06 | Organic hydrophilicizing agent for aluminiferous metals |
| US10/380,121 US20040014848A1 (en) | 2000-09-11 | 2001-09-06 | Organic Hydrophicizing agent for aluminiferous metals |
| PCT/US2001/028020 WO2002022279A1 (en) | 2000-09-11 | 2001-09-06 | Organic hydrophilicizing agent for aluminiferous metals |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000280152A JP3838856B2 (en) | 2000-09-11 | 2000-09-11 | Organic hydrophilic treatment agent for aluminum-containing metal material and treatment method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002088348A true JP2002088348A (en) | 2002-03-27 |
| JP3838856B2 JP3838856B2 (en) | 2006-10-25 |
Family
ID=18765047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000280152A Expired - Fee Related JP3838856B2 (en) | 2000-09-11 | 2000-09-11 | Organic hydrophilic treatment agent for aluminum-containing metal material and treatment method thereof |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP3838856B2 (en) |
| KR (1) | KR20020020837A (en) |
| CN (1) | CN1344766A (en) |
| AU (1) | AU2001288867A1 (en) |
| TW (1) | TW592839B (en) |
| WO (1) | WO2002022279A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004263095A (en) * | 2003-03-03 | 2004-09-24 | Nippon Shokubai Co Ltd | Composition for forming sheet-shaped product, sheet-shaped product and coated article |
| JP2007039776A (en) * | 2005-08-05 | 2007-02-15 | Taiyo Kagaku Co Ltd | Coated metal treated with catechin and catechin derivative |
| JP2007268860A (en) * | 2006-03-31 | 2007-10-18 | Furukawa Sky Kk | Aluminum-coated material and aluminum fin material for heat exchanger using it |
| KR20160071548A (en) | 2014-12-11 | 2016-06-22 | 주식회사 케미존 | One-solution type hydrophilic corrosion resistant coating agent for heat exchanger of air conditioner and preparing method thereof |
| JP2019073610A (en) * | 2017-10-16 | 2019-05-16 | 廣 閤田 | Deodorant paint |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107304320B (en) * | 2016-04-22 | 2021-08-13 | 马日专业涂层私人有限公司 | Organic hydrophilic coating composition, hydrophilic coating film, and aluminum material for heat exchanger |
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| JPH0545083A (en) * | 1991-08-12 | 1993-02-23 | Furukawa Alum Co Ltd | Self-deodorizing heat exchanger al fin materials |
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| JP2000279498A (en) * | 1999-03-29 | 2000-10-10 | Nippon Paint Co Ltd | Odor suppression treating agent and treatment using the same |
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| US4631084A (en) * | 1983-01-17 | 1986-12-23 | Minnesota Mining And Manufacturing Company | Heat-sensitive composition and imaging sheet incorporating same |
| CA2059742A1 (en) * | 1991-01-22 | 1992-07-23 | Mikio Watanabe | Coating solution for preventing adhesion of polymer scale and method for preventing scale adhesion during preparation of polymers |
| US6146497A (en) * | 1998-01-16 | 2000-11-14 | Hercules Incorporated | Adhesives and resins, and processes for their production |
| US6231875B1 (en) * | 1998-03-31 | 2001-05-15 | Johnson & Johnson Consumer Companies, Inc. | Acidified composition for topical treatment of nail and skin conditions |
-
2000
- 2000-09-11 JP JP2000280152A patent/JP3838856B2/en not_active Expired - Fee Related
-
2001
- 2001-08-16 TW TW090119429A patent/TW592839B/en active
- 2001-08-24 KR KR1020010051375A patent/KR20020020837A/en not_active Application Discontinuation
- 2001-09-04 CN CN01131245A patent/CN1344766A/en active Pending
- 2001-09-06 AU AU2001288867A patent/AU2001288867A1/en not_active Abandoned
- 2001-09-06 WO PCT/US2001/028020 patent/WO2002022279A1/en active Application Filing
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0545083A (en) * | 1991-08-12 | 1993-02-23 | Furukawa Alum Co Ltd | Self-deodorizing heat exchanger al fin materials |
| JPH05140482A (en) * | 1991-11-14 | 1993-06-08 | Nippon Paint Co Ltd | Antibacterial coating composition |
| JPH08232078A (en) * | 1994-12-07 | 1996-09-10 | Nippon Parkerizing Co Ltd | Hydrophilic aqueous processing agent of aluminum-containing metallic material and hydrophilic treatment |
| JPH09272819A (en) * | 1996-04-02 | 1997-10-21 | Nippon Parkerizing Co Ltd | Composition for hydrophilic treatment of fin material for heat exchanger |
| JPH11323597A (en) * | 1998-05-08 | 1999-11-26 | Matsushita Seiko Co Ltd | Aluminum anodized film subjected to antiviral, antibacterial and antimold treatment |
| JP2000279498A (en) * | 1999-03-29 | 2000-10-10 | Nippon Paint Co Ltd | Odor suppression treating agent and treatment using the same |
| JP2001311048A (en) * | 2000-02-22 | 2001-11-09 | Erubu:Kk | Functional coating composition and cover |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004263095A (en) * | 2003-03-03 | 2004-09-24 | Nippon Shokubai Co Ltd | Composition for forming sheet-shaped product, sheet-shaped product and coated article |
| JP2007039776A (en) * | 2005-08-05 | 2007-02-15 | Taiyo Kagaku Co Ltd | Coated metal treated with catechin and catechin derivative |
| JP2007268860A (en) * | 2006-03-31 | 2007-10-18 | Furukawa Sky Kk | Aluminum-coated material and aluminum fin material for heat exchanger using it |
| KR20160071548A (en) | 2014-12-11 | 2016-06-22 | 주식회사 케미존 | One-solution type hydrophilic corrosion resistant coating agent for heat exchanger of air conditioner and preparing method thereof |
| JP2019073610A (en) * | 2017-10-16 | 2019-05-16 | 廣 閤田 | Deodorant paint |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2001288867A1 (en) | 2002-03-26 |
| KR20020020837A (en) | 2002-03-16 |
| JP3838856B2 (en) | 2006-10-25 |
| TW592839B (en) | 2004-06-21 |
| CN1344766A (en) | 2002-04-17 |
| WO2002022279A1 (en) | 2002-03-21 |
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