JP2001113888A - Transfer sheet for molding and transferring method using the same - Google Patents

Transfer sheet for molding and transferring method using the same

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Publication number
JP2001113888A
JP2001113888A JP29364299A JP29364299A JP2001113888A JP 2001113888 A JP2001113888 A JP 2001113888A JP 29364299 A JP29364299 A JP 29364299A JP 29364299 A JP29364299 A JP 29364299A JP 2001113888 A JP2001113888 A JP 2001113888A
Authority
JP
Japan
Prior art keywords
layer
transfer
sheet
resin
molding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29364299A
Other languages
Japanese (ja)
Inventor
Hirohisa Yoshikawa
浩久 吉川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dai Nippon Printing Co Ltd
Original Assignee
Dai Nippon Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai Nippon Printing Co Ltd filed Critical Dai Nippon Printing Co Ltd
Priority to JP29364299A priority Critical patent/JP2001113888A/en
Publication of JP2001113888A publication Critical patent/JP2001113888A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To make the moldability compatible with the releasability of a transfer sheet for molding. SOLUTION: In this transfer sheet S for molding comprising a transfer layer 20 provided on a support sheet 10, the support sheet 10 has at least a layer A made of an ethylene-propylene random copolymer and a layer B made of a resin composition obtained by mixing a crystalline polypropylene resin with a propylene copolymer resin having no steric regularity in such a manner that the transfer layer is laminated on the layer B. For example, in two-layer constitution, a front layer 11 is the layer B, a rear layer 12 is the layer A, or in three-layer constitution, the layer 11 and the layer 12 are layers B, and an intermediate layer 13 is the layer A. The transferring method comprises the step of transferring the transfer sheet for molding by using a solid particle collision pressure or an elastic roller as a transfer pressure.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【０００１】[0001]

【発明の属する技術分野】本発明は、住宅の外装材或い
は内装材、家具、家電製品、車両等の用途に用いる、三
次元成形用の転写シートに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a transfer sheet for three-dimensional molding used for exterior or interior materials of houses, furniture, home appliances, vehicles and the like.

【０００２】[0002]

【従来の技術】従来、被転写面が平面の化粧部材等を転
写で製造するには、転写シートの支持体シートには、ポ
リエチレンテレフタレートフィルムが一般的であった。
しかし、例えば樹脂の成形品や木質基材等で、被転写面
が三次元曲面等と凹凸表面である場合には、ポリエチレ
ンテレフタレートフィルムでは成形性が十分に得られ
ず、成形性を有する樹脂フィルムがよく使用されてき
た。例えば、次の様な転写シートがあった。2. Description of the Related Art Conventionally, a polyethylene terephthalate film has been generally used as a support sheet of a transfer sheet for producing a decorative member having a flat surface to be transferred by transfer.
However, for example, when the transferred surface is a three-dimensional curved surface or the like with a concave-convex surface such as a resin molded article or a wooden base material, the polyethylene terephthalate film does not provide sufficient moldability, and the resin film having moldability is not obtained. Has been used frequently. For example, there has been the following transfer sheet.

【０００３】（１）特公平６−６９７５９号公報、
特公平７−２９５１８号公報、特公平７−１００３９
８号公報等に開示されている様な、支持体シートに塩化
ビニル樹脂フィルムを使用した転写シート。 （２）特開平７−１１０５５０号公報に開示されている
様な、塩化ビニル樹脂以外の樹脂として、ポリスチレ
ン、アクリロニトリル系樹脂、ＡＢＳ樹脂等の樹脂フィ
ルムを支持体シートに用いた転写シート。 （３）特開平５−２７０１９９号公報に開示されている
様な、ポリエチレン、ポリプロピレン等のポリオレフィ
ン系樹脂の樹脂フィルムを支持体シートとした転写シー
ト。 （４）特開平１０−３５０８６号公報に開示されている
様な、支持体シートのポリオレフィン系樹脂を熱可塑性
エラストマーとした転写シート。(1) Japanese Patent Publication No. 6-69759,
Japanese Patent Publication No. 7-29518, Japanese Patent Publication No. 7-10039
No. 8, a transfer sheet using a vinyl chloride resin film as a support sheet. (2) A transfer sheet using a resin film such as polystyrene, acrylonitrile-based resin, or ABS resin as a resin other than vinyl chloride resin as a support sheet, as disclosed in JP-A-7-110550. (3) A transfer sheet using a resin film of a polyolefin resin such as polyethylene or polypropylene as a support sheet as disclosed in JP-A-5-270199. (4) A transfer sheet in which the polyolefin resin of the support sheet is a thermoplastic elastomer as disclosed in JP-A-10-35086.

【０００４】（５）特開平１０−２１７６９２号公報に
開示されいる様な、支持体シートのポリオレフィン系樹
脂層を、２層乃至は３層とした転写シート。そして、転
写層と接する層を成形性は劣るが剥離性に優れる高結晶
性のポリプロピレン又は結晶質ポリエチレン層とし、転
写層に接し無い層を剥離性は劣るが成形性に優れる非晶
質プロピレン共重合体層として、成形性と剥離性の両立
を試みた転写シート。(5) A transfer sheet having two or three polyolefin resin layers of a support sheet, as disclosed in JP-A-10-217692. The layer that is in contact with the transfer layer is a highly crystalline polypropylene or crystalline polyethylene layer that is inferior in moldability but excellent in releasability, and the layer that is not in contact with the transfer layer is amorphous propylene inferior in peelability but excellent in moldability. A transfer sheet that attempts to achieve both moldability and releasability as a polymer layer.

【０００５】[0005]

【発明が解決しようとする課題】ところが、上記（１）
の支持体シートに塩化ビニル樹脂を使用した転写シート
では、次の様な問題点があった。すなわち、の転写シ
ートでは、転写層となる絵柄層を直接支持体シートに印
刷している為、印刷時にインキの溶剤が支持体シートを
アッタクして、剥離強度が不安定となる。の転写シー
トでは、支持体シートの塩化ビニル樹脂フィルムから可
塑剤がブリードアウトして、剥離強度が不安定となる。
の転写シートでは、支持体シートに接する剥離層に使
用される樹脂が、ポリビニルブチラール、セルロースア
セテートプロピオネートに限定される。However, the above (1)
The transfer sheet using a vinyl chloride resin as the support sheet has the following problems. That is, in the transfer sheet, since the picture layer serving as the transfer layer is directly printed on the support sheet, the solvent of the ink attacks the support sheet during printing, and the peel strength becomes unstable. In the transfer sheet, the plasticizer bleeds out of the vinyl chloride resin film of the support sheet, and the peel strength becomes unstable.
In the transfer sheet, the resin used for the release layer in contact with the support sheet is limited to polyvinyl butyral and cellulose acetate propionate.

【０００６】また、上記（２）の様に、支持体シートに
塩化ビニル樹脂以外を使用した転写シートでは、ウレタ
ン樹脂によるアンカー層を設けた支持体シートとする必
要があり、このアンカー層の為、適性成形温度範囲が狭
くなる。また、上記（３）の様に、支持体シートにポリ
オレフィン系樹脂を使用した転写シートでは、使用する
ポリオレフィン系樹脂の結晶性が高く、成形時の加熱で
昇温とともに、融点近傍で樹脂の流動性の増大が急峻の
為、凹凸面ヘの転写の場合、凹凸面に十分に成形出来る
温度範囲が狭い。また、成形時に局部的な伸びの集中
（ネッキング）により、絵柄の歪み、転写シートの破断
を生じ易い。また、上記（４）の様に、支持体シートの
ポリオレフィン系樹脂を熱可塑性エラストマーとした転
写シートでは、確かにエラストマー化で成形性は改良さ
れる。しかし、その反面、剥離強度が増して、転写層の
剥離性が悪くなる。Further, as described in (2) above, in a transfer sheet using a support sheet other than a vinyl chloride resin, it is necessary to use a support sheet provided with an anchor layer made of a urethane resin. And the suitable molding temperature range is narrowed. Further, as described in (3) above, in a transfer sheet using a polyolefin-based resin as the support sheet, the polyolefin-based resin used has high crystallinity. In the case of transfer to an uneven surface, the temperature range in which molding can be performed sufficiently on the uneven surface is narrow because of the sharp increase in the property. In addition, the pattern is easily distorted and the transfer sheet is easily broken due to local concentration (necking) of elongation during molding. Further, as in the above (4), in the transfer sheet in which the polyolefin-based resin of the support sheet is a thermoplastic elastomer, the moldability is surely improved by the use of the elastomer. However, on the other hand, the peel strength increases, and the peelability of the transfer layer deteriorates.

【０００７】また、上記（５）の様に、支持体シートの
ポリオレフィン系樹脂層を複層構成として、成形性と剥
離性の両立を試みた転写シートでは、予想に反して、非
晶質プロピレン共重合体層の成形性を以てしても、結晶
質ポリプロピレン乃至は結晶質ポリエチレン層の成形性
不足を補うことは完全には無理であった。特に大きな凹
凸段差、三次元的凹凸形状の場合に適用すると、成形性
の不足が目立って来る。Further, as described in the above (5), in a transfer sheet in which the polyolefin resin layer of the support sheet is formed into a multilayer structure to achieve both moldability and releasability, contrary to expectation, amorphous propylene Even with the moldability of the copolymer layer, it was completely impossible to compensate for the lack of moldability of the crystalline polypropylene or crystalline polyethylene layer. In particular, when applied to the case of a large uneven step and a three-dimensional uneven shape, the lack of moldability becomes conspicuous.

【０００８】そこで、本発明の課題は、支持体シートに
ポリオレフィン系樹脂を用いた成形用転写シートにおい
て、成形性を確保した上で、成形性と剥離性等を両立さ
せる事である。It is an object of the present invention to provide a transfer sheet for molding using a polyolefin-based resin as a support sheet while ensuring both moldability and releasability while ensuring moldability.

【０００９】[0009]

【課題を解決するための手段】そこで、上記課題を解決
すべく、本発明の成形用転写シートでは、支持体シート
に転写層を設けた成形用の転写シートにおいて、支持体
シートが、少なくとも、エチレン−プロピレンランダム
共重合体からなるＡ層と、結晶性ポリプロピレン樹脂
と、立体規則性の無いプロピレン共重合体樹脂を混合し
樹脂組成物からなるＢ層とからなり、該Ｂ層上に転写層
が積層されてなる構成とした。Therefore, in order to solve the above problems, in the transfer sheet for molding according to the present invention, at least a transfer sheet for molding in which a transfer layer is provided on a support sheet, wherein the support sheet has at least: A layer composed of an ethylene-propylene random copolymer, a crystalline polypropylene resin, and a B layer composed of a resin composition obtained by mixing a propylene copolymer resin having no stereoregularity, and a transfer layer on the B layer Are laminated.

【００１０】また、本発明の成形用転写シートは、上記
構成に対して、立体規則性の無いプロピレン共重合体樹
脂が、プロピレン−エチレン共重合体、プロピレン−
（１−ブテン）共重合体、プロピレン−（１−ブテン）
−エチレン三元共重合体、プロピレン−（１−ヘキセ
ン）−（１−オクテン）三元共重合体、プロピレン−
（１−ヘキセン）−（４−メチル−１−ペンテン）三元
共重合体のうちの１種又は２種以上の混合樹脂である構
成とした。Further, in the transfer sheet for molding of the present invention, the propylene copolymer resin having no stereoregularity is a propylene-ethylene copolymer, a propylene-
(1-butene) copolymer, propylene- (1-butene)
-Ethylene terpolymer, propylene- (1-hexene)-(1-octene) terpolymer, propylene-
It was configured to be one or a mixed resin of two or more of (1-hexene)-(4-methyl-1-pentene) terpolymers.

【００１１】また、本発明の成形用転写シートは、上記
いずれかの構成に対して、その支持体シートを、Ｂ層を
外側の表層及び裏層にしＡ層を内部の中間層にした、Ｂ
層／Ａ層／Ｂ層からなる３層構成とした。Further, the transfer sheet for molding of the present invention has a structure in which, in any one of the above-mentioned constitutions, the support sheet is such that B layer is an outer surface layer and an outer layer, and A layer is an inner intermediate layer.
It had a three-layer structure of layer / layer A / layer B.

【００１２】以上の様に、本発明の成形用転写シート
は、成形性と剥離性を両立させる為に、転写層に接する
側のＢ層に、結晶性のポリプロピレンに、立体規則性が
無いポリプロピレン共重合体を混合し、結晶性を有る程
度低下させて、その混合割合の調整によって最適剥離強
度を得て剥離性を確保し、且つ成形性も不十分ながらも
或る程度は付与しておく。そして、成形性が完全ではな
い分（不足分）のみ、転写層と接しない側のＡ層に、
（剥離性は不十分だが成形性が良好な）エチレン−プロ
ピレンランダム共重合体を用いることで、成形性を補う
ことができる様になる。As described above, the transfer sheet for molding of the present invention is characterized in that, in order to achieve both moldability and releasability, the B layer on the side in contact with the transfer layer is made of crystalline polypropylene or non-stereoregular polypropylene. By mixing the copolymer and lowering the crystallinity to a certain degree, adjusting the mixing ratio to obtain the optimum peel strength to secure the releasability, and to impart a certain degree of moldability even though insufficient. . Then, only the part where the moldability is not perfect (insufficient part) is added to the A layer on the side not in contact with the transfer layer,
By using the ethylene-propylene random copolymer (having insufficient peelability but good moldability), the moldability can be supplemented.

【００１３】また、支持体シートを、Ｂ層（表層）／Ａ
層（中間層）／Ｂ層（裏層）の３層構成とすれば、積層
体となった支持体シートの各層の熱膨張率（乃至は収縮
率）の差による支持体シートの反りを矯正し、また転写
シートを巻き取ったり、積み重ねて保存した際のブロッ
キング（転写層と支持体シート裏面との接着）を防ぐ事
ができる点で好ましい。Further, the support sheet is formed by layer B (surface layer) / A
With the three-layer structure of the layer (intermediate layer) / the B layer (back layer), the warpage of the support sheet due to the difference in the coefficient of thermal expansion (or shrinkage) of each layer of the support sheet as a laminate is corrected. In addition, it is preferable in that it can prevent blocking (adhesion between the transfer layer and the back surface of the support sheet) when the transfer sheet is wound up or stacked and stored.

【００１４】そして、本発明の転写方法は、前記いずれ
かの本発明の成形用転写シートを用い、固体粒子衝突圧
による転写圧で転写する様にした。この様に固体粒子衝
突圧を転写圧に用いて転写することで、弾性体ローラを
用いる転写方法では不可能な様な深い凹凸面でも転写抜
け等の転写不良無しに確実に且つ容易に転写できる。そ
の結果、高意匠の化粧材等の転写製品を容易に製造でき
る。In the transfer method of the present invention, the transfer sheet for molding according to any one of the above-mentioned present invention is used to transfer by the transfer pressure due to the solid particle collision pressure. By transferring the solid particle collision pressure as the transfer pressure in this manner, the transfer can be performed reliably and easily even on a deep uneven surface, which is impossible with a transfer method using an elastic roller, without transfer failure such as transfer omission. . As a result, it is possible to easily manufacture a transfer product such as a high-design decorative material.

【００１５】また、本発明の転写方法は、上記いずれか
の成形用転写シートを用い、弾性体ローラによる転写圧
で転写する様にした。この様に弾性体ローラによる転写
圧で転写することで、比較的平坦に近い凹凸面に対し
て、容易に転写できる。Further, in the transfer method of the present invention, any one of the above-described transfer sheets for molding is used, and the transfer is performed under a transfer pressure by an elastic roller. By performing the transfer with the transfer pressure by the elastic roller in this manner, the transfer can be easily performed on a relatively flat uneven surface.

【００１６】[0016]

【発明の実施の形態】以下、本発明の成形用転写シート
について、実施の形態を説明する。なお、図１は本発明
の成形用転写シートの形態例を例示する断面図、図２は
固体粒子衝突圧による転写圧で転写する転写方法を説明
する概念図、図３は弾性体ローラによる転写圧で転写す
る転写方法を説明する概念図、図４〜図６は固体粒子噴
出に用いる噴出器の説明図、図７は真空成形転写方法で
の成形性評価に用いた被転写体の凹凸形状を示す断面
図、図８は固体粒子衝突圧による転写方法での成形性評
価に用いた被転写体の凹凸形状を示す斜視図、図９は剥
離強度の測定方法を説明する概念図、そして、図１０は
真空成形転写方法で得た化粧材を示す断面図である。Embodiments of the transfer sheet for molding of the present invention will be described below. FIG. 1 is a cross-sectional view illustrating an embodiment of the transfer sheet for molding of the present invention, FIG. 2 is a conceptual diagram illustrating a transfer method for transferring by a transfer pressure by solid particle collision pressure, and FIG. 3 is a transfer by an elastic roller. FIG. 4 to FIG. 6 are illustrations of an ejector used for ejecting solid particles, and FIG. 7 is an uneven shape of an object used for evaluation of formability by a vacuum molding transfer method. FIG. 8 is a perspective view showing a concave-convex shape of a transferred body used for evaluation of formability in a transfer method using solid particle collision pressure, FIG. 9 is a conceptual diagram illustrating a method of measuring peel strength, and FIG. 10 is a sectional view showing a decorative material obtained by the vacuum forming transfer method.

【００１７】〔支持体シート〕支持体シートは複層構成
の積層体であり、代表的には２層構成〔図１（Ａ）参
照〕と３層構成〔図１（Ｂ）参照〕とがある。そして、
２層構成の場合、図１（Ａ）の断面図で例示の如く、支
持体シート１０を、転写層２０に面する側は表層１１、
転写層２０に面しない側は裏層１２と呼称すると、転写
層２０が接する表層１１は、結晶性ポリプロピレン樹脂
と立体規則性の無いプロピレン共重合体樹脂とを混合し
た樹脂組成物からなるＢ層として、そうでない裏層１２
は、エチレン−プロピレンランダム共重合体からなるＡ
層とした構成の支持体シートとする。一方、３層構成の
場合、図１（Ｂ）の断面図で例示の如く、支持体シート
１０を、転写層２０に面する側は表層１１、転写層２０
に面しない外側の層は裏層１２、表層１１及び裏層１２
で挟まれる内部の層を中間層１３と呼称すると、転写層
２０が接する表層１１と共に裏層１２も、結晶性ポリプ
ロピレン樹脂と立体規則性の無いプロピレン共重合体樹
脂とを混合した樹脂組成物からなるＢ層として、中間層
１３を、エチレン−プロピレンランダム共重合体からな
るＡ層とした構成の支持体シートとする。[Support Sheet] The support sheet is a laminate having a multilayer structure, and typically has a two-layer structure (see FIG. 1A) and a three-layer structure (see FIG. 1B). is there. And
In the case of a two-layer structure, as shown in the cross-sectional view of FIG. 1A, the side of the support sheet 10 facing the transfer layer 20 is the surface layer 11,
When the side not facing the transfer layer 20 is referred to as a back layer 12, the surface layer 11 in contact with the transfer layer 20 is a layer B made of a resin composition obtained by mixing a crystalline polypropylene resin and a propylene copolymer resin having no stereoregularity. As the back layer 12
Is A composed of an ethylene-propylene random copolymer.
A support sheet having a layered structure. On the other hand, in the case of a three-layer structure, the side of the support sheet 10 facing the transfer layer 20 is the surface layer 11 and the transfer layer 20 as illustrated in the cross-sectional view of FIG.
The outer layers which do not face are the back layer 12, the surface layer 11 and the back layer 12.
When the inner layer sandwiched between is referred to as an intermediate layer 13, the back layer 12 as well as the surface layer 11 in contact with the transfer layer 20 are made of a resin composition obtained by mixing a crystalline polypropylene resin and a propylene copolymer resin having no stereoregularity. As the B layer, a support sheet having a configuration in which the intermediate layer 13 is an A layer made of an ethylene-propylene random copolymer is used.

【００１８】支持体シートを、この様な構成とすること
によって、転写シートの成形性と剥離性を両立させるこ
とができる。また、特に３層構成の形態では、巻き取り
保存時のブロッキング発生を防げ、耐ブロッキング性を
より確実に付与できる他、２層構成の場合に起こり得る
熱収縮率や伸び率等の違いによる、製造時、保存時、使
用時等に於ける反りやカール発生を効果的に防ぐことも
できる。この為、３層構成では、成形機への転写シート
のセッティングも容易となる。By employing such a structure of the support sheet, it is possible to achieve both the moldability and the releasability of the transfer sheet. In particular, in the form of a three-layer structure, it is possible to prevent the occurrence of blocking during winding and storage, and to more reliably impart anti-blocking properties. In addition, due to differences in heat shrinkage and elongation that can occur in the case of a two-layer structure, Warpage and curling during production, storage, use and the like can also be effectively prevented. For this reason, in the three-layer configuration, setting of the transfer sheet to the molding machine becomes easy.

【００１９】なお、転写層に接しないＡ層に用いるエチ
レン−プロピレンランダム共重合体層のエチレン含有率
は、成形性を考慮して適宜な値に調整する。エチレン含
有率を多くすると、結晶化度が低下し、成形性は増大す
る（なお、転写層に接しないＡ層には関係ないが、剥離
強度も増大する）。このエチレン含有率は、質量基準で
５〜５０％程度であり、通常３０％程度とする。The ethylene content of the ethylene-propylene random copolymer layer used for the layer A not in contact with the transfer layer is adjusted to an appropriate value in consideration of moldability. When the ethylene content is increased, the crystallinity is reduced, and the moldability is increased (note that the peel strength is also increased irrespective of the layer A which is not in contact with the transfer layer). The ethylene content is about 5 to 50% on a mass basis, and usually about 30%.

【００２０】次に、Ｂ層の樹脂組成物に用いる、結晶性
ポリプロピレン樹脂と立体規則性の無いプロピレン共重
合体樹脂には、次の様な樹脂を使用することができる。
先ず、結晶性ポリプロピレン樹脂としては、例えば、ア
イソタクチックのポリプロピレン、或いはその他、立体
規則性を有するポリプロピレンと、α−オレフィン、例
えば、エチレン、１−ブテン、１−ペンテン、１−ヘキ
セン、１−ヘプテン、１−オクテン等との共重合体等が
使用できる。一方、立体規則性の無いプロピレン共重合
体樹脂は、通常軟質成分（ソフトセグメント）として用
いる樹脂であり、成形性を良くする。また、前記樹脂組
成物中での比率を増やすことによって、剥離強度が上が
る為、剥離性の調整ができる。この様な立体規則性の無
いプロピレン共重合体樹脂としては、例えば、プロピレ
ン−エチレン共重合体、プロピレン−（１−ブテン）共
重合体、プロピレン−（１−ブテン）−エチレン三元共
重合体、プロピレン−（１−ヘキセン）−（１−オクテ
ン）三元共重合体、プロピレン−（１−ヘキセン）−
（４−メチル−１−ペンテン）三元共重合体等を使用で
きる。なお、これら共重合体は１種、又は２種以上の混
合樹脂として使用する。これら、立体規則性の無いプロ
ピレン共重合体樹脂の添加量は、〔結晶性ポリプロピレ
ン樹脂／立体規則性の無いプロピレン共重合体樹脂〕＝
９５／５〜７０／３０（質量比）程度とする。Next, the following resins can be used as the crystalline polypropylene resin and the propylene copolymer resin having no stereoregularity used in the resin composition of the layer B.
First, as the crystalline polypropylene resin, for example, isotactic polypropylene or other polypropylene having stereoregularity, and an α-olefin such as ethylene, 1-butene, 1-pentene, 1-hexene, 1-hexene, Copolymers with heptene, 1-octene and the like can be used. On the other hand, a propylene copolymer resin having no stereoregularity is a resin usually used as a soft component (soft segment), and improves moldability. Further, by increasing the ratio in the resin composition, the peel strength is increased, so that the peelability can be adjusted. Examples of such a propylene copolymer resin having no stereoregularity include propylene-ethylene copolymer, propylene- (1-butene) copolymer, and propylene- (1-butene) -ethylene terpolymer. Propylene- (1-hexene)-(1-octene) terpolymer, propylene- (1-hexene)-
(4-Methyl-1-pentene) terpolymer and the like can be used. These copolymers are used as one kind or as a mixed resin of two or more kinds. The amount of the propylene copolymer resin having no stereoregularity is calculated as follows: [crystalline polypropylene resin / propylene copolymer resin having no stereoregularity] =
It is about 95/5 to 70/30 (mass ratio).

【００２１】なお、剥離強度は、常温（２０℃）下での
剥離角θ＝９０°（図９参照）の剥離で、通常、５０〜
１０００ｍＮ／２５ｍｍ幅、好ましくは２００〜５００
ｍＮ／２５ｍｍ幅程度に収めるのが、箔バリ発生を防ぎ
良好な箔切れ性を確保できる点で、好ましい。The peel strength is typically 50 to 50 at a peel angle θ = 90 ° (see FIG. 9) at room temperature (20 ° C.).
1000 mN / 25 mm width, preferably 200 to 500
It is preferable that the width is set to about mN / 25 mm width, since it is possible to prevent the occurrence of foil burrs and to ensure good foil breakability.

【００２２】なお、３層構成に於いて、表層１１と裏層
１２とに用いるＢ層には、その内容（結晶性ポリプロピ
レン樹脂と立体規則性の無いプロピレン共重合体樹脂の
両樹脂及びその平均分子量、両樹脂の混合割合、添加剤
等）が異なる樹脂組成物を使用しても良いが、カール防
止の点からは、それらが全く同一乃至は略同一の樹脂組
成物を使用する事が好ましい。In the three-layer structure, the B layer used for the surface layer 11 and the back layer 12 has the contents (both resins of a crystalline polypropylene resin and a propylene copolymer resin having no stereoregularity and an average thereof). Although resin compositions having different molecular weights, mixing ratios of both resins, additives, etc.) may be used, from the viewpoint of curling prevention, it is preferable to use the same or substantially the same resin compositions. .

【００２３】また、支持体シートの総厚は、用途に応じ
た厚みとすれば良く特に制限は無いが、支持体シートの
強度と成形性とのバランスから、通常は５０〜１００μ
ｍ程度とするのが良い。The total thickness of the support sheet is not particularly limited as long as it is a thickness suitable for the intended use, but is usually 50 to 100 μm from the balance between the strength of the support sheet and moldability.
m.

【００２４】また、Ｂ層を使用する表層１１は、表面物
性として良好な剥離性を付与する層と共に不十分ながら
も或る程度の成形性を付与する層である為、確実に成膜
でき、且つ安定した剥離を行うに必要最低限の厚みが有
れば良い。厚すぎると、支持体シート全体の成形性を低
下させる。従って、通常、最低５μｍ程度、最大で支持
体シート総厚の２０％程度とする。なお、これと関連し
て、Ａ層を使用する３層構成に於ける中間層１３、及び
２層構成に於ける裏層１２は、成形性を優先的に付与す
る層である為に、転写層の剥離に支障無い限りより厚い
（厚み比率大）方が好ましい。この為、３層構成の場合
でも、最低、支持体シート総厚の６０％以上とする。Further, since the surface layer 11 using the layer B is a layer that imparts a certain degree of moldability, though insufficient, together with a layer that imparts good releasability as a surface physical property, it can be reliably formed into a film. In addition, it is only necessary to have a minimum thickness necessary for performing stable peeling. If the thickness is too large, the moldability of the entire support sheet is reduced. Therefore, the thickness is usually at least about 5 μm and at most about 20% of the total thickness of the support sheet. In this connection, since the intermediate layer 13 in the three-layer structure using the A layer and the back layer 12 in the two-layer structure are layers which give moldability preferentially, they are transferred. Thickness (thickness ratio is large) is preferable as long as layer separation is not hindered. Therefore, even in the case of a three-layer structure, the thickness is at least 60% of the total thickness of the support sheet.

【００２５】以上の様な複層構成の支持体シートは、従
来公知のカレンダー法、インフレーション法、Ｔダイ押
出法等の成膜方法によって、シート（フィルム）として
用意することができる。これらの中でも、各層を密着良
く積層できる点で、Ｔダイ押出法の共押出法で各層を成
膜と同時に積層する方法は好ましい方法である。The support sheet having a multilayer structure as described above can be prepared as a sheet (film) by a conventionally known film forming method such as a calendar method, an inflation method, or a T-die extrusion method. Among these, the method of laminating each layer simultaneously with the film formation by the co-extrusion method of the T-die extrusion method is preferable in that the layers can be laminated with good adhesion.

【００２６】そして、以上の様な構成の支持体シートを
用いる事で、支持体シートは塩化ビニル樹脂を使用せず
に成形性や剥離性等を良好なものとして構成する事がで
き、廃棄燃焼時に塩酸ガスを発生せず環境対策的にも好
ましい支持体シートにもなる。By using the support sheet having the above structure, the support sheet can be formed with good moldability and releasability without using a vinyl chloride resin. In some cases, it does not generate hydrochloric acid gas and is also a preferable support sheet in terms of environmental measures.

【００２７】また、支持体シートの上記各層には、必要
に応じて適宜、熱安定剤、紫外線吸収剤、光安定剤、酸
化防止剤、帯電防止剤、充填剤等の各種添加剤を添加し
ても良い。これらは公知の添加剤の中から適宜なものを
使用すれば良い。Further, various additives such as a heat stabilizer, an ultraviolet absorber, a light stabilizer, an antioxidant, an antistatic agent, and a filler are appropriately added to the respective layers of the support sheet as required. May be. These may be appropriately selected from known additives.

【００２８】また、支持体シートの表面には凹凸模様を
設けても良い。例えば、絞模様等の凹凸模様を裏面（転
写層に面しない側の支持体シート面）に設ければ、巻き
取った場合の耐ブロッキング性や成形用転写シートの滑
り性を向上できる。また、絞模様等の凹凸模様を表面
（転写層に面する側の面）に設ければ（転写層形成面が
ポリオレフィン系樹脂でどちらかと言うと濡れ難い面に
対して）、転写層を印刷や塗工等で形成するときに、そ
のインキや塗液の（印刷では版面からの）転移性を良好
にすることもできる。これら耐ブロッキング性や転移性
向上の機能付与の為の凹凸模様は、中心線平均粗さＲａ
（ＪＩＳ Ｂ ０６０１）で０．１〜５μｍ程度の凹凸
形状が良好な結果を与える。なお、絞模様としては砂目
や梨地等がある。Further, an uneven pattern may be provided on the surface of the support sheet. For example, if an uneven pattern such as a squeezed pattern is provided on the back surface (the side of the support sheet that does not face the transfer layer), it is possible to improve the anti-blocking property when wound up and the slipperiness of the molding transfer sheet. If an uneven pattern such as a squeezed pattern is provided on the surface (the surface facing the transfer layer) (the surface on which the transfer layer is formed is made of a polyolefin-based resin and is relatively difficult to wet), the transfer layer is printed. When forming by coating or coating, the transferability of the ink or coating liquid (from printing plate surface in printing) can also be improved. The uneven pattern for imparting the function of improving the blocking resistance and the transferability has a center line average roughness Ra.
(JIS B 0601) An uneven shape of about 0.1 to 5 μm gives a good result. In addition, as a squeezing pattern, there are a grain of sand and a pear-skin.

【００２９】また、支持体シートの転写層側の面に設け
た凹凸模様を、転写後の転写層表面に賦形して艶消し意
匠な木目導管溝柄等の凹凸模様による意匠表現も可能と
なる。意匠表現に用いる凹凸模様としては、砂目、梨地
等、ヘアライン、万線状溝、皮絞、布目表面テキスチュ
ア、文字、幾何学模様等がある。なお、前記機能付与や
この意匠表現に用いる凹凸模様は、熱プレスによるエン
ボス加工、ヘアライン加工、サンドブラスト加工等の公
知の賦形方法で形成すれば良い。Also, it is possible to form a concave and convex pattern formed on the surface of the transfer sheet side of the support sheet on the transfer layer surface after the transfer by using a concave and convex pattern such as a matte wood groove pattern. Become. Examples of the concavo-convex pattern used in the design expression include a grain of sand, a satin finish, a hairline, a linear groove, a skin squeezing, a texture on a cloth surface, a character, and a geometric pattern. The concavo-convex pattern used for imparting the function or expressing the design may be formed by a known shaping method such as embossing by hot pressing, hairline processing, and sandblasting.

【００３０】〔転写層〕上記支持体シート１０に積層す
る転写層２０としては、特に制限は無く、従来公知の各
種転写シートに於ける転写層の材料及び構成等を採用す
ることができる。[Transfer Layer] The transfer layer 20 to be laminated on the support sheet 10 is not particularly limited, and the material and structure of the transfer layer in various conventionally known transfer sheets can be adopted.

【００３１】転写層は、通常は少なくとも装飾層から構
成し、更に適宜、剥離層、接着剤層等も転写層の構成要
素とすることもある。なお、転写層は機能性層として、
抗菌層、防黴層、導電層等の各種機能性を有する層でも
良い。転写層は従来公知の印刷法や塗装法、或いは手描
き等の任意の形成手段で形成する。The transfer layer is usually composed of at least a decorative layer, and a release layer, an adhesive layer and the like may be a component of the transfer layer as appropriate. The transfer layer is a functional layer,
Layers having various functions such as an antibacterial layer, an antifungal layer, and a conductive layer may be used. The transfer layer is formed by an arbitrary forming means such as a conventionally known printing method, coating method, or hand-drawing.

【００３２】装飾層は、例えば、グラビア印刷、シルク
スクリーン印刷、オフセット印刷、グラビアオフセット
印刷、インキジェットプリント等の従来公知の方法、材
料で絵柄等を印刷等で形成した絵柄層、アルミニウム、
クロム、金、銀等の金属を公知の蒸着法等を用いて部分
的或いは全面に形成した金属薄膜層等であり、用途に合
わせたものを用いる。絵柄としては、被転写体の表面凹
凸に合わせて、木目模様、石目模様、布目模様、タイル
調模様、煉瓦調模様、皮絞模様、文字、幾何学模様、全
面ベタ等を用いる。The decorative layer may be formed by, for example, a conventionally known method such as gravure printing, silk screen printing, offset printing, gravure offset printing, or ink jet printing, a pattern layer formed by printing a pattern or the like with a material, aluminum, or the like.
A metal thin film layer or the like in which a metal such as chromium, gold, silver or the like is partially or entirely formed by using a known vapor deposition method or the like. A wood pattern, a stone pattern, a cloth pattern, a tile pattern, a tile pattern, a brick pattern, a leather pattern, a character, a geometric pattern, a solid pattern, or the like is used in accordance with the surface irregularities of the transfer target.

【００３３】なお、絵柄層用のインキ（又は塗液）は、
一般的なインキ（又は塗液）同様に、バインダー等から
なるビヒクル、顔料や染料等の着色剤、これに適宜加え
る各種添加剤からなる。バインダーの樹脂には、アクリ
ル樹脂、塩化ビニル−酢酸ビニル共重合体、ポリエステ
ル樹脂、セルロース系樹脂、ポリウレタン樹脂等の単体
又はこれらを含む混合物を用いる。着色剤としては、チ
タン白、カーボンブラック、弁柄、黄鉛、群青等の無機
顔料、アニリンブラック、キナクリドン、イソインドリ
ノン、フタロシアニンブルー等の有機顔料、アルミニウ
ム箔粉、二酸化チタン被覆雲母の箔粉等の光輝性顔料、
或いはその他染料等を用いる。The ink (or coating liquid) for the picture layer is
Like a general ink (or coating liquid), the ink comprises a vehicle such as a binder, a coloring agent such as a pigment or a dye, and various additives appropriately added thereto. As the binder resin, an acrylic resin, a vinyl chloride-vinyl acetate copolymer, a polyester resin, a cellulosic resin, a polyurethane resin, or the like, or a mixture containing them is used. Examples of the coloring agent include inorganic pigments such as titanium white, carbon black, red iron oxide, graphite, and ultramarine blue; organic pigments such as aniline black, quinacridone, isoindolinone, and phthalocyanine blue; aluminum foil powder; and titanium dioxide-coated mica foil powder. Brilliant pigments such as
Alternatively, other dyes or the like are used.

【００３４】また、剥離層を、支持体シートと転写層と
の剥離性を調整する為、また、転写後の転写層の表面保
護等の為に、従来公知の転写シートと同様に、転写層の
支持体シート側に、必要に応じ適宜設けても良い。剥離
層には、例えば、上記絵柄層用インキのバインダーに用
いる樹脂等が用いられる。なお、この剥離層は転写層の
構成要素であり、転写時に装飾層と共に基材側に転写さ
れ、装飾層の表面を被覆する。The release layer may be formed in the same manner as a conventionally known transfer sheet to adjust the releasability between the support sheet and the transfer layer and to protect the surface of the transfer layer after the transfer. May be provided as needed on the side of the support sheet. For the release layer, for example, a resin or the like used as a binder of the picture layer ink is used. The release layer is a component of the transfer layer, and is transferred to the base material together with the decoration layer during transfer, and covers the surface of the decoration layer.

【００３５】〔接着剤〕なお、接着剤を、成形用転写シ
ートの転写層を構成する接着剤層としてや、被転写体上
の接着剤層として、事前又は転写の直前に、オンライン
塗工やオフライン塗工で必要に応じて施すことができ
る。被転写体に施す場合には、成形用転写シート側の接
着剤層を省略できる。用いる接着剤としては、例えば、
接着方式としては、感熱型接着剤、湿気硬化型感熱溶融
型接着剤、２液硬化型接着剤、電離放射線硬化型接着
剤、或いは粘着剤による感圧型接着剤等が挙げられる。
感熱型接着剤としては、熱可塑性樹脂を用いた熱融着型
と、熱硬化性樹脂を用いた熱硬化型とがある。また、接
着剤は溶剤希釈又は無溶剤、或いは常温で液体又は固体
のいずれでも良く、適宜使い分ける。また、粘着性を呈
する感圧型の粘着剤以外の接着剤では、接着剤層の単層
のみで転写層とすることができる。例えば熱溶融型接着
剤には、ポリ酢酸ビニル樹脂、塩化ビニル−酢酸ビニル
共重合体、アクリル樹脂、熱可塑性ポリエステル樹脂、
熱可塑性ウレタン樹脂、ダイマー酸とエチレンジアミン
との縮重合により得られるポリアミド樹脂等が用いられ
る。また、熱硬化型接着剤には、フェノール樹脂、尿素
樹脂、ジアリルフタレート樹脂、熱硬化型ウレタン樹
脂、エポキシ樹脂等が用いられる。[Adhesive] The adhesive may be used as an adhesive layer constituting a transfer layer of a transfer sheet for molding, or as an adhesive layer on a transfer object, in advance of or immediately before transfer, by online coating. Off-line coating can be applied as needed. In the case of applying to an object to be transferred, the adhesive layer on the molding transfer sheet side can be omitted. As the adhesive used, for example,
Examples of the adhesion method include a heat-sensitive adhesive, a moisture-curable heat-sensitive adhesive, a two-part curable adhesive, an ionizing radiation-curable adhesive, and a pressure-sensitive adhesive using an adhesive.
As the heat-sensitive adhesive, there are a heat-sealing type using a thermoplastic resin and a thermosetting type using a thermosetting resin. The adhesive may be diluted with a solvent or without a solvent, or may be a liquid or a solid at room temperature. In the case of an adhesive other than a pressure-sensitive adhesive exhibiting tackiness, a transfer layer can be formed with only a single adhesive layer. For example, hot melt adhesives include polyvinyl acetate resin, vinyl chloride-vinyl acetate copolymer, acrylic resin, thermoplastic polyester resin,
A thermoplastic urethane resin, a polyamide resin obtained by condensation polymerization of dimer acid and ethylenediamine, and the like are used. In addition, a phenol resin, a urea resin, a diallyl phthalate resin, a thermosetting urethane resin, an epoxy resin, or the like is used as the thermosetting adhesive.

【００３６】接着剤は、グラビアロールコート、スプレ
ーコート、フローコート等の従来公知の溶液塗工手段に
より成形用転写シートとなるシートや被転写体に施す。
被転写体にはホットメルト接着剤をアプリケータ等によ
る熔融塗工（溶融塗工）手段も適用できる。接着剤の塗
布量は、接着剤の組成、被転写体の種類及び表面状態で
異なるが、通常１０〜２００ｇ／ｍ2 （固形分）程度で
ある。The adhesive is applied to a sheet to be a transfer sheet for molding or an object to be transferred by a conventionally known solution coating means such as a gravure roll coat, a spray coat, and a flow coat.
Melt coating (melt coating) means using a hot melt adhesive with an applicator or the like can also be applied to the transferred object. The amount of the adhesive to be applied varies depending on the composition of the adhesive, the type of the object to be transferred, and the surface condition, but is usually about 10 to 200 g / m 2 (solid content).

【００３７】〔転写方法〕上述した本発明の成形用転写
シートは、例えば下記する〜等の従来公知の各種転
写方法によって、被転写体に転写する事ができる。それ
らは、被転写体、被転写面の表面凹凸、用途等に応じて
適宜選択すれば良い。[Transfer Method] The above-mentioned transfer sheet for molding of the present invention can be transferred to a transfer-receiving body by various conventionally known transfer methods such as those described below. These may be appropriately selected according to the transferred object, the surface unevenness of the transferred surface, the application, and the like.

【００３８】なかでも、本発明の転写方法として採用す
る転写方法（転写圧押圧方法）は、の弾性体ローラに
よる転写圧で転写する転写方法（ローラ転写方法）と、
の固体粒子衝突圧による転写圧で転写する転写方法で
ある。弾性体ローラによれば、多少の表面凹凸が有って
も平易に転写できる点で好適であり、また、固体粒子衝
突圧によれば、弾性体ローラ等によっては、従来は不可
能であった大きな表面凹凸にも容易に転写できる点で好
ましい。In particular, the transfer method (transfer pressure pressing method) used as the transfer method of the present invention includes a transfer method (roller transfer method) in which transfer is performed with a transfer pressure using an elastic roller.
Is a transfer method in which transfer is performed at a transfer pressure due to solid particle collision pressure. According to the elastic roller, it is preferable in that it can be easily transferred even if there are some surface irregularities, and according to the solid particle collision pressure, it was not possible with the elastic roller or the like in the past. This is preferable in that it can be easily transferred to large surface irregularities.

【００３９】弾性体ローラによる転写方法（ローラ転
写方法）：特公昭６０−５９８７６号公報、特開平５−
２７０１９９号公報、特開平５−１３９０９７号公報等
に記載されているように、転写シートを、転写層を被転
写体側に向けて、支持体シート側から弾性体ローラで加
圧し、転写層が被転写体に接着後、支持体シートを剥離
する、所謂ローラ転写方法。Transfer method using an elastic roller (roller transfer method): Japanese Patent Publication No. 60-59876,
As described in JP-A-270199 and JP-A-5-139097, the transfer sheet is pressed with an elastic roller from the support sheet side with the transfer layer facing the transfer object side, and the transfer layer is covered. A so-called roller transfer method in which the support sheet is peeled off after bonding to the transfer body.

【００４０】真空成形転写方法：特公昭５６−４５７
６８号公報（オーバーレイ法）、特公昭６０−５８０１
４号公報（真空プレス法）等に記載されるように、立体
形状の被転写体上に転写シートを対向又は載置し、少な
くとも被転写体側からの真空吸引による圧力差により転
写シートの転写層を被転写体に転写する、所謂真空成形
積層法を利用した転写方法。Vacuum forming transfer method: Japanese Patent Publication No. 56-457
No. 68 (overlay method), Japanese Patent Publication No. 60-5801
As described in Japanese Patent Publication No. 4 (vacuum pressing method) or the like, a transfer sheet is opposed or placed on a three-dimensionally-transferred object, and at least a transfer layer of the transfer sheet is generated by a pressure difference caused by vacuum suction from the object. A transfer method using a so-called vacuum forming and laminating method for transferring the material onto a transfer object.

【００４１】射出成形同時絵付け転写方法：特開平６
−３１５９５０号公報に記載されるように、転写シート
をその転写層側が射出樹脂側を向く様にして、射出成形
の雌雄両金型間に配置した後、加熱溶融等により流動状
態の樹脂を型内に射出充填し、被転写体である樹脂成型
品の成形と同時にその被転写体表面に転写シートから転
写層を転写させる転写方法。Injection molding simultaneous painting transfer method: JP-A-6
As described in JP-A-315950, the transfer sheet is placed between the male and female molds for injection molding so that the transfer layer side faces the injection resin side, and the resin in a fluid state is molded by heating and melting. A transfer method in which a transfer layer is transferred from a transfer sheet to the surface of a transfer-receiving body at the same time as molding of a resin-molded article as a transfer-receiving body by injection-filling the inside.

【００４２】ラッピング転写方法：特公昭６１−５８
９５号公報、特開平５−３３００１３号公報等に記載さ
れるように、円柱、多角柱等の柱状の被転写体の長軸方
向に、転写シートを供給しつつ、複数の向きの異なるロ
ーラーにより、被転写体を構成する複数の側面に順次転
写シートを加圧接着して転写層を転写してゆく、所謂ラ
ッピング加工方法による転写方法。Wrapping transfer method: JP-B-61-58
No. 95, Japanese Unexamined Patent Publication No. 5-330013, etc., while supplying a transfer sheet in the long axis direction of a columnar transfer object such as a cylinder or a polygonal column, a plurality of rollers having different directions are used. A transfer method using a so-called lapping method in which a transfer sheet is successively transferred to a plurality of side surfaces constituting a transfer object by pressure bonding to transfer a transfer layer.

【００４３】固体粒子衝突圧による転写方法：特許第
２８４４５２４号公報、特開平１０−１９３８９３号公
報等に開示された転写圧押圧手段が新規な転写方法であ
る。図２はこの転写方法を概念的示す概念図である。こ
の転写方法は図２の如く、被転写体Ｂの被転写面（表
面）側に、支持体シートと転写層とからなる転写シート
Ｓの転写層側を対向させ、該転写シートの支持体シート
側に多数の固体粒子Ｐを衝突させ、その衝突圧を利用し
て、被転写体の被転写面への転写シートの圧接を行う。
そして、転写層が被転写体に接着後、転写シートの支持
体シートを剥離除去すれば、転写層による被転写体への
転写が完了する。なお、固体粒子Ｐに付記した矢印は、
固体粒子の速度ベクトルを表す。Transfer method using solid particle impact pressure: The transfer pressure pressing means disclosed in Japanese Patent No. 2844424, Japanese Patent Application Laid-Open No. 10-193893, etc. is a novel transfer method. FIG. 2 is a conceptual diagram conceptually showing this transfer method. In this transfer method, as shown in FIG. 2, the transfer layer side of a transfer sheet S composed of a support sheet and a transfer layer is opposed to the transfer surface (front surface) of the transfer object B, and the support sheet of the transfer sheet is A large number of solid particles P collide against the transfer side, and the pressure of the collision is used to press the transfer sheet against the transfer surface of the transfer object.
Then, after the transfer layer is adhered to the transfer object, the support sheet of the transfer sheet is peeled off and removed, whereby the transfer to the transfer object by the transfer layer is completed. The arrow attached to the solid particles P is
Represents the velocity vector of a solid particle.

【００４４】その他、ＢＭＣ(Bulk Molding Compoun
d) 成形法、ＳＭＣ(Sheet Molding Compound)成形法、
ハンドレイアップ成形法等のＦＲＰ(Fiber Reinforced
Plastics) における各種成形法、或いは、ＲＩＭ(React
ion Injection Molding)、マッチドモールド成形法等の
成形と同時に行う転写方法、等がある。In addition, BMC (Bulk Molding Compoun
d) Molding method, SMC (Sheet Molding Compound) molding method,
FRP (Fiber Reinforced
Plastics) or RIM (React
ion injection molding), a transfer method performed simultaneously with molding such as a matched mold molding method, and the like.

【００４５】なお、上記、、及びは既に形状を
有する被転写体に転写する方法であり、及びは、樹
脂成形品として被転写体の形状発現と同時に転写する方
法である。また、上記の方法では、樹脂の成形型、又
は別の型により転写シートを予備成形した後に、樹脂を
射出成形して成形と同時に転写する方法もある。これと
同様に、に列記の方法においても、転写シートの成形
は樹脂成形と同時の場合と、樹脂成形の前に予備成形す
る場合がある。なお、ハンドレイアップ法では、転写シ
ートの成形は予備成形となる。The above-mentioned and the above-mentioned methods are methods for transferring to an already-formed transfer object, and the above-mentioned methods are methods for transferring a resin molded article simultaneously with the expression of the shape of the transfer object. In addition, in the above method, there is also a method in which after a transfer sheet is preformed by using a resin mold or another mold, the resin is injection-molded and transferred at the same time as molding. Similarly, in the methods listed above, the transfer sheet may be formed simultaneously with resin molding, or may be preformed before resin molding. In the hand lay-up method, the transfer sheet is formed by preliminary forming.

【００４６】次に、本発明にて特に採用する、の弾性
体ローラによる転写方法と、の固体粒子衝突圧の転写
圧で転写する転写方法について、更に説明しておく。Next, the transfer method using an elastic roller and the transfer method using a transfer pressure of a solid particle collision pressure, which are particularly adopted in the present invention, will be further described.

【００４７】〔弾性体ローラによる転写方法〕この転写
方法（すなわち、ローラ転写方法）は、表面凹凸が比較
的小さいか平坦な被転写体に対しては、平易に転写でき
る点で好適である。図３は、ローラ転写方法を概念的に
説明する概念図である。転写シートＳを、転写層を被転
写体Ｂ側に向けて、支持体シート側から弾性体ローラＲ
で加圧して転写圧を与え、転写層が被転写体に接着後、
支持体シートを剥離する。使用する弾性体ローラＲとし
ては、通常、鉄等の剛体の軸芯Ｒ１の周囲を弾性体Ｒ２
で被覆したローラを用いる。弾性体Ｒ２としては、シリ
コーンゴム、フッ素ゴム、バイトンゴム、ブタジエンゴ
ム、天然ゴム等を用いる。弾性体ローラのゴム硬度は、
被転写体表面の凹凸形状の凹部まで転写シートを追従さ
せるには、ゴム硬度を６５°以下とすると良い。ローラ
の直径は、通常、５〜２０ｃｍ程度である。また、通
常、弾性体ローラは内部の電熱ヒータや外部の赤外線輻
射ヒータ等の加熱源により加熱して加熱ローラとしても
使用する。[Transfer Method Using Elastic Roller] This transfer method (namely, the roller transfer method) is suitable in that a transfer can be easily performed on a transfer target having relatively small or uneven surface. FIG. 3 is a conceptual diagram conceptually illustrating the roller transfer method. The transfer sheet S is moved from the support sheet side to the elastic roller R with the transfer layer facing the transfer object B side.
Press to apply the transfer pressure, and after the transfer layer adheres to the transfer receiving body,
The support sheet is peeled off. As the elastic roller R to be used, usually, an elastic member R2 is formed around a rigid shaft center R1 such as iron.
Is used. As the elastic body R2, silicone rubber, fluorine rubber, viton rubber, butadiene rubber, natural rubber, or the like is used. The rubber hardness of the elastic roller is
In order for the transfer sheet to follow the concave and convex portions on the surface of the transfer object, the rubber hardness is preferably set to 65 ° or less. The diameter of the roller is usually about 5 to 20 cm. In addition, the elastic roller is usually heated by a heating source such as an internal electric heater or an external infrared radiation heater and used as a heating roller.

【００４８】〔固体粒子衝突圧による転写方法〕転写圧
に固体粒子衝突圧を用いるという転写圧押圧手段が新規
なこの転写方法では、ローラ転写方法等の旧来の転写方
法では不可能な様な大きな凹凸面にも転写出来る様にな
る。また、それが故に、本発明の成形用転写シートの如
く、成形性と剥離性の両立等の解決すべき課題が出て来
る事になる。また、特にこの転写方法は、その成形性に
より凹凸表面へも転写できると言う前述した本発明の成
形用転写シートの特性を活かせる転写方法の一つであ
る。[Transfer Method Using Solid Particle Impact Pressure] The transfer pressure pressing means using the solid particle impact pressure as the transfer pressure is new in this transfer method, which is too large for a conventional transfer method such as a roller transfer method. It becomes possible to transfer to uneven surfaces. Therefore, as in the transfer sheet for molding of the present invention, problems to be solved such as compatibility between moldability and releasability come out. In particular, this transfer method is one of the transfer methods that can make use of the above-mentioned characteristics of the transfer sheet for molding of the present invention, which can be transferred to an uneven surface by its moldability.

【００４９】そして、固体粒子Ｐとしては、セラミック
ビーズ、ガラスビーズ等の非金属無機粒子、亜鉛、鉄等
の金属粒子、ナイロンビーズや架橋ゴムビーズ等の樹脂
ビーズ等の有機粒子、或いは金属等の無機粒子と樹脂と
からなる無機物・樹脂複合粒子等を使用する。粒子形状
は球形状が好ましいが、その他の形状でも用い得る。例
えば、金属亜鉛球は、基材への衝撃による基材破壊が少
ない点で好適な固体粒子である。なお、粒径は通常１０
〜１０００μｍ程度である。The solid particles P include non-metallic inorganic particles such as ceramic beads and glass beads, metal particles such as zinc and iron, organic particles such as resin beads such as nylon beads and crosslinked rubber beads, and inorganic particles such as metals. Inorganic / resin composite particles composed of particles and resin are used. The particle shape is preferably spherical, but other shapes can also be used. For example, metal zinc spheres are suitable solid particles in that the substrate is less likely to break due to impact on the substrate. The particle size is usually 10
About 1000 μm.

【００５０】固体粒子は噴出器から成形用転写シートに
向かって噴出させ、成形用転写シートに衝突したその衝
突圧が転写圧となる。噴出器には、代表的には羽根車や
吹出ノズルを用いる。羽根車はその回転により固体粒子
を加速し、吹出ノズルは高速の流体流で固体粒子を加速
する。羽根車や吹出ノズルには、サンドブラスト或いは
ショットブラスト、ショットピーニング等とブラスト分
野にて使用されているものを流用できる。例えば羽根車
には遠心式ブラスト装置、吹出ノズルには加圧式や吸引
式ブラスト装置、ウェットブラスト装置等である。遠心
式ブラスト装置は羽根車の回転力で固体粒子を加速し噴
出する。加圧式ブラスト装置は、圧縮空気に混合してお
いて固体粒子を、空気と共に噴出する。吸引式ブラスト
装置は、圧縮空気の高速流で生ずる負圧部に固体粒子を
吸い込み、空気と共に噴出する。ウェットブラスト装置
は、固体粒子を液体と混合して噴出する。これらの中で
も、羽根車は、固体粒子の噴出量が多い点で効率的で好
ましい噴出器の一つである。The solid particles are ejected from the ejector toward the transfer sheet for molding, and the collision pressure that collides with the transfer sheet for molding becomes the transfer pressure. Typically, an impeller or a blowing nozzle is used for the ejector. The impeller accelerates the solid particles by its rotation, and the blowing nozzle accelerates the solid particles with a high-speed fluid flow. Sandblasting, shot blasting, shot peening and the like used in the blasting field can be used for the impeller and the blowing nozzle. For example, a centrifugal blast device is used for the impeller, and a pressurized or suction blast device, a wet blast device, or the like is used for the blowing nozzle. The centrifugal blast device accelerates and ejects solid particles by the rotational force of the impeller. A pressurized blasting device ejects solid particles together with air while being mixed with compressed air. The suction-type blast device sucks solid particles into a negative pressure portion generated by a high-speed flow of compressed air, and ejects the solid particles together with the air. The wet blast device mixes and ejects solid particles with a liquid. Among these, the impeller is one of the efficient and preferable ejectors in that the ejection amount of solid particles is large.

【００５１】図４及び図５は、羽根車による噴出器の一
例を示す概念図である。羽根車８１２は、複数の羽根８
１３がその両側を２枚の側面板８１４で固定され、且つ
回転中心部は羽根８１３が無い中空部８１５となってい
る。更に、この中空部８１５内に方向制御器８１６を内
在する（図５参照）。方向制御器８１６は、外周の一部
が円周方向に開口した開口部８１７を有し中空筒状で羽
根車８１２の回転軸芯と同一回転軸芯で、羽根車とは独
立して回動自在となっている。羽根車使用時は、方向制
御器の開口部を適宜の方向に向くように固定して、固体
粒子の噴出方向を調整する。更に、この方向制御器の内
部に、内部中空で羽根車８１２の回転軸芯と同一回転軸
芯のもう一つの羽根車が散布器８１８として内在する
（図５参照）。散布器８１８は外側の羽根車８１２と共
に回転する。そして、前記側面板８１４の回転中心には
回転軸８１９が固定され、回転軸８１９は、軸受８２０
で回転自在に軸支され電動機等の回転動力源（図示略）
によって駆動回転され、羽根車８１２が回転する。また
回転軸８１９は、羽根８１３を間に有する２枚の側面板
８１４間には貫通しておらず、軸無しの空間を形成して
いる。そして、散布器８１８の内部に固体粒子Ｐがホッ
パ等から輸送管を通って供給される。通常、固体粒子
は、羽根車の上方（直上又は斜上方）から供給する。散
布器内に供給された固体粒子は散布器の羽根車で外側に
飛び散る。飛び散った固体粒子は、方向制御器８１６の
開口部８１７によって許された方向にのみ放出され、外
側の羽根車８１２の羽根８１３と羽根８１３との間に供
給される。そして、羽根８１３に衝突し、羽根車８１２
の回転力で加速され、羽根車から噴出する。FIG. 4 and FIG. 5 are conceptual diagrams showing an example of the ejector using the impeller. The impeller 812 includes a plurality of impellers 8.
13 is fixed on both sides by two side plates 814, and the center of rotation is a hollow portion 815 without the blade 813. Further, a direction controller 816 is provided inside the hollow portion 815 (see FIG. 5). The direction controller 816 has an opening 817 that is partially open in the circumferential direction, has a hollow cylindrical shape, and has the same rotation axis as the rotation axis of the impeller 812, and rotates independently of the impeller. It is free. When using the impeller, the opening of the direction controller is fixed so as to face an appropriate direction, and the ejection direction of the solid particles is adjusted. Further, inside the directional controller, another impeller, which is hollow inside and has the same rotation axis as the rotation axis of the impeller 812, is provided as a sprayer 818 (see FIG. 5). The spreader 818 rotates with the outer impeller 812. A rotation shaft 819 is fixed to the center of rotation of the side plate 814, and the rotation shaft 819 has a bearing 820.
A rotary power source such as an electric motor that is rotatably supported by a motor (not shown)
, And the impeller 812 rotates. The rotating shaft 819 does not penetrate between the two side plates 814 having the blades 813 therebetween, and forms a space without a shaft. Then, the solid particles P are supplied into the sprayer 818 from a hopper or the like through a transport pipe. Usually, the solid particles are supplied from above (directly above or obliquely above) the impeller. The solid particles supplied into the sprayer are scattered outward by the impeller of the sprayer. The scattered solid particles are emitted only in the direction allowed by the opening 817 of the direction controller 816 and supplied between the blades 813 of the outer impeller 812. Then, it collides with the blade 813 and the impeller 812
It is accelerated by the rotational force of the gas and squirts from the impeller.

【００５２】羽根車８１２の寸法は、通常直径５〜６０
ｃｍ程度、羽根の幅は５〜２０ｃｍ程度、羽根の長さ
は、ほぼ羽根車の直径程度、羽根車の回転速度は５００
〜５０００〔ｒｐｍ〕程度である。固体粒子の噴出速度
は１０〜５０〔ｍ／ｓ〕程度、投射密度（基材単位面積
当たりに衝突させる固体粒子の総質量）は１０〜１５０
〔ｋｇ／ｍ2 〕程度である。The size of the impeller 812 is usually 5 to 60 in diameter.
cm, the width of the blade is about 5 to 20 cm, the length of the blade is approximately the diameter of the impeller, and the rotation speed of the impeller is 500.
It is about 5000 [rpm]. The ejection speed of the solid particles is about 10 to 50 [m / s], and the projection density ( total mass of the solid particles to be collided per unit area of the base material) is 10 to 150.
[Kg / m 2 ].

【００５３】次に、図６は吹出ノズルを用いた噴出器の
一例を示す概念図である。同図の噴出器８４０は固体粒
子加速流体として空気等の気体を用い、固体粒子噴出時
に該気体と固体粒子を混合して噴出する形態の噴出器の
一例である。噴出器８４０は、固体粒子Ｐと流体Ｆを混
合する誘導室８４１と、誘導室内に流体を噴出する内部
ノズル８４２と、ノズル開口部８４３から固体粒子及び
流体を噴出する吹出ノズル部８４４からなる。圧縮機等
からの加圧状態の流体Ｆを、内部ノズル８４２から噴出
し誘導室８４１を経てノズル８４４のノズル開口部８４
３から噴出する際に、噴出器内の誘導室８４１にて、高
速で流れる流体流の作用で負圧を作り、この負圧により
固体粒子を流体流に導き混合し、流体流で固体粒子を加
速、搬送して、ノズル８４４のノズル開口部８４３から
流体流と共に噴出するものである。なお、固体粒子加速
流体に液体を用いる吹出ノズル等もある。流体圧は吹付
圧力で通常０．０１〜１ＭＰａ程度である。流体流の流
速は、液流では通常１〜２０ｍ／秒程度、気流では通常
５〜８０ｍ／秒程度である。Next, FIG. 6 is a conceptual diagram showing an example of an ejector using an ejection nozzle. An ejector 840 shown in the figure is an example of an ejector in which a gas such as air is used as a solid particle accelerating fluid, and the gas and the solid particles are mixed and ejected when ejecting the solid particles. The ejector 840 includes an induction chamber 841 that mixes the solid particles P and the fluid F, an internal nozzle 842 that ejects the fluid into the induction chamber, and an ejection nozzle unit 844 that ejects the solid particles and the fluid from the nozzle opening 843. A fluid F in a pressurized state from a compressor or the like is ejected from an internal nozzle 842, passes through an induction chamber 841 and passes through a nozzle opening 84 of a nozzle 844.
3, a negative pressure is created by the action of a fluid flow flowing at a high speed in the guide chamber 841 in the ejector, and the negative pressure guides and mixes the solid particles into the fluid flow, thereby forming the solid particles in the fluid flow. It accelerates, conveys, and jets out together with the fluid flow from the nozzle opening 843 of the nozzle 844. In addition, there is a blowing nozzle or the like that uses a liquid as a solid particle acceleration fluid. The fluid pressure is generally about 0.01 to 1 MPa as a spray pressure. The flow velocity of the fluid flow is usually about 1 to 20 m / sec for the liquid flow, and is usually about 5 to 80 m / sec for the air flow.

【００５４】なお、噴出器は、１個のみでは加圧領域を
所望の形状、大きさに出来ない場合は、複数用いる。ま
た、実際に固体粒子を用いて転写する際は、固体粒子は
周囲の雰囲気中に飛散させずに且つ循環再利用するのが
好ましく、転写する空間を周囲空間と隔離するチャンバ
内で、固体粒子を成形用転写シートに衝突させると良
い。支持体シートの剥離は、チャンバ外でも良い。If the pressurized area cannot be formed into a desired shape and size by using only one ejector, a plurality of ejectors are used. Further, when actually transferring using solid particles, it is preferable that the solid particles are not scattered in the surrounding atmosphere and circulated and reused. May be caused to collide with the transfer sheet for molding. The peeling of the support sheet may be performed outside the chamber.

【００５５】また、好ましくは、予め成形用転写シート
は、赤外線輻射ヒータ等で加熱軟化させて延伸性を付与
し、被転写体が熱容量の大きい場合は予め予熱し、熱融
着型の接着剤層として作用させる層（場合によるが、絵
柄層、接着剤層等）は、加熱活性化させた状態で固体粒
子を成形用転写シートに衝突させる様にする。なお、熱
融着により転写する場合、接着剤層等の熱融着する層を
活性化して熱融着させる為に加熱するタイミングは、衝
突圧印加前、衝突圧印加中、或いは衝突圧印加前及び印
加中などのいずれでも良い。一方、成形用転写シートが
被転写体の表面形状に追従し、成形され、転写層が被転
写体に十分に接触すれば、冷風等の冷却手段で熱融着し
た層の冷却を促進しても良い。冷風は、例えば、成形用
転写シート側や被転写体側から吹き付ける。Preferably, the transfer sheet for molding is preliminarily heated and softened by an infrared radiation heater or the like to impart stretchability. When the transfer object has a large heat capacity, it is preheated in advance, and a heat-sealing adhesive is used. The layer acting as a layer (depending on the case, a picture layer, an adhesive layer, etc.) is made to collide solid particles with the transfer sheet for molding in a state of being heat-activated. When transferring by thermal fusion, the timing of heating to activate and thermally fuse a layer to be thermally fused, such as an adhesive layer, is before applying the collision pressure, during the application of the collision pressure, or before applying the collision pressure. And during application. On the other hand, if the transfer sheet for molding follows the surface shape of the transferred object and is formed, and the transfer layer is sufficiently in contact with the transferred object, cooling of the heat-sealed layer by cooling means such as cold air is promoted. Is also good. The cool air is blown from, for example, the molding transfer sheet side or the transfer receiving body side.

【００５６】〔被転写体〕ところで、被転写体Ｂとして
は特に制限は無いが、成形用転写シートの成形性を活か
して該シートを成形して転写するには、必然的に被転写
面は凹凸表面となる。例えば、被転写体の材質は、無機
非金属系、金属系、木質系、プラスチック系等である。
具体的には、無機非金属系では、例えば、抄造セメン
ト、押出セメント、スラグセメント、ＡＬＣ（軽量気泡
コンクリート）、ＧＲＣ（硝子繊維強化コンクリー
ト）、パルプセメント、木片セメント、石綿セメント、
ケイ酸カルシウム、石膏、石膏スラグ等の非陶磁器窯業
系材料、土器、陶器、磁器、セッ器、硝子、琺瑯等のセ
ラミックス等の無機質材料等がある。また、金属系で
は、例えば、鉄、アルミニウム、銅等の金属材料があ
る。また、木質系では、例えば、杉、檜、樫、ラワン、
チーク等からなる単板、合板、パーティクルボード、繊
維板、集成材等がある。また、プラスチック系では、例
えば、ポリプロピレン、ＡＢＳ樹脂、フェノール樹脂等
の樹脂材料がある。[Transfer object] The transfer object B is not particularly limited. However, in order to form and transfer the sheet by making use of the moldability of the transfer sheet for molding, the transfer surface must be formed. The surface becomes uneven. For example, the material of the transfer object is an inorganic nonmetal-based, metal-based, wood-based, plastic-based, or the like.
Specifically, in the case of inorganic nonmetals, for example, papermaking cement, extruded cement, slag cement, ALC (lightweight cellular concrete), GRC (glass fiber reinforced concrete), pulp cement, wood chip cement, asbestos cement,
Non-ceramic ceramic materials such as calcium silicate, gypsum and gypsum slag; and inorganic materials such as ceramics such as earthenware, pottery, porcelain, tableware, glass, and enamel. Further, in the metal system, for example, there are metal materials such as iron, aluminum, and copper. In the wood system, for example, cedar, cypress, oak, lauan,
There are veneers made of teak, etc., plywood, particle board, fiber board, laminated wood and the like. In the case of plastics, for example, there are resin materials such as polypropylene, ABS resin, and phenol resin.

【００５７】また、被転写体の形状は、その被転写面に
転写できれば、平板や屈曲した板、柱状物、成形品等の
立体物等と任意である。例えば、被転写体は全体として
（包絡面形状が）平板状の板材の他、断面が円弧状に凸
又は凹に１方向に湾曲した二次元的凹凸を有する物等で
も良い。The shape of the object to be transferred is arbitrary, such as a flat plate, a bent plate, a columnar object, a three-dimensional object such as a molded product, etc., as long as it can be transferred to the surface to be transferred. For example, the object to be transferred may be a flat plate material (envelope surface shape) as a whole, or a material having two-dimensional unevenness whose cross section is convex or concave in an arc shape and curved in one direction.

【００５８】被転写体の被転写面の凹凸形状は、使用す
る成形用転写シート及び採用する転写方法によって転写
可能な形状であれば良く任意である。凹凸形状は、例え
ば、複数のタイルや煉瓦を平面に配置した場合の目地、
花崗岩の劈開面、砂目等の石材表面の凹凸、木材羽目
板、浮造木目等の木材板表面凹凸、リシン調、スタッコ
調等の吹付塗装面の凹凸等である。The irregular shape of the transfer surface of the transfer object is not limited as long as it can be transferred by the forming transfer sheet to be used and the transfer method to be used. The uneven shape is, for example, a joint when a plurality of tiles and bricks are arranged on a plane,
It is the unevenness of the surface of the stone material such as the cleavage surface of the granite and the grain, the unevenness of the surface of the wood plate such as the wood paneling and the floating grain, and the unevenness of the spray painting surface such as ricin or stucco.

【００５９】また、これらの被転写体表面には、下地処
理として、必要に応じて予め、接着剤との接着を補助す
る為の易接着プライマー、被転写体がアルカリ性基材の
場合ではアルカリ成分の滲出を防ぐシーラー剤、或いは
表面の微凹凸や多孔質を目止めし封じる目止剤等を塗工
法で形成しておいても良い。また、下地処理には下地
（被転写体）色の調整用の下塗り塗料（ベースコート）
等もある。易接着プライマー、シーラー剤、目止剤、或
いは下塗り塗料としては、イソシアネート、２液硬化ウ
レタン樹脂、エポキシ樹脂、アクリル樹脂、酢酸ビニル
樹脂等の樹脂を塗工し形成する。また、これらは、目的
により１層又は多層で用いる。In addition, as a base treatment, an easy-adhesion primer for assisting the adhesion with an adhesive is provided on the surface of the transfer object, if necessary, or an alkaline component when the transfer object is an alkaline substrate. A sealant agent for preventing oozing of the surface, or a sealing agent for sealing and sealing fine irregularities and porosity on the surface may be formed by a coating method. In addition, the undercoating (base coat) for adjusting the base (transfer) color is used for the base treatment.
And so on. A resin such as an isocyanate, a two-part curable urethane resin, an epoxy resin, an acrylic resin, or a vinyl acetate resin is applied and formed as an easy-adhesion primer, a sealer, a sealant, or an undercoat. These may be used in a single layer or a multilayer depending on the purpose.

【００６０】〔転写製品の用途〕本発明の成形用転写シ
ート或いは本発明の転写方法で得られる、化粧材等の転
写製品の用途は、転写された装飾面が凹凸面、特に三次
元形状等の凹凸表面の物品であるようものが好適であ
り、各種用途に用いられ得る。例えば、化粧材として、
サイディング等の外壁、塀、屋根、門扉、破風板等の外
装、壁面、天井、床等の建築物の内装、窓枠、扉、手
摺、敷居、鴨居等の建具類の表面化粧、箪笥等の家具や
テレビ受像機等の弱電・ＯＡ機器のキャビネットの表面
化粧、自動車、電車、航空機、船舶等の乗物内装材等の
各種分野で用いられ得る。化粧材は化粧板等として利用
される。なお、化粧材も含めて転写製品の形状は、平
板、曲面板、棒状体、立体物等と任意である。[Uses of Transfer Products] The transfer products such as decorative materials obtained by the transfer sheet for molding of the present invention or the transfer method of the present invention may be used when the transferred decorative surface is an uneven surface, particularly a three-dimensional shape. Such an article having an uneven surface is suitable and can be used for various applications. For example, as a cosmetic material,
Exterior such as siding, exterior walls such as fences, roofs, gates, gable boards, interiors of buildings such as walls, ceilings, floors, window frames, doors, handrails, thresholds, surface decorations for fittings such as sluices, chests, etc. It can be used in various fields such as surface decoration of cabinets for light electric and OA equipment such as furniture and television receivers, and interior materials for vehicles such as automobiles, trains, aircraft, and ships. The decorative material is used as a decorative board or the like. In addition, the shape of the transfer product including the cosmetic material is arbitrary such as a flat plate, a curved plate, a rod-shaped body, and a three-dimensional object.

【００６１】〔後加工〕なお、転写後の化粧材等の転写
製品の表面には、必要に応じ適宜、耐久性、意匠感等を
付与する為に、更に透明保護層等の従来公知の上塗り層
（図１０の符号４２参照）を塗装法等で形成しても良
い。[Post-processing] The surface of a transferred product such as a cosmetic material after the transfer is further provided with a conventionally known overcoat such as a transparent protective layer in order to appropriately impart durability and design feeling, if necessary. The layer (see reference numeral 42 in FIG. 10) may be formed by a coating method or the like.

【００６２】[0062]

【実施例】次に実施例及び比較例により本発明を更に説
明する。なお、文中、「部」とあるのは、全て質量基準
である。Next, the present invention will be further described with reference to Examples and Comparative Examples. In the description, “parts” are all based on mass.

【００６３】〔実施例１〕図１（Ｂ）の如き３層構成の
支持体シート１０を用いた成形用転写シートＳを次の様
にして作成した。支持体シート１０は、転写層と接する
表層１１、及び転写層に面しない裏層１２にはＢ層を用
い、これら両層に挟まれる中間層１３にはＡ層を用い
た。そして表層１１及び裏層１２とするＢ層には、結晶
性ポリプロピレン樹脂としてのアイソタクチックホモポ
リプロピレン１００部に、立体規則性の無いプロピレン
共重合体樹脂としてのプロピレン−エチレン共重合体
（５０／５０）３０部とに、更に添加剤として、フェノ
ール系酸化防止剤０．２部、ヒンダードアミン系ラジカ
ル捕捉剤０．２部、及び、ベンゾトリアゾール系紫外線
吸収剤０．２部を配合した樹脂組成物を用いた。また、
中間層１３とするＡ層には、エチレン−プロピレンラン
ダム共重合体（３０／７０）１００部に、更にＢ層同様
に添加剤として、フェノール系酸化防止剤０．２部、ヒ
ンダードアミン系ラジカル捕捉剤０．２部、及び、ベン
ゾトリアゾール系紫外線吸収剤０．２部を配合した樹脂
を用いた。なお、エチレン−プロピレンランダム共重合
体等の共重合体における括弧内の数値は、例えば「エチ
レン−プロピレンランダム共重合体（３０／７０）」と
は、エチレン対プロピレンの共重合比が質量基準で、３
０（エチレン）対７０（プロピレン）を意味する。以
下、他の実施例及び比較例に於ける共重合体についても
同様である。Example 1 A transfer sheet S for molding using a three-layered support sheet 10 as shown in FIG. 1B was prepared as follows. In the support sheet 10, the B layer was used for the surface layer 11 in contact with the transfer layer and the back layer 12 not facing the transfer layer, and the A layer was used for the intermediate layer 13 sandwiched between these layers. The B layer serving as the surface layer 11 and the back layer 12 includes 100 parts of isotactic homopolypropylene as a crystalline polypropylene resin and propylene-ethylene copolymer (50/50) as a propylene copolymer resin having no stereoregularity. 50) 30 parts, and further, as additives, 0.2 part of a phenolic antioxidant, 0.2 part of a hindered amine radical scavenger, and 0.2 part of a benzotriazole ultraviolet absorber 0.2 parts Was used. Also,
In the A layer, which is the intermediate layer 13, 100 parts of an ethylene-propylene random copolymer (30/70), 0.2 parts of a phenolic antioxidant and a hindered amine radical scavenger as additives as in the B layer. A resin blended with 0.2 part and 0.2 part of a benzotriazole-based ultraviolet absorber was used. In addition, the numerical value in the parenthesis in the copolymer such as the ethylene-propylene random copolymer is, for example, "ethylene-propylene random copolymer (30/70)" means that the copolymerization ratio of ethylene to propylene is based on mass. , 3
Meaning 0 (ethylene) to 70 (propylene). Hereinafter, the same applies to the copolymers in other Examples and Comparative Examples.

【００６４】そして、表層／中間層／裏層とするＡ層／
Ｂ層／Ａ層の３層を、Ｔダイによる３層共押出法によっ
て熔融状態で押出して成膜と同時に積層して、厚み１０
μｍの表層１１（Ｂ層）、厚み８０μｍの中間層１３
（Ａ層）、厚み１０μｍの裏層１２（Ｂ層）からなる総
厚１００μｍの積層体を、支持体シート１０として用意
した。Then, the surface layer / intermediate layer / A layer as the back layer /
The three layers B and A were extruded in a molten state by a three-layer co-extrusion method using a T-die and laminated simultaneously with the film formation.
μm surface layer 11 (layer B), 80 μm thick intermediate layer 13
A laminate having a total thickness of 100 μm including the (A layer) and the back layer 12 (B layer) having a thickness of 10 μm was prepared as the support sheet 10.

【００６５】そして、上記支持体シート１０の表層１１
の面に（転写層の剥離性を持たせる為に、この面にはコ
ナロ放電処理は行っていない）、転写層２０として絵柄
層をグラビア印刷にて形成して成形用転写シートを作製
した。なお、絵柄層としては、熱可塑性アクリルウレタ
ン樹脂をバインダーの樹脂として、着色剤に弁柄、イソ
インドリノン、フタロシアニンブルー、及びチタン白を
用いた着色インキを使用し、３色印刷で木目柄の絵柄層
（固形分基準の塗布量２ｇ／ｍ2 ）を形成した。The surface layer 11 of the support sheet 10
On the surface of No. (a conaro discharge treatment was not performed on this surface in order to make the transfer layer peelable), a pattern layer was formed as a transfer layer 20 by gravure printing to prepare a transfer sheet for molding. As the pattern layer, a thermoplastic acrylic urethane resin is used as a binder resin, and a reddish pattern, isoindolinone, phthalocyanine blue, and a coloring ink using titanium white are used as a coloring agent. A picture layer (coating amount 2 g / m 2 based on solid content) was formed.

【００６６】〔実施例２〕実施例１に於いて、３層構成
の支持体シートの内容を表１に示す如く変更した他は、
実施例１と同様にして成形用転写シートを作製した。該
変更は、支持体シートに於ける表層１１及び裏層１２と
するＢ層の樹脂組成物（の樹脂分）を、結晶性ポリプロ
ピレン樹脂としてのアイソタクチックホモポリプロピレ
ン１００部に、立体規則性の無いプロピレン共重合体樹
脂としてのプロピレン−（１−ブテン）共重合体（５０
／５０）３０部を配合した樹脂組成物とした。また、中
間層１３とするＡ層は、実施例１と同じである。なお、
Ｂ層（及びＡ層）には実施例１同様に添加剤が配合され
ている。Example 2 The procedure of Example 1 was repeated, except that the contents of the three-layered support sheet were changed as shown in Table 1.
A transfer sheet for molding was produced in the same manner as in Example 1. This change is performed by adding the resin composition of (the resin component) of the layer B serving as the surface layer 11 and the back layer 12 in the support sheet to 100 parts of isotactic homopolypropylene as a crystalline polypropylene resin, and applying stereoregularity. Propylene- (1-butene) copolymer (50
/ 50) 30 parts of a resin composition. The A layer serving as the intermediate layer 13 is the same as that of the first embodiment. In addition,
An additive is blended in the B layer (and the A layer) as in the first embodiment.

【００６７】〔実施例３〕実施例１に於いて、３層構成
の支持体シートの内容を表１に示す如く変更した他は、
実施例１と同様にして成形用転写シートを作製した。該
変更は、支持体シートに於ける表層１１及び裏層１２と
するＢ層の樹脂組成物を、結晶性ポリプロピレン樹脂と
してのアイソタクチックホモポリプロピレン１００部
に、立体規則性の無いプロピレン共重合体樹脂としての
プロピレン−（１−ブテン）−エチレン共重合体（３０
／３０／４０）３０部を配合した樹脂組成物とした。ま
た、中間層１３とするＡ層は、実施例１と同じである。
なお、Ｂ層（及びＡ層）には実施例１同様に添加剤が配
合されている。Example 3 The procedure of Example 1 was repeated except that the contents of the three-layered support sheet were changed as shown in Table 1.
A transfer sheet for molding was produced in the same manner as in Example 1. This change is achieved by adding a resin composition of the layer B as the surface layer 11 and the back layer 12 in the support sheet to 100 parts of isotactic homopolypropylene as a crystalline polypropylene resin by using a propylene copolymer having no stereoregularity. Propylene- (1-butene) -ethylene copolymer (30
(30/40) 30 parts of a resin composition. The A layer serving as the intermediate layer 13 is the same as that of the first embodiment.
Note that the B layer (and the A layer) contains the same additives as in the first embodiment.

【００６８】〔実施例４〕実施例１に於いて、３層構成
の支持体シートの内容を表１に示す如く変更した他は、
実施例１と同様にして成形用転写シートを作製した。該
変更は、支持体シートに於ける表層１１及び裏層１２と
するＢ層の樹脂組成物を、結晶性ポリプロピレン樹脂と
してのアイソタクチックホモポリプロピレン１００部
に、立体規則性の無いプロピレン共重合体樹脂としての
プロピレン−（１−ヘキセン）−（１−オクテン）共重
合体（３０／３０／４０）３０部を配合した樹脂組成物
とした。また、中間層１３とするＡ層は、実施例１と同
じである。なお、Ｂ層（及びＡ層）には実施例１同様に
添加剤が配合されている。Example 4 The procedure of Example 1 was repeated except that the contents of the three-layered support sheet were changed as shown in Table 1.
A transfer sheet for molding was produced in the same manner as in Example 1. This change is achieved by adding a resin composition of the layer B as the surface layer 11 and the back layer 12 in the support sheet to 100 parts of isotactic homopolypropylene as a crystalline polypropylene resin by using a propylene copolymer having no stereoregularity. A resin composition was prepared by mixing 30 parts of a propylene- (1-hexene)-(1-octene) copolymer (30/30/40) as a resin. The A layer serving as the intermediate layer 13 is the same as that of the first embodiment. Note that the B layer (and the A layer) contains the same additives as in the first embodiment.

【００６９】〔実施例５〕実施例１に於いて、３層構成
の支持体シートの内容を表１に示す如く変更した他は、
実施例１と同様にして成形用転写シートを作製した。該
変更は、支持体シートに於ける表層１１及び裏層１２と
するＢ層の樹脂組成物を、結晶性ポリプロピレン樹脂と
してのアイソタクチックホモポリプロピレン１００部
に、立体規則性の無いプロピレン共重合体樹脂としての
プロピレン−（１−ヘキセン）−（４−メチル−１−ペ
ンテン）共重合体（３０／３０／４０）３０部を配合し
た樹脂組成物とした。また、中間層１３とするＡ層は、
実施例１と同じである。なお、Ｂ層（及びＡ層）には実
施例１同様に添加剤が配合されている。Example 5 The procedure of Example 1 was repeated, except that the contents of the three-layered support sheet were changed as shown in Table 1.
A transfer sheet for molding was produced in the same manner as in Example 1. This change is achieved by adding a resin composition of the layer B as the surface layer 11 and the back layer 12 in the support sheet to 100 parts of isotactic homopolypropylene as a crystalline polypropylene resin by using a propylene copolymer having no stereoregularity. A resin composition containing 30 parts of a propylene- (1-hexene)-(4-methyl-1-pentene) copolymer (30/30/40) as a resin was prepared. The A layer serving as the intermediate layer 13 includes:
This is the same as the first embodiment. Note that the B layer (and the A layer) contains the same additives as in the first embodiment.

【００７０】〔実施例６〕図１（Ａ）の如き２層構成の
支持体シート１０を用いた成形用転写シートＳを、支持
体シートの内容を表１に示す如く変更した他は、実施例
１と同様にして成形用転写シートを作製した。該変更
は、支持体シート１０を、転写層と接する表層１１には
Ｂ層を用い、反対側の転写層に面しない裏層１２にはＡ
層を用いる２層構成として、Ｂ層及びＡ層の各内容は、
実施例１のＢ層及びＡ層とそれぞれ同じである。但し、
厚みは支持体シートの総厚１００μｍは同一のままとし
て、Ｂ層による表層１１は１０μｍ、Ａ層による裏層は
９０μｍとした。また、この２層構成の支持体シート
は、Ｔダイによる２層共押出法によって成膜と同時に積
層した積層体として用意した。Example 6 A transfer sheet S for molding using a two-layered support sheet 10 as shown in FIG. 1A was replaced with a transfer sheet S as shown in Table 1 except that the content of the support sheet was changed as shown in Table 1. A transfer sheet for molding was produced in the same manner as in Example 1. The change is that the support sheet 10 uses the layer B for the surface layer 11 in contact with the transfer layer and the layer A for the back layer 12 not facing the transfer layer on the opposite side.
As a two-layer configuration using layers, the contents of the B layer and the A layer are as follows:
This is the same as the B layer and the A layer of the first embodiment, respectively. However,
The thickness was 10 μm for the surface layer 11 of the B layer and 90 μm for the back layer of the A layer while keeping the total thickness of the support sheet 100 μm the same. The support sheet having the two-layer structure was prepared as a laminate which was simultaneously formed with a film by a two-layer coextrusion method using a T-die.

【００７１】〔比較例１〕支持体シートとして、実施例
１の支持体シートに於けるＢ層（中間層１３）のみの単
層の厚み１００μｍのシートを用意し、この支持体シー
トに実施例１と同様に転写層２０を形成して成形用転写
シートを作製した。[Comparative Example 1] As the support sheet, a single-layer 100 μm thick sheet of only the layer B (intermediate layer 13) in the support sheet of Example 1 was prepared. The transfer layer 20 was formed in the same manner as in Example 1 to prepare a transfer sheet for molding.

【００７２】〔真空成形転写方法での成形性評価〕被転
写体として、キッチンパネルの基材となる図７の如き断
面形状のＭＤＦ（中密度繊維板）を用意し、真空プレス
機による真空成形転写で、上記各成形用転写シートの性
能を評価した。被転写体Ｂの形状は、厚さ２０ｍｍ、縦
２５０ｍｍ、横１５０ｍｍの直方体状の板材で、上面
（図７で上方）及び各側面（４面）に転写した。上面と
側面、隣接する側面と側面の稜線（エッジ）は、断面が
曲率半径３ｍｍの円となる様に面取りをしてある。そし
て、真空成形転写は、上記被転写体の被転写面に水性ウ
レタン系接着剤をスプレー塗布（ウェット塗布量１００
ｇ／ｍ2 ）した後、８０℃に加温してから成形用転写シ
ートを転写した。なお、真空成形転写条件は、圧空圧力
０．４ＭＰａ、真空圧力（絶対圧）７３ｋＰａ（負圧７
００ｍｍＨｇ）、加温時間１５０秒とした。被転写体に
成形用転写シートを積層後、支持体シートを剥離して転
写後、更に、転写された転写層表面に、２液硬化型ウレ
タン樹脂塗料を後塗装して、図１０の断面図で示す如き
化粧材Ｄを作製した。ちなみに、同図の化粧材Ｄは、被
転写体Ｂ上に接着剤層４１を介して転写層２０が積層さ
れ、更にその上に上塗り層４２が積層された構成であ
る。[Evaluation of Formability by Vacuum Forming Transfer Method] An MDF (medium density fiberboard) having a cross-sectional shape as shown in FIG. In the transfer, the performance of each transfer sheet for molding was evaluated. The shape of the transfer object B was a rectangular parallelepiped plate material having a thickness of 20 mm, a length of 250 mm, and a width of 150 mm, and was transferred to the upper surface (upper in FIG. 7) and the side surfaces (four surfaces). The upper surface and the side surface and the adjacent side surface and the ridge line (edge) of the side surface are chamfered so that the cross section is a circle having a radius of curvature of 3 mm. In the vacuum forming transfer, the aqueous urethane-based adhesive is spray-coated (wet coating amount 100
g / m 2 ), heated to 80 ° C., and then transferred the transfer sheet for molding. The vacuum molding transfer conditions were as follows: compressed air pressure 0.4 MPa, vacuum pressure (absolute pressure) 73 kPa (negative pressure 7
00 mmHg) and the heating time was 150 seconds. After laminating the transfer sheet for molding on the transfer object, peeling off the support sheet and transferring, and further applying a two-component curable urethane resin paint on the surface of the transferred transfer layer, a cross-sectional view of FIG. The decorative material D as shown by was produced. Incidentally, the decorative material D shown in the figure has a configuration in which the transfer layer 20 is laminated on the transfer object B via the adhesive layer 41, and the overcoat layer 42 is further laminated thereon.

【００７３】そして、成形用転写シートの成形性を評価
したところ、表１の如き結果となった。すなわち、全実
施例（実施例１〜６）は良好、比較例１は不良となっ
た。また、各実施例で得られた化粧材は外観良好なキッ
チンパネルとなった。これに反して、比較例１の成形用
転写シートを用いた場合は、成形性不足の為に、転写層
が全ての被転写面に転写せず、外観不良の不良品となっ
た。When the moldability of the transfer sheet for molding was evaluated, the results were as shown in Table 1. That is, all the examples (Examples 1 to 6) were good, and Comparative Example 1 was bad. Further, the decorative material obtained in each example was a kitchen panel having a good appearance. On the other hand, when the transfer sheet for molding of Comparative Example 1 was used, the transfer layer was not transferred to all the transfer surfaces due to lack of moldability, resulting in a defective appearance.

【００７４】なお、成形性の評価基準は、被転写体の厚
み２０ｍｍの側面全面に成形用転写シートが追従したも
のは「良好」、側面全面に追従しないものは「不良」と
した。The evaluation criteria for formability were "good" when the transfer sheet for molding followed the entire side surface of the transfer object having a thickness of 20 mm was "good", and "bad" when the transfer sheet did not follow the entire side surface.

【００７５】[0075]

【表１】 [Table 1]

【００７６】[0076]

【表２】 [Table 2]

【００７７】表１に示す如く、成形性は全実施例（実施
例１〜６）は良好となったが、比較例１は、ネッキング
し易く不良であった。また、３層構成の実施例１〜５
は、転写シート取扱い中の反りも無かった。As shown in Table 1, the moldability was good in all Examples (Examples 1 to 6), but Comparative Example 1 was easy to neck and was poor. Examples 1 to 5 having a three-layer structure
No warpage during handling of the transfer sheet.

【００７８】〔剥離性の性能評価〕各成形用転写シート
の剥離性は基本的に転写方法にはよらず、表１に纏めて
示す。すなわち、全実施例（実施例１〜６）は、剥離強
度は適切な値で良好であったが、比較例１は、剥離強度
が小さすぎて（剥離が軽くて）箔落し易く、不良となっ
た。[Evaluation of Releasability Performance] The releasability of each transfer sheet for molding is basically shown in Table 1 without depending on the transfer method. That is, in all of the examples (Examples 1 to 6), the peel strength was an appropriate value and was good, but in Comparative Example 1, the peel strength was too small (the peel was light) and the foil was apt to fall off, resulting in a defect. became.

【００７９】なお、剥離性としての剥離強度の測定評価
は、各成形用転写シートを、４０℃の恒温槽中に２週間
放置後、図９の説明図で概念的に示す様な剥離角θ＝９
０度の剥離の剥離試験を行った。成形用転写シートＳ
は、その支持体シート１０側を両面粘着テープ（不図
示）によって厚さ３ｍｍ鉄板製の支持台３１に貼り付
け、転写層２０側に幅２５ｍｍのセロハン粘着テープ３
２〔ニチバン株式会社製、「セロテープ」（登録商
標）〕を貼り付け、少し剥がした末端を、引っ張り試験
機にて支持台３１面に垂直方向に引っ張って、剥離強度
を測定して評価した。The peel strength as a peeling property was measured and evaluated by leaving each transfer sheet for molding in a constant temperature bath at 40 ° C. for 2 weeks and then measuring the peel angle θ as conceptually shown in the explanatory view of FIG. = 9
A 0 degree peel test was performed. Transfer sheet S for molding
Is affixed to a 3 mm-thick iron plate support base 31 with a double-sided adhesive tape (not shown) on its support sheet 10 side, and a 25 mm wide cellophane adhesive tape 3 is attached to the transfer layer 20 side.
2 [Nippon Ban Co., Ltd., "Cellotape" (registered trademark)] was affixed, and the slightly peeled end was pulled in a direction perpendicular to the surface of the support 31 with a tensile tester, and the peel strength was measured to evaluate.

【００８０】〔固体粒子衝突圧による転写方法での成形
性評価〕また、成形性は、固体粒子衝突圧による転写方
法でも評価した。この評価では、被転写体としては、図
８の斜視図で示す如き形状の被転写体Ｂで、それは、厚
さ１５ｍｍのセメント系基材で、被転写面が直線溝状の
凹部を有する凹凸形状を成しており、溝状凹部の間口Ｌ
ｗが５ｍｍ、その深さＬｄが４ｍｍの基材である。な
お、斜面部の傾斜角は４５度である。[Evaluation of Formability by Transfer Method Using Solid Particle Impact Pressure] The moldability was also evaluated by the transfer method using solid particle impact pressure. In this evaluation, the transfer object was a transfer object B having a shape as shown in the perspective view of FIG. 8, which was a 15 mm-thick cement-based base material, and whose transfer surface had a linear groove-shaped recess. It has a shape and the width L of the groove-shaped recess
The base material has w of 5 mm and a depth Ld of 4 mm. In addition, the inclination angle of the slope is 45 degrees.

【００８１】転写は、この被転写体を予め、アクリルエ
マルション系のエナメル塗料によるベースコート層と、
その上に更に、アクリルポリオール（ガラス転移温度−
２０℃）１００部と１，６−ヘキサメチレンジイソシア
ネート５部とからなる２液硬化型ウレタン樹脂の接着剤
層を、スプレー塗装した。そして、上記被転写体のベー
スコート層及び接着剤層を加熱乾燥して（接着剤層の２
液硬化型ウレタン樹脂は完全硬化前）、被転写体の上
に、前記成形用転写シートを、その転写層側を被転写体
側に向ける様にして載せて、被転写体表面温度を１００
℃に加熱した状態で、支持体シートの裏面側に固体粒子
を衝突させて衝突圧を転写圧として与えて、成形用転写
シートを被転写体に圧接し、その凹凸面に追従させる様
に試みた。なお、固体粒子としては５０℃に予熱された
平均粒径０．４ｍｍの球形の亜鉛球を用い、噴出器には
図４及び図５の様な羽根車を用いた噴出器を使用した。
固体粒子の噴出速度は３５ｍ／ｓとした。そして、固体
粒子の衝突終了後、２５℃の冷風で冷却して、熱融着で
成形用転写シートが被転写体に接着した後、支持体シー
トを剥離角（但し、被転写体の天面部５１から測った角
度）θ＝８０°で剥がし取って、転写層のみを被転写体
側に移行させて、転写を完了させた。In the transfer, the transferred body is previously coated with a base coat layer of an acrylic emulsion-based enamel paint,
On top of that, an acrylic polyol (glass transition temperature-
(20 ° C) An adhesive layer of a two-part curable urethane resin consisting of 100 parts and 5 parts of 1,6-hexamethylene diisocyanate was spray-coated. Then, the base coat layer and the adhesive layer of the transfer object are dried by heating (2 of the adhesive layer).
Before the liquid-curable urethane resin is completely cured), the transfer sheet for molding is placed on the object to be transferred such that the transfer layer side faces the object to be transferred, and the surface temperature of the object to be transferred is 100%.
In the state of heating to ℃, the solid particles collide against the back side of the support sheet, and the collision pressure is given as the transfer pressure, and the molding transfer sheet is pressed against the transfer object and attempts to follow the uneven surface. Was. Note that, as the solid particles, spherical zinc spheres having an average particle diameter of 0.4 mm preheated to 50 ° C. were used, and as the ejector, an ejector using an impeller as shown in FIGS. 4 and 5 was used.
The ejection speed of the solid particles was 35 m / s. After the collision of the solid particles is completed, the molding sheet is cooled with cold air at 25 ° C., and the transfer sheet for molding is adhered to the transfer object by heat fusion. (The angle measured from 51) θ = 80 °, and only the transfer layer was moved to the transfer-receiving body side to complete the transfer.

【００８２】この結果、成形性は表１に示す評価結果と
同様に、全実施例（実施例１〜６）は良好、比較例１で
は不良となった。なお、評価は、溝内等各部に転写層が
転写されたものは良好、溝角や溝の底部で転写層が浮く
「転写浮き」が発生したのもは不良とした。As a result, the moldability was good in all Examples (Examples 1 to 6) and poor in Comparative Example 1, as in the evaluation results shown in Table 1. In the evaluation, those in which the transfer layer was transferred to various portions such as the inside of the groove were good, and those in which "transfer floating" in which the transfer layer floated at the groove angle or the bottom of the groove were poor.

【００８３】〔弾性体ローラによる転写方法での成形性
評価〕また、成形性は、弾性体ローラによる転写方法で
も評価した。この評価では、被転写体としては、固体粒
子衝突圧による転写方法で用いた被転写体に対して、溝
状凹部の間口Ｌｗを２０ｍｍとして、その深さＬｄが４
ｍｍとした被転写体を用いた。なお、斜面部の傾斜角は
４５度のままである。この被転写体の下地処理は、固体
粒子衝突圧による転写方法の場合と同様である。そし
て、弾性体ローラとしては、鉄芯の周囲をシリコーンゴ
ムで被覆して表面の硬度をＪＩＳで規定するゴム硬度３
５°とした直径１０ｃｍの加圧ローラを表面温度１００
℃に加熱したものを用いた。なお、転写の方向は被転写
体の溝の走行方向と一致させた。この結果、成形性は、
全実施例（実施例１〜６）は良好であったが、比較例１
では不良となった。なお、成形性評価基準は前述の固体
粒子衝突圧による転写方法の場合と同様である。[Evaluation of Formability by Transfer Method Using Elastic Roller] The formability was also evaluated by the transfer method using an elastic roller. In this evaluation, the width Lw of the groove-shaped concave portion was set to 20 mm, and the depth Ld was set to 4 mm with respect to the transferred material used in the transfer method using the solid particle collision pressure.
The transfer object having a thickness of 1 mm was used. The inclination angle of the slope remains at 45 degrees. The base treatment of the transfer object is the same as in the case of the transfer method using solid particle collision pressure. For the elastic roller, the periphery of the iron core is covered with silicone rubber, and the hardness of the surface is set to a rubber hardness of 3 defined by JIS.
A pressure roller with a diameter of 10 cm and a surface temperature of 100
What was heated to ° C was used. The transfer direction was made to coincide with the running direction of the groove of the transfer object. As a result, the moldability is
All Examples (Examples 1 to 6) were good, but Comparative Example 1
Then it became bad. The moldability evaluation criteria are the same as in the case of the above-described transfer method using solid particle collision pressure.

【００８４】〔評価総括〕以上の結果、各実施例（実施
例１〜６）の成形用転写シートのみが、成形性と剥離性
の両方が両立できるものである事が分かる。[Evaluation Summary] From the above results, it can be seen that only the transfer sheet for molding of each of the examples (Examples 1 to 6) is compatible with both moldability and releasability.

【００８５】[0085]

【発明の効果】本発明の成形用転写シートによれば、
成形性と剥離性とが両立する。また、転写層に接するＢ
層に於いて立体規則性の無いプロピレン共重合体樹脂に
特定樹脂を使用すれば、確実に上記効果が得られる。そ
して、支持体シートが３層構成の形態では、耐ブロッキ
ング性にも優れる上、製造時、保存時、使用時等に於い
てカール発生を防げる。 本発明の転写方法では、固体粒子衝突圧による転写圧
を用いる形態では、弾性体ローラを用いる転写方法では
不可能な様な深い凹凸面でも転写抜け等の転写不良無し
に確実に且つ容易に転写できる。その結果、高意匠の化
粧材等の転写製品を容易に製造できる。 また、本発明の転写方法にて、弾性体ローラによる転
写圧を用いる形態では、比較的平坦に近い凹凸面に対し
て、容易に転写できる。According to the transfer sheet for molding of the present invention,
Both moldability and peelability are compatible. In addition, B in contact with the transfer layer
If the specific resin is used as the propylene copolymer resin having no stereoregularity in the layer, the above-mentioned effects can be surely obtained. When the support sheet has a three-layer structure, it has excellent blocking resistance and can prevent curling during production, storage, use, and the like. In the transfer method of the present invention, when the transfer pressure by the solid particle collision pressure is used, the transfer is reliably and easily performed without transfer defects such as transfer omission even on a deep uneven surface that is impossible with the transfer method using the elastic roller. it can. As a result, it is possible to easily manufacture a transfer product such as a high-design decorative material. In the transfer method of the present invention, when the transfer pressure by the elastic roller is used, the transfer can be easily performed on a relatively flat uneven surface.

【図面の簡単な説明】[Brief description of the drawings]

【図１】本発明の成形用転写シートの形態例を示す断面
図。FIG. 1 is a sectional view showing an embodiment of a transfer sheet for molding of the present invention.

【図２】固体粒子衝突圧による転写圧で転写する転写方
法を説明する概念図。FIG. 2 is a conceptual diagram illustrating a transfer method for transferring with a transfer pressure by a solid particle collision pressure.

【図３】弾性体ローラによる転写圧で転写する転写方法
を説明する概念図。FIG. 3 is a conceptual diagram illustrating a transfer method for performing transfer with a transfer pressure by an elastic roller.

【図４】固体粒子を噴出させる為の、羽根車を用いた噴
出器の一例を概念的に説明する斜視図。FIG. 4 is a perspective view conceptually illustrating an example of an ejector using an impeller for ejecting solid particles.

【図５】図４の羽根車内部を説明する概念図。FIG. 5 is a conceptual diagram illustrating the inside of the impeller of FIG. 4;

【図６】吹出ノズルによる噴出器の一例を概念的に説明
する断面図。FIG. 6 is a cross-sectional view conceptually illustrating an example of an ejector using an ejection nozzle.

【図７】真空成形転写方法での成形性評価に用いた被転
写体の凹凸形状を示す断面図。FIG. 7 is a cross-sectional view showing a concave-convex shape of a transferred body used for evaluation of formability by a vacuum forming transfer method.

【図８】固体粒子衝突圧による転写方法での成形性評価
に用いた被転写体の凹凸形状を示す斜視図。FIG. 8 is a perspective view showing a concave-convex shape of an object to be transferred used for evaluation of formability by a transfer method using solid particle collision pressure.

【図９】剥離強度の測定方法を概念的に説明する説明
図。FIG. 9 is an explanatory view conceptually illustrating a method of measuring peel strength.

【図１０】真空成形転写方法で得た化粧材を示す断面
図。FIG. 10 is a sectional view showing a decorative material obtained by a vacuum forming transfer method.

【符号の説明】[Explanation of symbols]

１０ 支持体シート １１ 表層（Ｂ層） １２ 裏層（２層構成：Ａ層、３層構成：Ｂ層） １３ 中間層（Ａ層） ２０ 転写層 ３１ 支持台 ３２ セロハン粘着テープ ４１ 接着剤層 ４２ 上塗り層 ５１ 被転写体の天面部 ８１２ 羽根車 ８１３ 羽根 ８１４ 側面板 ８１５ 中空部 ８１６ 方向制御器 ８１７ 開口部 ８１８ 散布器 ８１９ 回転軸 ８２０ 軸受 ８４０ 吹出ノズルを用いた噴出器 ８４１ 誘導室 ８４２ 内部ノズル ８４３ ノズル開口部 ８４４ ノズル Ｂ 被転写体 Ｄ 転写製品（化粧板等） Ｆ 流体 Ｌｗ 間口 Ｌｄ 深さ Ｐ 固体粒子 Ｓ 成形用転写シート DESCRIPTION OF SYMBOLS 10 Support sheet 11 Surface layer (B layer) 12 Back layer (2 layer structure: A layer, 3 layer structure: B layer) 13 Intermediate layer (A layer) 20 Transfer layer 31 Support base 32 Cellophane adhesive tape 41 Adhesive layer 42 Top coating layer 51 Top surface portion of transferred object 812 Impeller 813 Blade 814 Side plate 815 Hollow portion 816 Direction controller 817 Opening 818 Sprayer 819 Rotating shaft 820 Bearing 840 Sprayer using blowing nozzle 841 Induction chamber 842 Internal nozzle 843 Nozzle opening 844 Nozzle B Transfer object D Transfer product (decorative board etc.) F Fluid Lw Frontage Ld Depth P Solid particles S Transfer sheet for molding

Claims (5)

【特許請求の範囲】[Claims] 【請求項１】 支持体シートに転写層を設けた成形用の
転写シートにおいて、 支持体シートが、少なくとも、エチレン−プロピレンラ
ンダム共重合体からなるＡ層と、結晶性ポリプロピレン
樹脂と立体規則性の無いプロピレン共重合体樹脂とを混
合した樹脂組成物からなるＢ層とからなり、該Ｂ層上に
転写層が積層されてなる、成形用転写シート。1. A transfer sheet for molding in which a transfer layer is provided on a support sheet, wherein the support sheet has at least an A layer comprising an ethylene-propylene random copolymer, a crystalline polypropylene resin and a stereoregularity. A transfer sheet for molding, comprising: a layer B made of a resin composition obtained by mixing a propylene copolymer resin with no transfer layer; and a transfer layer laminated on the layer B. 【請求項２】 立体規則性の無いプロピレン共重合体樹
脂が、プロピレン−エチレン共重合体、プロピレン−
（１−ブテン）共重合体、プロピレン−（１−ブテン）
−エチレン三元共重合体、プロピレン−（１−ヘキセ
ン）−（１−オクテン）三元共重合体、プロピレン−
（１−ヘキセン）−（４−メチル−１−ペンテン）三元
共重合体のうちの１種又は２種以上の混合樹脂である、
請求項１記載の成形用転写シート。2. The propylene copolymer resin having no stereoregularity is a propylene-ethylene copolymer, propylene-
(1-butene) copolymer, propylene- (1-butene)
-Ethylene terpolymer, propylene- (1-hexene)-(1-octene) terpolymer, propylene-
(1-hexene)-(4-methyl-1-pentene) is a terpolymer, and is a mixed resin of one or more kinds.
The transfer sheet for molding according to claim 1. 【請求項３】 支持体シートが、Ｂ層を外側の表層及び
裏層にしＡ層を内部の中間層にした、Ｂ層／Ａ層／Ｂ層
からなる３層構成である、請求項１又は２記載の成形用
転写シート。3. The support sheet according to claim 1, wherein the support sheet has a three-layer structure of B layer / A layer / B layer in which the B layer is an outer surface layer and a back layer, and the A layer is an inner intermediate layer. 3. The transfer sheet for molding according to 2. 【請求項４】 請求項１〜３のいずれか１項に記載の成
形用転写シートを用い、固体粒子衝突圧による転写圧で
転写する転写方法。4. A transfer method using the transfer sheet for molding according to any one of claims 1 to 3, wherein the transfer is performed at a transfer pressure by a solid particle collision pressure. 【請求項５】 請求項１〜３のいずれか１項に記載の成
形用転写シートを用い、弾性体ローラによる転写圧で転
写する転写方法。5. A transfer method using the transfer sheet for molding according to claim 1, wherein the transfer is performed by transfer pressure using an elastic roller.
JP29364299A 1999-10-15 1999-10-15 Transfer sheet for molding and transferring method using the same Pending JP2001113888A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29364299A JP2001113888A (en) 1999-10-15 1999-10-15 Transfer sheet for molding and transferring method using the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29364299A JP2001113888A (en) 1999-10-15 1999-10-15 Transfer sheet for molding and transferring method using the same

Publications (1)

Publication Number Publication Date
JP2001113888A true JP2001113888A (en) 2001-04-24

Family

ID=17797367

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29364299A Pending JP2001113888A (en) 1999-10-15 1999-10-15 Transfer sheet for molding and transferring method using the same

Country Status (1)

Country Link
JP (1) JP2001113888A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008120633A1 (en) * 2007-03-30 2008-10-09 Dai Nippon Printing Co., Ltd. Transfer decorative sheet, process for producing decorated molded product, and decorated molded product
WO2010033488A3 (en) * 2008-09-19 2010-06-24 Barton Nelson, Inc. Method of producing solid decorated graphic arts objects
JP2013126740A (en) * 2011-12-19 2013-06-27 Okura Ind Co Ltd Transfer base film
JP2013126741A (en) * 2011-12-19 2013-06-27 Okura Ind Co Ltd Transfer base film with support layer, method of film forming the same, and method of decorating the molding using the same
JP2013251271A (en) * 2007-03-30 2013-12-12 Dainippon Printing Co Ltd Catalyst layer transfer film

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2133201A4 (en) * 2007-03-30 2013-01-02 Dainippon Printing Co Ltd Transfer decorative sheet, process for producing decorated molded product, and decorated molded product
JP2008247011A (en) * 2007-03-30 2008-10-16 Dainippon Printing Co Ltd Transfer decorative sheet, method for manufacturing decorative molded product, and decorative molded product
EP2133201A1 (en) * 2007-03-30 2009-12-16 Dai Nippon Printing Co., Ltd. Transfer decorative sheet, process for producing decorated molded product, and decorated molded product
CN101631674A (en) * 2007-03-30 2010-01-20 大日本印刷株式会社 Transfer decorative sheet, process for producing decorated molded product, and decorated molded product
WO2008120633A1 (en) * 2007-03-30 2008-10-09 Dai Nippon Printing Co., Ltd. Transfer decorative sheet, process for producing decorated molded product, and decorated molded product
US8535788B2 (en) 2007-03-30 2013-09-17 Dai Nippon Printing Co., Ltd. Transfer decorative sheet, process for producing decorated molded product, and decorated molded product
JP2013251271A (en) * 2007-03-30 2013-12-12 Dainippon Printing Co Ltd Catalyst layer transfer film
CN101631674B (en) * 2007-03-30 2014-07-16 大日本印刷株式会社 Transfer decorative sheet, process for producing decorated molded product, and decorated molded product
KR101436667B1 (en) * 2007-03-30 2014-09-01 다이니폰 인사츠 가부시키가이샤 Transfer decorative sheet, process for producing decorated molded product, and decorated molded product
WO2010033488A3 (en) * 2008-09-19 2010-06-24 Barton Nelson, Inc. Method of producing solid decorated graphic arts objects
US8187403B2 (en) 2008-09-19 2012-05-29 Barton Nelson, Inc. Method of producing solid decorated graphic arts objects
JP2013126740A (en) * 2011-12-19 2013-06-27 Okura Ind Co Ltd Transfer base film
JP2013126741A (en) * 2011-12-19 2013-06-27 Okura Ind Co Ltd Transfer base film with support layer, method of film forming the same, and method of decorating the molding using the same

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