JP2000510175A - エチレン、α―オレフィン及びジエンのターポリマーを調製する方法 - Google Patents

エチレン、α―オレフィン及びジエンのターポリマーを調製する方法

Info

Publication number
JP2000510175A
JP2000510175A JP09539794A JP53979497A JP2000510175A JP 2000510175 A JP2000510175 A JP 2000510175A JP 09539794 A JP09539794 A JP 09539794A JP 53979497 A JP53979497 A JP 53979497A JP 2000510175 A JP2000510175 A JP 2000510175A
Authority
JP
Japan
Prior art keywords
group
transition metal
ligand
groups
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP09539794A
Other languages
English (en)
Japanese (ja)
Inventor
レンケマ，ヤコブ
トル，マウリツ，フレデリック，ヘンドリック ファン
ウィンドミューラー，ペーター，ヨゼフ，フベルト
ベーク，ヨハネス，アントニウス，マリア ファン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke DSM NV
Original Assignee
DSM NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DSM NV filed Critical DSM NV
Publication of JP2000510175A publication Critical patent/JP2000510175A/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
JP09539794A 1996-05-03 1997-05-01 エチレン、α―オレフィン及びジエンのターポリマーを調製する方法 Pending JP2000510175A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP96201112 1996-05-03
EP96201112.8 1996-05-03
PCT/NL1997/000244 WO1997042239A1 (en) 1996-05-03 1997-05-01 PROCESS FOR THE PREPARATION OF A TERPOLYMER OF ETHYLENE, AN α-OLEFIN AND A DIENE

Publications (1)

Publication Number Publication Date
JP2000510175A true JP2000510175A (ja) 2000-08-08

Family

ID=8223921

Family Applications (1)

Application Number Title Priority Date Filing Date
JP09539794A Pending JP2000510175A (ja) 1996-05-03 1997-05-01 エチレン、α―オレフィン及びジエンのターポリマーを調製する方法

Country Status (9)

Country Link
EP (1) EP0896597A1 (id)
JP (1) JP2000510175A (id)
KR (1) KR20000010950A (id)
AU (1) AU2412097A (id)
BR (1) BR9708891A (id)
CA (1) CA2253514A1 (id)
EA (1) EA199800975A1 (id)
ID (1) ID16858A (id)
WO (1) WO1997042239A1 (id)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6294495B1 (en) 1998-05-01 2001-09-25 Exxonmobil Chemicals Patent Inc. Tridentate ligand-containing metal catalyst complexes for olefin polymerization
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
KR100826080B1 (ko) * 2001-12-27 2008-04-29 삼성토탈 주식회사 고용융체 강도를 갖는 에틸렌/디엔 공중합체의 제조방법
KR100501398B1 (ko) * 2003-01-15 2005-07-18 삼성토탈 주식회사 긴가지를 갖는 α-올레핀/환상올레핀/디엔 공중합체 및 그제조방법
KR100586922B1 (ko) * 2004-11-18 2006-06-08 금호폴리켐 주식회사 고수율의 이피(디)엠의 제조방법 및 수율의 제어방법,이피(디)엠의 회수방법
KR101829222B1 (ko) 2011-02-15 2018-02-19 엘지전자 주식회사 냉장고
KR101248423B1 (ko) * 2011-06-09 2013-04-02 에스케이종합화학 주식회사 에틸렌 - α-올레핀 - 디엔 공중합체의 제조방법
KR101391693B1 (ko) 2012-11-14 2014-05-07 주식회사 엘지화학 3원계 탄성 공중합체 및 이의 제조 방법
KR101391692B1 (ko) * 2012-11-14 2014-05-07 주식회사 엘지화학 3원계 탄성 공중합체 및 이의 제조 방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1327673C (en) * 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
JPH10508055A (ja) * 1994-10-31 1998-08-04 ディーエスエム エヌ．ブイ． オレフィン重合用触媒組成物及びオレフィン重合法

Also Published As

Publication number Publication date
CA2253514A1 (en) 1997-11-13
EP0896597A1 (en) 1999-02-17
AU2412097A (en) 1997-11-26
EA199800975A1 (ru) 1999-04-29
WO1997042239A1 (en) 1997-11-13
BR9708891A (pt) 1999-08-03
KR20000010950A (ko) 2000-02-25
ID16858A (id) 1997-11-20

Similar Documents

Publication Publication Date Title
KR101685662B1 (ko) 폴리올레핀의 제조 방법 및 이로부터 제조된 폴리올레핀
JPH10508055A (ja) オレフィン重合用触媒組成物及びオレフィン重合法
JP6499280B2 (ja) メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法
KR101927460B1 (ko) 혼성 담지 촉매 및 이를 이용하는 올레핀 중합체의 제조 방법
CN111051366A (zh) 双功能催化剂组合物
WO2014061921A1 (ko) 신규한 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀계 중합체의 제조방법
JP2000513761A (ja) 官能性ポリオレフィンの製造法
US6479646B1 (en) Metallocene compounds having indenyl ligand and catalysts for olefin polymerization containing the same
JP2000510175A (ja) エチレン、α―オレフィン及びジエンのターポリマーを調製する方法
JP2000509742A (ja) α―オレフィンの重合法
JP2000509741A (ja) エチレンおよびα―オレフィンコポリマーの製造法
JP2002037795A (ja) インデニル配位子を有するメタロセン化合物およびこれを含むオレフィン重合用触媒
KR100958676B1 (ko) 이핵으로 구속된 배열을 갖는 균일계 촉매의 합성방법 및이를 이용하여 제조한 선형알파올레핀 공중합체
JP4607289B2 (ja) インデニル化合物、その配位子前駆物質、配位子前駆物質の製造法およびオレフィンの重合法
JP2000509740A (ja) オレフィンモノマー重合のための担持触媒組成物および方法
WO2016195424A1 (ko) 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법
KR100770291B1 (ko) 다핵으로 연결된 전이금속 화합물 촉매 및 이를 이용한중합체 제조방법
WO1997042237A1 (en) A process for making polyolefins having broad molecular weight distributions
JP2000513760A (ja) オレフィンおよびビニル芳香族モノマーの共重合法
KR102092271B1 (ko) 전이금속 화합물 및 이를 포함하는 촉매 조성물
WO1997042235A1 (en) Process for the production of polymers containing cyclic olefins
WO1997042238A1 (en) Inverted polyolefin copolymers
MXPA98009115A (en) Procedure for the co-polymerization of an olefine and an aromat vinyl monomer