JP2000107708A - Method for removing electrolyte - Google Patents
Method for removing electrolyteInfo
- Publication number
- JP2000107708A JP2000107708A JP10286190A JP28619098A JP2000107708A JP 2000107708 A JP2000107708 A JP 2000107708A JP 10286190 A JP10286190 A JP 10286190A JP 28619098 A JP28619098 A JP 28619098A JP 2000107708 A JP2000107708 A JP 2000107708A
- Authority
- JP
- Japan
- Prior art keywords
- cleaning
- electrolytic solution
- liquid
- electrolytic
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Cleaning By Liquid Or Steam (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、電解処理したワー
ク、例えば、電解バリ取り処理したワークに付着してい
る電解液を除去するための洗浄方法の改良に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improvement in a cleaning method for removing an electrolytic solution adhered to an electrolytically treated work, for example, a work subjected to electrolytic deburring.
【０００２】[0002]
【従来の技術】従来、電解バリ取り処理したワークを次
工程に移行させるとき、使用した電解液が付着して持ち
出されるので、これを除去するために、２段または多段
洗浄槽の洗浄水で水洗する向流水洗処理が多く利用され
ている。１例を図示すると、図２に示すように電解バリ
取り槽７１で処理されたワークは、実線矢印で示すよう
に、第１水洗槽７２ａで持ち込まれた電解液を水洗、除
去した後、第２水洗槽７２ｂで濯ぎ水洗する。次いで、
防錆処理槽７３で防錆液に浸漬してから乾燥装置７４に
よって乾燥され一連の工程が完了する。2. Description of the Related Art Conventionally, when a work subjected to electrolytic deburring is transferred to the next step, the used electrolyte adheres and is taken out. To remove this, use washing water in a two-stage or multi-stage washing tank. The countercurrent washing process for washing is often used. As shown in FIG. 2, the work treated in the electrolytic deburring tank 71 as shown in FIG. 2 is used to wash and remove the electrolyte brought in the first washing tank 72a as shown by the solid line arrow, (2) Rinse in the washing tank 72b and wash with water. Then
After being immersed in the rust preventive liquid in the rust preventive treatment tank 73, it is dried by the drying device 74 to complete a series of steps.
【０００３】そして、この水洗方法では、水洗槽の洗浄
水は電解液で汚染されるため、用済み洗浄水をそのまま
放出することができず、浄化処理槽７５にて排水浄化処
理を行う必要があった。また、用済み洗浄水をリサイク
ルしようとするときには、イオン交換装置（図示せず）
などによって清浄水を回収したり、電解液のリサイクル
のためには、洗浄水で希釈された濃度を復元させるため
特殊な濃縮回収装置（図示せず）などが必要であった。In this washing method, since the washing water in the washing tank is contaminated with the electrolytic solution, the used washing water cannot be discharged as it is, and it is necessary to perform the wastewater purification treatment in the purification treatment tank 75. there were. When recycling used washing water, an ion exchange device (not shown) is used.
For example, in order to recover clean water or recycle the electrolytic solution, a special concentration / recovery device (not shown) or the like is required to restore the concentration diluted with the cleaning water.
【０００４】なお、ワークの材質が鉄系の場合には、前
記洗浄水による水洗処理のみでは錆が生じやすいため、
上記のように防錆処理を行い、かつ迅速に水分を取り除
くため加熱乾燥処理が必要であるため、処理工数を要す
るほか、熱エネルギーコストがかかるという問題があっ
た。[0004] When the work is made of an iron-based material, rust is liable to be generated only by the washing treatment with the washing water.
As described above, a heat drying treatment is required to perform the rust prevention treatment and to quickly remove moisture, so that there is a problem that a processing man-hour is required and a heat energy cost is required.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、上記の問題
点を解決するためになされたものであり、電解処理した
ワークから電解液を除去するにあたり、排水浄化処理、
防錆処理、加熱乾燥処理を不必要とする電解液の除去方
法を提供する。さらに、洗浄液と除去した電解液を容易
に個別に回収して再利用できる電解液の除去方法をも提
供する。SUMMARY OF THE INVENTION The present invention has been made in order to solve the above-mentioned problems, and in removing an electrolytic solution from an electrolytically treated work, a wastewater purifying treatment,
Provided is a method for removing an electrolytic solution which does not require rust prevention treatment and heat drying treatment. Further, the present invention also provides a method for removing an electrolytic solution in which a cleaning liquid and a removed electrolytic solution can be easily collected and reused.
【０００６】[0006]
【課題を解決するための手段】上記の問題を解決した本
発明の電解液の除去方法は、電解液中にて電解処理した
ワークを、界面活性剤を含み、かつ電解液との比重差を
有し、水との相溶性に乏しい水切り乾燥溶剤からなる洗
浄液に浸漬し、超音波を照射しながら付着していた電解
液をワークから分離、除去することを特徴とするもので
ある。According to the present invention, there is provided a method for removing an electrolytic solution, comprising the steps of: removing a work which has been subjected to electrolytic treatment in an electrolytic solution, containing a surfactant and reducing a specific gravity difference from the electrolytic solution; It is characterized in that it is immersed in a cleaning solution made of a draining dry solvent having poor compatibility with water, and the attached electrolytic solution is separated and removed from the work while irradiating ultrasonic waves.
【０００７】そして、本発明は次の形態に具体化するこ
ともできる。 （１）ＨＦＥおよびＨＦＣなどのフッ素系不活性液体、
または炭化水素系液体からなる水切り乾燥溶剤にアニオ
ン系界面活性剤を１重量％以下含有させた洗浄液を用い
る電解液の除去方法。 （２）洗浄液側に移行した電解液を比重差を利用して分
離して、電解処理工程に返送するとともに、電解液を分
離した洗浄液を再利用する電解液の除去方法。The present invention can be embodied in the following modes. (1) fluorinated inert liquids such as HFE and HFC,
Alternatively, a method of removing an electrolytic solution using a cleaning liquid containing an anionic surfactant in a dry solvent of a hydrocarbon-based liquid and containing 1% by weight or less of an anionic surfactant. (2) A method of removing an electrolytic solution which separates the electrolytic solution transferred to the cleaning solution side by utilizing a difference in specific gravity, returns the separated electrolytic solution to the electrolytic treatment step, and reuses the cleaning solution from which the electrolytic solution has been separated.
【０００８】[0008]
【発明の実施の形態】次に、本発明の電解液の除去方法
に用いられる電解液の除去装置を示す原理図である図１
を参照しながら、本発明をさらに説明する。図１におい
て、この電解液の除去装置では、電解バリ取り処理など
の電解処理を行うための電解処理槽１と、電解処理され
たワークを洗浄して付着した電解液を除去するための第
１洗浄槽２と第２洗浄槽３とを連結した洗浄槽と、洗浄
液側に移行した電解液を洗浄液から分離して回収するた
めの電解液回収槽４とを備えている。FIG. 1 is a principle diagram showing an electrolytic solution removing apparatus used in the electrolytic solution removing method of the present invention.
The present invention will be further described with reference to FIG. In FIG. 1, the electrolytic solution removing apparatus includes an electrolytic treatment tank 1 for performing an electrolytic treatment such as an electrolytic deburring treatment, and a first electrolytic treatment tank for cleaning an electrolytically treated work and removing an attached electrolytic solution. The washing tank includes a washing tank in which the washing tank 2 and the second washing tank 3 are connected to each other, and an electrolytic solution collecting tank 4 for separating and collecting the electrolytic solution transferred to the washing liquid from the washing liquid.
【０００９】ここで、本発明の電解液の除去方法は、図
１の一点鎖線の経路で示すように、電解処理槽１の電解
液１１中にて電解処理したワークを取り出し、第１洗浄
槽２に移動させて、この第１洗浄槽２に溜められている
特定の洗浄液２１にて、電解処理槽１からワークに付着
して持ち込まれた電解液１１をワークから分離、除去す
るものであり、必要に応じて、さらに第２洗浄槽３の同
様な洗浄液３１にて濯ぎ洗浄する方法である。Here, in the electrolytic solution removing method of the present invention, as shown by a dashed line in FIG. 1, a work which has been subjected to electrolytic treatment in the electrolytic solution 11 of the electrolytic treatment tank 1 is taken out, and the first cleaning tank is removed. 2 to separate and remove the electrolytic solution 11 adhered to the work from the electrolytic treatment tank 1 and brought into the work with the specific cleaning solution 21 stored in the first wash tank 2. This is a method of rinsing and cleaning with a similar cleaning liquid 31 in the second cleaning tank 3 if necessary.
【００１０】そして、本発明の第１の要件は、この洗浄
液２１として、界面活性剤を含み、かつ電解液との比重
差を有し、水との相溶性に乏しい水切り乾燥溶剤を用い
るところにある。ここでこの水切り乾燥溶剤には、洗浄
対象の電解液との比重差を有し、水との相溶性に乏しい
という要件に合うものとして、ＨＦＥおよびＨＦＣなど
のフッ素系不活性液体、または炭化水素系液体などを応
用するのが好適である。[0010] The first requirement of the present invention is that a draining dry solvent containing a surfactant, having a specific gravity difference from an electrolytic solution, and poor in compatibility with water is used as the cleaning solution 21. is there. Here, the draining dry solvent has a specific gravity difference with respect to the electrolytic solution to be washed, and meets the requirement of poor compatibility with water, such as a fluorine-based inert liquid such as HFE and HFC, or a hydrocarbon. It is preferable to apply a system liquid or the like.
【００１１】例えば、ＨＦＥは、ハイドロフルオロエー
テルの略称であり、化学式C4F9OCH3またはC4F9OC2H5 で
表されるフッ素系不活性液体であり、表面張力や粘性が
低く、固体材料との濡れ性にすぐれ、水との相溶性はほ
とんどなく、また熱的、化学的に安定でオゾン破壊係数
が０で実用上無害という性能の溶剤である。また、ＨＦ
Ｃは化学式C5H2F10 で示されるフッ素系不活性液体であ
って、ＨＦＥと同様な溶剤として用いられ得る。また、
これらフッ素系不活性液体は、比重が水より大であるケ
ースであるが、比重が水より小さい水切り乾燥溶剤とし
て応用される炭化水素系液体は、具体的には、比重が
０．７〜０．８程度の精製ノルマルパラフィンの単一成
分を主成分とした洗浄液が適当である。これらは引火点
が高く、乾燥性に優れ、蒸留再生がし易く液組成が変化
しにくいという性能の溶剤であり、前記ハイドロフルオ
ロエーテルと同様に利用できる。For example, HFE is an abbreviation for hydrofluoroether and is a fluorine-based inert liquid represented by the chemical formula C 4 F 9 OCH 3 or C 4 F 9 OC 2 H 5 and has a low surface tension and low viscosity. It has excellent wettability with solid materials, has almost no compatibility with water, is thermally and chemically stable, has an ozone destruction coefficient of 0, and is practically harmless. Also, HF
C is a fluorine-based inert liquid represented by the chemical formula C 5 H 2 F 10 and can be used as a solvent similar to HFE. Also,
These fluorinated inert liquids have a specific gravity greater than that of water, but hydrocarbon-based liquids used as drainage drying solvents having a specific gravity smaller than water specifically have a specific gravity of 0.7 to 0. A cleaning solution containing a single component of about 0.8 purified normal paraffin as a main component is suitable. These are solvents having a high flash point, an excellent drying property, a property of being easily regenerated by distillation, and a property of a liquid composition that is hard to change, and can be used in the same manner as the above-mentioned hydrofluoroether.
【００１２】次に第２の要件は、前記水切り乾燥溶剤に
適量の界面活性剤を添加して洗浄液とする点にある。こ
の場合、アニオン系界面活性剤を１重量％以下含有させ
るのが適当である。また、このような洗浄液は、洗浄効
率を高めるため加温するのが好ましい。洗浄液に前記Ｈ
ＦＥを応用するときには、その沸点、またはその近傍の
温度まで加温し洗浄液の活性を高めておくのが特に好ま
しい。Next, the second requirement is that an appropriate amount of a surfactant is added to the draining and drying solvent to obtain a cleaning solution. In this case, it is appropriate to contain 1% by weight or less of an anionic surfactant. Further, it is preferable that such a cleaning liquid is heated to increase the cleaning efficiency. H
When FE is applied, it is particularly preferable to increase the activity of the cleaning solution by heating to the temperature at or near the boiling point.
【００１３】本発明では、このように洗浄液には界面活
性剤を含ませているので、ワークを洗浄液から取り出し
た際に、液が滑らかに流れ落ちて液滴が残りにくいとい
う、いわゆる液切り作用を奏するとともに、洗浄処理後
のワークの発錆を防止する効果が得られる。従って、従
来の洗浄水による場合に必要であった防錆処理工程が不
要となる顕著な利点が得られるのである。In the present invention, since the cleaning liquid contains the surfactant, when the work is taken out from the cleaning liquid, the liquid flows smoothly and the liquid drops hardly remain. As well as playing, the effect of preventing rusting of the work after the cleaning process is obtained. Therefore, a remarkable advantage is obtained in that the rust prevention treatment step which was required in the case of the conventional washing water is not required.
【００１４】このアニオン系界面活性剤の添加量は、
０．２５％程度でも相当な効果が得られるが、１％を超
過しても液切り効果に顕著な改善は見られなかった。ま
た、この洗浄処理による防錆効果を、市販の水性防錆剤
で処理した場合と比較したが、市販品の場合は放置３日
で発錆が観察されたが、本発明の場合には発錆は放置２
週間後であり、十分な防錆効果が認められた。なお、こ
の界面活性剤はワークに付着して持ち出されるので、逐
次に補充してその濃度を維持するようにするのがよい。The amount of the anionic surfactant added is:
Even at about 0.25%, a considerable effect can be obtained, but even if it exceeds 1%, no significant improvement in the draining effect is observed. The rust-preventing effect of this washing treatment was compared with the case of treatment with a commercially available water-based rust-preventive agent. In the case of a commercial product, rusting was observed after 3 days of standing, but in the case of the present invention, rusting was observed. Rust is left 2
After a week, a sufficient rust prevention effect was recognized. Since the surfactant adheres to the work and is taken out, it is preferable to replenish the surfactant sequentially to maintain its concentration.
【００１５】さらに、第３の要件は、前記ワークを洗浄
するに際して、前記洗浄液に浸漬しながら、超音波振動
子２３により超音波を照射する点にある。この超音波の
照射は重要な操作であって、超音波を使用せず、浸漬処
理だけのときは、乾燥後ワークに電解液成分である硝酸
ナトリウムのような塩類が結晶として残留するのが認め
られる。この現象は、ワーク表面の加工傷のような凹凸
部に特に顕著に認められ、洗浄不良の原因となるのであ
る。Further, a third requirement is that, when cleaning the work, ultrasonic waves are irradiated by the ultrasonic vibrator 23 while being immersed in the cleaning liquid. This ultrasonic irradiation is an important operation, and when only immersion treatment is performed without using ultrasonic waves, it is recognized that salts such as sodium nitrate, which is an electrolyte component, remain as crystals in the work after drying. Can be This phenomenon is particularly noticeable in uneven portions such as processing scratches on the work surface, and causes poor cleaning.
【００１６】そして、本発明の実施形態では、第１洗浄
槽２での洗浄後、図１に示す第２洗浄槽３において濯ぎ
洗浄を行うことにより、一連の洗浄操作が終了する。こ
の場合、この第２洗浄槽３中の洗浄液３１は、先の第１
洗浄槽２の洗浄液２１に準じて調製しておけばよい。な
お、この濯ぎ洗浄は、必ずしも必須ではなく必要に応じ
て配置すればよく、濯ぎ洗浄をより完全に行う必要があ
るときには、このような濯ぎ用の洗浄槽を２〜３段に配
置すればよい。In the embodiment of the present invention, after the cleaning in the first cleaning tank 2, the rinsing is performed in the second cleaning tank 3 shown in FIG. 1, thereby completing a series of cleaning operations. In this case, the cleaning liquid 31 in this second cleaning tank 3
What is necessary is just to prepare according to the washing | cleaning liquid 21 of the washing tank 2. Note that this rinsing cleaning is not necessarily essential, and may be arranged as necessary. When rinsing cleaning needs to be performed more completely, such rinsing washing tanks may be arranged in two to three stages. .
【００１７】本発明の電解液の除去方法では、このよう
に電解バリ取り処理後の洗浄工程において、洗浄液とし
て、フッ素系不活性液体、または炭化水素系液体からな
る水切り乾燥溶剤を使用し、ワークを浸漬し、同時に超
音波を照射して、ワーク表面に超音波振動を付与するこ
とにより、ワークに付着している電解液を効率よく剥離
させ、袋孔加工部のような洗浄し難い部位についてま
で、持ち込み電解液を確実に取り除くことができる。In the method of removing an electrolytic solution according to the present invention, in the cleaning step after the electrolytic deburring treatment, a draining dry solvent composed of a fluorine-based inert liquid or a hydrocarbon-based liquid is used as the cleaning liquid, and And irradiate ultrasonic waves at the same time to apply ultrasonic vibrations to the surface of the work, so that the electrolyte adhering to the work can be efficiently peeled off. Until then, the brought-in electrolyte can be reliably removed.
【００１８】この方法において用いられる前記洗浄液自
体の沸点はごく低いので、洗浄処理後にワークに付着し
ている洗浄液は、迅速に揮発して乾燥するのであるが、
前記洗浄液を沸点近くまで加温し、その上方空間に冷却
ゾーン２２を設けておけば、洗浄済ワークを取り出すと
きにこの冷却ゾーン２２に一時的に滞留させるだけで、
極めて容易に乾燥することができる。かくして、従来用
いていた加熱乾燥工程は全く不要となり、洗浄処理直後
にワークを次の工程へ移すことができるのである。Since the boiling point of the cleaning liquid itself used in this method is very low, the cleaning liquid adhering to the work after the cleaning treatment is quickly volatilized and dried.
If the cleaning liquid is heated to near the boiling point and a cooling zone 22 is provided in a space above the cleaning liquid, only the cleaning work is temporarily retained in the cooling zone 22 when the cleaned work is taken out.
It can be dried very easily. Thus, the conventionally used heating and drying step becomes completely unnecessary, and the work can be transferred to the next step immediately after the cleaning treatment.
【００１９】次に、同じく図１を参照して本発明の他の
実施形態について説明する。図１において電解処理槽１
と洗浄槽２、３との間に配置した電解液回収槽４は、洗
浄液側に移行した電解液を洗浄液から分離して回収する
ためのものである。洗浄液に比重の大きいフッ素系不活
性液体を用いた場合を例に説明すると、第１洗浄槽２の
洗浄液２１をその上部から電解液回収槽４に導出する。
この電解液回収槽４内で溜められた洗浄液は静置する
と、比重の大きなフッ素系不活性液体からなる下部液相
４１と、相対的に比重の小さい電解液からなる上部液相
４２に分離することになる。Next, another embodiment of the present invention will be described with reference to FIG. In FIG. 1, the electrolytic treatment tank 1
The electrolytic solution recovery tank 4 disposed between the cleaning liquid and the cleaning tanks 2 and 3 is for separating and recovering the electrolytic solution transferred to the cleaning liquid from the cleaning liquid. Taking the case where a fluorine-based inert liquid having a large specific gravity is used as the cleaning liquid as an example, the cleaning liquid 21 of the first cleaning tank 2 is led out to the electrolyte recovery tank 4 from above.
When the cleaning liquid stored in the electrolyte recovery tank 4 is allowed to stand, it is separated into a lower liquid phase 41 made of a fluorine-based inert liquid having a large specific gravity and an upper liquid phase 42 made of an electrolyte having a relatively small specific gravity. Will be.
【００２０】そこで、このように分離した上部液相４２
については、電解処理槽１に返送することにより、電解
液として再利用することができるし、また下部液相４１
については、第２洗浄槽３に返送することにより、洗浄
液として再利用することができる。なお、この実施形態
では、電解液回収槽４からそれぞれ直接に返送している
が、不純物の混入程度によっては，必要に応じて適宜な
浄化処理を行ってから返送するようにしてもよい。ま
た、下部液相４１は、第２洗浄槽３ではなく、第１洗浄
槽２に返送するよう設定することもできる。Therefore, the upper liquid phase 42 thus separated is
Can be reused as an electrolytic solution by returning it to the electrolytic treatment tank 1, and the lower liquid phase 41
Can be reused as a cleaning liquid by returning it to the second cleaning tank 3. In this embodiment, the electrolyte is directly returned from the electrolytic solution recovery tank 4. However, depending on the degree of contamination of the impurities, the electrolyte may be returned after performing appropriate purification treatment as needed. Further, the lower liquid phase 41 can be set to be returned to the first cleaning tank 2 instead of the second cleaning tank 3.
【００２１】なお、洗浄液に前記フッ素系不活性液体の
代わりに、比重の小さい炭化水素系液体からなる水切り
乾燥溶剤を用いた場合には、比重の小さい炭化水素系液
体からなる上部液相４２と、相対的に比重の大きい電解
液からなる下部液相４１に分離することになる。そこ
で、フッ素系不活性液体のケースとは反対に、上部液相
４２は、第１または第２洗浄槽２または３に返送し、ま
た下部液相４１は、電解処理槽１に返送するようにすれ
ばよい。When a draining dry solvent composed of a hydrocarbon liquid having a low specific gravity is used in place of the fluorine-based inert liquid as the cleaning liquid, an upper liquid phase 42 composed of a hydrocarbon liquid having a low specific gravity is used. Thus, the lower liquid phase 41 composed of the electrolyte having a relatively large specific gravity is separated. Therefore, contrary to the case of the fluorine-based inert liquid, the upper liquid phase 42 is returned to the first or second cleaning tank 2 or 3, and the lower liquid phase 41 is returned to the electrolytic processing tank 1. do it.
【００２２】以上説明した本発明の最大の実用的価値
は、排水浄化装置が不要になるところにあるが、この点
をさらに付言すると、次のようなかなり大型の排水浄化
装置が節約できることが理解できよう。すなわち、通
常、表面積１００ｃｍ2 のワークが持ち出す電解液は、
約３ｍｌであるから、毎分３個のワークを処理できる電
解処理ラインから持ち出される電解液は、１時間あたり
０．５４リットルに相当し、それらを水洗洗浄する場合
には１００倍の洗浄水が必要となるから、排水浄化装置
としてその能力が日量約５００リットルに達するかなり
大型の施設が必要とされるのである。The greatest practical value of the present invention described above lies in the fact that a waste water purifying device is not required. To further add this point, it is understood that a considerably large waste water purifying device as described below can be saved. I can do it. That is, usually, the electrolyte brought out by a work having a surface area of 100 cm 2 is
Since it is about 3 ml, the amount of electrolytic solution taken out of the electrolytic processing line capable of processing three works per minute is equivalent to 0.54 liter per hour, and when washing them with water, 100 times of washing water is required. Because of the need, a rather large facility is required as a wastewater purification device, with a capacity of about 500 liters per day.
【００２３】[0023]
【発明の効果】本発明の電解液の除去方法は、以上に説
明したように構成されているので、（１）電解処理後の
洗浄工程において、洗浄水を使用しないので廃液も発生
しないから排水浄化装置を設置する必要がなく、またリ
サイクルのためのイオン交換装置や濃縮回収装置も必要
とせず、洗浄液や電解液を比較的容易に再利用できるの
で設備費、メンテナンス費、洗浄剤など材料費が節約で
きる。（２）防錆工程や乾燥工程も不要であるので、そ
のための設備費、防錆剤などの材料費、エネルギーコス
トが省略でき、その分コストダウンに寄与する、などの
優れた効果がある。よって本発明は従来の問題点を解消
した電解液の除去方法として、その工業的価値は極めて
大なるものがある。The method for removing an electrolytic solution according to the present invention is constituted as described above. (1) In the washing step after the electrolytic treatment, no washing liquid is used, so that no waste liquid is generated, so that drainage is performed. There is no need to install a purification device, and there is no need for an ion exchange device or concentration / recovery device for recycling, and cleaning liquids and electrolytes can be reused relatively easily, so equipment costs, maintenance costs, material costs such as cleaning agents. Can be saved. (2) Since neither a rust prevention step nor a drying step is required, there is an excellent effect that the equipment cost, material cost such as a rust preventive agent, and energy cost can be omitted, thereby contributing to cost reduction. Therefore, the present invention has a very large industrial value as a method for removing an electrolytic solution which has solved the conventional problems.
【図１】本発明の実施形態を説明するための当該除去装
置の要部フロー図。FIG. 1 is a main part flowchart of the removal apparatus for explaining an embodiment of the present invention.
【図２】従来の水洗方式のフローブロック図。FIG. 2 is a flow block diagram of a conventional water washing method.
１ 電解処理槽 ２ 第１洗浄槽 ３ 第２洗浄槽 ４ 電解液回収槽 １１ 電解液 ２１ 洗浄液 ２２ 冷却ゾーン ２３ 超音波振動子 ３１ 洗浄液 ４１ 下部液相 ４２ 上部液相 REFERENCE SIGNS LIST 1 electrolytic treatment tank 2 first cleaning tank 3 second cleaning tank 4 electrolytic solution recovery tank 11 electrolytic solution 21 cleaning liquid 22 cooling zone 23 ultrasonic transducer 31 cleaning liquid 41 lower liquid phase 42 upper liquid phase
Claims (3)
活性剤を含み、かつ電解液との比重差を有し、水との相
溶性に乏しい水切り乾燥溶剤からなる洗浄液に浸漬し、
超音波を照射しながら付着していた電解液をワークから
分離、除去することを特徴とする電解液の除去方法。1. A work which has been subjected to an electrolytic treatment in an electrolytic solution is immersed in a cleaning solution containing a surfactant, having a specific gravity difference from the electrolytic solution, and having a low compatibility with water, comprising a draining dry solvent.
A method for removing an electrolytic solution, comprising separating and removing an attached electrolytic solution from a work while irradiating ultrasonic waves.
液体、または炭化水素系液体からなる水切り乾燥溶剤に
アニオン系界面活性剤を１重量％以下含有させた洗浄液
を用いる請求項１に記載の電解液の除去方法。2. The electrolytic solution according to claim 1, wherein a cleaning solution containing an anionic surfactant in an amount of 1% by weight or less in a fluorinated inert liquid such as HFE or HFC or a draining dry solvent comprising a hydrocarbon liquid is used. How to remove liquid.
して分離して、電解処理工程に返送するとともに、電解
液を分離した洗浄液を再利用する請求項１または２に記
載の電解液の除去方法。3. The electrolytic solution according to claim 1, wherein the electrolytic solution transferred to the cleaning solution side is separated by utilizing a difference in specific gravity and returned to the electrolytic treatment step, and the cleaning solution from which the electrolytic solution has been separated is reused. How to remove liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10286190A JP2000107708A (en) | 1998-10-08 | 1998-10-08 | Method for removing electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10286190A JP2000107708A (en) | 1998-10-08 | 1998-10-08 | Method for removing electrolyte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000107708A true JP2000107708A (en) | 2000-04-18 |
Family
ID=17701126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10286190A Pending JP2000107708A (en) | 1998-10-08 | 1998-10-08 | Method for removing electrolyte |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000107708A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015058385A (en) * | 2013-09-18 | 2015-03-30 | Ｊｘ日鉱日石エネルギー株式会社 | Dewatering cleaning method and dewatering detergent composition |
-
1998
- 1998-10-08 JP JP10286190A patent/JP2000107708A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015058385A (en) * | 2013-09-18 | 2015-03-30 | Ｊｘ日鉱日石エネルギー株式会社 | Dewatering cleaning method and dewatering detergent composition |
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