ITMI20040077A1 - Procedimento per la idrodealchilazione catalitica di idrocarburi alchilaromatici - Google Patents

Procedimento per la idrodealchilazione catalitica di idrocarburi alchilaromatici

Info

Publication number
ITMI20040077A1
ITMI20040077A1 IT000077A ITMI20040077A ITMI20040077A1 IT MI20040077 A1 ITMI20040077 A1 IT MI20040077A1 IT 000077 A IT000077 A IT 000077A IT MI20040077 A ITMI20040077 A IT MI20040077A IT MI20040077 A1 ITMI20040077 A1 IT MI20040077A1
Authority
IT
Italy
Prior art keywords
hydrodekylation
alchylaromatic
hydrocarbons
catalytic
procedure
Prior art date
Application number
IT000077A
Other languages
English (en)
Inventor
Vittorio Arca
Boscoletto Angelo Boscolo
Original Assignee
Polimeri Europa Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polimeri Europa Spa filed Critical Polimeri Europa Spa
Priority to IT000077A priority Critical patent/ITMI20040077A1/it
Publication of ITMI20040077A1 publication Critical patent/ITMI20040077A1/it
Priority to US10/586,586 priority patent/US7880045B2/en
Priority to ES04803798T priority patent/ES2741149T3/es
Priority to JP2006549906A priority patent/JP2007518856A/ja
Priority to PL04803798T priority patent/PL1706471T3/pl
Priority to PT04803798T priority patent/PT1706471T/pt
Priority to EA200601202A priority patent/EA010238B1/ru
Priority to HUE04803798A priority patent/HUE045833T2/hu
Priority to DK04803798.0T priority patent/DK1706471T3/da
Priority to PCT/EP2004/014165 priority patent/WO2005071045A1/en
Priority to CN2004800407582A priority patent/CN1906272B/zh
Priority to EP04803798.0A priority patent/EP1706471B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
    • C07C4/18—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16—Clays or other mineral silicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/46—Iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
IT000077A 2004-01-22 2004-01-22 Procedimento per la idrodealchilazione catalitica di idrocarburi alchilaromatici ITMI20040077A1 (it)

Priority Applications (12)

Application Number Priority Date Filing Date Title
IT000077A ITMI20040077A1 (it) 2004-01-22 2004-01-22 Procedimento per la idrodealchilazione catalitica di idrocarburi alchilaromatici
EP04803798.0A EP1706471B1 (en) 2004-01-22 2004-12-13 Process for the catalytic hydrodealkylation of alkylaromatic hydrocarbons
PL04803798T PL1706471T3 (pl) 2004-01-22 2004-12-13 Sposób katalitycznego hydrodealkilowania węglowodorów alkiloaromatycznych
ES04803798T ES2741149T3 (es) 2004-01-22 2004-12-13 Proceso para la hidrodesalquilación catalítica de hidrocarburos alquilaromáticos
JP2006549906A JP2007518856A (ja) 2004-01-22 2004-12-13 アルキル芳香族炭化水素の触媒水素化脱アルキル化方法
US10/586,586 US7880045B2 (en) 2004-01-22 2004-12-13 Process for the catalytic hydrodealkylation of alkylaromatic hydrocarbons
PT04803798T PT1706471T (pt) 2004-01-22 2004-12-13 Processo para a hidrodealquilação catalítica de hidrocarbonetos alquilaromáticos
EA200601202A EA010238B1 (ru) 2004-01-22 2004-12-13 Способ каталитического гидродеалкилирования алкилароматических углеводородов
HUE04803798A HUE045833T2 (hu) 2004-01-22 2004-12-13 Eljárás alkil-aromás szénhidrogének katalitikus hidro-dealkilezésére
DK04803798.0T DK1706471T3 (da) 2004-01-22 2004-12-13 Fremgangsmåde til katalytisk hydrodealkylering af alkylaromatiske carbonhydrider
PCT/EP2004/014165 WO2005071045A1 (en) 2004-01-22 2004-12-13 Process for the catalytic hydrodealkylation of alkylaro­matic hydrocarbons
CN2004800407582A CN1906272B (zh) 2004-01-22 2004-12-13 烷基芳族烃的催化加氢脱烷基化方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT000077A ITMI20040077A1 (it) 2004-01-22 2004-01-22 Procedimento per la idrodealchilazione catalitica di idrocarburi alchilaromatici

Publications (1)

Publication Number Publication Date
ITMI20040077A1 true ITMI20040077A1 (it) 2004-04-22

Family

ID=34803699

Family Applications (1)

Application Number Title Priority Date Filing Date
IT000077A ITMI20040077A1 (it) 2004-01-22 2004-01-22 Procedimento per la idrodealchilazione catalitica di idrocarburi alchilaromatici

Country Status (12)

Country Link
US (1) US7880045B2 (it)
EP (1) EP1706471B1 (it)
JP (1) JP2007518856A (it)
CN (1) CN1906272B (it)
DK (1) DK1706471T3 (it)
EA (1) EA010238B1 (it)
ES (1) ES2741149T3 (it)
HU (1) HUE045833T2 (it)
IT (1) ITMI20040077A1 (it)
PL (1) PL1706471T3 (it)
PT (1) PT1706471T (it)
WO (1) WO2005071045A1 (it)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20040554A1 (it) * 2004-03-23 2004-06-23 Polimeri Europa Spa Procedimento per la idrodealchilazione catalitica selettiva di idrocarburi alchilaromatici
JP5292699B2 (ja) * 2006-03-29 2013-09-18 東レ株式会社 エチルベンゼンの転化方法およびパラキシレンの製造方法
US20100179360A1 (en) * 2006-03-29 2010-07-15 Toray Industries, Inc., A Corporation Of Japan Method for conversion of ethylbenzene and process for production of para-xylene
ITMI20061548A1 (it) * 2006-08-03 2008-02-04 Polimeri Europa Spa Composizioni catalitiche per idrodealchilazioni altamente selettive di idrocarburi alchilaromatici
DE102007004075A1 (de) 2007-01-26 2008-07-31 Linde Ag Verfahren zur Temperaturführung einer Dampf-Dealkylierung
DE102007004078A1 (de) 2007-01-26 2008-07-31 Linde Ag Verfahren zur Dampf-Dealkylierung unter Einbindung einer Wassergas-Shift-Reaktion
DE102007004074A1 (de) 2007-01-26 2008-07-31 Linde Ag Verfahren und Vorrichtung zur Regeneration eines Katalysators zur Dampf-Dealkylierung
DE102007004079A1 (de) 2007-01-26 2008-07-31 Linde Ag Verfahren zur Trennung der gasförmigen Reaktionsprodukte der Dampf-Dealkylierung
DE102007004077A1 (de) 2007-01-26 2008-07-31 Linde Ag Verfahren zur Dampf-Dealkylierung
TWI439447B (zh) * 2008-03-19 2014-06-01 Toray Industries 乙苯的轉化方法及對二甲苯的製造法
CN104174428B (zh) * 2013-05-22 2019-11-12 中国石油化工股份有限公司 一种催化剂及其用于c9以上重质芳烃轻质化的方法
CN105085153B (zh) * 2014-05-08 2018-01-23 中国石油化工股份有限公司 一种使用碳9以上的芳烃生产苯、甲苯、二甲苯的方法
JP6566306B2 (ja) * 2015-06-24 2019-08-28 Ｊｘｔｇエネルギー株式会社 芳香族転換反応用触媒及び芳香族炭化水素の製造方法
EP3524587A1 (en) * 2015-08-21 2019-08-14 SABIC Global Technologies B.V. Process for producing btx from a c5-c12 hydrocarbon mixture
US10093873B2 (en) 2016-09-06 2018-10-09 Saudi Arabian Oil Company Process to recover gasoline and diesel from aromatic complex bottoms
US11066344B2 (en) 2017-02-16 2021-07-20 Saudi Arabian Oil Company Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock
US10053401B1 (en) 2017-02-16 2018-08-21 Saudi Arabian Oil Company Process for recovery of light alkyl mono-aromatic compounds from heavy alkyl aromatic and alkyl-bridged non-condensed alkyl aromatic compounds
US10508066B2 (en) 2017-02-16 2019-12-17 Saudi Arabian Oil Company Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock
US11279663B2 (en) 2017-02-16 2022-03-22 Saudi Arabian Oil Company Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock
CN108435235B (zh) * 2018-03-26 2021-01-05 福州大学 一种介孔Zn-ZSM-5分子筛及低成本制备方法
US11267769B2 (en) 2019-10-07 2022-03-08 Saudi Arabian Oil Company Catalytic hydrodearylation of heavy aromatic streams containing dissolved hydrogen with fractionation
US10899685B1 (en) 2019-10-07 2021-01-26 Saudi Arabian Oil Company Catalytic hydrodearylation of heavy aromatic stream containing dissolved hydrogen
FR3116818A1 (fr) * 2020-11-30 2022-06-03 IFP Energies Nouvelles Procede d’hydrogenolyse selective de charges comportant des composes aromatiques c8+ mettant en œuvre un catalyseur a structure zeolithique
US11484869B2 (en) 2020-12-09 2022-11-01 Saudi Arabian Oil Company Modified ultra-stable Y (USY) zeolite catalyst for dealkylation of aromatics
US11613714B2 (en) 2021-01-13 2023-03-28 Saudi Arabian Oil Company Conversion of aromatic complex bottoms to useful products in an integrated refinery process
US11591526B1 (en) 2022-01-31 2023-02-28 Saudi Arabian Oil Company Methods of operating fluid catalytic cracking processes to increase coke production

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Publication number Priority date Publication date Assignee Title
US4351979A (en) 1980-04-14 1982-09-28 Mobil Oil Corporation Manufacture of aromatic compounds
EP0109962B2 (en) * 1982-11-23 1992-12-16 Toray Industries, Inc. Conversion of xylenes containing ethylbenzene
CA1227809A (en) 1983-10-17 1987-10-06 Nancy A. Kutz Modification of hydrocarbon conversion processes over crystalline aluminosilicate zeolite-based catalysts by incorporation of a molybdenum compound
US5689027A (en) * 1994-11-18 1997-11-18 Mobil Oil Corporation Selective ethylbenzene conversion
US5744674A (en) * 1996-02-06 1998-04-28 China Petrochemical Corporation Catalyst and process for the conversion of heavy aromatics to light aromatics
US5877374A (en) * 1997-04-02 1999-03-02 Chevron Chemical Company Low pressure hydrodealkylation of ethylbenzene and xylene isomerization
TW482751B (en) * 1997-06-06 2002-04-11 China Petro Chemical Technolog Catalysts and processes for the conversion of aromatic hydrocarbons and uses thereof in the production of aromatic hydrocarbons
US5883034A (en) * 1997-07-09 1999-03-16 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
KR100557558B1 (ko) * 2000-11-30 2006-03-03 에스케이 주식회사 탄화수소 혼합물로부터 방향족 탄화수소 및 액화석유가스를 제조하는 방법

Also Published As

Publication number Publication date
EP1706471B1 (en) 2019-05-08
EA010238B1 (ru) 2008-06-30
US7880045B2 (en) 2011-02-01
HUE045833T2 (hu) 2020-01-28
PT1706471T (pt) 2019-08-07
US20070203377A1 (en) 2007-08-30
WO2005071045A1 (en) 2005-08-04
EP1706471A1 (en) 2006-10-04
EA200601202A1 (ru) 2006-12-29
ES2741149T3 (es) 2020-02-10
PL1706471T3 (pl) 2020-01-31
CN1906272A (zh) 2007-01-31
CN1906272B (zh) 2010-09-08
DK1706471T3 (da) 2019-08-05
JP2007518856A (ja) 2007-07-12

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