IT1096979B - Procedimento per preparare citronellale otticamento attivo - Google Patents
Procedimento per preparare citronellale otticamento attivoInfo
- Publication number
- IT1096979B IT1096979B IT25303/78A IT2530378A IT1096979B IT 1096979 B IT1096979 B IT 1096979B IT 25303/78 A IT25303/78 A IT 25303/78A IT 2530378 A IT2530378 A IT 2530378A IT 1096979 B IT1096979 B IT 1096979B
- Authority
- IT
- Italy
- Prior art keywords
- optication
- citronellal
- prepare
- procedure
- active
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
- B01J31/188—Amide derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
- B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
- B01J31/2457—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7721377A FR2396735A1 (fr) | 1977-07-04 | 1977-07-04 | Procede de preparation de citronellal optiquement actif |
Publications (2)
Publication Number | Publication Date |
---|---|
IT7825303A0 IT7825303A0 (it) | 1978-07-04 |
IT1096979B true IT1096979B (it) | 1985-08-26 |
Family
ID=9193250
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT25303/78A IT1096979B (it) | 1977-07-04 | 1978-07-04 | Procedimento per preparare citronellale otticamento attivo |
Country Status (7)
Country | Link |
---|---|
US (1) | US4237072A (it) |
EP (1) | EP0000315B1 (it) |
JP (1) | JPS5414911A (it) |
CA (1) | CA1117981A (it) |
DE (1) | DE2860165D1 (it) |
FR (1) | FR2396735A1 (it) |
IT (1) | IT1096979B (it) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2934250A1 (de) * | 1979-08-24 | 1981-03-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von olefinisch ungesaettigten carbonylverbindungen und alkoholen |
FR2651152B1 (fr) * | 1989-08-23 | 1991-11-29 | Elf Aquitaine | Perfectionnement a la preparation de catalyseurs chiraux a base de complexes du ruthenium et du phosphore. |
ZM3391A1 (en) * | 1990-08-06 | 1992-04-30 | R & C Products Pty Ltd | Insect repellent |
JP3247277B2 (ja) * | 1994-07-29 | 2002-01-15 | 高砂香料工業株式会社 | 液状l−n−メントール組成物及びその調製法 |
DE102004049631A1 (de) | 2004-10-11 | 2006-04-20 | Basf Ag | Verfahren zur Herstellung optisch aktiver Carbonylverbindungen |
DE102005036340A1 (de) * | 2005-07-29 | 2007-02-01 | Basf Ag | Verfahren zur Herstellung optisch aktiver Bis-Phosphinylalkane |
JP4938786B2 (ja) * | 2005-11-17 | 2012-05-23 | ビーエーエスエフ ソシエタス・ヨーロピア | シトロネラールの生産法 |
ATE424465T1 (de) | 2005-11-17 | 2009-03-15 | Basf Se | Verfahren zur herstellung von citronellal |
JP5479320B2 (ja) * | 2007-04-25 | 2014-04-23 | ビーエーエスエフ ソシエタス・ヨーロピア | 光学活性カルボニル化合物の調製方法 |
US8318985B2 (en) | 2007-11-30 | 2012-11-27 | Basf Se | Method for producing optically active, racemic menthol |
WO2010061909A1 (ja) | 2008-11-27 | 2010-06-03 | 高砂香料工業株式会社 | 不斉水素化触媒 |
CN101747152B (zh) * | 2008-12-18 | 2012-10-24 | 复旦大学 | 一种柠檬醛液相加氢合成不饱和醇的方法 |
EP2438989B1 (en) * | 2009-06-03 | 2016-04-13 | Takasago International Corporation | Use of asymmetric hydrogenation catalyst |
JP5711209B2 (ja) | 2010-03-04 | 2015-04-30 | 高砂香料工業株式会社 | 均一系不斉水素化触媒 |
JP5913352B2 (ja) | 2010-11-29 | 2016-04-27 | 高砂香料工業株式会社 | 不斉水素化触媒、およびそれを用いた光学活性カルボニル化合物の製造方法 |
JP5560464B2 (ja) | 2010-11-29 | 2014-07-30 | 高砂香料工業株式会社 | 不斉水素化触媒 |
MX2013008826A (es) | 2011-02-22 | 2013-11-01 | Firmenich & Cie | Hidrogenacion de dienales con complejos de rodio bajo atmosfera libre de monoxido de carbono. |
DE102013103563A1 (de) | 2013-04-10 | 2014-10-16 | Basf Se | Verfahren zur Herstellung von Citronellal |
WO2016097242A1 (de) * | 2014-12-19 | 2016-06-23 | Basf Se | Verfahren zur herstellung optisch aktiver carbonylverbindungen |
CN105254474B (zh) * | 2015-10-20 | 2017-07-21 | 万华化学集团股份有限公司 | 一种由柠檬醛不对称催化氢化制备手性香茅醇的方法 |
CN105330515B (zh) * | 2015-10-20 | 2017-07-21 | 万华化学集团股份有限公司 | 一种光学纯香茅醇的制备方法 |
CN105218335B (zh) * | 2015-10-20 | 2017-06-16 | 万华化学集团股份有限公司 | 一种由柠檬醛不对称催化氢化制备手性香茅醛的方法 |
MX2018013563A (es) | 2016-05-06 | 2019-03-14 | Basf Se | Ligandos p-quirales de fosfina y su uso para sintesis asimetrica. |
WO2020048975A1 (de) | 2018-09-05 | 2020-03-12 | Basf Se | Kontinuierliche herstellung einer optisch aktiven carbonylverbindung durch asymmetrische hydrierung |
CN109851486B (zh) * | 2018-12-20 | 2022-03-11 | 万华化学集团股份有限公司 | 一种钌络合物选择性氢化二烯酮的方法 |
US20230043867A1 (en) | 2019-12-09 | 2023-02-09 | Wanhua Chemical Group Co., Ltd. | Preparation method for optically active citronellal |
CN111056932A (zh) * | 2019-12-09 | 2020-04-24 | 万华化学集团股份有限公司 | 一种制备光学活性香茅醛的方法 |
CN110872217A (zh) * | 2019-12-09 | 2020-03-10 | 万华化学集团股份有限公司 | 一种光学活性的香茅醛的制备方法 |
CN111004102B (zh) * | 2019-12-23 | 2022-11-04 | 万华化学集团股份有限公司 | 一种制备光学活性香茅醛的方法及用于该方法的催化剂 |
CN111056933B (zh) * | 2019-12-24 | 2022-11-08 | 万华化学集团股份有限公司 | 一种制备光学活性香茅醛的方法及用于该方法的催化剂体系 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3489786A (en) * | 1964-12-10 | 1970-01-13 | Shell Oil Co | Hydrogenation process |
US3849480A (en) * | 1968-09-09 | 1974-11-19 | Monsanto Co | Catalytic asymmetric hydrogenation |
US3860657A (en) * | 1970-03-25 | 1975-01-14 | Givaudan Corp | Process for the preparation of citronellal |
FR2116905A5 (fr) * | 1970-12-10 | 1972-07-21 | Inst Francais Du Petrole | Nouveaux coordinats bidentes,leur fabrication et leurs applications |
CA1022187A (en) * | 1971-12-23 | 1977-12-06 | Peter S. Gradeff | Process for the semihydrogenation of citral to citronellal |
US3939188A (en) * | 1972-03-24 | 1976-02-17 | Exxon Research And Engineering Company | Preparation of zerovalent phosphine substituted rhodium compounds and their use in the selective carbonylation of olefins |
FR2314911A1 (fr) * | 1975-06-18 | 1977-01-14 | Rhone Poulenc Ind | Procede de semi-hydrogenation du citral et de ses homologues en citronnellal et homologues du citronnellal |
US4029709A (en) * | 1976-02-17 | 1977-06-14 | Rhodia, Inc. | Process for the hydrogenation of citral to citronellal and of citronellal to citronellol using chromium-promoted Raney nickel catalyst |
-
1977
- 1977-07-04 FR FR7721377A patent/FR2396735A1/fr active Granted
-
1978
- 1978-06-14 EP EP78420001A patent/EP0000315B1/fr not_active Expired
- 1978-06-14 DE DE7878420001T patent/DE2860165D1/de not_active Expired
- 1978-06-30 US US05/920,981 patent/US4237072A/en not_active Expired - Lifetime
- 1978-06-30 CA CA000306584A patent/CA1117981A/fr not_active Expired
- 1978-07-04 JP JP8062078A patent/JPS5414911A/ja active Granted
- 1978-07-04 IT IT25303/78A patent/IT1096979B/it active
Also Published As
Publication number | Publication date |
---|---|
JPS5414911A (en) | 1979-02-03 |
CA1117981A (fr) | 1982-02-09 |
FR2396735A1 (fr) | 1979-02-02 |
IT7825303A0 (it) | 1978-07-04 |
EP0000315B1 (fr) | 1980-09-17 |
FR2396735B1 (it) | 1980-02-01 |
US4237072A (en) | 1980-12-02 |
DE2860165D1 (en) | 1980-12-18 |
JPS6123775B2 (it) | 1986-06-07 |
EP0000315A1 (fr) | 1979-01-10 |
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