IT1059528B - Processo di ossidazione di un idrocarburo alifatico o cicloalifatico in fase liquida con un gas contenente ossigeno molecolare - Google Patents

Processo di ossidazione di un idrocarburo alifatico o cicloalifatico in fase liquida con un gas contenente ossigeno molecolare

Info

Publication number
IT1059528B
IT1059528B IT29405/75A IT2940575A IT1059528B IT 1059528 B IT1059528 B IT 1059528B IT 29405/75 A IT29405/75 A IT 29405/75A IT 2940575 A IT2940575 A IT 2940575A IT 1059528 B IT1059528 B IT 1059528B
Authority
IT
Italy
Prior art keywords
aliphatic
liquid phase
gas containing
oxidation process
molecular oxygen
Prior art date
Application number
IT29405/75A
Other languages
English (en)
Original Assignee
Ici Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ici Ltd filed Critical Ici Ltd
Application granted granted Critical
Publication of IT1059528B publication Critical patent/IT1059528B/it

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/022—Preparation from organic compounds
    • C01B15/024—Preparation from organic compounds from hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00182—Controlling or regulating processes controlling the level of reactants in the reactor vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
IT29405/75A 1974-11-21 1975-11-18 Processo di ossidazione di un idrocarburo alifatico o cicloalifatico in fase liquida con un gas contenente ossigeno molecolare IT1059528B (it)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5044374 1974-11-21

Publications (1)

Publication Number Publication Date
IT1059528B true IT1059528B (it) 1982-06-21

Family

ID=10455909

Family Applications (1)

Application Number Title Priority Date Filing Date
IT29405/75A IT1059528B (it) 1974-11-21 1975-11-18 Processo di ossidazione di un idrocarburo alifatico o cicloalifatico in fase liquida con un gas contenente ossigeno molecolare

Country Status (5)

Country Link
US (1) US4055600A (it)
DE (1) DE2552119A1 (it)
FR (1) FR2291956A1 (it)
IT (1) IT1059528B (it)
NL (1) NL7513502A (it)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2951956A1 (de) * 1979-12-22 1981-07-23 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von gemischen aus cyclohexylhydroperoxid
US5043481A (en) * 1990-09-28 1991-08-27 Arco Chemical Technology, Inc. Cyclohexane oxidation
US5149885A (en) * 1992-02-20 1992-09-22 Arco Chemical Technology, L.P. Oxidation of isobutane to tertiary butyl hydroperoxide
US5883292A (en) * 1996-01-17 1999-03-16 Twenty-First Century Research Corporation Reaction control by regulating internal condensation inside a reactor
US6039902A (en) * 1996-06-24 2000-03-21 Rpc Inc. Methods of recycling catalyst in oxidations of hydrocarbons
US6288270B1 (en) 1996-06-24 2001-09-11 Rpc Inc. Methods for controlling the reaction rate of a hydrocarbon to an acid by making phase-related adjustments
US6337051B1 (en) 1996-06-24 2002-01-08 Rpc Inc. Device for detecting formation of a second liquid phase
US6143927A (en) * 1996-06-24 2000-11-07 Rpc Inc. Methods for removing catalyst after oxidation of hydrocarbons
US5922908A (en) * 1996-06-24 1999-07-13 Twenty-First Century Research Corporation Methods for preparing dibasic acids
US20010053864A1 (en) * 1996-08-21 2001-12-20 Decoster David C. Devices for controlling the reaction rate and/or reactivity of hydrocarbon to an intermediate oxidation product by adjusting the oxidant consumption rate
US5801273A (en) 1996-08-21 1998-09-01 Twenty-First Century Research Corporation Methods and devices for controlling the reaction rate of a hydrocarbon to an intermediate oxidation product by pressure drop adjustments
AU3811597A (en) 1996-08-21 1998-03-06 Twenty-First Century Research Corporation Methods and devices for controlling the reaction by adjusting the oxidant consumption rate
US6103933A (en) * 1996-11-07 2000-08-15 Rpc Inc. Methods for controlling the oxidation rate of a hydrocarbon by adjusting the ratio of the hydrocarbon to a rate-modulator
US5817868A (en) * 1996-11-12 1998-10-06 Twenty-First Century Research Corporation Method and devices for controlling the oxidation of a hydrocarbon to an acid by regulating temperature/conversion relationship in multi-stage arrangements
US5824819A (en) * 1996-12-18 1998-10-20 Twenty-First Century Research Corporation Methods of preparing an intermediate oxidation product from a hydrocarbon by utilizing an activated initiator
US6037491A (en) * 1997-07-25 2000-03-14 Rpc Inc. Methods and devices for controlling hydrocarbon oxidations to respective acids by adjusting the solvent to hydrocarbon ratio
US5929277A (en) 1997-09-19 1999-07-27 Twenty-First Century Research Corporation Methods of removing acetic acid from cyclohexane in the production of adipic acid
US5908589A (en) * 1997-12-08 1999-06-01 Twenty-First Century Research Corporation Methods for separating catalyst from oxidation mixtures containing dibasic acids
CN1290244A (zh) 1998-02-09 2001-04-04 Rpc公司 处理在烃氧化成二元酸的混合物中的钴催化剂的方法
BR9907998A (pt) * 1998-02-19 2000-10-24 Rpc Inc Processos e dispositivos para a separação de catalisador de misturas de oxidação
US6433220B1 (en) 1998-07-02 2002-08-13 Rpc Inc. Methods of extracting catalyst from a reaction mixture in the oxidation of cyclohexane to adipic acid
US6340420B1 (en) 1998-07-06 2002-01-22 Rpc Inc. Methods of treating the oxidation mixture of hydrocarbons to respective dibasic acids
MXPA01010648A (es) 1999-04-20 2002-06-04 Rpc Inc Metodos para el reemplazo de agua y ciclohexano con acido acetico en soluciones acuosas de catalizador.
FR2955322B1 (fr) 2010-01-21 2013-09-06 Rhodia Operations Procede de fabrication d'un hydroperoxyde d'alkyle
RU2468860C1 (ru) * 2011-08-24 2012-12-10 Сергей Николаевич Кузнецов Установка каскадного окисления циклогексана
CN108579639B (zh) * 2018-04-03 2024-01-30 浙江新和成股份有限公司 一种制备氧代异佛尔酮的装置及方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2557281A (en) * 1951-06-19 Oxidation op petroleum cyclohexane
US3274254A (en) * 1966-09-20 Oxidation of cyclohexane
US2429115A (en) * 1944-04-03 1947-10-14 Standard Oil Dev Co Hydrogenation process and apparatus
US2825742A (en) * 1954-05-04 1958-03-04 Du Pont Liquid phase oxidation of cyclohexane
US3551482A (en) * 1966-06-14 1970-12-29 Vickers Zimmer Ag Cyclohexane oxidation products recovery
DE1593700A1 (de) * 1966-12-07 1970-07-16 Vickers Zimmer Ag Verfahren zur Herstellung von Cyclohexanol und Cyclohexanon
US3932513A (en) * 1971-02-05 1976-01-13 Halcon International, Inc. Cyclohexane oxidation

Also Published As

Publication number Publication date
DE2552119A1 (de) 1976-05-26
NL7513502A (nl) 1976-05-25
FR2291956A1 (fr) 1976-06-18
US4055600A (en) 1977-10-25

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