IE54867B1 - Process for dry deinking of secondary fiber sources - Google Patents
Process for dry deinking of secondary fiber sourcesInfo
- Publication number
- IE54867B1 IE54867B1 IE2924/83A IE292483A IE54867B1 IE 54867 B1 IE54867 B1 IE 54867B1 IE 2924/83 A IE2924/83 A IE 2924/83A IE 292483 A IE292483 A IE 292483A IE 54867 B1 IE54867 B1 IE 54867B1
- Authority
- IE
- Ireland
- Prior art keywords
- fibres
- fines
- ink
- secondary fibre
- fibre source
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 94
- 238000000034 method Methods 0.000 title claims abstract description 56
- 239000002761 deinking Substances 0.000 title claims abstract description 36
- 230000008569 process Effects 0.000 title claims description 31
- 239000010893 paper waste Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 235000019504 cigarettes Nutrition 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 230000036571 hydration Effects 0.000 claims description 2
- 238000006703 hydration reaction Methods 0.000 claims description 2
- 241000237519 Bivalvia Species 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 235000020639 clam Nutrition 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 3
- 239000000976 ink Substances 0.000 description 28
- 239000000463 material Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000006223 plastic coating Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000013055 pulp slurry Substances 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- -1 tissue Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/02—Working-up waste paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/14—Secondary fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
- D21B1/06—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods
- D21B1/08—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods the raw material being waste paper; the raw material being rags
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
- D21B1/12—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
- D21B1/30—Defibrating by other means
- D21B1/32—Defibrating by other means of waste paper
- D21B1/325—Defibrating by other means of waste paper de-inking devices
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/02—Working-up waste paper
- D21C5/025—De-inking
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Paper (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Artificial Filaments (AREA)
Abstract
Ink-bearing secondary fibre feedstocks are deinked by mechanically fiberizing the feedstocks in a substantially dry state to produce substantially discrete fibres and fines and separating the fines from the fibres. The feedstock may be shredded printed waste paper. Fiberisation may be effected in any conventional fiberisation equipment. Separation of fines from fibres may be carried out using a mesh bag, or a continuously moving wire screen, preferably with the assistance of a vacuum box. The fibres recovered may be cleaned by aqueous centricleaning, or by wet deinking methods.
[GB2133817A]
Description
2 This invention relates to the deinking of secondary fibre sources to enable them to be used, for example, for the production of paper.
The commercial production of various types 5 of paper requires the use of recycled paper as a source of papermaking fibres due to the expense of virgin fibres. Prior to using such secondary fibre sources for ma’-ing a commercial product, it is necessary to treat the fibre source to remove unwanted 10 chemical constituents which adversely affect the quality of the final paper product. The most notable contaminants to be removed are inks or dyes which • adversely affect the colour and brightness of secondary fibres used as a feedstock. Ink deposits on 15 paper are extremely thin and roughly have a thickness of only about 0.0001 inch (0.000254 cms).
Chemically, the inks are generally a mixture of pigment or organic dye, binder, and solvent. Some inks also contain metallic driers, plasticizers, and 20 waxes to impart desired properties. Hence their chemical make-up can be very complex. However, inks are not to be equated with other additives or contaminants such as varnishes, sizes and plasticizers, which are chemically and physically of a 3 different nature as those skilled in the art of deinking will appreciate.
The prior art has addressed secondary fibre clean-up generally by subjecting secondary fibre S sources to a variety of treatments, the most common form of which is chemical wet deinking. For example, United states Patent No. 3,098,784 teaches a process for deinking printed paper wherein the printed paper is slurried in water containing 0.2 to 5.0 percent io (based on the weight of the paper) of a water-soluble non-ionic surface active agent at a temperature of from about 90° to 180°F.. The treatment is carried out in standard pulp fiberizing equipment wherein the paper stock is reduced to substantially individual 15 fibres. However, this and other wet deinking processes can be expensive and produce large quantities of sludge, which creates a disposal problem. In addition, there are certain types of paper which cannot be successfully deinked at all by 2o conventional wet methods because they are chemically unreactive with the deinking agents.
Other treatments of secondary fibres have been directed toward separating other contaminants besides inks from the-secondary fibres, such as plastic coatings and miscellaneous particulates.
However, previously, none of these methods are directed to deinicing. All are concerned with removal of plastic films and coatings, which separate out as relatively large pieces. Also, the methods use water and accordingly are not suggestive of a dry process.
Accordingly, there remains a need for a deinking process which avoids or minimizes sludge formation and chemical costs. Although various prior art treatments of waste paper have attempted to satisfy this need, none of the methods have been successful.
A method of deinking in accordance with the indention comprises: (a) mechanically fiberizing an ink-bearing secondary fibre source consisting essentially of ink-containing waste paper or feedstock in a substantially dry state, preferably air dry, thereby producing substantially discrete fibres and fines; and (b) separating the fines from the fibres. Fiberization is conducted when the secondary fibre source is air dry or sufficiently dry to prevent adhesion of the resulting fibres and fines.
Such a method is simpler and more economical than the commonly used wet deinking methods.
The fines, which may include the ink-bearing 5 fines, can be removed or separated from the fibres, for example, by screening through a screen having mesh openings sufficiently small to retain the fibres, yet large enough to permit the fines to pass through. The 5 fines may comprise ink particles, fibre fragments bearing ink, other particulate matter bearing ink, such as loading or filler materials, fibre fragments formed during the fiberization, fibre fragments initially 6 present in the secondary fiber source, and particulate loading or filler materials present in the secondary fiber source It is understood, however, that in all instances at least a portion of the fines 5 would include ink-bearing fines or ink particles.
The terms, as used herein .and in the appended claims, have the following meanings: "Secondary fiber source" means cellulosic products bearing or containing ink; it consists 10 essentially of ink-containing waste paper such as printed waste paper, reclaimed for use as a source of papermaking fibers.
"Air dry" means the moisture content of the secondary fiber source is in equilibrium with the 15 atmospheric conditions to which it is exposed "Substantially discrete fibers* means essentially individual fibers, with allowance for some fiber aggregates, which are many times longer than their diameter.
Typically, secondary fiber sources contain from about three to nine weight percent moisture, 7 which, for purposes of this invention, is about the range for air dry paper. It, therfore, is preferred in carrying out the invention, that no additional water be present or added to the secondary fiber 5 source to be fiberized. It has been found that as the water content of the paper increases, the energy requirement of the fiberization apparatus increases rapidly. Shis energy increase tends to destroy the fibers resulting in unacceptable fiber degradation.
Also, as the water content increases, the fibers and fines formed during fiberization tend to agglomerate or adhere to each other, which can plug up the apparatus, hinder separation and diminish the yield of useable fiber. Hence, the secondary fiber source is 15 in a substantially dry state when fiberization is conducted, and although water may be present or added, it should not be so much as to cause an unacceptable or uneconomical amount of fiber degradation or energy consumption or plugging of the fiberizer. A specific 20 numerical limitation for the water content will depend mainly on the characteristics of the 8 secondary fibre source and the operation and economics of the fiberization apparatus used in the process.
These limitations can be determined by experimentation by those skilled in the art. In general, however, a 5 moisture content of about 20 weight percent based on solids is believed to be a practical limit for most situations.
The process of this invention is particularly useful for removing inks from secondary lo fibre sources which have been treated or coated with a surface size or a barrier material. The size serves as a holdout to the ink in such a manner as to provide resistance to passage of the ink after application to the secondary fibre source. In such cases, at least 15 some of the size or coating is removed with the ink fines during fiberization and separated from the fibres. Examples of barrier coatings or surface sizes include starches, casein, animal glue, carboxymethyl cellulose, polyvinyl alcohol, methyl cellulose, wax 2o emulsions, and a variety of resin polymers.
The discrete fibres obtained by the process of this invention, which do not exhibit hydration (which is characteristic of fibres obtained by wet deinking methods), are suitable as secondary fibre θ and can be recycled for the manufacture of cellulosic products such as tissue, papers, pads, batting, sheeting, newsprint, and the like.
The invention will now be further described 5 by way of example with reference to the accompanying drawings in which:- Figure 1 is a perspective view of an example of a fiberizer apparatus used to carry out a process in accordance with this invention; lo Figure 2 is a perspective view of the fiberizer of the type of Figure 1 with the front lid opened to expose the impeller blades and the serrated working surface; Figure 3 is a cut-a-way perspective view of 15 the opened fiberizer with the impeller removed to expose the orifice through which the processed fibres are withdrawn from the working chamber; Figure 4 is a side elevation of the fiberizer partially in section illustrating its 2o operation; Figure 5 is a perspective view of a fiberizer modified to operate in a continuous mode.
Figure 6 is a schematic flow diagram illustrating a process in accordance with this invention, and Figure 7 is a block diagram illustrating the use of this invention in connection with making paper.
Referring first to Figure 1, the 5 fiberization apparatus generally illustrated is a turbomill. However, those skilled in the art will appreciate that a variety of fiberization apparatus is available to carry out the process of this invention, such as nammermills, disc mills, pin mills, wing lo beater mills, etc.
In general, the fiberizer 1 comprises a housing which encloses rotating rotor blades 9, (see Figure 2) .driven by a suitable drive means 2. The secondary fibre source, e.g., printed waste paper, 15 which may be shredded, is fed to the fiberizer through a feed inlet 3 and the waste paper is comminuted or fiberized substantially to individual fibres and fines An internally disposed fan draws air in through the feed inlet 3 along with the waste paper, 2o and expels the air through exit port 4 carrying the fibres and fines along with the air. The fibres are collected in a tubular meshed bag 5. which permits the fines to pass through the mesh openings while retaining the fibres. The specific meshed bag 5 11 material which was found to work satisfactorily had a mesh size of 50 x 60 openings per inch (50 x 60/2.54 openings per cm). The wire diameter was 0.009 inch (0.023 cms) and the openings were 0.006 inch 5 (0.015 cms) by 0.012 inch (0.04 cms). The open area of the screen was 23 percent of the surface area.
Also shown in Figure 1 is a cooling means having a water supply inlet 6 and exit ports 7 for removing heat generated due to friction by the 10 shearing of the fibre feedstock. Aside from the tubular meshed bag, fiberizers as illustrated in 12 commercially available equipment. Such a fiberizer is illustrated in U.S. 3,069,103. The specific apparatus illustrated and used for purposes herein was a Pallman Ref. 4 fiberizer.
Figure 2 illustrates the internal working chamber of the fiberizer, primarily illustrating the position of the rotor blades. There is shown a serrated, grooved working surface 8 against which the feed material is abraded by the action of the moving rotor blades 9. Although not clearly 10 shown in this Figure, there is a space between the serrated working surface and the blades in which cellulosic materials are buffetted about. The blade position relative to the working surface 8 is adjustable to add a degree of control over the extent of fiberization, which is also controlled by 15 the rotor speed, the residence time, and nature of the working surface. The working surface 8 consists of six removable segments. These can be replaced by a greater or fewer number of segments having a different design or configuration with, respect to the surface. This flexibility provides an infinite 20 number of choices for altering and optimizing the fiberization. However, the configuration illustrated herein has worked very satisfactorily. More specifically, the grooves of each segment as shown are parallel to each other and are spaced apart by about 2 millimeters (mm.), measured 25 peak-to-peak. Each groove is about 1.5 mm. deep. The radial width of each segment is about 10 centimeters (cm.) These dimensions are given only for purposes of illustration and are not limiting, however. Also partially shown is the working surface on the inside of the hinged cover 10, which is 30 substantially identical to the other working surface 8 already described. When the cover is closed, the two working surfaces provide an inner chamber in which the feed material is fiberized.
Figure 3 is cut-a-way perspective of the fiberizer 35 with the rotor removed to expose the orifice 11 through which the fiberized material passes before exiting through the exit 13 pert 4. The size of the orifice is a variable which controls the degree of fiberization by increasing or decreasing the air flow rate and hence the residence time within the fiberizer. The orifice is contained within a removable plate 12 for convenient changing of the orifice size. An orifice diameter of 160 mm. has been found to be suitable in conjunction with an air flow rate of about 10 cubic meters per minute. Also shown in Figure 3 are the impeller blades 13 of the fan which provides the flow of air through the fiberizer.
Figure 4 is a cross-sectional, cut-a-way view of the fiberizer schematically illustrating its operation. The arrows indicate the direction of flow of air and fibers. More specifically, secondary fiber source 15 is introduced into the feed inlet 3 where it is contacted by the rotating blades 9. The air flow directs the secondary fiber source between the rotor blades and the working surface 8 such that the secondary fiber source is comminuted into smaller and smaller particles, eventually being reduced or fiberized to substantially discrete fibers and fines. The centrifugal forces created by the rotor blades tend to force the particles, preferentially the larger particles, to the apex 16 between the angled working surfaces. These forces tend to keep the larger particles from escaping before they have been completely fiberized. Upon substantially complete fiberization, the comminuted solid materials are carried through the orifice 11 of the removable plate 12. The fan impellers 13 then force the airborne fibers out through the exit port 4.
Figure 5 illustrates the operation of the fiberizer previously described, but slightly modified for continuous operation as would likely be required for commercial operation. In this embodiment, the feed inlet 3 is shown as a tubular inlet rather than the hopper as shown in Figure 1.
The feed tube will provide a continuous supply of shredded secondary fiber sources material of suitable size and quality. Generally speaking, such a material can be in form of sheets of from about 2 (5.08 ems) to about 4 (10.16 oms) inches square or less and should be 14 free of debris to protect the fiberization apparatus. However/ the particle size and shape of the feed will depend on the capabilities of the particular fiberizer being used and is not a limitation of this invention.
Rip shears can be and were used, for example, for shredding the secondary fibre sources used to gather the data presented in Tables I-III.
A further modification illustrated is the continuously moving screen 18 which collects the l0 fibres in the form of a web or batt 19. The mesh of the screen is selected to allow the fines to pass through, preferably aided by a vacuum box 20, which collects fines and channels them to an appropriate recovery site. A wire cloth from W. S. Tyler 15 Incorporated having a mesh of 150 (150 openings per linear inch) a wire diameter of 0.0026 inch (0.0066cm),an opening width of 0.0041 inch (0.01 an), and an open area of 37.4 percent has been found to work best when producing a web having a basis weight of about 12 lb./2800 square 20 feet (5.44kg/260sq.m) or less. Thicker webs tend to trap the fines within the web itself regardless of the size of the wire openings.
Shown in phantom lines is a modified exit port 4 which has been widened to accommodate the width 15 of the moving screen.
In actual practice on a continuous basis, for example, shredded wastepaper was fed to the Pallman fiberizer at a rate of 1.5 pounds per minute 5 (0.113 kg/h). The fiberizer was set up with a 3 mm. clearance between the serrated working surface and the rotor blades. A removable plate having an orifice of 140 mm. was installed behind the impeller, which travelled at 4830 rounds per minute (r.p.m.) with no 10 load. Air flow through the fiberizer was about 365 cubic feet (9.4 cubic metres) per minute. Cooling water was fed to the cooling jacket at the rate of 2 litres per minute. Initial water temperature measured 59 to 60 degress Fahrenheit (°F.) (15 to 15.56 °C) and 15 levelled off at 66 to 68°F (18.89 to 20 °C)., after an extended run. The speed of the wire receiving the fiberized material from the fiberizer was set at 350 feet per minute (11.48 metres per minute). Vacuum under the wire measured 0.6 inch (1.52 cm) of water.
About 18.85 percent of the secondary fibrt source passed through the wire as fines, whereas the remainder was collected on the wire as a 18 dry aeinked product. The fines portion contained about 75 weight percent fiber particulates and about 25 weight percent clay (filler).
Figure 6 schematically illustrates an overall view 5 of a process in accordance with this invention. More particularly, it shows a source of secondary fibers 15 being fed to a fiberizer 21 identical to or similar in function to the type described in the previous Figures. As previously suggested, for most fiberizers it is probably preferable to 10 first shred the secondary fiber source. In the fiberizer the secondary fiber source, whether shredded or not, is substantially reduced to individual or discrete fibers and fines and deposited on a moving screen 18. Deposition of the fibers onto the screen is aided by a vacuum box 20 which 15 facilitates fines removal. The fines include much of the ink present in the raw feed and are collected in a suitable receptacle 22 for disposal. Vacuum for the vacuum box is provided by fan 23, which pulls the fines through the screen and blows them into the receptacle 22. The fibrous mass or 20 batt of fibers deposited on the moving screen is thereafter recovered by metering to a uniform thickness in a suitable metering device 24 and thereafter converted into bales of pulp in a baler 25 or, alternatively, fed directly into a pulper to form a pulp slurry for making paper in the conventional 25 manner. In addition, the recovered fibers can be fed directly to an air-forming apparatus for producing air laid webs or faatts. Those skilled in the art will recognize that a variety of apparatus or equipment can be used in performing the functions illustrated herein.
Figure 7 further illustrates the process of this invention with a block diagram showing the overall process for making paper using fibers recovered from a dry-deinked secondary fiber source. As shown, an ink-bearing secondary fiber source (such as printed waste paper) is fiberized air 35 dry to produce substantially discrete fibers and fines. The fines are separated from the fibers in any suitable manner 17 leaving the recovered fibers tc be used as desired. There are at least several options. As shown, the fibers can be baled for subsequent pulping as shcwr. by the phantom lines. They also can be fed directly to an air-former to produce air-laid webs. Alternatively, the fibers can be cleaned, as by aqueous centricleaning (illustrated in Tables IV and V), or by wet deinking methods which are well known in the industry.
In either case, the resulting fibers can be pulped by slurrying with water and diluted into papermaking stock of an appropriate consistency. The papermaking stock is then wetlaid to form a fibrous web and dried to form a paper sheet. The specific papermaking steps can vary but are also well known in the art. The dry-deinked fiber of this invention is useful as a secondary fiber for tissue, fine paper, printing paper, and other papers.
EXAMPLES In order to illustrate the effectiveness of the process of this invention, six different secondary fiber sources were mechanically fiberized in accordance with this invention as previously described using the fiberizer illustrated in Figures 1-4. The six different samples were computer printout, Xerocopy Bond,* ink-coated board cured by ultra-violet light (UV-coated board), lacquered board, newsprint, and magazines. The second, third, and fourth samples mentioned above are virtually untreatable by standard wet deinking processes. All of the secondary fiber sources were air dry and were processed at room temperature. However, it will be appreciated that certain inks and sizes can be more optimally processed at higher temperatures where they are more friable and therefore form finer particles more easily. On the other hand, some inks or sizes may be thermoplastic and therefore can be more easily processed at lower temperatures.
Husky2 Xerocopy Bond, (Eastman Kodak) photocopy paper 18 The optimum processing temperatures will therefore depend upon the properties of the specific predominant secondary fiber source and the economics of providing a suitable temperature.
Deinked fibers recovered by subjecting each sample 5 to the process of this invention (Test) and non-deinked fibers (Control) recovered by shredding each sample into small pieces and slurrying in warm water (110°F.) with gentle mixing to break the fiber-to-fiber bonds of the sample were each used in an aqueous slurry as a pulp for making paper handsheets in a 10 conventional manner. The handsheets so formed were then tested for brightness using an Elrepho Photoelectric Reflectance Photometer (ISO 3688) and ash content (a measure of coating and/or filler removal (TAPPI T211M-58)). In addition, the Test and Control pulps were also tested for their drainage 15 properties (Canadian Standard Freeness TAPPI T227ra-58). The results are set forth in Tables I, IX, and III below.
(Canadian Standard Freeness (ml.)) Sample Control Test Computer Printout 380 590 Xerocopy 500 700+ UV-Coated Board 500 700+ Lacquered Board 500 700+ Newsprint 100 270 Magazine 130 280 TABLE II (Ash Content (weight percent)) Sample Control Test Computer Printout 10.3 6.2 Xerocopy 9.3 4.6 UV-Coated Board 4.6 2.4 Lacquered Board 5.1 3.2 Newsprint — — Magazine 23 15 TABLE I 19 , 7 TABLE III (Brightness) Sample Control Test Computer Printout 72 77 Xerocopy 81 85 UV-Coated Board 75 78 Lacquered Board 79 82 Newsprint 35 44 Magazine 51 58 10 As is clear from the resulting data, the brightness and ash content of the final sheet were improved when the fibers recovered from the process of this invention were used to form the sheet. In addition, the drainage properties (freeness) of the pulp was also improved by the dry-deinking 15 process of this invention. The dry-deinked samples also exhibited a dramatic reduction in the number of visible ink specks when compared to the untreated samples. Although not specifically measured, this improvement is at least partially reflected in the brightness measurements.
In addition to being a sole treatment for a secondary fiber source to be used as a feedstock for papermaking, the dry deinking process of this invention can also be used as a pretreatment to be followed by further cleaning of the fibers or a conventional wet deinking process. 25 As a pretreatment, this process will decrease wet sludge formation during the wet deinking process (which minimizes the disposal problem created by the sludge formation) and reduces chemical costs since a portion of the inks will have already been removed prior to the subsequent wet deinking treatment.
Tables IV and V contain comparative data for deinked cigarette cartons, illustrating improvement in some of the physical properties of two secondary fiber sources (cigarette cartons) when dry-deinked and subsequently cleaned in a hydroclone (centricleaning). so TABLE IV (Cigarette Cartons) 10 15 20 Freeness Elrepho Brightness Ash, % WET DBINKIKG 616 76.5 DRY DEINKING 619 75.3 3.3 ~ TABLE V (SALEM Cigarette Cartons) WET DEINRING DRY DEINKING 658 79.5 3.0 DRY DEINKING PLPS CENTRICLEANING 700 77.6 1.8 DRY DEINKING PLOS CENTRICLEANING 699 79.9 2.1 Freeness 636 Elrepho Brightness 81.2 Ash, S - In each Table the first column contains physical property data for the product obtained by subjecting the particular sample to a conventional wet deinking process. The particular process used is of no consequence with respect to the process of this invention, but merely serves as a benchmark for purposes of comparison. Specifically, the deinking solution comprised 3.0 grams sodium hydroxide, 0.2 grams tetrasodium pyrophosphate, 0.2 grans Armak (Trade I&xk) Ethofat 242/25 surfactant, and 1667 ml. water. The deinking solution was heated to 180° F. and 50 grams of oven dried waste paper 25 cut or tom into half inch pieces was added with mixing.
After fiberization of the sample occurred, the sample was washed three times by diluting with water to a consistency of 1%. The washed product was then tested for Canadian Standard Freeness and formed into handsheets for the brightness tests. 30 The second column contains corresponding data for the products of the dry deinking process of this invention as previously described.
The third column contains corresponding data for the products obtained by centricleaning the fibers obtained from the dry deinking step of the second column. In particular, the dry deinked fibers were slurried with water to a feed 35 ό '4 ο ο * 21 consistency of about 0.5 dry weight percent. The slurried fibers were fed under 42 pounds per square inch gauge (psig.)(295.26 kg/m2) pressure to a Bauer "600N" Centricleaner at a rate of approximately 40 5 gallons (182 litres) per minute. The particular apparatus referred to is a hydrocyclone (liquid cyclone) of a nylon construction having a generally concical shape with a 3 inch nominal internal diameter at the top and a height of approximately 36 inches 10 (91.44 cm). The Centricleaner serves to separate the fibers from smaller and more dense particulates in a manner well known to those familiar with mechanical separations.
These results illustrate the effectiveness 15 of the dry deinking process of this invention as a pretreatment followed by cleaning, especially with regard to fines reduction as measured by the increased fceeness in both samples. In addition the brightness of both washed samples was slightly improved over the 20 dry-deinked product.
Although not illustrated, the dry-deinked fibers can also be subsequently wet-deinked by conventional means well known to those skilled in the art of deinking. For example, the dry-deinked fibers 25 can be slurried in the deinking solution previously described herein for a period of time to remove additional ink and washed and/or centricleaned. 22 It therefore is appreciated that the invention has application either as a deinking process, per se, or as a process in combination with other paper-making processes. Further, the invention has numerous advantages not achieved by the prior art.
Claims (16)
1. A method of deinking an ink-bearing secondary fibre source consisting essentially of ink-containing waste paper comprising mechanically 5 fiberizing the secondary fibre source to produce substantially discrete fibres and ink-containing fines, said fiberizing being carried out with the secondary fibre source being substantially air dry or sufficiently dry to prevent adhesion of the resulting 10 fibres and fines, and then separating the said ink-containing fines from the fibres.
2. A method as claimed in Claim 1 wherein the secondary fibre source contains no more than about 20 weight percent moisture. 15
3. A method as claimed in Claim 1 wherein the secondary fibre source is air dry.
4. A method as claimed in any of the preceding claims wherein the fines are separated from the fibres by passing the fines through a screen having a mesh 20 size sufficiently small to prevent passage of the fibres.
5. A method a3 claimed in any of the preceding claims wherein the separated fibres are directly slurried in water for making a cellulosic product.
6. A method as claimed in any of Clams 1 to 4 wherein the separated fibres are fed directly to an air-former.
7. A method as claimed in any of claims 1 to 4 wherein the separated fibres are formed into a substantially uniform batt and baled.
8. A method as claimed in any of the preceding Claims 1 to 5 wherein the separated fibres are cleaned in· an aqueous solution.
9. method as claimed in claim 6 wherein the separated fibres are cleaned in a hydrocyclone,
10. A method as claimed in Claim 6 wherein the separated fibres are cleaned by a wet deinking method.
11. A method as claimed in any of the preceding claims wherein the secondary fibre source is computer printout paper, photocopy paper, ink-coated board cured by ultra-violet light, lacquered board, newsprint, cigarette cartons, or magazines.
12. A method of deinking an ink-bearing secondary fibre source consisting essentially of ink-containing waste paper having a surface size which comprises mechanically fiberizing the secondary fibre source to produce substantially discrete fibres and fines comprising ink and size, said fiberizing being carried out with said secondary fibre source being substantially air dry or sufficiently dry to prevent adhesion of the resulting fibres and fines, and separating the fines from said fibres, whereby said fibres are suitable as secondary fibre.
13. A process for making paper from an ink-bearing secondary fibre source consisting essentially of ink-containing waste paper comprising: (1) mechanically fiberizing the secondary fibre source to produce substantially discrete fibres and fines, said fiberizing being carried out with said secondary fibre source being substantially dry to prevent adhesion of the resulting fibres and fines; (b) separating said fines from said fibres; (c) slurrying said fibres with water to form a papermaking stock; (d) wet-laying the papecmaking stock to form a web of fibres; and (e) drying the web.
14. A secondary fibre useful in recycle for the manufacture of cellulosic product and produced from an ink-bearing secondary fibre source consisting essentially of ink-containing waste paper comprising discrete fibres obtained by mechanical fiberization of said fibre source when air dry or sufficiently dry to prevent adhesion of the resulting fibres and fines and obtained separately from the resulting fines, and said discrete fibres exhibiting no hydration which -is characteristic of fibres obtained from wet recycle.
15. Deinked fibres produced by a method as claimed in any one of Claims 1 to 4 or 8 to 12.
16. A method according to Claim 1 or 12 of deinking an ink-bearing secondary fibre source consisting essentially of ink-containing waste paper, substantially as hereinbefore described. F. R. KELLY & CO., AGENTS FOR THE APPLICANTS.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US45081282A | 1982-12-20 | 1982-12-20 | |
US55417483A | 1983-11-22 | 1983-11-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
IE832924L IE832924L (en) | 1984-06-20 |
IE54867B1 true IE54867B1 (en) | 1990-02-28 |
Family
ID=27036139
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE2924/83A IE54867B1 (en) | 1982-12-20 | 1983-12-12 | Process for dry deinking of secondary fiber sources |
Country Status (26)
Country | Link |
---|---|
KR (1) | KR880001122B1 (en) |
AT (1) | AT391492B (en) |
AU (1) | AU570419B2 (en) |
BR (1) | BR8306973A (en) |
CA (1) | CA1235013A (en) |
CH (1) | CH665233A5 (en) |
DD (1) | DD223745A5 (en) |
DE (1) | DE3345623A1 (en) |
DK (1) | DK586983A (en) |
ES (1) | ES528218A0 (en) |
FI (1) | FI73268C (en) |
FR (1) | FR2538012B1 (en) |
GB (1) | GB2133817B (en) |
GR (1) | GR79451B (en) |
HU (1) | HUT36509A (en) |
IE (1) | IE54867B1 (en) |
IL (1) | IL70481A (en) |
IN (1) | IN159108B (en) |
IT (1) | IT1169396B (en) |
LU (1) | LU85147A1 (en) |
MX (2) | MX174348B (en) |
NL (1) | NL8304349A (en) |
NO (1) | NO158549C (en) |
PH (1) | PH21639A (en) |
PT (1) | PT77851B (en) |
SE (1) | SE8307003L (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
YU246783A (en) * | 1983-11-22 | 1986-06-30 | Kimberly Clark Co | Process for dry color removal from secondary yarn batches |
CA1249903A (en) * | 1984-05-10 | 1989-02-14 | Christopher C. Mollett | Composition and method of deinking of recycled cellulosic material |
US4615767A (en) * | 1984-10-25 | 1986-10-07 | Kimberly-Clark Corporation | Process for removing ink-bearing fines from dry-deinked secondary fiber sources |
US5762756A (en) * | 1994-11-21 | 1998-06-09 | The Black Clawson Company | Methods and apparatus for pulping and deinking |
DE102011120630A1 (en) * | 2011-12-09 | 2013-06-13 | Aerocycle Gmbh | Process for recycling waste paper |
DE102015223333B4 (en) | 2014-11-25 | 2018-06-28 | Technische Universität Dresden | Process and plant for processing high-strength paper products |
CN111304944A (en) * | 2019-12-13 | 2020-06-19 | 义乌拓延贸易有限公司 | Intermittent blanking makes stirring more even waste paper deinking equipment for beating machine |
CN113529462A (en) * | 2021-07-21 | 2021-10-22 | 浙江五星纸业有限公司 | Facial tissue bowl disintegrating device |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1417961A (en) * | 1920-10-07 | 1922-05-30 | Williams Patent Crusher & Pulv | Method of reducing fibrous sheet material |
GB247284A (en) * | 1924-11-11 | 1926-02-11 | Kurt Gerson | Improvements in the treatment of household and street waste |
US2532660A (en) * | 1944-05-11 | 1950-12-05 | Arthur J P Care | Apparatus for producing fiber staples |
GB675178A (en) * | 1948-04-15 | 1952-07-09 | Paper Patents Co | Method of and apparatus for making a loosely felted web of fibrous material |
DE1097802B (en) * | 1957-07-30 | 1961-01-19 | Condux Werk | Process for dissolving waste fibers, especially waste paper |
DE1246382B (en) * | 1961-03-30 | 1967-08-03 | Battelle Institut E V | Process for the digestion of waste paper |
SE320876B (en) * | 1966-08-17 | 1970-02-16 | Mo Och Domsjoe Ab | |
GB1134611A (en) * | 1967-01-28 | 1968-11-27 | Australian Paper Manufacturers | Process and apparatus for cleaning and disintegrating fibrous materials |
US3933577A (en) * | 1971-01-08 | 1976-01-20 | Penque Ronald A | Process of sonically treating municipal waste to produce high quality paper pulp and fertilizer |
US3741863A (en) * | 1971-08-27 | 1973-06-26 | Rust Eng Co | Method of recycling waste cellulosic materials |
US3773613A (en) * | 1971-10-13 | 1973-11-20 | Int Paper Co | Method for converting plastic-containing broke to fluff |
US3902672A (en) * | 1974-01-31 | 1975-09-02 | Bauer Bros Co | Waste handling apparatus |
-
1983
- 1983-12-12 IE IE2924/83A patent/IE54867B1/en unknown
- 1983-12-16 CA CA000443544A patent/CA1235013A/en not_active Expired
- 1983-12-16 DE DE19833345623 patent/DE3345623A1/en not_active Withdrawn
- 1983-12-19 MX MX1154883A patent/MX174348B/en unknown
- 1983-12-19 AU AU22514/83A patent/AU570419B2/en not_active Ceased
- 1983-12-19 NO NO834694A patent/NO158549C/en unknown
- 1983-12-19 CH CH6749/83A patent/CH665233A5/en not_active IP Right Cessation
- 1983-12-19 FR FR8320269A patent/FR2538012B1/en not_active Expired
- 1983-12-19 IL IL7048183A patent/IL70481A/en unknown
- 1983-12-19 BR BR8306973A patent/BR8306973A/en not_active IP Right Cessation
- 1983-12-19 GR GR73278A patent/GR79451B/el unknown
- 1983-12-19 MX MX19984183A patent/MX157760A/en unknown
- 1983-12-19 SE SE8307003A patent/SE8307003L/en not_active Application Discontinuation
- 1983-12-19 NL NL8304349A patent/NL8304349A/en not_active Application Discontinuation
- 1983-12-19 IT IT4953783A patent/IT1169396B/en active
- 1983-12-19 PT PT7785183A patent/PT77851B/en not_active IP Right Cessation
- 1983-12-19 FI FI834675A patent/FI73268C/en not_active IP Right Cessation
- 1983-12-19 GB GB08333769A patent/GB2133817B/en not_active Expired
- 1983-12-20 PH PH30008A patent/PH21639A/en unknown
- 1983-12-20 IN IN1553/CAL/83A patent/IN159108B/en unknown
- 1983-12-20 DD DD83258239A patent/DD223745A5/en not_active IP Right Cessation
- 1983-12-20 ES ES528218A patent/ES528218A0/en active Granted
- 1983-12-20 KR KR1019830006022A patent/KR880001122B1/en not_active IP Right Cessation
- 1983-12-20 DK DK586983A patent/DK586983A/en not_active Application Discontinuation
- 1983-12-20 LU LU85147A patent/LU85147A1/en unknown
- 1983-12-20 AT AT0445583A patent/AT391492B/en not_active IP Right Cessation
- 1983-12-20 HU HU435783A patent/HUT36509A/en unknown
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4668339A (en) | Process for dry deinking of secondary fiber sources | |
JP2987272B2 (en) | Method for producing fiber pulp | |
US4440635A (en) | Process and apparatus for the recovery of cellulose fibers from paper-plastic mixtures | |
US7279073B2 (en) | Apparatus for liquid-based fiber separation | |
US6419787B2 (en) | Process for recycling paper broke containing wet strength additives | |
IE54867B1 (en) | Process for dry deinking of secondary fiber sources | |
US4615767A (en) | Process for removing ink-bearing fines from dry-deinked secondary fiber sources | |
US20060016568A1 (en) | Process for sheeting raw cotton linters | |
US3224925A (en) | Fibrous products from barking waste | |
NZ206656A (en) | Dry de-inking of paper by fiberization | |
WO1998026874A1 (en) | Reducing wax content and enhancing quality of recycled pulp from occ and waste paper | |
IE914553A1 (en) | Fibrous component for paper production, paper made therewith¹and use thereof and method for producing fibrous component¹and paper | |
Chaudhary | Circular economy of paper industry in Finland | |
PL141851B1 (en) | Method of decolorization from the ink or dye secondary fibrous materials,especially waste paper | |
US20080073044A1 (en) | Apparatus for liquid-based fiber separation | |
NO793357L (en) | PROCEDURE FOR AA IMPROVING THE CHARACTERISTICS OF PAPER MANUFACTURED BY THREE BY MECHANICAL SIZE | |
MXPA03011909A (en) | Apparatus for liquid-based fiber separation. |