HUP0004824A2 - Thermoset interpolymers and foams - Google Patents

Thermoset interpolymers and foams

Info

Publication number
HUP0004824A2
HUP0004824A2 HU0004824A HUP0004824A HUP0004824A2 HU P0004824 A2 HUP0004824 A2 HU P0004824A2 HU 0004824 A HU0004824 A HU 0004824A HU P0004824 A HUP0004824 A HU P0004824A HU P0004824 A2 HUP0004824 A2 HU P0004824A2
Authority
HU
Hungary
Prior art keywords
olefin
vinyl
units derived
mol
polymer units
Prior art date
Application number
HU0004824A
Other languages
Hungarian (hu)
Inventor
Edwin R. Feig
Thoi H. Ho
Seema V. Karande
Kevin W. Mckay
Francis J. Timmers
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/921,642 external-priority patent/US5977271A/en
Priority claimed from US08/921,641 external-priority patent/US5869591A/en
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Publication of HUP0004824A2 publication Critical patent/HUP0004824A2/en
Publication of HUP0004824A3 publication Critical patent/HUP0004824A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/22—Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0838—Copolymers of ethene with aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

Abstract

A találmány tárgya részlegesen vagy teljesen térhálósított készítmény,amely (A) az (A) és (B) komponensek együttes tömegére vonatkoztatva 1-99 tömeg% legalább egy olyan, lényegében random interpolimerttartalmaz, amely (1) 1-65 mol%-ban (a) legalább egy vinil- vagyvinilidén aromás monomerből vagy (b) legalább egy gátolt alifás vinil-vagy vinilidénmonomerből, vagy (c) legalább egy vinil- vagy vinilidénaromás monomerből és legalább egy gátolt alifás vinil- vagyvinilidénmonomerből származó polimer egységeket, és (2) 35-99 mol%-banlegalább egy 2-20 szénatomos alifás a-olefinből származó polimeregységeket tartalmaz; (B) az (A) és (B) komponens együttes tömegérevonatkoztatva 1-99 tömeg%-ban a következő polimerek legalább egyikéttartalmazza: (1) homopolimer, amely egy 2-20 szénatomos a-olefinből,aromás csoporttal helyettesített 2-20 szénatomos a-olefinből vagyhalogénatommal helyettesített 2-20 szénatomos a-olefinből származóegységeket tartalmaz; (2) interpolimer, amely (a) 2-98 mol%-banetilénből származó polimer egységeket és (b) 98-2 mol%-ban legalábbegy 3-20 szénatomos a-olefinből, akrilsavból, metakrilsavból, vinil-alkoholból, 4-20 szénatomos diénből, vinil-acetátból származó polimeregységeket tartalmaz; (3) sztirolos blokk-kopolimer; (4) az (A) alattmeghatározott, lényegében random interpolimer, ahol az (A) és (B)/(4)interpolimerek különböznek. A találmány tárgyát képezi továbbá a fentikészítmény előállítására szolgáló eljárás is. ÓThe subject of the invention is a partially or fully cross-linked composition, which (A) contains 1-99% by weight of at least one essentially random interpolymer based on the combined weight of components (A) and (B) which (1) in 1-65 mol% ( polymer units derived from a) at least one vinyl or vinylidene aromatic monomer or (b) at least one hindered aliphatic vinyl or vinylidene monomer, or (c) at least one vinyl or vinylidene aromatic monomer and at least one hindered aliphatic vinyl or vinylidene monomer, and (2) 35 - 99 mol% contains polymer units derived from at least one C2-20 aliphatic α-olefin; (B) contains 1-99% by weight of at least one of the following polymers, based on the combined weight of components (A) and (B): (1) homopolymer, which is a 2-20 carbon a-olefin from a 2-20 carbon atom, substituted with an aromatic group contains units derived from -olefin or halogen-substituted α-olefin with 2 to 20 carbon atoms; (2) interpolymer comprising polymer units derived from (a) 2-98 mol% of banethylene and (b) 98-2 mol% of at least one C3-20 α-olefin, acrylic acid, methacrylic acid, vinyl alcohol, 4-20 contains polymer units derived from carbon diene, vinyl acetate; (3) styrene block copolymer; (4) the essentially random interpolymer as defined under (A), where the interpolymers (A) and (B)/(4) are different. The subject of the invention is also the method for producing the above preparation. HE

HU0004824A 1997-08-27 1998-08-26 Thermoset interpolymers and foams HUP0004824A3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/921,642 US5977271A (en) 1994-09-02 1997-08-27 Process for preparing thermoset interpolymers and foams
US08/921,641 US5869591A (en) 1994-09-02 1997-08-27 Thermoset interpolymers and foams
PCT/US1998/017673 WO1999010395A1 (en) 1997-08-27 1998-08-26 Thermoset interpolymers and foams

Publications (2)

Publication Number Publication Date
HUP0004824A2 true HUP0004824A2 (en) 2001-04-28
HUP0004824A3 HUP0004824A3 (en) 2004-04-28

Family

ID=27378528

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0004824A HUP0004824A3 (en) 1997-08-27 1998-08-26 Thermoset interpolymers and foams

Country Status (9)

Country Link
EP (1) EP1007577A1 (en)
JP (1) JP2001514275A (en)
KR (1) KR20010023264A (en)
AU (1) AU8920998A (en)
BR (1) BR9814448A (en)
CA (1) CA2300062A1 (en)
HU (1) HUP0004824A3 (en)
NO (1) NO20000963L (en)
WO (1) WO1999010395A1 (en)

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US6709742B2 (en) 1998-05-18 2004-03-23 Dow Global Technologies Inc. Crosslinked elastic fibers
AR018359A1 (en) 1998-05-18 2001-11-14 Dow Global Technologies Inc HEAT RESISTANT ARTICLE, CONFIGURED, IRRADIATED AND RETICULATED, FREE FROM A SILANAN RETICULATION AGENT
CA2333114A1 (en) * 1998-06-03 1999-12-09 Trexel, Inc. Microcellular thermoplastic elastomeric structures
WO2000053669A1 (en) * 1999-03-11 2000-09-14 The Dow Chemical Company Olefin polymers and alpha-olefin/vinyl or alfa-olefin/vinylidene interpolymer blend foams
US6613811B1 (en) 1999-06-03 2003-09-02 Trexel, Inc. Microcellular thermoplastic elastomeric structures
US6365658B1 (en) * 1999-08-12 2002-04-02 The Dow Chemical Company Polymer compositions
US6239242B1 (en) * 1999-08-21 2001-05-29 Nova Chemicals Corporation Vinylaromatic and olefin pseudoblock polymers
JP5128955B2 (en) * 2004-12-03 2013-01-23 ダウ グローバル テクノロジーズ エルエルシー Kibe fiber plastic composite material
AU2005316788B2 (en) 2004-12-17 2012-04-05 Dow Global Technologies Llc Rheology modified polyethylene compositions
JP5435942B2 (en) 2006-05-29 2014-03-05 電気化学工業株式会社 CROSS COPOLYMER MANUFACTURING METHOD, OBTAINED CROSS COPOLYMER AND USE THEREOF
KR101591120B1 (en) 2008-04-15 2016-02-02 덴카 주식회사 Thermoplastic resin composition
JP5719517B2 (en) * 2010-02-25 2015-05-20 東ソー・ファインケム株式会社 α-olefin / styrene copolymers and process for producing the same
KR101248423B1 (en) * 2011-06-09 2013-04-02 에스케이종합화학 주식회사 Method for preparing ethylene - α-olefin - diene copolymer
RU2523799C1 (en) 2011-12-20 2014-07-27 Чайна Петролеум Энд Кемикал Корпорейшн Additive and method of terminating polymerisation and/or reducing viscosity of polymer solution
JP6589976B2 (en) * 2015-03-04 2019-10-23 Ｊｓｒ株式会社 Copolymer, polymer composition and cross-linked polymer
WO2019216109A1 (en) * 2018-05-08 2019-11-14 株式会社ブリヂストン Vulcanized rubber composition, tire tread and tire

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IT1004558B (en) * 1972-08-31 1976-07-20 Ppg Industries Inc SILANATE COPULATING AGENT FOR RUBBER
JPS6011329A (en) * 1983-07-01 1985-01-21 Mitsubishi Petrochem Co Ltd Continuous manufacture of crosslinked and foamed body
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5739225A (en) * 1993-12-28 1998-04-14 Idemitsu Kosan Co., Ltd. Process for preparing olefin polymer, and ethylenic polymer
EP0778852B1 (en) * 1994-09-02 1999-10-20 The Dow Chemical Company Thermoset elastomers

Also Published As

Publication number Publication date
BR9814448A (en) 2001-11-06
CA2300062A1 (en) 1999-03-04
HUP0004824A3 (en) 2004-04-28
NO20000963L (en) 2000-04-26
JP2001514275A (en) 2001-09-11
AU8920998A (en) 1999-03-16
KR20010023264A (en) 2001-03-26
EP1007577A1 (en) 2000-06-14
NO20000963D0 (en) 2000-02-25
WO1999010395A1 (en) 1999-03-04

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