HUE029885T2 - Amidoszulfuront és egy piridin-herbicidet tartalmazó herbicid kombinációk - Google Patents

Description

Description

Herbicide combinations comprising amídosuiíumn anda pyrimnafoerblcide: ?ha invention is in the teoifoicai fieid cf cmp protection pmducts which es« fee employed against harmful plants, íor example incrop piants, and which comprise, as active compounds, a combination; ßf atleast two specie herbicides.

The document EP-A- 13125adisdoses syifônyiyfeas and their sailsand alsó-their use as herbicides and/ef plan? growth regulators. the efficacy of these herbicides against harmful plants in the crop plants Is at a high issei, hut depends in general en the application rate, the formylation inguastion, the barmiul giants or spectrum of barmiul piahts tobe oontmlied in each ease, the climatic conditions, thesoii conditions arfo; the like. Another criterion is the duration of action, or the breakdown rate of the bethieide, ifappfopbets, changes In the sensitivity of harmful plants,"which may occur upon iproiongsd use of the herbicides or

Within geegraghic iimitations, must aiso ba taken into--congjdersitet^ in tf;: o dint action in the case (d individual harmhil piants by increasing the appiication rates of ihmherblddes » only possible to a cédáin dogreer for example ihecause such a precedyre frequently reduces the seiacbvify ot the herbicides or because the action is not improved, even when applying higher rates,

In some cases, the selectivity in crops can ; be improved by adding safenera in générai, however, there remáiitea need for methods to achieve the herbicidai action with a fewer appiieaiipn rate of ^, active compounds. Hot only does a lower application rate reduce the feguired for application, but, as a ruie, it also reduces ihartmou.aitf formulation auxiliaries required, it bath feddoes the economic input and improves the ecological compatibility ofthe herbicide fmatment.

One possibility of improving the application profiie of a herbicide btn-i^ifea^mblbibf thfia^e compound with one or more other active compounds. However, the combined use Ola piymiy of active compounds frequently causes phenomena of physics! and biological incompatibility, for example a iaok of stability In a coformulation, decomposition of an active compound, or anfogonism ot the active compounds. What is desired are, in contraah eombinadons of active compounds having äh advaotageoue activity profile, high stability and, if possibie, a spetgistioaiiy improved action, which allows the application rate to be reduced in comparison with tbe individual application cl the active ccmpeunda to be combined. WQêZiWWM arfo WOÖ3/QT38M disclose herbicide combinations with amidosuifufon.

Suiptsingly» it has now been fö'ufii^ÄE eefÄ :^iy^:ööii^iö!üi^di;^Ä the gmuh öf fe süffóhyihíeas or their sails in combination with certain structurally diiereui herbicides act logatÄ in a pafticuiatiÿ advantageous manner, for example when they are employed in crop plants. fhe invention thus provides herbicide combinations oomphsing components p} and (S). Where (A) denotes one or more henvcKies of the formula (1} and their seifs:

and (B) denotes one or more herbicides selected from the group consisting of picioram and its salts and: esters and aminopyraiid and Is salts end esters.

Preferred compounds (8) are (iisted with the “common name” and a iiterature reference, for example from "The Pesticide Manual" 14th Ed., British Crop Protection Council 2006, abbreviated as "PM”} (B1} pioioram, in padiodlar also Including its salts and esfeîs fBfâ, pp. 838 --040), for exaipple ^ amino-6, Sid- tilohloropyndine-O-oartsoxylio acid (appilcetion rate generaiiy: 20 - 300 g of AS/ha, preferably 50 -150 g of AS/ha; application i^tratlo A,; ^gea^ify;·*: 4 :1 ~ 1 ; 60:, preferably 1 : 2 - 1 :10), (62) aminopyralidj iln iparficuiar also InPiUdiog Its salts and esters (PM, pp, 3G - 31}, Aar example 4-amino-SjS-dichíomdyndíne-S-oarbdíryiic adid (application irate generally; 16 - 260 g of AB/ha, preferably 30 ~ yQ:$:öf;AS/ha48pp| ratio Ad; i&genarsliy -1 : 20, preferably 1 ; i - 1 . 5).

Preferred mixing partners (B) am piworarc (81.1), p;ciorgav-dimethyíammonipSP:|B1s2|npícioram isoctyl pi,3), picioram-eodium (B1 4}, picloram-potassium (Βΐ.δ). (81,6), piciorarn-tnsfhandiammonlum (~ picioram-trolamine) {Bi.?}, piolöramdriisöpropylarnmöninm :(01,8), aminopyraíid:(i2vl), emjnopyralid-sodjum (Β2 2), arninopyraid-potassium iCBS.O}, aminopyraiid-4f1C2-'hydroxyprO:pyi)animoniuntiÖ2;:4y 'TheherPioide oombiriafiorrsaeoording

Oornpeheois (A) and (B) and : may comprise: turf her components,: for example sgroohemieaiiy active caöR^öynd^-of :â: diflgpnt type and/or fbrmM^^C^uxlilari^is ei#á cusfoawy in crop protection, or they may be employed together with these, lb a preferred embodiment, the: herbicide c^mbiostions according fe the insertion have synergistic effects, The synergistic effects can M obsewed, fer example. when the active compounds (A} and (8} ere applied together, but they oen Mpuentfy also be observed whert the compounds are applied ae a split application over lime. Another possibility is the appiicatlonsdf the individual herbicides or the herbicide cprnbsndtiops in a plurality of portions {sepuentlal sppiioatleh}, fer:example alter preemergence applications, followed by post-emergence applications or alter early post-emergence appl ications , followed by applications at medium or late posbemergenee Preferred is the simultaneous or nearly simultooous application of the sofiya eofttpounds of the herbicide combination according to the invention.

The synergistic effects allow the applfpaöbh fîtesöfihétrafivMuaí active compounds to be reduced, a more potent action at the same applieetion:fate, the control of hitherto anoontrolladfe species ifocfívity gaps}, an extended: application period and/pra reduced number of individual applibahons teguifed and - as a: result for the user - more advantageous weed control systems both from: an economical arid ecological point of view.

The abovomentloned: formula (I) piclorarn and amlnopyralid Include all stereoisomers and their mixtures, in parbcular also pcamle mixtures ahi-I/enabfteme^iParjpoas^#- the fospeobye bfeioglcafly active enantiomer The compounds of the formulae (f) and (11} are capable offorming: salts, for example, In which a hydrogen atom is replaced by an agriculturally suitable cation. These salts are, tor example, metat salts, la particular alkali metal salts or alkaline earth metal salts, Ip particular sodium and potassium saitsr or else ammonium salts or salts with organic amines. Salt formation may also take place by addition of an acid: to basic groups, such as, for example, amino and alkylamlno, /fefes suitable for this purpose are strong inorganic and organic acids, for example HCI, Hir, :N*S% or ididfSa. Compounds of the formula (1} and their salts end also their preparation are described, for examp le* in Ert~A-1312bS:and US 4,718,93?. Preferred compounds of the formula (1} and''j^elb§eilfs.Wf:'IH4#--' dMie^oxypybmldin-2~yiH-misyl(mefhp^jiPmoyiit»a (amldosujfuron, A1,1} and its sodium salt (A1.2) (see, for example, £foA-1312§8 and Pfe, pp. 27-28),

Ths abpvemenfioned active oompounds of the formula (1) and their salts are capable of Inhibiting the enxyrpe acefolaetate synthsié::{ALS^afí4:^#::^ot#te: synthesis In plants. The application rate of the active compounds of the fermula (1): ahditheir salts can be varied within a wide range, fer example between T g: and §00 g of AS/ha (AS/ha means ^activa suhsfonco per hectare”, based on 100% active compound}, in the case of applications at application rates of from 10 g fe 300 g of AS/ha of the active compounds of the foitnMif:#SPâÂlf'm^,:ipf#limWy the active compounds (A1,1), (Α1,2|, a relatively broad spectrum of harmfui plants is co.ntrolied pre-and posbernergence. in the ©embteafions according tóibainvention,the application raiesare generally lovster, for example ín thé rarsge from 0,5 to 200 g of APia, pmíerafeSy from 1 to 120 giof AS/ha ff, in '$mmméf'étán a©five compound ü usad;: this embraces esters, salts and ísornors, in partíouíar optical ísomera, in partieulartha commercial Mm m forma, öntess the context indicates otherwise, Also included to iha case of stefonamldes syohas sutfenytureas are salts which ara formed fey exchanging; a hydrogon aiorn at the sulfonamide group fey a cakón. €f partteoiar interest are herbicide combinations according to the tevehtioo hading a content of the t'oiiowing compounds (A) * (8): (At 1} * (81.1), (At. 1} *· (81.2), (All) * (81 3), (At.1} + {81.4}, #1.1} + (81,5), (All# (816), (At 1}-MB 1.7), (At. 1} *- {81.8), (All) + (82.1), (All) + (82.2), (All) + (82 3), (All) + (82,4); #1.2): *181.1 ), (A1.2) *· (81.2). #12)-+ (81 3), (Ä^) ^ + (816), #12); *181.7), (At.2) -(· (81.8), #12) + (82 1), (A1.2) + (82.2), (A1.2) + (82.3), (At .2) + (82,4). it may he advantageous to combine one or more ©impounds (A); with a piurafify of compounds (Bfe or Ίο combine a piuralriy of compounds (A) with one or more compounds (8). Furthermore, the combinations according to the inyention may comprise agrochemicaiiy notice stempounds of a diffetehf structure (active compounds {£)). for exempte lorn the group of the sateners, :füh|ieides, herbicides, insecticides and: piarif growth repteters or formulation in crop protection, or they may be used together with these. For such combinations, the preferred conditions illustrated below in particular ter combinations (A): + (8)according to the: invention also primarily epply, provided they comprise the combinations #·)·* (8):according totha ihvantídh. ahd With: respect to the combination (A) * (8) in question; Additives are, for example, fertilisers and colorants; Preferred agrochemioeily active compounds (8) are herbicides and/or ssfbnaite,

For use of the herbieida combihetion according te thé invention in plant crops, it may be expedient, depending on the plant prop, to apply a safener {£} from certain application rates upward in orderte reduce or to avoid possibfe damage to the crop plant Ine foiiowing groups of compounds are exampies of suitable safeners (C). a) Compounds of the dichiorephenylpyrazolim acid (81) type, preferably compounds such as ethyl 1-(2,4--dlcfeterophenyl:}';S>:(MboxyParbony!}#-methyi<'2«-pyraeoitee-3* cerhoxyiate (81-1, rnefenpyr-diethyi), and ratefed compounds as they are described for : exampte: in wo 9i/0?87##nd:Pfe cpp Sid-Sib}. b) Dichioröphenyípyrapoíecarhoxylíe apid derivatives, preferably compounds such as ethyl 1'.(2i4'dtehiorophenyl)"5~methyipyraxote-3-carbQxyiate (81-2), ethyl 1 -{2!4-dtehiorpgbeny!)'-5~isopropylpyr;a£0te-3--carboxylate (SI ethyl 1,1 -4), ethyl: l^pi^itóliií^p^íiy^'S'-őbeinyípyfséaiövá'Mifhóxyíáfó (SI -S) and related compounds as are dMcrlbed Id: IE4-3S3 1:31 and EP-M8# 8©S. ο) Compounds of the inaxoiocarboxytlc acid ($ 1 ) type, preferably compoonos such as: fepehiemxcle. le, ethyl 1«{2,44ΐ0ΐιΙόι:όρΗ^8|?!}·δ4?κ^ίΙόίοπ^®Φ>νί·(1 Η)··ί,2.4#g^öie4”: earbpXÿlate lSi -^Mbd related compounds: (see EP4-1T4 582 and £^--4-348628)( d) Compounds of the S-benayl - or S-phenyi-C-lsoxazollne-C-carboxyiic acid type or of the 6.5-diphenyl-2·isoxaxoiine-feearboxylie acid type, preferably compounds such as ethyl 5-(2,4-dichlorobenzyi)“2"isoxazc!ine-3"Carboxylate (S1 ·?} or ethyl S'-phen^^ïidôtMôîîfi^â-diflpôï^iiâli ä£.£äl described for example in WO @1/08262, or of sthyf (St4* isoxadifenfethyi} or mprőpyí §,d- diph;8nyl-Cdsoxaeeilhe:>Sfearboxylate (SI -18) dr ethyl 8-p4uorophen:ÿl|'§-phenyi2fe isoxaxoiine-3 carboxylate (SI -11), as are described in patent application (VYOA-95/0789?}. a) Compounds of the bidulholinoxyaeetlc acid (S2) type, preferably femethyihex-feyl (Sfehloro-d-quinoitncxylseetate (S2-1, eipquintoeebnfexy!. e.g. Efdltpp. 191-136), (1;3feimefhyteubfeyi) (i-dhiom-3-güinoisnôxÿJeoetate (S2-2:), 4-allyioxybutyl {5*chioro*8--quinoiinoxy)acetate (S2-3). 1 allyíoxyprop-2-yi (8-ctdoro--8-qulnoiírioxy)acetatö (82-4), ethyl (8-chloro-8-quinolirîoxy)acotate (S2-5) rnefhyl (:5-chioro-6-gdtnoiinoxy)aostate (S2-6), a ily I (S-chioro~8-quinoli noxy feoetate (S2- ? ), 2~(|*pmpylldeeel:m(npoxy}-feefhyt^p^ (S2-8), 2-oxoprop-1 -yl {6-chioro-8-quinolinoxy}ac«tata (S2-9) and related compounds ae are described In EP-A-86 7SÔ, &amp;P-A-34 349 and EF-A-191 736 or EP-A-0 492 366 :| Cempdphde of the (S-c:hidfe4-quineileexy)malo:!!c acid type, preferably compounds such ae diethyl: (Smh|qf0~8-quíböiiddxyp^^ diallyl (5-chio?p4~dU:lPcilnoxy)maiQnate. methyl ethyl (5--chlaro~8-quin0Sinoxy)rna!onat8 and related compounds as are described in EP-A-0 582 136. gf APtivo compounds of the phenoxyacetic acids, pheooxypmpiomo acids or aromatic carboxylic: acids type, such as, for example, 2,4'dichlcrophendxyacetic acid (end esters) (2,4-D), 4:-chioro-2-methyipbehcxypmpiCbib asters (meedprop), MCPA or 3,8-dichicro-2-rnethoxybenxoic acid (and esters) (dlcamba) N) pyrimMine type, su# as. fereysr'npie, "fenciorinf (ΡΜ; pp. 386-31/} fe 4 ,β-tí iph ^r#^2“0isg^ipYr}^i^|: i) active compounds of the dlcbSerosMfemide type, which pro frequently used m pre-emergence safeners (soil-acting safeners) such os, for example, ’d-chiormkf (PM pp. 270-271} {» N.sN -diaiiyi-2,2 -dichloroacetarolde}, 'ΆΡ -2§148" ('- 3-d!Chioroacefy1--2,2,5-tnrnethyi--1 .Saaxazoiidone by Steuffer), oenoxacor' (PM, pp. 34¾) (~ 4-idfehbmacetyP3,4<-djbydro-3--rsafhyl-2H -1.4-bspsoxazioo}, APP8-1292” (-- N--oliyhl4((1i3MfOi<piap#yi}waihyi)dichloroaeetarbide by PPC3» Industries}, "ADN824" # N-allyr-N-ftaliyiamlnocari^arn'IimethyildiChiomacetarnide by Sagro-Chem}, "AA ©-6F or "AM©^4660" # 3-biebSoroao8tyP4-oxa-3”asasplro|4,:81beoane by Ntirekemia or Monsanto), "dlcionon" or "ABASldSlilO" or"ALâBl46l38“ (-- (--dlazabjoyeiöid J,0}nonahe bySABff and; "furilapote" pf "AMON 1:390ό" (æe FM, pp, 482-463) (« d imethylcxszeiidone} J) active compounds of the dichlomacatcne derivatives type, such as, for exafnpie, "AMO 19Γ (CAS Nag No· by

Nitrokerma}, k) active compounds of the oxyimino compounds type which ore known as seed-dressing materials such as, for example. "oxabefenif -PM, p. 889} fe iZ)-i,3-ciio>îoian-2 ylmeilK>xyin'krK:>(phenyl}acetonltriie), which is known as safener in seed dressing to prevent metolaehior damage, "fíuxofeníhf (PNI, pp: 467--488) P- 1-(4<«bloro:phenyt}-2,:2:,2--trf8uoro-'1-ethahone O--(1::,:3-: diöXdia:n'>2-yim@thyf)osifnei which is known as safener in seed dressing to prevent fnetelachior damage, and '’cyometrlmi' or "Á-COA-43ÖB8" :(PM, p- 983} (-- (Z}~cyanomeihoxy4rtinc(pheny!}acetoniirlle}, which is (known as safener in seed dressing :te prevent metPlschior damage, !) active eompeunde of fee thfexplecarhexy tin esters type, which ere Rncwa as seed“-dressing: materiais, such as, for example. (FM, pp, 468-481} (e benzyl 2--chföro-44#uön3methy!--l ,3-feiazpie-0--oarbPxyiate}í which is known as safener tn seed dmssing bs preveht aiachipr and metdiaebior damage, m). active compounds of fee napbtbatenedlcarbexyflc acid derivatiyes ^pa which are known as seed-dressing agents, such as, for example, foaphthailo anhydride" (PM, pp 1000-401:-0} (~ 1 ,0-mebhthaieríedicaröpxytjc anhydre), yÉiíef) is known as Mfener for maize ie-s©$jl dressing ipipreyent thiocwbamate herbicide damag©. ή) Actlee dempeunds of the ehromaneapeticaeid denyatNes |ipe, euch as, for example* “ACL 304415" (CAS Reg. No. 31541-57-5} (~ 2-84 -carboxychroroan“4--yj}aee!ic acid by American Cyanamid), b| d<4;ivc ecmpounds ^|icht in aÄlen to a herbloidai action against harmful plants, also hay© ® aafener action on efapspiants, such as* for example, foimepipefafe* or'Afo1Af3:< (RfA pp. 302-103) (» piperidine-d·- carbofhloate), “daimnrons or hASK 23‘( |PM, p. 247} {* 1 ^i.-^iiihy? -1 -pbedÿfefbyfK^^bt^iiii'fee}:,· foyrbyiurorl «* “ÁJG--94Í" 1-3--(2--0010^130057110^1571^1:-11 -meibyil -pfi#dÿ|~e$%f)y?eii see JP-A-0D087254), bhathoxyphenons' or * ANf€04§s ifo 3:,3‘--dimethyl-4foiefHöxy-benxophenone). ^CSB-: fo 1-brnme^a-fobforemethyisulfonylfoenseoe} (€AS Reg. No. 54001--01-4: by KymlaS}.

Preferred herbicides (G) are iedesylfoton and lie salts and esters (€1}( forexampie Sedosyifurbn-îôéthyi-sodium {C7.1}, bromoxynii and ila sails and esters 1G2), for (0¾ bromoxynii heptanoate (C2.2), brompxynli-sodfum (02¾ bmmoxymhpoiessiym (¢2,4), ibxynil and its salts and esters (€3), for example ioxyeÍÍ--SDdlurn 103.1), loxynlf ocfanoate (03-2), metribosin (G47 propoxyearbazone and its salts and esters (€b)< for examplepropexparbaxene" sodium (CG I), ethofemesaie (G6), difiatariloan (0?), ethoxysuifuron and its salts and esters (€8),. for example efboxysoifuron (C8.1}.

Farffoniariy preferred herbicide corobinstienssef this type are: (All) + (81.1) + (01.1), (AH) + {812) -f- (OU). (A1 1) + (81.3} + (C11), (All) + (B1.4) + (CU), (All) + (Bib) + (Ci l), (A1 1) * (816} + (€11), (All) + (81?) + (C1.1), (All) * (81.8} + (Cl 1). (A1 1} * (82.1} + (€11), (At 1) + (82.2} + (01.1), (A1.1) + (82.3) + (Cl .1). (At 1} * (82.4) + (€1.1); (A12) + (81.1} + (€1.1), (A 1.2):4- (812) 4- (81.4), (Ä12) ♦ (81.3) + (011), (A12) 4- (81 4}-i-(C1.1), (A 1.2} + (BIS) 4· (GH), (A1.2) * (816) * (€11), (AI 2} 4* (81.7} 4- (Oi l), (A12) -r (81.8) + (GH). (Ai.2) + p21) + (€117 (AI 2} + (82.2) 4- (01.1), (AI 2) + (82.3) + (€1.1), (Al2) * (B2 4) + (€11); (All) + (81.1) + (€2.1:), (Alt) + (81.2) + (G2.1). (AH) + (81 3} + (€2 1} (AIΛ) + (Bl.4} + (G2,i), .{A1.1} -+ (81.5} + (02.1}, (AI.1) + {01,6} + (02.1}. (All) + (Bl.7} + (02.1). (All) + (818) + (02.1}: (AH) + {82.1} * (02.1). (All) + (82.-2:} + (02.1). (All) + (82.3) + (C2.1}; (All) + (8.2.4) + (0.2.1): (AI .2) ·+ (Bl .1} + (02.1}, (AI .2) + (812) + <C2.1}, (A1.2) + (81.3) ♦ (02.1 ). (A12) + (Bl.4) ·* (02/1), (A12) + (815) + (02.1), (Al2} + (81,6) + (02.1). (A12) + (81.7) + (02.1), (AI .2) + (81.8) + (02 1}: {A12}: + (82.1) + (02,1). (Al.2} + (82.2) + (02,1). (AI.2} + (82,3) + (02.1), (AI,2) + (B2.4) + (02.1); (All) + (81.1) + (02.2), (Al .1} + (812) + (¢2,2),. (All) + (81,3) + (02.2), (Alt) + (814) + (02.2), (All) + (81,6)+ (02,2), (All): + (81,8) + (02.2), (All) + (817) + (02,2), (Alt) + (81.8} + {02,2), (AI.1) +- (82,1) + (02.2), (All) + (82 2) + (02 2), (AH) + (82 8) + {02 2), (AI,i}: + {82.4} + (02,2); (AI .2) + (81,.1) + (02 2), (A12) + (81.2) + (02 2), (Al .2) + (81..3} + (02.2), (A1.2} + (81,4) + (02,2), (A1.2} + (816) + (02.2), (Al,2) + (81 8) + (02.2), (A1 2} s· *81 7) + (02.2), (A1.2) + (818) + (02 2), (A12) + (82 1) * (02.2), {A1 2i + (82 2) + (02.2), (A1.2) + (82.3) + (02 2), (AI.2) + (82 4} + (C2..2); (All) + (811) + (02.3), (AH) + (812) + (02.3), (All) * (813) * (02.3), (All) + (81,4) + (02.3). (All) + (Bl.8} + (02,3), (All) + (816) * (02.3). (Al l) + (817) + (02.3), (All) + (Bl.8} + (02.3), (All) + (82.1) + (02.3), (AI 1) + (82.2) + (02.3), (All) * (82.3) + (02.3), (AH) + (82.4) + (02.3): (At,2} + (811) + (02,3), (A12) + (812) + (02.3), (AI ,2) + (81.3) + (02.3). (AI .2) + (814) + (02.3), (AI,2) + (BIS) + (02.3), (Alá) + (81.8) +· (02.3). (AI,2) + (81,7) + (02,3), (AI,2} * (.81,8) + (02,3), (A1:2) + (82.1) + (02.3). (AI 2) + (82,2) + (02,3), (Al .2) + (82,3) + (02.3), (Al2) + (82,4) + (02.3): (All) + (811) + (02.4), (AI 1) ♦ (Bl.2) + (02.4), (AI 1) + (813) + (02,4), (All) + (814)-4- (02.4). (A11) * (BIS) + (02..4), (AH) + (816) + (02.4). (All) + (81.7) + (02,4), (All) * (Bl .8} + (02.4), (AI .1) * (82.1) + (02,4), (All) + (82,2) 4 (02.4). (AI .1) ♦ (B2.3) + (02.4), (AH) + (82.4) + (02.4}; (A1.2) + (811) 4 (02.4). (A1.2) ♦ (Bl .2) + (02.4). (Al2) + (813) + (02.4), (A12) + (81,4) + (02,4). (A12) * (BIS) + (02.4). (Al2) + (81.6) + (02.4), (Ai,2) + (817) 4 (02.4), (A1.2) + (B1.8) + (02,4). (Al2) + (82.1) + (02.4), (AI .2) + (82.2} + (02,4), (A12) + .(82,3} + (02.4). (A1.2) + (82.4) + (02.4); (All) 4 (B 1.1} * {€3.1}. (AU). + (81.2) -¾ (€3.1). {A1 ,.1): + (81,3) * (€3,1), (A 1.1) + (81.4} + {€3,1}. (A1.1) * (81.3) - ÍC3.1). (A1.1) * (81,8) * (03,1), (All) + (81.7} * {€3.1}. (A 1.1} 4· (81.8) + <03.1). (All) + (82,1) + (03,1¾ (All) + (82.2} * (03,1). (AU) + (82.3) t (€3.1), (All) + (82.4) * (03,.1)) (A1.2) + (81.1} + (€3,1 }, (Ai .2} + (81.2) - (€3.1}. {AI .2) + (81.3) * (03,1 ), (Ai .2) * (81.4) -i- (03,.1), (AI .2).+ (81.5) * (03.1). {A1.2)+ (81,8) + (03.1), (A 1,2) 4 (81.7} 4· (03,1), (A1.2) + (81.8) * (C3..1). .{A1.2)+ (82.1) * (03.1), (Al,2) 4 {82.2} 4· (€3,1) (Ai.2} 4- (82.3) * (03.1). (A1.2)+ (82,4) * (03.1); (A 1,1) + (81 1} -* (€3.2) (AU). 4- (81,2) * (€3,2),.(All) + (81,3) 4- (03,2) (AU) + (81.4} 4 (03,2) (AU) 4- (81,5) + (€3.2), (AU) + (81.8) 4 (03,2), (A 1,1) 4 (81.7} 4v (€3,2) (AU} 4- (81.8) 4 (€3,2), (Ali).+ (82:.1} + (€3,2) (AU) 4 (82.2) 4· (€3,2) (AU) 4· (82,3) 4 (€3.2), (A! 1} + (82.4) 4 (€3,2); (Al.2) + (81.1) 4- (€3,2) (Al.2) 4- (81.2) + (€3,2), (AI,2} * (81,3) + (€3,2) (Al,2) 4 (81,4) 4- (€3,2) (Al ,2) 4· (81.8) * (€3.2), (A12) 4- (81.6) + (€3,2) (Ali.2) 4 (81.7} 4· (03,2) (Ai .2} 4- (818) 4 (€3.2), (Al ,2} + (82.1:} + (03,2.) (Ali,2) 4 (82.2) 4- (€3,2) (A1.2) 4- (82.3) + (03.2),(Al.2}: + (82.4) + (C3.2); (AU) 4 (81.1) 4- ;€4). (AU) * (81.2) 4 (84) (AU) -s- (813) + (Ci). (AU) 4 {81.4} 4- (04). (Ali)· + {81.5}:* (G4) (AU) * (81.6} 4 (C4), (AU) * {81.7)+(04). (AU) * {81.8): + (04:) (AU) * (82.1) + (€4), (AU) + {82.2} * (04), (All)· + (82,3): * (C4.) (AU) * (82.4) * (C4); (Al,2) 4 (81.1} * (€4), (Al .2) 4 (81.2) 4 (04), (Ai .2} * (81.3) * (C4), (Al ,2) 4 {81.4} 4- (04). (A1.2} - (81.5) + (04) (Al .2} + (81:.6) + (C4), (À 1:.2) 4 (81.7) 4- (€4), (AI 2) - (81 8} 4- (04) (Ai .2) 4- (82,1) 4 (C4), (Al2) + {82.2} * (04), (AI .2) 4 (82.3) + (04), (Ai .2} + (82,4) + <04); (AU) * (81,1) + (06,1), (AU) * (81,2) * (05,.1),.(AU) + (81.3) * (€3,1 }, (AU) 4 {81.4} 4- (06,1):, (AU} * (81.8) * (€8.1), {Al 1} + (81.6) 4 (05,1): (AU) 4 {:81,7)- + (C8.1):; (AU) * (81.8) * (€5.1), (AU) + (82.1) 4 (05,1¾ (A 1.1) 4 (82,2): * (€8,1), (AU) 4· (82.3) 4· (€8.1), (AU) + (82.4) 4 (€5,1); (A 12) 4 {81.1} * (€8.1): (Ä1.2). + (81.2) + (€8.1), (A1.2) 4 (81.3) * (05,1¾ (A 12) 4 {81.4) 4- (CS 1): (A 1.2): + (81,8) + (05.1). ÍA12U (81.8) * (05,1¾ (A 1.2) 4 (81J): * (€8.1), (Al .2) * (81.8) * (€8.1), {A12}; + (82.1) * (08.1), (A 12} 4 (82.2) 4- (€8,1),. (AI.2) * (82.3) + (05.1). (AI,2}4 (82.4) * (08; 1); (A 11} * (föll) + (Cß), (.A 1.1} + (Bl,2) 4' {AI,1):+181.3} + (CB). (AI .1} + (81.4) + (Cß), (AU) + (Bl:#4' 'Al' ^ + (Cß,s. (Alt)* (81 .7} + ($§ΜΑ&amp;# + (Bl·,#* :(^>··(Α1 «*|B2.a) + (Cß). (AI. 1} + (82.2} * (Qß), |A|,|) + (82.3)+ (€#> #1,1) + (82.4} + {Cß}: (7(12} * (81.1) * (Oß), (A:l:2) + (B1.#*(&amp;#> #1 .£>:···+ (81.3} + (MS), (AI,2) + (81.4} + (Cß), (AI.2) + (81·#* (AI,*):’«· (81.¾} + (06). (AI .2} + (81,7} + (Cß), (AI .2} + (81.3) 4' (*-"#: #1# 4 îB2. b {Lb}. (AI ,2} + (82.2} + (Cß). (AI .2} + (82.3) 4 (£#·· ^ ^ # * $*#}, (Al,1} + (81,1) + {CT}. (AI. 1} + (81.2) *'{&amp;?).= (AI- )} ~ (81.3} + {LJ}. (All) + (81.4) * (CT), (AI. 11+ (81.# + (071(Alvl) + (81.8) + (C/}: (AI.!) + (81.7) + (C7). (AI. 1} + (EU.8} H;0$< (AI - 0 ->· (82.1) + (t#, (A1.1) + (82.2} + (C7). (AI . 1) + (82.3} * (^¾ W' ^ * (82.4) + (07», (AI.2} + (81.1) + (C7). (AI.2) + (81.2)4 (Oll (A1.2) + (8 ..3} + (LJ), (AI 2) * (81.4) + (07), (AI.2) + (81# 4 (C?>= (A1.2) + (81.8) + (07), (AI 2) + (Bl.7} + (07). (A1.2) + (81# 4 (CP* (A1# + (82.1) + (€/), (AI 2) * (B2.2) + (C7), (AI 2} + (82.:3) +(C7), (A1.2) + (82 4} + (07); (Al 1) * (Bl .1) + (08 1): (A1.1) + {£11-2} + (CBA). (All) + (81.3} + (08 1), (Ai 1) + (B1.4} + (08.1), (A1.1) + (Öl# + (C8.1). (All) + (81.8} + (08.1), (AI. 1} + (B1.7) + (C8 1). (All) + (81.8} + (08 1 ), (AI 1) + (82.1) + (Cß. 1}, (AI 1} + (B2.2) + (C8 1), (A1.1) + (82.3} + (08.1). (All) + (82.4) + (08.1); (AI.2) + (B 1.1) + (08 1), (AI.2} + (81.2} + (08 1). (AI/2) +(81.3} + (08.1), (AI 2) + (81.4} + (08 1), (AI.2) + (81.5) + (08 1). (AI.2) * (Bl.6} + (08.i), (AI.2) + (Bl.7) + (08 1), (AI.2.) + (Bl.8} + (€8.1). (Al2} + (82.1) + (08.1), (Ai.2} + (82.2) + (08 1), (AI,2} + (82.3) + (08:i)v (A1.2) * (82.4) + (08.1). Bére thá appiicatton Taté naßgaS: and 8p#ieätlöfl:. rats ratios nisntsonsd abav® ar® In ®®cn eaa® prafprs-ed, 1st addition,: aaah oHhg 2>-eoroj»®nsnt and S^oönipodohleos'nbiiiatioas mantionsd abav® áiy la psartiduiar â saigner sadh M matenpyr-diÂy! (81-1), Îso^aÂn^tiiyi (Si*#. eiaqumtdeataasxyi (32-1) and aypreauHamlde (83+1), foi axámpía: (A 1.1) + (B 1.1) + (SOI). (A 1.1} + (81 2} + (SM}. (A1.1) + (81.3) + (SOI), (All) + (81.4) + (SOI). (A 1.1} + (81.5} + (81-1), (AAI) + (61 6) + (Sl-1), (All) * (81.7) + (SOI), (All) + (8:18) + (Sl-1;, (All) + (82,1) + (81,-1), (All) 4 (02:2} MSU), (All) + (82.3) -+ (81-1), (AI .1} + (B2.4) 4 (SU); (AU) + (8.1.1) 4 (S1-Ô), (Alt) 4 (812) + (S1-8), (Alt) ·+ (81,3) 4 (81-9), (AU) 4 (81.4) + (81-9), (Ai.t} ·+ (81.5) * (81-2), (AU) ·+ (81..8) 4 (81-9), (AU) -i- (817) 4 (81 -9), (Al: 1} + (818) * (S1-S), (AU) -+ (82,1) 4 (S1-9), (AU) -i- (82.2) * (Si Ai), (Alt) 4 (82,3) * (81-9), (AU) -f- (82,4) 4 (81-9); (AU) -i- (BU) * (82-1), (AU) 4 (81,2) * (82-1), (AU) + (81,3) 4 (82-1), (AU.) J· (814) 4- (82-1), (AU) + (81.5) + (82-1), (AU) 4- (81.6) 4 (82-1), (AU) -i- (817) 4 (82-1), (AU) * (81,3) 4 (82-1), (AU) 4 (82.1) 4 (82-1), (AU) 4 (82.2) 4 (82-1), (AU) + (82.3) + (82-1), (AU) + (82.4) 4 (82-1); (AU) -i- (81 1} 4- (83-1), {AU}* (B1.2) 4 ($3-1), (AU) * (BI S) + (83-1), (AU) + (81,4) * (83-1), (AU) * (B1.5) 4 ($3-1), (AU) + (B1.6) * (83-1), (AU) -J- (81 7) 4· (83-1), (AU) * (Bl.S) 4 ($3-1), (AU) 4 {82.1} 4- (83-1), (AU) 4· {82.2} 4- ($3-1), (AU) * {82.3}* (83-1), (AU) 4 (82.4} + (83-1).: (Al .2) 4 {811} + (81-1), (A 1,2) 4 (B1.2) 4 (SU), (A12) * {81.3} + (S1-1), (A1.2) 4 {814} 4 (S1-1), (AI 2) 4 (B16} 4 (SU), {Al.2} 4 {81.6} 4- (SU}. (A 1.2) 4 (8178 4 ($1-1), (Al.2) 4 (BIS) 4 (SU), (A12) 4 (B2.1) 4- (S1-1), (A12) + (82.2) 4· (81-1), (A 1.2} 4 (82.3} 4 (SU), (A12) ♦ (82.4} -f- (SI-1» (A 12) + (81.1) 4- (81-.-9), (A 1.2} 4- (81.2} 4 ($19}, (AÏS) * (81.3} + (81-9), (A 1.2}·4 (81,4) 4- (81-9), (Al .2) 4 (815) 4 ($1-9), (A12) * (B1.6) + (S1-9), (A 1.2) 4 (81.7) 4 (81-8), (AI .2) + (818) 4 (8-19), (A12) 4 (82.1) 4 (81-9), (A 1.2} 4 (82,2) 4 (81-8), (Al .2) 4 (82.3} 4 ($19). (Al 2) + (82.4) 4 (81-9); (A1.2) 4 (81,1) 4 (82-1), (AI .2) 4 (B1.2) + ($2-1). (Al 2} + (813) 4 (82-1). (A 1.2} + (81,4) 4 (82-1), (A1.2) 4 (81.8) 4 (82-1), (Al 2) + (818) 4 {82-1). (A 12) 4 {817) 4 (S2-1), (Al 2) 4 (818) 4 (S2-1), (Al 2.) 4 (82.1) 4 (82-1), (A1.2) + (82.2) 4 {82-1:}, (Al,2} 4 (82.3) 4 (S2-1), (Al,2) 4 (82,4) 4 (82-1); (A12) + (8:11) 4 {83-1:}, (AI .2) 4 (81:.2) 4 (83-1), (Al 2} 4 (813) 4 (83-1), (Al2) 4 (8:1,4) 4 (S3-1), (Al ,2) 4 (81:,5) 4 (S3-1), (Al,2) + (818) 4 (83-1), {A 1.2) 4 (81 7} 4 (83-1), (AI ,2) 4 (816) 4 ($3-1), (A12) 4 (82.1) + (83-1), {A 1,2} 4 (82,2) 4 iS3-1), (A1.2) 4 (82.3) 4 ($3-1), (Al 2} 4 (82.4) + (83-1); (AU) 4 (81 1) 4 (81-1) 4 (GU), (AU) + .(812) 4(81-1) + (81 1), (AU) 4 (81.3) 4 (81-1:) 4 (01,1), (AU) 4.(814) + (81-1) 4 (Cil), {AU} * {81.5} » ($1-1) s- <G11); (AU) 4 {81,6} 4 {$1-1} 4 (01.1% (A 1.1} -s- {81.7} * (S1-1} 4 {€1,1% {A1.1} 4 {81,8} 4 {$1-1} 4 {01,1% (Al. 1} 4 {82.1} ♦ ($1-1) Ψ {€11% (AU) 4 (82,2) 4 .{.$1-1} 4 (01.1), (AU) 4 {82.3} ♦ (SU) 4 {€1,1% {Al.1} 4 {82,4} 4 {81-1} 4 (01.1% (Al .1} 4 {$1.1} 4 ($1-9) 4.(011% {A1.1} 4 (81.2) 4 {$1-9} 4 {011% (AU) -s- {81.3} 4 {81-8} 4 {€1,1% (AU) 4 {81.4} 4 {$1-8} 4 {01,1% (Al .1} -s- (81,8) 4 (81-9) 4 {011% (A1,1) 4 (81.6} 4 {$1-8} 4 {01,1}, (AI .1)4 {BU) 4 (SU) 4 (Cl,1 % (Al 1} 4 (81.6) 4 {$1-8} 4 (CI .1}, (AU) 4 (B2..1) 4 (Si-9} 4 (€1,1% (Al, 1} 4 (82,2) 4 {$1-8} 4 (01.1% {Alt} 4 (B2,3) 4 {SI-9} + (Ci l), (Alt) 4 (82,4) 4 {$1-8} 4 (01.1); (AU) 4 (81,1)4 (S2-1 ) 4 (€1,1% (AU) + {81 2} 4 {$2-1} + (Cl.1), (AU) 4 (81.3} -s- {82-1} 4 (€1.1% (AI 1} + (81 4) 4 (SS-1) 4 (C1.1), (AU) 4 (81.5} 4 (82-1} 4 (01.1% {AU} 4 (81 8} * ($2-1) 4 {011% {Al ,1} 4 (81.?} 4 {82-1} 4 (€1.1}, (Al 1} 4 (81.8} * {$2-1} 4 {01.1 % {AU} 4 (82,1} 4 (82-1} 4 (01.1% (AU) 4 (82 2} 4 (S2-1) 4 (OU), (AU) 4 (82.3} 4 (82-1)-4 (€1,1% (AU) 4 (82 4} 4 ($2-1) 4 (OU); {AU} 4 (BU) 4 {83-1} 4 (Cil), (AU) 4 {B12)4 (S3-1) -s- (01,1% {AU} 4 (81.3} 4 (83-1) 4 (GU), (AU} 4 (81.4) -s- (S3 1) 4 (01.1% (AU) 4 {BI S} 4 ($3-1) -4 (Cil), (AU) 4 {81.6} 4 (83-1) 4 {01.1% (AU) 4 (B1.?} 4 ($3-1} 4 (C-1.1), {AU} 4 (81.8) 4 (SS-1) 4 (01.1% (AU) 4 (B2 1) 4 ($3-1} * (GU), (AU) 4 (82.2) 4 (83-1)+ (CU% {AU} 4 {82.3} 4 ($3-1) 4 (01.1), (AU) 4 (82.4) 4 {$3-1} + .<011% {A 1.2} 4 ($U) 4 ($1-,1} * {GU}, (AU) + (81.2) 4 (SU) 4 (01,1}, (Al.2} 4 {$1.3} 4 {$1-1} * (01.1% (Al,2} + (B1,4) 4 {$1-1} + <011% (Al .2} -s- {81,5} 4 {$1-1} 4 {01.1), (Al ,2} 4 (BU) 4 {$1-1} + (01.1% (Ai .2} 4 (BIT) * {$1-1} 4 {€1.1}, (AU) 4 (BU) 4 ($1-1) + (01.1% (Ai.2} 4 (82.1 ) + (SU) 4 {€1.1}, (AU) 4 {82.2} 4 {81-1} 4 {01.1), (A1.2) 4 (82,3) 4 ($1-1) 4 (C1.1), (AU) 4 {82.4} 4 (SU) 4 (OU); (A 1.2} -s- (BU) 4 (S 1-8) -s- (C1.1), (AU) 4 (81.2} 4 {81-8} 4 (01.1% (Al 2} -s- (81.3) 4 (SI-9) 4 (OU), (AI.2) 4 (81,4} 4 ($1-8) 4 (01..1% (AI.2} 4 (B 1.5) 4 {$1-9} 4 {€11}, (Al.2) -s- (81.6} 4 (S1-3) 4 (01..1.% (Al .2} 4 (BU) 4 (SI-9) 4 (€1.1), (AU) 4 (81.8} 4 {$1-8} 4 (01.1% {Al 2} -s- (82.1} 4 (SI-9} 4 (011% (A1 2) 4 (B2.2) 4 ($1-8) 4 (01.1% {Al 2} 4 (82..3) 4 {81-9} 4 (OU), (A1 2} + (B2.4) 4 ($1-8) 4 .(OU); (M,2) + (BU) ♦ (82-1} + (C1 1). (Α1.2) + (81.2) -(- (82-1) + (011),: (AI.2) + (81,3) -(- (82-1) -(- (01.1), (A1.2) -(- (81.4} -(- (S2-1) + (CU),. (AI.2) + (81 ,S) + (82-1} + (CI 1).. (AI 2) + (81.8} + (S2-1) * (CU), (AI.2) + (BO)* (82-1} + (C1 1), (AI.2) + (81.8} -(- {82-1} + (CI 1).

(AU) * (B2.1) ·(· CS2--1) -(- (01 1)) ÍA1.2) + (82.2) + (S2-1) + (CUT (A(.2) -(-112.2) -(- (82-1} ·( íCU}v(A:!,2):+ (82.4) + (82-1} + :(GUI, (Al J) * (8U) + (83-1)4· (CU), (A 1.2) + (81.2) + (83-1) + (CU). (AI.2) + (81 3} + (83--1) + (CU), (AI 2) + (B1.4) + (83-1) + (01,1), (A1.2) +(Bl 5) + (83-1) + (CU), (A1 2) + (Bl.6) + (83-1) + (CI 1), (AI.2) * (81 7) 4- (S3-1) + (CU), (A1 2) + (81.8) + (83-1) + (CU), (AI.2) + (B2J) + (83-1) + (CU), (A1 2) + (B2.2) + (83-1) + <C1.1},. (Al,2) + (82 3) + (83-1) + (CU), (A1.2) + (B2.4) + (83-1) + (CU).

The betbpde combinations acoordihf io tha Invention (~ herbieidal compositions) have an outstanding herbicide! activity againsf a bread spectrum of eoooornisaSiy iniportant harmfulplants, Here, tho substances cam be applied by the am-sowing. (he pre-emergence and/or the entefgafie© or aeparatniy· PosOmargenoe appírbatipn, or early prs- ehiergence appitoaiion, is pmfeneri

BpeOiboaHy, examples may be mentioned of sepia representatives of the dicotyledonous weed flora which can be controlled by (he combinations according to the invandenpÄsai tba onomaradon being a restriction to certain species:

Ahutiion spp., Arnarantnus spp.. Chenopodium spp., Chrysanthemum spp.. Galium spp. such as Galium apanne. ipomoea spp,,l<ocbia spp., Camium spp., Matricaria spp., Bbarbitia spp., Poiygonum app,, Sida spp., Sioapis spp,, ietanpm spp., Oteliaria spp., Vamnica spp. and Mtola spp., Xanthium spp. from among the annua! waedsaod Oonsroiyptus, Cirsiun'î, Bun^ex and Artemisia from arnong the pereooiai weeds, and also Acacia spp,, Acaiypha acalopecurus, Agératum Odnpoides, Ammis május, Apium ieptepnyiiium, Asoiapias curassavica, Raeeharis coridifoiia, Bauhinia spp., Baltimore recta, BPeboreria niyeam, iowtesia ineana, Cassia oceipentaiis, Carduus acanthoides, Cassia tom, Chsmaecrysta tnchoppda, Cirsium vuigare, Cleomo viscosa, Ciidemia Hirta, Conpá bonarionsis, Coronöpoa didimus,Crotaiana spp., Boiipta aida, iíepbaníopus splcatus, Eupatefium sguaMom, Euphorbia spp.; FumariicaphpÄ, Furnaria offkunaiis, Gamochaaia spicata, GnaphalMum spp., Heiiconia bifai, Hyptis suaveoiens, i..antana catriara. yppia nudiflpra, tudwigia octovalvls, Malva spp.. Melampodium spp, Mimosa spp., Mucnna pririens. Nephroiepsis spp.. Pachira odorata, Pethmräa aiieacoa, Phitscoiiobium spp,, Pisonia acniaata, Flantago ianceoiaia, Piantago major. Priva iapoiacoa, Prosopis joHflotapBteddium aduíilmim:, Raevoila teiraphiila. Ricinus oomanis, Solaria ptsrdta, Soneeio brasiiiensis, Senns <MUÄi$yTseortib sites, Thalia gdhidb&amp;ilj Vemoniaspp;,: testera dentate, W-ssadyla amptisSims,

If this herbicide por?ifeä«aöön§.:apeptPirtt#:t>i1hV#h^öh are applied to the soil sortes before germination, teft'^'s^ásiPPdiihpi'ar# elthaf-prë^Rfeiicô^fâlt^yÂmii^né^thg, or te weeds grow until they have rosette the cotyledon stage but then their growth stops, sod;,eventually. after three is four weeks have eídpM, they die completely. if the active compounds are applied post-emergence to the green parts Ofthe plants, growth likewise steps drasticaiiy a very short tlte after the treatment and the weed plants femaih at the growth stage ef the point: In imeof application, or dfe. eorppi^te!yi;aifter#toeittih' tiass, soithaf itn this manner competition by the weeds, which is harmful to the crop plants, is eliminated at a very' early point in time and in a sustained manner,

The herbicidaf compositions according to the Invention arc distinguished by a rapldlyoommeneihg and ibng-iasting herploiOal action, És a rui®, the ralnfastness of the active: Compounds in the: combinations acsording to the invention is adverdapous. ^particular advantage is that the: dosages of the compounds (A) and (8), which are used In the combinations and are eftettvo, can be adjusted to snob a low quantity that their soli action is optimally low. Not only does this allow them to be employed in sensitive crops in the first piaca, but groundwater contaminatiens am vtftueüy avoided. The herbicide combination according to the tnvenfion allows the application rats of; me active compounds rsqulred to be reduced considerably. in a preferred embodiment, when herbicides of the typo fM+{8) are used jointly, superaddltiya synergistic) effects are observed. This means that the effect in the combinations exceeds the expected totai of the effects of the individual herbicides employed. The synergistic affects allow the application rate to be reduced, a broader spectrum of breaddeavod weeds and grass weeds to be controlled, the herbjoidal action to take place more rapidly, the duration of action to be lopgatyfha harmful: plants to be controiiad better while using only -one, or few, applications, and te application: period which is possible to be extended.

The aboyamentipned properties and advantages are of benefit for weed control practice to keep and thus to safeguard and/or increase the; yields from the quaiitatlve and quantitative point of view. These novel combinations markedly exceed the technical: state of the art with a view to the properties described.

While fee combinations according to the Invantioo havean outstanding herbicide! activity against harmful piants. the crop piants are damaged only to a minor extent, If at ail. propertieson the: crop plants They esigag® in the plants' metaOOiism in a regulatory manner and can thus M ompjoyod Tor provoking directs : affects· on plant constituents and ίο facilitate harvesting soph a^fp!f^pm^lt.Py:fl|prpg desiccation and Stunted growth. Mmmvw, they are also suitable tor the genera; control and m:hifeíiití^::0f·:Mt1éiföistre<3:: vegetatívig:;grôvÿth-;^i^^t,slmuilaneoti&amp;iv destroying the plants. An inhibition of vegetative growth is very important in a large number of monocotyledanous anb:piMÿjappnρgâ:^¾rP;p¾.sínca:;ÿteid losses as P: result of lodging nan thus be reduced, or prevented opippietely,:

Owing to their herbioidai and piant-growth'-reguiatory properties, the combinations according to the Invention ean also be atpplppdf#r:'dôntrÂ'g fiáitnfüí''pÍ0me.in genetically modified crop plants or crop plants obtained by rnuletion/se'eotion, These crop plants are distinguished as a rule by partipidari: edvantegeoua properties, such as resistances to herbieldal compositions ocrasislances to plant diseases: or causative agents Of plant diseases such as particular insects or microorganisms such as fungi, baótéria or viruses. Other particular properties relate, lot* example, to the harvested : material; with regard to quantity, quality, storahillty,: composition and specific constituents, Thus, for example, transgenic plants at© known whose starch content is increased or whose Starch quality is altered, or those where the harvested material has a different fatty acid; composition.

Conventional: methods of generating novel plants which have modified properties In comparison to plants occurring to date consist, tor example, in traditions! ireeding methods and the generation of mutants fsaa, for example, US 5,162.602; US 4,761.373; US 4,443,971). Alternatively; novei plants with altered properties can be generated with the aid of recombinant methods (see, for example, EP-· A-0221044, EP-A-0131624). For example, the foiiowing have been described in several eases: the modification, Of crop plants with the aim of modifying the

starch synthesized in the plants {tor example WO 92/11376, WO 92/14627, WO 91/19806), transgenic crop plants which exhibit resistances to other herbicides, for example to sulfonyldreas t£P-#-02S7993, USrA4613059T transgenic croppianfs with the capahitity of producihg iadiiius titoringiensls toxins (St toxins), which make the plants resistant to certain pests {EP-W-ÖI42924, EP-A-öl 93299), transgenic crop plants with a modified fatty acid composition (WO 91/13972). A large number of techniques iri rfioiecolar biology are known so principle With the aid of which novel transgenicgiants with niOdled properties can be generated: see, for example, SambrooK ót al,,,1:988,. Molecular Oíohing, A Laboratory Manual. 2"'J Edison. Cold Spring Harbor Laboratory Press, Gold Spring: Harbor, NY: or Wlnnackor "Gene und Klone”. VCH Weinheim 2ná Edition iQOioiGhrisfou« "Trends in Plant Science" 1 £1:998} 423-431).

To ëérry dut such recombinant manipulations, puelefoacid mutagenesis or sequence changes by recombination of DNA sequences can fee introduced into plasmids. For example, the abovememloned standard methods allow base exchanges to be carried out, subsequences to be removed;,or:na:tupái:pidybífeetíd^queneed:td:.:Í3^;:e^^d; To connect the ONA. fragments to each other, adapters or linkers may be added to the fragments. :Pôrdîè8<¥t^i:. îb$:i®n#faMn· of plant cells with a reduced activity of ärgerte product can: be achieved by expressing at least caei ecrresponding anttsenea ;$$&amp;, a sense RNA tor achieving a eosugpfession effect or by expressing at laa# one suitably oonefructed'pfeoxyme which epecificaiiy cleaves transcripts oi: the abovemanfioned pens product

Tofhisand,: if its possible to use DPI A molecules whicbéncempeustheíentíre coding sequence of w gene product inclusive of any flanking sequences and also DMA moleculee

Which only encompass portions of the coding sequence. if being necessary for these poftlens to b® iong anougb to have an antisense effect in .the :ΜΙ§^'^Hlü^^equençes. whichiiíí^iye a high degree of horoofogy fo the encoding sequences of e gene Oi'dduct, feuf are not completely identical to them, is also possible.

When expressing nucieio acid molecules ip plants Jhe protein synthesised can be localised in any desired compartment of the plant ceü However, to achieve localisation in a particular compartment, it is possible* for example,:, to link fee coding region with UNA sequences whieb ensure localisation in a particular compartment:, Such sequences are known to those akled in the art (see, for example,

Braurr et ai ., ifulBG J. 11 (lö&amp;tfe Sgi9-322?; Wolter et ai.. Pme, Matt to Sei. USA 85 (1988), 846-8:>0; Sonnewald etai, Plant J. 1 (1991). 96-106).

The transgenic plant cells can be regenerated by:gîy# rise to intact plants. In principle, the transgenic planta oan fee giants of any desired: plant species, is, pot only rnonocotyiedonous. nut also dicotyledonous. plants. Thue.iffdnsgeeicrplsnfspan be obtained: whose properties are altered by overexpression, suppression or inhibition of homologous (- natural) genes or gene sequences or the expression of hefemlogousT“ teteign) gepes or gape sequences.

The present invention furthermore provides a mefbod for controlling unwanted plant growth, preferably In plant crops such as ^οηο#|ιΙΐ0!^^.:ΙΙΓ -IÉtd!^l#donous plant crops, |pr exampie pasture crops:, cereals (for example wheat, barley, rye, pats, pee, corn and millet), sugar beet,, sugar cape, Oilseed rage, cotton and soybeans, preferably In mopopqtyiedcnous crops such as pasture crops or cereals (for example wheat, barley, rye, oats, rice, corn and millet), where one or more herbicides of type (.A) arid one or more herbicides of type |$) are applied jointly or separately to the harmful plants, plant parts, plant seeds or io the area on wbish the piqnts grow, for example the area under cultivation or the pasture area.

The herbicide combinations according te the invention ate used with particular preference in pssiure crops: in particular gross crops., such as native perennial grass species, Brachiarla (hrdtaniha, rux&amp;iensis, dddumPensi, ;PaiiifâMm mäxim«m; Cynodon piesctöstaehyurn, Andropogum gayanus, Dichantium aristalurn Plgitaria depambens (Pangóié), Panieren maximum. MédiPagd saiva (Alialfa), officinalis, Lotus dornicuiatus, Lotus tshuss, Bfomus uhioioldes, Collum spp, an©, Loilum mulfifiomm or Löiiuln parenne.rFestUda afundinacaa, Dactyiis glomerate. Phaiaris bulboso, Agroplrum repose.

Tha plant crops pan also have been genetically i*iödi©id':isr'l>aöei'bltÉOid by mUtbfioh/selèction and ara preferably tolerant to acefoiactate synthase |AlS:Kinbibltors,

The invention ©iso relates to îhe use of ti-!© herbicide combinaisons according to the invention for controliiog harmful plants, preferably in pian? crops.

The herbicide comi3inalions according to the invention can exist hot odiy os mixed formulations of the components (A) and (8), if appropriate together with further' agrochemically active compounds, additives and/or çusti£^a«^t^^ulÂd'::sdïti|iâriôi, which are then applied In the customary manner, for example os a dilutiee witb watars but also as so-called tank mixes by jointly diluting the separably formulated, or partially separately formulated:, components with water.

The components (A) and (8) or their combinations combe farm Plated: in various ways, depending on the prevailing bioiog-cai and/or chemical-physios! parameters, the following are examples bhgeneta! possibilities: for formulations. weltable powders CW^^iat^r#OlöilemöhOefiM^ emuisifiible cohcentrates yEC), aqueous solutions (SI.), emulslone pW) such as oiMmwotef arid:: water-ln-oil: emulsions:,: sprayabi© solutions Of emulsions, suspension concentrates (BG), oil-or wafer-based dispersions, such as oil suspension concentrates :(Ä), suspoemuisions, dusts (DP), seed-dressing: materials:,: granules for seil application or 1er broaddasifng. Or water-dispersible granules (WG), .Utó/" fermuiations;,: microns psuies or waxes.

The individual formulation types are known in principle end are described:for example In: vyinnackeo Küchler. “Chemische Technologie”, Volume t, plHsoser Verleg Mtíttfch*·4%1Μίορ,..lt:É88·;;:vah ValRsnhurg, "Pesticide Formulations“, Marcel Dekker N.Y., 1973. K. ivtarfons, "Spray Drying Handbook", 3rd Ed. 1979, G. Goodwin Ltd, London.

The formulation auxiliaries required such as inert materials, surfactants, solvants and Other additives are also known and are described, for example, in: Watkins, “Handbook of insecticide Dust Diluents and Carriers“, 2nd Ed., Dariand Books, Caldwell N.J.; H.v. Oiphen, "Introduction to Clay Goiioid Chemistry”; 2nd Ed., >i. Wiley &amp; Sons, NY. Idarsden, "Solvents Guid©'V2nd Ed., interscience, N,Y. 1Í50; McCíátóhean's, 'Oetergents ánö Emuísinors: AbnuamifdC J= ; ÄlSf and Wood, ’’Encyclopedia of Surface Active Agenfsö Chem. FigbUO&amp; iné,, di, Y. 1864; SobbnMbl: ^^snzifâcbénakfive Athylenoxidabdukfe’’ ISuriacaxactiye ethylene oxide adducts], Wies, yodagsgeseilschaft, StuttgaitlSTI/tdlidndckaAKdotdef;, 'Chemische Tàçbuoiôgid“, Volume?* €, Háhser Verlag Munich, #: Edition 1SÄ

Eased on these formulates, compounds, such as other herbicides, fungicides or insecticides, :Sft#jÉiihiiôfan$f§Afè may also he prepared, forexample in the term of a readyrnix or a tank mix, YVettsbie powders (sprayebie powders) ore produnfs which iere uniformly diepsrsibie in water and; which, besides the active compoundi also comprise lomc or non ion ic surf acton is (wetting agents, dispersants), for example polyoxyeihyiafed aikyiphenois, poiyeihoxylated fatty alcohols or tatty amines, aikanesuifonates nr alkylbensenesulfönaíes, sodium iigoosuifonafe, sodium dinaphthyimethane-6,8!-disulfö:néta,: sodium: dibufyinap^^ or else sodiu in oieoylmelhyltauride, in addi'tion::lto;#íd)!aant::örfn#fl;::matedái^

Emuisifiable concentrates am prepared by dissoivingAne aofive compound in an organic spiveoi, for example butanol, cyclohexanone, dimethylformemido, xyleneόρ#!#Ρ'W hydrocarbons with addition of one or more ionic or nomonio soÄtanfs tamoisifäers). Examples of emulsifiers which may bo used are: caicium salts of aikylaryisuiibnic acids, such as calcium dodecyibenxenesulfonata, or nonionic emulsifiers such as tatty acid poiygiycoi esters, alkyiaryl poiygiycoi ethers, fatty alcohol poiygiycoi ethers, propylene oxide/ethyiena oxide eondepssies. alkyl polyethers, sorbiian fatty acid esters, polyoxyethylene sorbiian fatty acid esters or polyoxyethylene sorbitol esters.

Dusts ara obtained by grinding the active compound With finely dlyidObdolid foatedeis, for exemple; talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth

Suspension concentrates ($£)] can be water- or oil-based. They Odd W prepared, for example,: éÿ wet grinding by means of commercially available bead mis and, if appropriate, addition of further surfactants as they have already been mentioned for example above in the case of the other formulation types,

Emulsions. for example oii-irvwater emulsions (EW), can be prepared fee example by means of Stirrers, cdliold: mills and/or siatiemixers using apoeoue:organic soiyente and, if appropnatSi: further euffaciams ee have alseady been mentioned for example above in the case of the other formuipfion: types.

Granules can hupreparedeither by spraying the materialer by applying aotlvs compound MMmdbm&amp;wû*» mich as sand, kaoiinitas qí'.gmnpfsl^-M' material with mp aid of bipoof% Äaxämpip polyvinyl aioohel sodium pbiperyíaieéreisé rnmmî oils, Suitable active compounds may also be granulated In the manner sonvsotiehaiiy used for the pro$^«of ftiPprf fibtiil» 1 desired in a mixture with iertsitears.

As a rule, water-dispersible iranuies aia pi^preu by custody processes such as spray drying, buldiaaP-bed granbiation, e:granuiate>:«nf::With high-sped mixers and extrusion without solid inert material; R8§aÄi.:l#::pröd.ööÖöh;'#pi<· granules, f!uldhred~bed granuies. æPPér iranules and spray granules, see, for example, methods in "Spray-Drying Handbook" 3rd od. 1979, Ö. Goodwin Ltd,, London; JM. Browning, "Agglomeration", Chemical and ingineerlng IBB?, page 147 et sag; "Perry's Chemicai Engineer's Handbook". 6th Ed., BteGraw-Hiil, New York 1973, pp 8-57.

Tbs herbicide combinations aeooPng-to the invention are preferabiy fermuiafed In the form of an oil suspension concentrate pp). The öií:s«^nalonídon^p^^íOom|iHisee( for exampie, at at least one of the herbicides {A} and fi). in suspended: form, b) one or more organic solvents, e) optionally one or more sulfosuccinates. d) optionally one Or more ggrochemiesily active compounds different from a), c) optionally one or more inorganic salts, and I) optionally customary auxiliaries and additives.

The term oil suspension concentrate (OD) is to be understood;as meaning a suspension concentrate biased on organic solvents Here, one or more active compounds ate suspended in thé organic solvent, further active compounds may be dissolved in the organic: solvent.

In the ait suspension concentrates according; to the invention, theharpcidaiiy apifvf compounds a| are genèraiiy present in amounts ef from 0.01 to h0% by weight, prefereuiy from Oil to 30% by weight; here and lit the entile description, the; term "% by weight" refers, unless: defined otherwise, to the relative weight of the component In question, based on me total weight of the fonnulafion, preferred suspended herbicides a) are (A1.1} and (At.2;·, the free acids and salts oi (81) and (132), and also: (Cl ), (C4|, p!|, (07), :(80) anddheifreo acids d (C2) and (C3).

Suitable organic solvents (coniponeni 0} an«, for example: 1) hydrocarbons, which may be unsubstituted or substituted, let example la) aromatic hydrocarbons, for example: « mono- or polyaikpsubstituteb mesitylene, ethyibensene. or > mono- or poíyalkyimuhstitutsd ímphthaienes, such as imtsíhytnaphlhaiene, 2^ethyinaphmaien«or:^imethy^^y!ene, w: other benzene-derived aromatic hydrocarbons, such as indán©: or Tetralin®, or mixtures thereof, 1 b) aliphatic hydrocarbons, fer example :i straighfmhain or branched aiiphaßcs, for example of the foro>ule CnHs?»s, such as pentane, hexane, octane.. 2-methyibutane or 2,2.4-triroethylpentane, or - oyeíie, optionally aíkyi-sub&amp;ittuíed aliphatic«, such as cyciohexapf or methylcyciopentane, or mixtures thereof, such as solvents of the Exxsol® D series, isopar® series ohlpyol® series, for sample Bayol® 82 (ExxonMobil Chemicals), or the Isane® IP series or hiydroseaf?<I series flptalFinaElf), lc) rhÂIW:'#ff!bP^c-açd'aiip.hatfeî hydrocarbons, such as solvents of the Solvesso® series, for example faolvesso® 100, Spivsssp® 180 or felvesse® 200 (ExxonMobil Chemicals), ol die Böjyafex^fBolvaro® series (TotalFrnailf) or the Caromax® seriesbfer example Carornax^lB (Petrochern Caness}; or ld) halopnated hydrocarbons, suchas hajogenated aromaticand aliphatio hydrocarbons. such as·, chlorobenzene or methylene chloride, or 2} peler solvents, fór example apróié polar solvents, such as felly atherlfied and felly esterlfied C r CValkanoic acids which may he mono-, dt~ or poiyfunctionai, for example the ethers and esters Wish CrOis-efeyi alcohols, •^^hi^witbia.i^'^hishW-^'^Mldmerizas phosphoric sold esters, amides, nitrlfes Of Sulfones, for example diisobutyl adipate, Hhodlasolv® fitPDi (Rhodia), cyclohexanone, Jeffsoi® PC (Huntsman), γ-buiyroiactone, N-rnethyipyrro!iclone, dimethyl sulfoxide, acetonitrile, tnbufyiphosphatam or the HOstarex® PC) series (Clarion!;}. or protic polar solvents, such as alcohols, amines or carboxylic acids. The alcohols, amines or carboxylic acids preferably have 1 ;te 18 carbon atoms and can ha stralghimhaio, branched or cyclic and saturated or Ohssferafed and; may optionally comprise heteroatoms and he mono - or poiyfunctionai. Examples of aifcobels aremehbhydfioiCyC^^^ ethanol, propanol, Isopropanol heptanol, ocfenoljsoocfanbifdfiphendi, or polyols, such asglyeerol or fefeyslyobie, cornmerdíáliy available, for example, as ÈxmP Mfiss (ExxonMobil), Agrisynth^PA (iSF), Arcoséi v® series (Lyondell Chemioa!) or Macof 8-98(PEA), Examples of amines ate diethyiamtne, hexyiarnlne or anilthe iExamplee df earboxytic acids ere adipic mM and adipic acid monoesters, 3) fatty acid esters, for exemple of natural origin, for example natural oils, such as animal oils or vegetable oils, or of synthetic origin, for example the Edehoi^ series:, lor example Edenor® MEFa br Ëdatfei^MEBU, m senes (Cognis), the

Baten® BfE series {:§§|feí|, the Rsdis^ssries, for example Radja^Sülö? (IQ), the Pr!lubO'S s&amp;hM, for example Pniob#1130 (Peiroftna), fos Stepteh® G sérias (Stepan) or the Wstconol^ff; sebes (Wltco), The forty seid esters are preferably esters of Q^Gsa*, with pmforence C<3-Csr·: acids. The Cíö Cs2-4Stty seiet esters are, fer exempte, asters of eesatdtafoe or saturated G-srCcr ftetiy acids, in particular those having an even number of perben atoms, for example erucis acid, leuric Sold, palmitic acid, and in pafoeotar G,rte% aside, such as stearic acid, oleic acid, llnoieie acid dr iinoienle acid. ixampltes of fotty acid esters such as esters are giycero! and glycol esters of fatty acids such as Ct(rö2rfoíty acids, or fransesforificatieP prööácfo thereof; for exempte fatty acid alkyl esters such acid dy-ö^alNyl esters, which can be obtained; for example, by ftansasterifieatish of foe abovementioned glycerol or giyeef fotty acid esters seoir as C<c-C22<-fatty acid esters with GtB^wicohois (for exampie mefoanei, ethanol* propane! or butanol) The transestérification can be carried out by known methods, as described, for example, in Römpp Chemie Lexikon, §th edition, volume 2. page 1343. Thieme Verlag Stuttgart.

Preferred fatty acid alky! esters such as Gis-Cyrfatty acid CrCsç-alkyl esters are methyl esters, ethyl esters, pmpyf esters, bátyi esters, 2^athyihexyt estem and dodeey! esters, Preferred glycol and glycerol fatty acid esters such as C^C^tty acid esters are the uniform or mixed glycol esters and giycero! esters of ClCrC2a»tetty acids, in particular of suoh fatty acids having an even number of carbon atoms, for exemple emeléseid, iauric acid, palmitic acid and in particular Ctir-fotty acids such as síesne seid, efeie acid, llnoieie acid or iinctenie acid.

Animai oils h) are generally known and commercially available For the purpose of the present invention, the term "animal oils" is to be understood as meaning^ for example; oils of animai origin such as whale oil, cod-liver oil, musk oil or mink oil.

Vegetable oils b) are generally known and commercially available, For the purpose of foe present Invention, foe fenn "vegetable oils” is to be understood as meaning, for example, oils of oleaginous plant species, such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed fii, linseed oil, coconut oil, palm oil. thistle oil, walnut oil, arachis oii, olive oil or castor oil, In particular rapeseed oil, where the vegetable oils also include their transestérification products, for example alkyl esters, such as rapeseed pi! methyl ester or rapeseed oil ethyl aster.

The vegetable oils are preferably psters of Gir^sr. preferably €.r-CW·, fotty odds, the Ci,c-Cj.2"fatiy add testers are, for example, esters of unsaturated or saturated Gir-Gisr-fotty acids having, in particular, an even number of carbon atoms, for example eruac acid, lauric aeid^ palmitic ateid:end in particuiar Oi8-fetty acids such as stearic acid, oieic acid,: llnoieie acid or iiholtehte acid,

Examples of vegetable oils are Ciir-Cggdaify seid oolds, or

Cig-CxrMíiy seid OrQas-sIKyl ©stars which cae be oÄipedv f©r example, by tehsasterification of the glycerol or glycol C;ii-C.«-f8tiy acid esters mentioned a&amp;bve'With (lor example imethanol, efhanof. popanoi or butanol). The transestérification can be battled ou* by known methods as described, for example, ln Römpp ©hernia lexikon. Ifit οΟίΐίοιρ voluma |,: page 1343, Thieme1 Verlag Stuttgart

The vegetable oils can be contained in the oil suspension cbnoertfmtes according to the invention for example in the form of commercially available vegetable oils. In particular rapeseed oils, such as rapeseod oil methyl ester, for example Phytorob® B (Novance, France). Edener® MEBU and the Agnsgue# ME series (Cognis, Germany), the Rad sa® series (ICI), the Pdlube® series (Petrofina), or biodiesel or in the forrrs of commercially available plant-oil-containing formulation additives, in particular those based on rapeseed oris, such as rapeseed oil methyl esters, for example Hasten® {Victorian Chemical Company, Australia, hereinbelow referred to as Hasten, main Ingredient: rapeseed oil ethyl ester), Actrrob®8 (Novance, France, hereinbelow referred to as ActirobB, main Ingredient; rapeseed oil methyl ester), Rako-Blnop payer AG, Germany, herelnbeiow mterred to as Rateilnei,main ingredient Germany, hemibbelow referred to as

Rendi, vegetable oil ingredient: rapeseed oil methyl eater·) Pr hereinbelow referred to as ivlero, main Ingredient rapeseed oil methyl ester)

Examples of synthetic fatty aold ester s are, for example, those derived from tally acids: haying an odd number of carbon atoms, such as

Preferred öfpnio solvents are aromatic hydfpCSÉöna, aliphatic esftrs* SUbh as vegetable oils, such as triglycerides of fatty aids having 10 to 21 carbon atoma, vyhloh may be saturated or else unsaturated, straight-chain or branched and which may or may not: carry further functional groups, such as corn oil, rapeseed oil, oil* ItnseedÄ '^p^nrotti coconut oil, palm oil, thistle oil or castor oil, and their transestérification products, such as fatty acid alkyi esters, and mixtures thereof

The solvents may be present on fheir own oras a mixture, TbP tótat proportion of solvents In the oil suspension concentrates according to the invention is generally between 5 and 85% by weight, preferably In the range between 20 and 80% by weight. The proportion of polar solvents such as aprotio polar solvents Is generally below MQ% by weight, f^ferib|?:j|p the range from 0 to 10% by weight.

Tiie oïl to the invention may opfjonulty 0^ (component <$,; ifbrekampfe mohe- nr distem of sufipeimcinlo *#&amp; fftj&amp;fgbiff thestiofteé formula {Hi} in which f? is hi or an unsubstituteb or subshtuted Ctdp^ydreeirbon radical, such as CrGxretkyi or C ?- C'ssyiSikyiaryi, R2 is H or an unsubstliuied or subslated C,-Osr hydrocarbon radical, such as ót-Css-aikyl or

GrCsrPtkylaryi, or a cation, for axante ® metal cation, such as an alkali métakor alkaline ossfth metal cation. or an ammonium cation, such as HH4 or an alkyi-, aikylaryl· or C0iy(afyialky|}phenyiamn^önium cation, ;l:\ K2 arc identicalor dsberentand independently of one another are a spacer unit, such as. a poiyeiher unit or a polyester unit, n, m are identical-bi different and independently of one another are zero or 1, preferably zero, and M i§ a cation, for example a metal cafsen, such as an alaii metal or alkaline earth metal cation, or an ammcnlum catien, such as Miik or and|kyi~; aikylaryl- or poiy(aryialkyi}phenyiammonium cation,

Preference is given to euifosecclnetee of the formuia (III) irr which R1 and are identical or different and independently of one another are linear, branched or cyclic, saturated or ynsatyrated preferahly C^S,8¾ eikfI; radicale; such as methyl, ethyl, butyl hexyl, cyolohexyl, octyl, such as 2-ethyibexyl, decyl tridecyi or octadeoyl radicale, or R! end are Cv-C20-aikylaryl radicals, such as nonylphenyl, 2,4,€vtr! -sec-butyipheny| 2,4,84nsf 1~phenyiethyl;iphanyl, aikyibensyi or a hydrocinnamic radical,

Xs and X;; ere identical or different and independently of one another are ppiyether units, such as polyethylene glycols «{C*H*OV or polypropylene glycols -{CÄChjr where p ~ 1 to p ~ 20, in particular p « I to p - 1¾ or polyester units, such as polyhydroxybutyric acid -(CRpHgl-QHa-COO),,-or polyiactio acid -(CHpt#£W)c where q = 1 to q = 15, In particular q~ 1 to q = 8, n. m areildentleel or different and independently of one another are zero or 1, preferahtyxerc, and M Isa cation, far example a metal cation, such as an alkali metal or alkaline earth metal cation, or an ammonium dation whicb may he aikyl-suhstituied,

Examples of sutfosaccinaies presentaccording to the Invenfinn are si} sutfosuccinaie which is ostedtled onee: nr twice with linear, cyclic or branched aliphatic, <f^iog||pheUcand/dr#reme^'ÄÄplii¥ing, for example, l to 22 carbon atoms In the alkyl radical, preferably mono- or #tMs:rtiiil;;fdilfO$udOihgte, in particular mono- or disodlum suifosucelhaferwhlch^de esienfied cnee of twice with methanol, ethanol, (Sso)propanoi, fisoibufanoM-süípentsnoi. uydiohexpboi. (Ipô^^tâMÈ* (isofootanoi (in particular ethylhexano!) (isosnonsnoi, (isoldecsnol, {Isolyndeotnbi, :(isö}d0dse8noi er (iso)tndecanoi, a2) sulfosucünate whíct'i is esferified one®: or twice with (poiy}8lky1ene oxide adducts of alcohols, haying, ferexafPpie, 1 to 22 carbon atoms in the aikyl radscai and 1 to 2Ö0. preferably 2 to 20Ö, afkyfene oxide units in the (peiy)alkylehe oxide moiety, preferably mono- or diáikáli metal sulfesueelpaia, In particular mono·· or disodiium sulfbsuOeihate, which is esterified mm or twice with hedepyi/tetfadepyi iteodoi> 2>S mot of afhyione oxide or with Idridecyi * 3 mol of ethylene oxide, aS) the diaikali metal sait, pfefafehly the disoctium salt, of maleic anhydride which has been reacted with one equivalent of an amine or an amino-fernunsfed fpo!y}aikytene oxide adduct of an alcohol, an amine, a fatty ac-d. an ester or att amldo and then sulfonatad, having, for example, % WM carbon atoms in the alkyl radios! and i to IQ#, ptefemhiy I to 100, oxyafkylene units in the (poiylalkyiane oxide; moietyv prefetahiy the disodium salt of maleic anhydride which has been rmcim with one equivalent of coconut tatty amine end then sulfonated. a4)i the diaikaO metal salt, preferably the disodlam salt, of maleic anhydride which bas been reacted with one equivalent of an amide or a {pniyiaikyieoe oxide adduct of an amide and then sulfonafed. hayipg, for example, 1 to 22 carbon atoms in the aikyl radical and 1 is 200, preferably 2 to 200, oxyaikyiene units in the fpoly}aikyiene oxide moiety, preferably the disedium sait of maleic anhydride which has been reacted with one -equivalent of oteylamlde * 2 mo! of ethylene oxide and then sufehaied: and/or aS) the tetraafkaii metal salb preferabiy the tetfasodium salt, of N-( 1,2-dioarboxyethyi;)»N~ octsdeeyisuifasuednamafe.

Examples of suifosuccioefes of groups alt a£$. whfbfe· âft· eqftmPfÄ^· available and preferred within the context of the present invention are iisted below: aly sodium diaikyisyffpsuecinate, for example sodium dltC^-CigtaikyieyilosuiXtinato, such as sodium diisoocfyjsuifopuccinate, preferably sodium di{:2-etbyihexyijsoffosyccinate, commerdaliy avaiiahie, tor example, m the lorm of the Aerosol brands (Cytec), the Agnian # e a otLankropol brandsi&amp;kso Nobel), limimplmlft brandsCAIbrightMMson), the Oropoi © © brands (Croda), the Lutensst brands (BASF}, the Triton brands (Union Carbide), the a ® a © .

Geropon brands (Rhodia) or the Imbiroi , kiadeol or Eoiiroi brands (Cesaipinia), s2) .:. sodium alcohol; polyethylene glycol ether sulfoauecihafo, commercially available, for example; i'n the form of Gempon® ACR brande {Rhodia), a3f disodium alcohol polyethylene glysoteiher aemtsuifosuecinate, commercially available, for example,, in the form of the Aerospf1 btandbtfôytee}, the Mariinet® οηΕοπηηί® brande |Çondeë|: the Emptcpi® brande íAfeíight&amp;vyílsön}, the Secosot® brands .(Steps®!,· the Geroponf "brands (Rhodia), the Disport# or Texapoh® brands (Cognia) or the Rblpon® brands (Cesalpinia). s4) disodlum N-aikylsuliosuccinamate, commercially available, for example, in the form of the

Aerosol® brands (Gytec), the Rewapr# or Rowoderr# brands (Rewo),: the Empimtn® brands (AfonghtSWilson), the Geropon* brands {Rhodia) or the Polin# brands (Cesalp-nia). all dfoogum fatty apid amide polyethylene glycol ether semssulfosucdipefo,: commercially available, for exemple, in the form of the Eifanof or Lankropof brands (Akzc Nobel), the Rewodenn#:Rewodds or RewoppP brande pewo), the Emcof brands (VViteo), the Standapoi® brands iCo^nff^thfÄpöß^tritbds (Cesalpinia), and elf 'lslf®^ibmiN^(i,2^dioejffe®^étH#^^iÉlfe!il.soifQsdrfoinámeÉar:dor®meráiatiy available:: for example, In foe form of Aerosol :t2® (Cytec).

Sulfosucoinotos ora commerclaily ayaiiahie, ter example, as: Aerosol® (Qyieo|, A|riian® dr lenkropo!® (Akxo Nobel). Empimtn®;puntsman). Crop«# (Crcda), Lulens# (BASF), Tutor# GR series iUnionCarblde), imbiml^^adeel^Rolirol® fCesalpInia); as Gsropon®AR series er as Geropo# SDS (Rhodia). f referred sptfosyccinefes are, for example, fee sodlnm, potaesium and ammonium salts of bis(aikyi)suifosuccinates, where the alkyl radicals are identical or different and contain 4 to lő csaton atoms and are, preferably, butyl, hexyl, octyl, such as 2-ethyihexy!. or decyl radicals, which may be straight-chain or branched, Particular preference Is given to sodium d!(C,fCi(-eikyi)sulfosuccinate such as sodium di(2-ethyihexyi)suitosuccinafe

If the oil suspension concentrates according fo the invention comprise suifosuecinates d). their proportionby weight isgeneratiy Ö.S to 60% by weight in particular 1 to 30% by weight. 0ption#®gmohemi^lly':®o(iyi compounds i| that may be present are, for example, egneohemioaiiy active compounds different from component a), such as herbicides, fungicides, insecticides, safeners or plant growth regulators, The d) may be present in suspended and/or dissolved form in the organic eefy®®!, form am In paftieular foe esters of INpíterMcides (B1) and (B2) From among the :ä compounds (G), in particular the estersof the herbicides (C2), (C3); {06} and lhe sftert» (S1~1) ami^ilâs^feàïlSÂi,, TN© inps^sníp ssíis (component e) optionaiiy remained in the ölj ©«©pension concentrates according te |N© invention:: are preferably basic ino^anio :saf&amp;. These ere fo he understood m meaning gelte which , In i;% strengthagueous solution, have a pH > 2, preferably weaklybasic salts having a pH hetwnnn ? and 11, ixanpies of such salts ara carbonates, hicaftonates, hydroxides, oxides, hypeehionles and saifites, preterahiy carbonate© and Nicarhonatas. As cations, the inorganic sait© pretdrahiy containmatat ions, inparticularaikall metal, alkaline earth me^i and trahsition mstei Id©©, preferably alkali meta! and aikaiine earth metai ion©, such as sodium,:aata©siumv magnesiuth or eaicium. Particularly preferred salts are alkali metai salts, in particular aikaii metal carbonates and alkali metal bicarbonate©, such as NagGQ* bsPGx; MaHCO;5 and KHC^, The inorganic ©alts may b© present on their own or in a mixture,

If the oil ©uspnsion concentrates according to the Invention contain inorganic satis e), their pmporiion by weight (©generally bom 0,01 te :20% by weight, preferably from fM1 to 10% by weight, particularly preferably from Ö.ÖS# S% by weight.

Guatornaty auxiilarfes and additives {compn©nt f} which may also P contained in the oil suspension concentrate© iocofOing to the invention are, tor example: surfeetanf©, such as ernuisihers and dlsprsants, tNlekeners and thixotropic agents, wetting agents, anti-drift agents, adhesives, pénétrants, preservatives and arftjtaexe agents, antioxidants, solubilizers, fillers, carriers and COterantS, gnfiipams, fertilizers, evaporation inhibitors and agents which modify pH and viscosihr.

Suitable emulsifier© and dispersants are, for example, nonionic emulsifiers and dispersants, for example. 1 ) poiyaikoxyiatod. preferably poiyafhoxyiafed, saturated and unsaturated aiiphetic alcohols, • having 8 to 24 carbon atoms in the alkyl radical, which is derived from the corresponding fatty acids or fron·; petrochemical product©, and: • having 1 to 100, preferably 2 to 60. ethylene oxide units (EO}; it being possible for the free hydroxyl group to be aPoxylated, which are commercially available, for example, as -GeaápdP X and Gehapoi^ 0 series (Glanant), Grovel® U ssnes (Grade) or as Lulansoi® senes (BASF), 2) potyaltioxytated, preferablypaiyethoxyiafed, arylalkyiphenois, such as, for example, 2,4,:04rl©(1-phenyfethy|)ph©noi (fristyrylphenol) haying an average degree of ©thoxyiation of between 10 and B0, preferably tom lb to 40, such as, for exampis, Soprophor* BSU (Bhodia} or HOE S 3424 (Glanant). 3} preferably $t$jpfhoxyiyi4 âikÿjphenofs having one or more alkyl faisais, such as, forexample. nonySehahhiiar irhaae-hu^iphano!, and a degree oLetmxyisllon of between 2 add 40, preferably from 4 to IS, soon as, for example, Arkopaf N aeries or Sapogenat® T series (Glanant), 4} poiyalkoxylated, preferably polyeihoxy iat ed, hydroxyfatty acids or glycerides which contain hydroxyfatty acids, such as. for example, riclnina or castor oil, having a degree of ethoxyiation of between 18 and 80, preferefely from 25 to 40. such as, for example, the Emui sogen® EL series {Clariant} or the Agnique® CSO series (Cognls), §} poiyalkoxyiafeit preferably plpihoxylated, sorhifan eaters, such as, for example. Atplos® 300 F (Uníqema) of the Aikemuls® series {RhodlS}, S} poiyalkoxylated, pretemdly pdiyelddxyiated, amides, such as, for example, Genomin® series (Clariant), lmfcantl#£Al3 aeries (földi dr tufensof5 FA series (8AÍF}, 7} di~ and frbbiock copeiymers; for example from alkyleoO oxides, for example fmm ethylene oxide arsd propylene oxide, having: average molar messes between 20Q end 10 880, preferably Item 1000 to 4000, g/rnol, the pmporhph by mass of the polyetboxylated block verylog between 10 and 8ö%, such as, lor example, the Cenapol® FF series {Clariant}, the Plumose^ series (ÍA8F), or the Cynperohio® PE sériés CUnigema}.

Preferred nonionic emulsifiers and dispersants: are, for example, poiyethoxytated alcohols, polyéthöxylafed triglycerides which contain hydroxyfatfy acids and polyethylene nxidefediypmpyieoe oxide block copolymers. if the oil: suspension concentrates according to the invenhon contain nontonle emulsifiers and dispersants, their proportion by weight is; generaliy from 1 to 20% by weight

Also suitable are ionic emulsifiers and dispersants, for example. 1} polyaikoxyfsted, preferably polyeihoxylatsd, emuisiiersfdispemanfe (of. component e) whioh are sonicafiy modified, for example by conversion of the ferminel free hydroxyl function of the polyethylene oxide biook: Into a sulfate or phosphate ester (for example as alkali matai and alkaline aarth rnetai salts), such as, for example, Cefiapof IRO or dispersant 3618 (Clariant}, Emulphor® (BASF) or Crafol* AP (Cognls), 2} elkeli metal end: alkaline earth metal Ms. of aikyiaryisuifenle aoids having a sffaight-nhain: er branched alkyl chain, such es pheny lsuffonate CA or phenylsuifonate CAL {CiarîaoÇ,

Aflox^ 3377Ä: (iCi). or the Impiphos® TM series (fduntsman), 3} poSpleotroiytefo sdeh as lignesulfOnates, condensates of haphthaiehesulfooato and fermsldehyde, polystyrenssulfdoafe or suSfonaied unsaturated or aromatic polymers (polystyrenes, polyPidadlsnss: of poiyterpsocs), such m the tamof series: (BASE),,

Morwéf exes (Wife®), m® ΚΛρ*§&amp;® mmím<ám®>yBofrespers# senes: {Borregard}:,

Prétasd sonic: emuisifiefs/dispersante pf#, fer example, salts of aikylaryisulfonic: acids and poiysfeeffaiytss: from the polycondensation of naphthaienesuifonate and: formaldehyde. if the oil: suspension concentrates according to the invention contain ionic emulsifiers and dispersants, their proportion By weight is generally frop Ö.1: to 2Bi> By weight, in pdicular from 0,.§ to WM By weight. if oohiohlc ár Ionic emulsifiers and dispersants ate used not only Because of their emulsify!ng/dispersing properties but also to increase the Bloiogicai effectiveness, for example as penef®nts or fackifiers. their proppffioo in the oil suspension concentrates according fothe Invention may be increased to up to 60% by weight

Suitable thickeners and: thixotropic agents are, for example: 1} modified natural silicate®, such as chemically modified Bentonites, hectonfes, afiapulglte®, mcntmofiilonites, smectites: of other silicate minerals:, such as Sentons® fEiementis), Attagei® fBngeihafdl, AgSorB® (Oli> Dfi Borporafien) or Hectorite® (Akeo Nobel), I) synthetic silicates, such as silicates of the: Sipernat®;, Aerosil® or Durosll® series: (Bagyssa), the GAS-0>;Sit® series (Cahot) of the Van Gel: series p.T. Vanderislit). 3) thickeners Based on synthetic polymers, such as thickeners of the Thsxln® or Ihixatfof series (Biemehtis), 4} thickeners Based On natural polymers and natural oiis, tor example from the Thixin* or Thixatroi® series: (Elernentis),

Preferred thickeners and thlxotropic agenls are, fef example, modified phyilosiiicaies and: thickeners Based on synthetic polymers.

If the oïl suspension concentrates according to the Invention contain thickeners and thixotropic agents, their proportion: By weight IS: generally irons 0 1 to S% By weight, In particular from 0 2 to 3%

By weight.

Preference is given io öli suspension concentrates according: te tes Inventionmomprisiag: s) 'Mi tO: 5ö% by; weight preferably ö.1io -30%- by 'Weight of one or more herbicides (A): unci: (B), in suspended form, h) 6 lb §h% by weight, preferably SO to 80% by weight,, of one or more solvents, o) optionally OJ to 60% by weight, preferabiy 1 to 30% by weight, of one or more suifosuceinates, 0) pptionaiiy OM to. 30% by weight preferably 3 to S0%: by weight, of one or mere agroehemicaily active compounds different tern a). ei optionaiiy 0.01 to 20% by weight, preferably 0.01 to 10% by weight, of one: or more inorganic saits, f) optionally 1 to 20% by weight of one or more nohionic emulsifiers and dispersante, optionaiiy ! to 20% by weight of one or more ionic emulsifiers: end dispersants, optionaiiy 0,1 to 5% by weight, preferably 0.® to 3% by weight, of one anmom: thickeners and thixotropic agents.

The oil suspension concentrates according to the invention can he prepared by known processes, for example by mixing: the components, Thus, it: is possible, for example, to prepare a premiX; by adding any suifosuccinata 0} present and, if appropriate, further auxiliaries and: additives f) to the organic solvent b). Any soluble agrochemicaliy active compounds df used: are then dissolved in the premix. Once the dissolution process has ended, solid herbicide a) and, if appropriate, any insoluble active compounds d) used and also Inorganic saltse) are suspended in the mixture, The coarse Suspension is, if appropriate after pregfihding, subjected to line grinding;

In another embodiment, solid herbicide s$*pd< if appropriate any insoluble: components d), e) and f) used are suspended: In the Organic solvent b) which optionally contains a auifosueeinata cj and subjected to grinding, Any soluble active compounds <$, used: and any auxiliaries and additives f) which do not require grinding: or are not required for the grinding process are added after grinding.

To prepare the mixtures, it is possible to use customary mixing: apparatus which;, if required, are ihermostatted. For pregrinding, It is possible to usa, tor exempte high-pressure hsmogenisers or milis operating; by the rotor-stator principle, such as Uitraturrax homogenilers, for axampte these tern tKA, or toothed colloid malte fer exempte from Fuck. For fine grinding, if is possible to: use, for example, bead mills which operate bafohwise, for example from Orate or bead mills which operate eantinuouáíy, for example fmnviaehofercThe preparation proems pan beadupted do the properties (rt tim cort^penents opöönaiíy pretreatert aed to. technical end apfety neppim^ants and to economical considerations, and pre|nndtng and even fine grinding at the suspension may be dispensad aiith, if required. 'the odrtiponents a} to f) used for thé::preparation may comprise water as a minor component which is then also found in the oii suspension concentrates: according to the invention, Accordingly,; filed!! suapansron concentrates according to the invention may comprise small amounts of wafer, in general from 0 to 5% by weight. Preferably^ the oil suspension concentrates according to the invention:áré: not subjected to any drying:

For use. the oil suspension: oonceotfaies adoatdidi%lfeéihwition may, d appropriate, be diluted in a odefoiaery manner (for example using waters fa give,for example, suspensions, emulsions, Sdppeemuislons or solutions, preferably to give emulsions. If may be advanfegeous M add hjrtder airodhemicaily active compounds (tor exempte tans mix partners in the term of corresponding: fprmaiatidns) and/or auxiliaries and additives customary for application, for example selhemulsifylng oils, such as vegetable oils or parafhn olis, and/or fertilisers to obtained spray emulsions. Aeedfdingiy, the prasénf invention also provides such harbicidalicomposltions based on the oil suspension concentrates acoord-ng to the invention::

As regards further details on the formulation of crop protection products,; see, for example, 0>®>. Kl-ngman, “Weed Contrôlas aiSelenee”, John Wiley and Sons, Inc., New York, Ildi:, pages 81*98 áhd d, 0,. Frayer, SW iyans, ^Weedi Control Handbook", 5th Fid,:, Biackweil Scientiiie Publications, Oxford; 1968. pages 101--103.

Asityule, the agrocbemicai farmulations comprise from 0.1 to 90% by weight, in particular from: 2 to 95% by weight, of aetive compounds of types (A) and/or (B), the loi lowing concentrations being customary depending cm the type of formulation: in weitahie powders, the active compound concentration Is, for axempia, approximately 10 to 95% by weight, the remainder to 106% by weight being composed of customary formulation constituents, in the case of emuisifiabie concentrates, the active compound concentration can, for example, amount to from 6 to 80% by weight Formulations in the form of dusts generally comprise horn 5 to 20% by weight of active compound, and sprayehie solutions comprise approximately 0 3 to 2534 by weight of active compound, In the case of grenu les such os dispefsibie granules, the active compound content depends partly on whether the active compound is in liquid or solid form and on the 9râhdliate,âytdiiMÎd®:'pndrîi|ii|tf which are being used, in the case of Ä:y^iiMia^^ibte;:0fähöi^:Ä>oöbteht is generaily between 10 and 99% by weight, in the case of oil suspension doncentrates, the active compound concentration is generally from JQ,M to 5054 by weight in addition, the formuÄhs-.mey eonplMfc if appropnaf^ {Um gppvinöonal adhesives, wetting aganlav^P^^^Mlsitlifl,. ppseivativus. antifreeze tpttfs, solvents, fillers, colorante, earners, antifoams, evaporation inhibitors. pH regulators or viscosity regulators.

Tin perttioidal actiorv of the herbicide ooniPHatiens accoMiftg to tpe invention can be improved, for example, by surfactants. preferably by wetting agents from the group of the fatty alcohol poiyglyco! ethers. The fatty alcohol poiyglyco! ethers preferably contain 10-18 carbon atoms in the tatty alcohol radical and 2 ~ 20 efoyfone oxide units in the polyilyebi ether moiety. The tatty eicohoi poiygiycoi ethers dan fee nonlbnic or ionic, for example -rvfoe form of fetty aloohoi polygiycoi ether sfeifates, which are used, for example, as alkali metal salts (e g. sbdidnr salts or potassium salts) or ammonium salts, but also as alkaline earth metal salts such as magnesium salts, such as sodium Gig/G t 4-fafey alcohol diglycoi ether sulfate (Genapof* LRO, Ciariant GmbH); see, for example, EP-A-0478555, EP~ A-0Ö48438, EP-A-03361 o 1 or US-yt-4,400,110 and afso Pfoc, IWRf Symp, ^FaÄrs Affootinp Herbicidai Acfiyity and Selectivity*, 22? ~ 232 (1988). Noniorsic fatty alcohol poiyglyco! ethers era, for example;, (0^-0¾)¾ pteforably (Cin-C^HIÏy #fobh0f poiygtycol ethers eonfafolnp 2- S preferably 3 -15, ethylene oxide units (e g. ssofodsby! eiçohd! pöíyglycp! ether), such as Genepof M-Ö00, Gonapof* X-06Ö. Genapo!^ X -Ö8Ö or GunapcP X- 150 (all from Clariant GmfeB}> The present invention furthermore embraces the combination of compounds of the formula -l) and their saits with the wetting agents mentioned above:from the group of the fatty alcohol polyglycef ethers which preferably contafo 10 -· IS oarbeh aterns in the fatty alcohol rafeicai artd : 2- 20 ethylene oxide units in; the pciygiycoi ether moiety and which can be presentm neniorticor fonlç fenn (for example as fatty alcohol pblyglycei sfoer sulfates), preference: is given to Q*y/C^fattyalechof:bigiyobi ether sulfate sodium penapof LPG, Glarian! GmbH) and isotfidecyi alcohol polygiycci ether' having 3 - is ethylene oxide units, for example from the Ganapol® X senes, such as Genapbl® X« Gehapbf X-Cfod, Genapof X^880 and Genapoi* XfoS'S' fall fromiCi^pbísmííH^.R^i&amp;ver, itm known^tbatfapy aicehol polyglycoi efoers sucli as nonionic or Ionic fatty alcohol poiyglyco! ethers (for example fatty alcohol poiyglyco! ether suifotesl are also suitable as penetrants and synergists for a number of other herbicides, inter aha also for herbicides from tha group of foe imidezolinones (see, for example, £foduÖ5Ö2öM).

Tbc herblcidai effect of the herbicide combinations accofoing to foe invention can also be Increased using vegetable oils. The term vegetable oils is to be understood as meaning oils from olbplanf species, such as soybean; oil, rapseed oh, com oil, sunflower oh, ceifonseed: oil, linseed oh, coconut oil, palm oil, safflower oitor castor oh, in particular mpeseed oil, ap their transestérification products, for example alkyl esters, such as mpeseed«il methyl ester er rapeseed oil: ethyl ester.

The vegetable oils are preferably esters of C„rC?.r-> preferably C!rC;ïir?atty acids. Tha ClirC?r-fatty acid esters are, for example, esters of unsetureted or saturated CUrC2rfatiy acids, in particular those ΠΊ#prfep. atoms,example «meto acid, isurie acid, ptmitícsoid aad, la particular, Cirfotfy aofos sued as: alsanc acidr oidiC: acid, iinoleic acid or Sinoienic acid. ëxamptes.#Ç^CayMÿ «oîd esters cm esters obtained by reacting glycerol or giyootwith the ΤοίΓ Css-fatty acids as they exist, for example In bile from ofopishf species, er örCssre^yrtSarCss-'^tty acid estera as cable obtained, 1er example, by tahsesfabfídafípn of tbsabovementioned glycerol« or giycoi-Qso-e^datty methanol, ethanol, propanol or hufanofo f raneMtehtlcaftou can be camed out by known methods as are described, tor example, in volume 2, page IPS, Thleme Aferiag Stuttgart.

Preferred arÄ-aikykiio-CärÄy acid eaters are the methyl, ethyl, propyl, butyl, 2*ethyihexyi end dodecyl esters. Preforred giyceband g^teroP%-Càdi% acid eaters are the uniform or mixed glycoi $mm and glycerol eaters m particular those fatty acids which have an even number of carbon atoms, for example erucic add, iauric acid, palmitic acid and, in particular, Css-fatty acids such as stearic acid, oleic acid, llnolelc acid or linoianic acid.

The vegetable foils esu be present In foe herbicide! compositions according fo the indention for example in the form of commamlaily ayalfobfo eii-containing formulation additives, in particular these based on rapeseed oilmuch as Hasten® fdjciorlan Chemical Company, Australia, hereinbeiow termed Hasten, maihi censfituent; i'epeseod oil ethyl ester), ActiroÄ pdvance, Pmnce, iereinheiew tenood ActirobB, main censtifoentc raposeed oil methyl ester), RekoÄöi® (Bayer AQ, Germany, termed Rako-iinc? tmreinbelow, main constituent: rapeseed sii), Renef (States, Cenmany, termed Bendl herainhefow, vegetable oil constituent: rapeseed;oil methyl ester), or Sfofos foero® {Stetes, Germany, hereinbeiew termed tviero, main constituent: rapeseed oil methyl ester}.

For use, foe formulations, which are present in cpmmerclaiiy available form, are optionally diiuied in the customary manne?; for example using water. Preparations in the form of dusts, soil granules, granules for broadcasting and spfspble solutions are usually not dilated further with other inert substances prior to use.

The active compounds can be applied to the plants, parts of the plants, seeds of the plants or the efoa an which the plants grow, for example the psturearea or the ansa under cultivation, preferably to the green plants and parts of the plants and, if appropriate, additionally to the soil.

Che possible use is the joint appiicatloh oftha active compounds in fhe form of tank mixes, the concentrated formulations of {heM^ltohlÉvg^WtpOifodS, in optimal formulations, jointly being mixed with water »n the tank and the msultipg spray mixture being applied.:: A joint herbifeiefoi: formulation of the combination according to the invention of the active compounds (A) and (8} has the advantage of being easier to apply since the quantities of the components are already presented in the correct ratio to each other, Moreover, the adjuvants in the formulation can be matched optimally to each ether, A, Générai formulation examples a) A dust is obtained by mixing t o parts by weight of an active compound fautive compound mixture and up; parts hy weight of taid aeiihert material and c^mÄdtlrtiÄtidlKtdft Id a hammer mill. h) A waiabio powder which is readily dispersible in water is obtained by mixing 25 parts by df an. ebte-eörnpeubdi / activa oempeund mixture, 84 pens by weight ot kaoism containirsgipyartg m inert mafonai. iQigarts by weight of potassium lignosuifenata and i part iby weight oi sodium dieoyimethyitaurihate as Wetting agent and dispersant, and grinding the mixture in a pinned-disk msif 0:} iAdispersion edneehtiáte: which is readily dispersihia in water is obtained by mixing 2Ö parts by weight of an active compound / achve compound mixture with δ parts by weight of alhyiphendiipoiyitycol ether (€) rmon X 207), 8 parts Py weight of laotridecanot poiyglycol ether (8 EO) and 71 parts by weight of paraffinic minerai ci! (bailing range for example appro* 2SP to 21f"d), and grinding the mixture in a hail mi to a hheness efiheidw 8 microns. d) An emuisifiahie ennbehirate iS: obtained from 16 pads by weight of an active oompound / active oompduhd mixture. 78 parts by weight of epiohexsnoneas soivenf end 10 parts by Weight of exÿethyiated iionyiphenoiws amtii e) Watendlspersibie granules are: obtained by mixing 78 parts by weight of: art active compound:/ active compound mixture,: 10 parts by weigbtof calcium: íignoahiföhate, 5 parts by weight of sodlum lauryi suifate, 3 parts by weight of poiyvinyiiaicehOf and 7 parts by weight of kaolin, grinding the mixture on a pinned-disk mill and gran Gating the powder in a fiuid&amp;ed bed by spraying on -water as granulation liquid

Watep'dispersibie grannies are also obtained by homogenizing and pracomminating, in a coiloid mifi, 28 parts fey weight of am active cornpourm / activa compound mixture, S parts by weight of sodiuo5 2v2hdlnaphthytmethane-'8,8<~disuifonate, 2 parts by weight of sodium oieoylmethyitaurinate. 1 part by weight of polyvinyl alcohol. IT parts iby weight of ©aictum carbonate and 50 poos by weight of water. sphsequentiy gnadipg thenifdute In a bead; wi-:|*lálliÍ@!if!iíiÉljag: »0:drÉ$ing. th^raatiflng suspension in a spray tower B. Bidiog lea i esarn pi©s: 1. Herbicidai action against weadáilpfaenböusatrtaial

The seeds: Of rhiyorne pseces o? typical hamifyi plantewôfe: placed ini© sandy loam ©oil to round pats» siy© 13, coysrad with soil and grown in a greenhouse undargoöd groeatv oendiiioim Mar the harmful plants bad ©otefged* they ware treated, as a ttsie at the t~ tö 3Baaf stage, with various dosages ©f the eoinpositions Odeording to the Inversion at a water applioefion tat© of 100 to 4ÖÖ Ifaa teonvertod:); 4tfpta*b -4 week© after appiioatierO,the herhidloal activity of the active compound© or acfiye oornpound niMures was: sooted .vísm©!%: iby- ro^ptdng the treated plants with untreated contrôle, Äi§gt-;iadi ieviafppPteii of all eboya^feund: pari© of the plants was recorded; Scoring was dona on a percentage seal© (100¾¾ action « all plant© dead; 60% action ~ 60% of the plant© and green plant part© dead; 0% action - no disoefniPI© action}.

The results efé iiístsd íln tee tables below. where the activity maeeurod for the independent use of the açtiveweâopouhds fáó and (Si is stated te brackets,

Table 1 :

2. Herbididal action against wood y ©hr oh weed© |groehhease thtes}

Thetptents wore cultivated to the 6« to Odeaf stage. Herbicide application and sconhg of the triai: were carried out as In Example 1.

Table 2:

Claims (9)

1. Bzabadalnti ígénypontók LMeddőid kömbkíáéiCu amely 02 (A) ás (I) magában, ahol (A) jelentése az Cl) képisrö vegyületek hsrbwUS és

   (B) jelénlésö piklöram és: m &amp; teerst» továbbá ambtopitiallö éö söti és fesrei· csoportjából megválasztó« egy vagy több hednmd
2. 2. Az I. igénypont sminti hedddö kombináció, améiy (A) IbsnponenSíkéht amidoszuifnroti: és aoddószölftsröít-náAiöí-i exportjából megválasztött egy vagy több hérfeíeklec taidáímaz,
3. 3, Az I - 2. igényoatitok közül egy vagy több szerinti hörbléid: keaíbimkiö, arneíy járulékosan eltérő ti-pusü agröliÖmkiBág aknv vegyöletek, iómtázásii segédanyagok és a növényvédelemben: szokásosan basznál! segédanyagok alkotta csoportból egy vagytöbb további komponenst tartalmaz.
4. 4. Az I: - 3:, igénypontok közöl· egy vagy íöbb szedőd herbick! kombináció, amely járulékosan az (A) és (B) komponensekké éiíérö egy vagy több borókádét és/vogy saldiert usríalmax.
5. 5. Az I V 4. igénypontok közöl egy vagy több szemei herb leid kombináció, amely járulékosa« gkiszniinroo és sőt és észterek msfenpír és sói és észterek bromosiml és sói és észterei, iosinlí és sói és észterei, íHStdbuziri, pröpoXlkarbazöii és sás és észterei, etotaezáí, diílüfenikáo és etoxiszulfuroo és sót és észterei esö-portjábólstepálasztöltegy vagy több hatóaoyagitf msaimaz.
6. 6, Ellátás káros növények irtására, amelynek során: az: I - $, tgénypomok: közül egy vagy több szerinti bednek!: 'kombináció köinponenseit együtt vagy külön-knlöit a öövéöyékre, síi növények részesre, a ttövéoyek magvaíra vagy arra ä területre .kijnttasjyk, aboi a növények növekednek,
7. 7, A 6. igénypont szerűm eljárás káros növények mására haszonnövényekben.
8. 8, a 7. Igénypont szedni! eljárás káros növények irtását« egyszikű böszonnövényekbérs.
9. 9. A f. vagy 8. Igénypont szerinö eljárás, aboli a bäszonriövenyek pnetikniiag módosítottak v&amp;gy mm-cián szelektálás tkján jötték létre, lő. Az I ·· S. %éöyp^nk4bir.i»elyjfce »«wniíi herbkkü kombiMóió káröá növényiek: irtására való aíkak mazásra.