HU215458B - Katalizátorhordozó és eljárás előállítására, hordozós metallocén katalizátorok, valamint felhasználásuk poliolefinek előállítására - Google Patents

Katalizátorhordozó és eljárás előállítására, hordozós metallocén katalizátorok, valamint felhasználásuk poliolefinek előállítására Download PDF

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Publication number
HU215458B
HU215458B HU9501631A HU9501631A HU215458B HU 215458 B HU215458 B HU 215458B HU 9501631 A HU9501631 A HU 9501631A HU 9501631 A HU9501631 A HU 9501631A HU 215458 B HU215458 B HU 215458B
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HU
Hungary
Prior art keywords
catalyst
polymerization
aluminoxane
mao
mol
Prior art date
Application number
HU9501631A
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English (en)
Hungarian (hu)
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HU9501631D0 (en
HUT73069A (en
Inventor
Eberhard Ernst
Wolfgang Neissl
Jens Reussner
Original Assignee
Pcd Polymere Gmbh.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Pcd Polymere Gmbh. filed Critical Pcd Polymere Gmbh.
Publication of HU9501631D0 publication Critical patent/HU9501631D0/hu
Publication of HUT73069A publication Critical patent/HUT73069A/hu
Publication of HU215458B publication Critical patent/HU215458B/hu

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • C08F4/025Metal oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
HU9501631A 1994-06-03 1995-06-02 Katalizátorhordozó és eljárás előállítására, hordozós metallocén katalizátorok, valamint felhasználásuk poliolefinek előállítására HU215458B (hu)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT113094 1994-06-03

Publications (3)

Publication Number Publication Date
HU9501631D0 HU9501631D0 (en) 1995-07-28
HUT73069A HUT73069A (en) 1996-06-28
HU215458B true HU215458B (hu) 1999-01-28

Family

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Family Applications (1)

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HU9501631A HU215458B (hu) 1994-06-03 1995-06-02 Katalizátorhordozó és eljárás előállítására, hordozós metallocén katalizátorok, valamint felhasználásuk poliolefinek előállítására

Country Status (16)

Country Link
US (2) US5910463A (no)
EP (1) EP0685494B1 (no)
JP (1) JP3639346B2 (no)
KR (1) KR100351013B1 (no)
CN (1) CN1062871C (no)
AT (1) ATE171957T1 (no)
BR (1) BR9502617A (no)
CA (1) CA2150890A1 (no)
CZ (1) CZ288235B6 (no)
DE (1) DE59503827D1 (no)
DK (1) DK0685494T3 (no)
ES (1) ES2122394T3 (no)
FI (1) FI952640A (no)
HU (1) HU215458B (no)
NO (1) NO952191L (no)
SK (1) SK280653B6 (no)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0685494B1 (de) * 1994-06-03 1998-10-07 PCD Polymere AG Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
MX9703592A (es) * 1994-11-17 1997-08-30 Dow Chemical Co Componente de catalizador soportado, catalizador soportado, su preparacion y proceso de polimerizacion por adicion.
US6043180A (en) * 1994-11-17 2000-03-28 The Dow Chemical Company Supported catalyst component, supported catalyst, their preparation, and addition polymerization process
EP0754706B1 (en) * 1995-07-08 1998-08-05 PCD-Polymere Gesellschaft m.b.H. Supported polymerization-catalyst and its use for olefin polymerization
CN1047388C (zh) * 1995-07-14 1999-12-15 中国石油化工总公司 负载型金属茂类化合物/铝氧烷催化剂的制备
AT403919B (de) * 1996-02-02 1998-06-25 Danubia Petrochem Polymere Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen
JP3959132B2 (ja) 1996-03-19 2007-08-15 住友化学株式会社 アルミニウム化合物含有固体触媒成分、オレフィン重合用触媒及びオレフィン重合体の製造方法
SG84505A1 (en) * 1996-06-12 2001-11-20 Phillips Petroleum Co Process for producing an organo-aluminoxane composition for olefin polymerization
KR20000022440A (ko) * 1996-07-04 2000-04-25 스타르크, 카르크 담지된 전이 금속 촉매의 제조 방법
CN1049439C (zh) * 1996-08-26 2000-02-16 中国石油化工总公司 负载型金属茂催化剂、其制备及应用
CN1095474C (zh) * 1996-08-26 2002-12-04 中国石油化工集团公司 负载型金属茂催化剂、其制备及应用
US6129904A (en) * 1996-09-19 2000-10-10 Sud-Chemie A.G. Aluminum oxide masses with very narrow pore radius distribution
US20030195109A1 (en) * 1996-10-31 2003-10-16 Jose Sancho Royo Catalytic systems for the polimerisation and copolimerisation of alpha-olefins
GB9700945D0 (en) * 1997-01-17 1997-03-05 Bp Chem Int Ltd Catalyst activators
EP0864595B1 (en) * 1997-03-13 2001-08-16 Borealis Technology Oy Supported catalysts for the ringopening metathesis polymerization of cycloolefins
US5789502A (en) * 1997-04-22 1998-08-04 Fina Technology, Inc. Process for co-polymerization of propylene and ethylene
DE19733017A1 (de) * 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
PT953581E (pt) * 1998-04-27 2004-07-30 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas
AT406868B (de) * 1998-04-28 2000-10-25 Borealis Ag Verfahren zur herstellung von katalysatorträgern und geträgerten polyolefinkatalysatoren
DE19821370A1 (de) * 1998-04-28 1999-11-18 Borealis Polymere Holding Gmbh Verfahren zur Herstellung von Katalysatorträgern und geträgerten Polyolefinkatalysatoren
DE69916358T2 (de) * 1998-04-29 2005-04-21 Repsol Quimica Sa Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation
US7220804B1 (en) 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
ES2321806T3 (es) 2001-12-19 2009-06-12 Borealis Technology Oy Produccion de catalizadores soportados para la polimerizacion de olefinas.
GB0220681D0 (en) * 2002-09-05 2002-10-16 Borealis Tech Oy Process
WO2006049699A1 (en) 2004-10-29 2006-05-11 Exxonmobil Chemical Patents Inc Catalyst compound containing divalent tridentate ligand
US7875568B2 (en) 2004-12-17 2011-01-25 Yangzi Petrochemical Company Co., Ltd. Supported nonmetallocene olefin polymerization catalyst, preparation method and use thereof
KR101206940B1 (ko) 2007-10-16 2012-11-30 시노펙 양지 페트로케미컬 컴퍼니 엘티디. 마그네슘 화합물 상에 담지된 비-메탈로센 촉매 및 이의 제조방법
US8193288B2 (en) 2007-10-16 2012-06-05 Sinopec Yangzi Petro-Chemical Ltd. Supported nonmetallocene catalyst and preparation thereof
US8598094B2 (en) * 2007-11-30 2013-12-03 Halliburton Energy Services, Inc. Methods and compostions for preventing scale and diageneous reactions in subterranean formations
KR100996336B1 (ko) 2008-08-26 2010-11-24 삼성토탈 주식회사 폴리올레핀 중합용 촉매의 제조방법
US20100089578A1 (en) * 2008-10-10 2010-04-15 Nguyen Philip D Prevention of Water Intrusion Into Particulates
WO2010080870A2 (en) 2009-01-08 2010-07-15 Univation Technologies,Llc Additive for polyolefin polymerization processes
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
WO2010139720A1 (en) * 2009-06-04 2010-12-09 Teijin Aramid B.V. Process for manufacturing ultra-high molecular weight polyethylene catalyst
US8586685B2 (en) 2009-07-23 2013-11-19 Univation Technologies, Llc Polymerization reaction system
JP5523572B2 (ja) 2009-10-26 2014-06-18 中国石油化工股▲ふん▼有限公司 担持型非メタロセン触媒、その製造方法およびその使用
WO2011050565A1 (zh) 2009-10-26 2011-05-05 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
US8957169B2 (en) 2009-11-13 2015-02-17 China Petroleum & Chemical Corp. Supported nonmetallocene catalyst, preparation and use thereof
WO2011057469A1 (zh) 2009-11-13 2011-05-19 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
JP6023069B2 (ja) 2010-11-22 2016-11-09 アルベマール・コーポレーシヨン 活性剤組成物、その製造及び触媒中でのその使用
RU2577324C2 (ru) 2010-12-22 2016-03-20 Юнивейшн Текнолоджиз, Ллк Добавка для способов полимеризации полиолефина
CN102153681B (zh) * 2010-12-30 2012-07-18 湖南大学 一种负载型茂金属催化剂及其应用
HUE052713T2 (hu) * 2012-04-27 2021-05-28 Grace W R & Co Aktivátor készítmények, elõállításuk és katalizátorokban történõ alkalmazásuk
CN107107433B (zh) 2015-01-21 2019-09-13 尤尼威蒂恩技术有限责任公司 用于聚烯烃中的凝胶减少的方法
EP3915759A1 (en) 2015-01-21 2021-12-01 Univation Technologies, LLC Method for controlling polymer chain scission
KR102028736B1 (ko) * 2015-03-19 2019-10-04 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매
CN110573540A (zh) * 2017-03-21 2019-12-13 埃克森美孚化学专利公司 制备催化剂体系和聚合烯烃的方法

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE296898C (no) *
DE870242C (de) 1941-09-26 1953-03-12 Degussa Verfahren zum Verdicken von Fluessigkeiten
SU422255A1 (ru) * 1970-10-05 1976-07-25 Институт Химии Нефти И Природных Солей Ан Казахской Сср Способ получени карбоцепных полимеров
GB1489599A (en) * 1973-10-09 1977-10-19 Nippon Oil Co Ltd Process for preparing polyolefins and catalyst and catalyst component therefor
SU597201A1 (ru) * 1975-11-20 1986-03-15 Ордена Ленина Институт Химической Физики Ан Ссср Катализатор ди-,олиго- и (со)полимеризации @ -олефинов
US4169926A (en) * 1978-01-16 1979-10-02 Phillips Petroleum Company Inorganic hydrogels and uses thereof
US4530912A (en) * 1981-06-04 1985-07-23 Chemplex Company Polymerization catalyst and method
US4435519A (en) * 1982-11-24 1984-03-06 Cities Service Co. Novel catalyst composition
JP2566889B2 (ja) * 1987-07-13 1996-12-25 出光興産株式会社 オレフィン系重合体またはスチレン系重合体の製造方法
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US4912075A (en) * 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
JPH0791327B2 (ja) * 1988-03-24 1995-10-04 出光興産株式会社 スチレン系重合体の製造方法とその触媒
ATE122688T1 (de) 1990-01-02 1995-06-15 Exxon Chemical Patents Inc Ionische metallocenkatalysatoren auf träger für olefinpolymerisation.
FR2660926B1 (fr) * 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
JP2935878B2 (ja) * 1990-08-22 1999-08-16 チッソ株式会社 オレフィン重合用触媒成分
KR100192716B1 (ko) * 1991-01-18 1999-06-15 그레이스 스티븐 에스. 실리카 지지된 전이금속 촉매
TW300901B (no) * 1991-08-26 1997-03-21 Hoechst Ag
DE4139262A1 (de) * 1991-11-29 1993-06-03 Basf Ag Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
FI112233B (fi) 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
EP0578838A1 (en) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
DE4228711A1 (de) 1992-08-28 1994-03-03 Degussa Silicium-Aluminium-Mischoxid
CA2129794A1 (en) * 1993-08-10 1995-02-11 Toshiyuki Tsutsui Olefin polymerization catalysts and methods of olefin polymerization
US5648310A (en) * 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
AT401520B (de) 1994-03-22 1996-09-25 Danubia Petrochem Polymere Metallocene und deren einsatz für die olefinpolymerisation
EP0685494B1 (de) * 1994-06-03 1998-10-07 PCD Polymere AG Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen
US5468702A (en) * 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
US5670589A (en) * 1995-02-08 1997-09-23 Phillips Petroleum Company Organoaluminoxy product, catalyst systems, preparation, and use
BR9604776A (pt) * 1995-03-10 1998-06-23 Dow Chemical Co Componente de catalisador sustentado catalisador sustentado processo para preparar um componente de catalisador sustentado e um catalisador sustentado aduto de um composto organometálico processo de polimerizaçao por adiç o composto complexo e método para preparar um composto complexo

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Publication number Publication date
BR9502617A (pt) 1996-03-05
EP0685494A1 (de) 1995-12-06
KR960000932A (ko) 1996-01-25
US5910463A (en) 1999-06-08
DK0685494T3 (da) 1999-02-15
SK73495A3 (en) 1995-12-06
CN1062871C (zh) 2001-03-07
CZ288235B6 (en) 2001-05-16
US6069108A (en) 2000-05-30
JP3639346B2 (ja) 2005-04-20
NO952191D0 (no) 1995-06-02
FI952640A (fi) 1995-12-04
HU9501631D0 (en) 1995-07-28
DE59503827D1 (de) 1998-11-12
FI952640A0 (fi) 1995-05-31
CN1120550A (zh) 1996-04-17
JPH0848712A (ja) 1996-02-20
NO952191L (no) 1995-12-04
KR100351013B1 (ko) 2002-11-05
CZ142995A3 (en) 1995-12-13
ES2122394T3 (es) 1998-12-16
HUT73069A (en) 1996-06-28
CA2150890A1 (en) 1995-12-04
EP0685494B1 (de) 1998-10-07
SK280653B6 (sk) 2000-05-16
ATE171957T1 (de) 1998-10-15

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