HRP20121012T1 - Pirandioni, tiopirandioni i cikloheksantrioni koji imaju herbicidna svojstva - Google Patents
Pirandioni, tiopirandioni i cikloheksantrioni koji imaju herbicidna svojstva Download PDFInfo
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- HRP20121012T1 HRP20121012T1 HRP20121012AT HRP20121012T HRP20121012T1 HR P20121012 T1 HRP20121012 T1 HR P20121012T1 HR P20121012A T HRP20121012A T HR P20121012AT HR P20121012 T HRP20121012 T HR P20121012T HR P20121012 T1 HRP20121012 T1 HR P20121012T1
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- Prior art keywords
- c5alkyl
- halogen
- substituted
- nitro
- cyano
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- 230000002363 herbicidal effect Effects 0.000 title claims 3
- CZVTYGFISHLVHK-UHFFFAOYSA-N 4h-pyran-2,3-dione Chemical class O=C1CC=COC1=O CZVTYGFISHLVHK-UHFFFAOYSA-N 0.000 title 1
- SUEVWEWAIVZWCQ-UHFFFAOYSA-N cyclohexane-1,2,3-trione Chemical class O=C1CCCC(=O)C1=O SUEVWEWAIVZWCQ-UHFFFAOYSA-N 0.000 title 1
- 229910052736 halogen Inorganic materials 0.000 claims 64
- 150000002367 halogens Chemical group 0.000 claims 64
- 125000004093 cyano group Chemical group *C#N 0.000 claims 50
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 46
- 125000006677 (C1-C3) haloalkoxy group Chemical group 0.000 claims 35
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 33
- -1 C2-C4haloalkenyl Chemical group 0.000 claims 30
- 150000001875 compounds Chemical class 0.000 claims 28
- 125000001072 heteroaryl group Chemical group 0.000 claims 26
- 229910052739 hydrogen Inorganic materials 0.000 claims 20
- 239000001257 hydrogen Substances 0.000 claims 20
- 125000000217 alkyl group Chemical group 0.000 claims 16
- 125000004455 (C1-C3) alkylthio group Chemical group 0.000 claims 14
- 229910052760 oxygen Inorganic materials 0.000 claims 14
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 12
- 229910052717 sulfur Inorganic materials 0.000 claims 11
- 239000001301 oxygen Substances 0.000 claims 10
- 125000004768 (C1-C4) alkylsulfinyl group Chemical group 0.000 claims 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 8
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 8
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 claims 8
- 125000004434 sulfur atom Chemical group 0.000 claims 8
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 claims 7
- 150000002431 hydrogen Chemical class 0.000 claims 7
- 125000006274 (C1-C3)alkoxy group Chemical group 0.000 claims 6
- 125000005240 diheteroarylamino group Chemical group 0.000 claims 6
- 125000005241 heteroarylamino group Chemical group 0.000 claims 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 6
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims 6
- 125000006526 (C1-C2) alkyl group Chemical group 0.000 claims 5
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 5
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims 5
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims 5
- 229910052799 carbon Inorganic materials 0.000 claims 5
- 229920006395 saturated elastomer Polymers 0.000 claims 5
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 4
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims 4
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 claims 4
- 125000004399 C1-C4 alkenyl group Chemical group 0.000 claims 4
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims 4
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims 4
- 125000003545 alkoxy group Chemical group 0.000 claims 4
- 125000004076 pyridyl group Chemical group 0.000 claims 4
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 3
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims 3
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 150000003839 salts Chemical class 0.000 claims 3
- 125000001424 substituent group Chemical group 0.000 claims 3
- 125000004771 (C1-C4) haloalkylsulfinyl group Chemical group 0.000 claims 2
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 claims 2
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 claims 2
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 claims 2
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 claims 2
- 125000005865 C2-C10alkynyl group Chemical group 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 241000196324 Embryophyta Species 0.000 claims 2
- 150000001204 N-oxides Chemical class 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims 2
- 125000001584 benzyloxycarbonyl group Chemical group C(=O)(OCC1=CC=CC=C1)* 0.000 claims 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 125000000392 cycloalkenyl group Chemical group 0.000 claims 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims 2
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims 2
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims 2
- 125000002541 furyl group Chemical group 0.000 claims 2
- 125000002883 imidazolyl group Chemical group 0.000 claims 2
- 229910052740 iodine Inorganic materials 0.000 claims 2
- 239000011630 iodine Substances 0.000 claims 2
- 125000001786 isothiazolyl group Chemical group 0.000 claims 2
- 125000000842 isoxazolyl group Chemical group 0.000 claims 2
- 125000001715 oxadiazolyl group Chemical group 0.000 claims 2
- 125000002971 oxazolyl group Chemical group 0.000 claims 2
- 125000003566 oxetanyl group Chemical group 0.000 claims 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims 2
- 125000006678 phenoxycarbonyl group Chemical group 0.000 claims 2
- UYWQUFXKFGHYNT-UHFFFAOYSA-N phenylmethyl ester of formic acid Natural products O=COCC1=CC=CC=C1 UYWQUFXKFGHYNT-UHFFFAOYSA-N 0.000 claims 2
- 125000003373 pyrazinyl group Chemical group 0.000 claims 2
- 125000003226 pyrazolyl group Chemical group 0.000 claims 2
- 125000002098 pyridazinyl group Chemical group 0.000 claims 2
- 125000005400 pyridylcarbonyl group Chemical group N1=C(C=CC=C1)C(=O)* 0.000 claims 2
- 125000000714 pyrimidinyl group Chemical group 0.000 claims 2
- 125000000168 pyrrolyl group Chemical group 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 125000003831 tetrazolyl group Chemical group 0.000 claims 2
- 125000001113 thiadiazolyl group Chemical group 0.000 claims 2
- 125000000335 thiazolyl group Chemical group 0.000 claims 2
- 125000001544 thienyl group Chemical group 0.000 claims 2
- 125000004306 triazinyl group Chemical group 0.000 claims 2
- 125000001425 triazolyl group Chemical group 0.000 claims 2
- 125000005951 trifluoromethanesulfonyloxy group Chemical group 0.000 claims 2
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 claims 1
- 125000006559 (C1-C3) alkylamino group Chemical group 0.000 claims 1
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 claims 1
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 claims 1
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 claims 1
- 125000006643 (C2-C6) haloalkenyl group Chemical group 0.000 claims 1
- 125000006577 C1-C6 hydroxyalkyl group Chemical group 0.000 claims 1
- 241000209504 Poaceae Species 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000002671 adjuvant Substances 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 125000000304 alkynyl group Chemical group 0.000 claims 1
- 125000005418 aryl aryl group Chemical group 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 125000000262 haloalkenyl group Chemical group 0.000 claims 1
- 125000004438 haloalkoxy group Chemical group 0.000 claims 1
- 125000001188 haloalkyl group Chemical group 0.000 claims 1
- 239000004009 herbicide Substances 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000003446 ligand Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 125000001624 naphthyl group Chemical group 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 230000001681 protective effect Effects 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 244000045561 useful plants Species 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/10—Spiro-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
- C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
- C07D309/16—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D309/28—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D335/00—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
- C07D335/02—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/10—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Pyrane Compounds (AREA)
Claims (23)
1. Spoj sa formulom I
[image]
pri čemu
R1 je halogen, C1-C4alkil, C1-C4haloalkil, C3-C6cikloalkil, C2-C4alkenil, C2-C4haloalkenil, C2-C4alkinil, C1-C4alkoksi, C1-C4haloalkoksi, C1-C4alkiltio, C1-C4alkilsulfinil, C1-C4alkilsulfonil, nitro ili cijano;
R2 je aril ili heteroaril; ili aril ili heteroaril koji su oba supstituirani sa halogenom, C1-C4alkilom, C1-C4haloalkilom, fenoksi, C2-C4alkenilom, C2-C4haloalkenilom, C2-C4alkinilom, C1-C4alkoksi, C1-C4haloalkoksi, C1-C4alkiltio,C1-C4alkilsulfinilo, C1-C4alkilsulfonilom, C1-C4haloalkiltio,C1-C4haloalkilsulfinilom, C1-C4haloalkilsulfonilom, nitro ili cijano;
r je 0, 1, 2 ili 3;
R3, ako r je 1, je halogen, C1-C6alkil, C1-C6haloalkil, C1-C6alkoksi, C1-C6haloalkoksi, C2-C6alkenil, C2-C6alkinil, C1-C6alkiltio, C1-C6alkilsulfinil, C1-C6alkilsulfonil, cijano ili nitro; ili supstituenti R3, ako r je 2 ili 3, neovisno jedan od drugoga, su halogen, C1-C6alkil, C1-C6haloalkil, C1-C6alkoksi, C1-C6haloalkoksi, C2-C6alkenil, C2-C6alkinil, C1-C6alkiltio, C1-C6alkilsulfinil, C1-C6alkilsulfonil, cijano ili nitro;
R4, R5, R6 i R7, neovisno jedan od drugoga, su vodik, C1-C4alkil, C1-C4haloalkil, C1-C4alkoksiC1-C4alkil, C1-C4alkiltioC1-C4alkil, C1-C4alkilsulfinilC1-C4alkil, C1-C4alkilsulfonilC1-C4alkil, ciklopropil ili ciklopropil supstituiran sa C1- ili C2alkilom, C1- ili C2haloalkilom ili halogenom; ciklobutil ili ciklobutil supstituiran sa C1- ili C2alkilom; oksetanil ili oksetanil supstituiran sa C1- ili C2alkilom; C6-C7cikloalkil ili C5-C7cikloalkil supstituiran sa C1- ili C2alkilom ili C1- ili C2haloalkilom, gdje je metilen skupina cikloalkilne skupine proizvoljno zamijenjena sa atomom kisika ili sumpora ili sulfinil ili sulfonil skupinom; C4-C7cikloalkenil ili C4-C7cikloalkenil supstituiran sa C1- ili C2alkilom ili C1- ili C2haloalkilom, gdje je metilen skupina cikloalkenilne skupine proizvoljno zamijenjena sa atomom kisika ili sumpora ili sulfinil ili sulfonil skupinom; ciklopropilC1-C5alkil ili ciklopropilC1-C5alkil supstituiran sa C1- ili C2alkilom, C1- ili C2haloalkilom ili halogenom; ciklobutilC1-C5alkil ili ciklobutilC1-C5alkil supstituiran sa C1-C2alkilom; oksetanilC1-C5alkil ili oksetanilC1-C5alkil supstituiran sa C1- ili C2alkilom; C5-C7 cikloalkilC1-C5alkil ili C5-C7cikloalkilC1-C5alkil supstituiran sa C1-ili C2alkilom ili C1- ili C2haloalkilom, gdje je metilen skupina cikloalkilne skupine proizvoljno zamijenjena sa atomom kisika ili sumpora ili sulfinil ili sulfonil skupinom; C4-C7cikloalkenilC1-C5 alkil ili C4-C7cikloalkenilC1-C5alkil koji je supstituiran sa C1- ili C2alkilom ili C1- ili C2haloalkilom, gdje je metilen skupina cikloalkenilne skupine proizvoljno zamijenjena sa atomom kisika ili sumpora ili sulfinil ili sulfonil skupinom; fenil ili fenil supstituiran sa C1-C4alkilom, C1-C4alkoksi, C1-C4haloalkilom, halogenom, nitro, cijano, C1-C4alkiltio, C1-C4alkilsulfinilom, C1-C4alkilsulfonilom ili C1-C4alkilkarbonilom; benzil ili benzil supstituiran sa C1-C4alkilom, C1-C4alkoksi, C1-C4haloalkilom, halogenom, nitro, cijano, C1-C4alkiltio, C1-C4alkilsulfinilom, C1-C4alkilsulfonilom ili C1-C4alkilkarbonilom; heteroaril ili heteroaril supstituiran sa C1-C4alkilom, C1-C4alkoksi, C1-C4haloalkilom, halogenom, nitro, cijano, C1-C4alkiltio, C1-C4alkilsulfinilom, C1-C4alkilsulfonilom ili C1-C4alkilkarbonilom; ili
R4 i R5, ili R6 i R7, su spojeni da tvore 5-7 člani zasićeni ili nezasićeni prsten u kojem je metilen skupina proizvoljno zamijenjena sa atomom kisika ili sumpora, ili 5-7 člani zasićeni ili nezasićeni prsten supstituiran sa C1- ili C2alkilom, gdje je prsten metilen skupine proizvoljno zamijenjen sa atomom kisika ili sumpora; ili
R4 i R7 su spojeni da tvore 4-8 člani zasićeni ili nezasićeni prsten koji je nesupstituiran ili supstituiran sa C1-C2alkilom, C1-C2alkoksi, C1-C2alkoksiC1-C2alkilom, hidroksi, halogenom, fenilom ili fenilom supstituiranom sa C1-C4alkilom, C1-C4alkoksi, C1-C4haloalkilom, halogenom, nitro, cijano, C1-C4alkiltio, C1-C4alkilsulfinilom, C1-C4alkilsulfonilom ili C1-C4alkilkarbonilom; heteroaril ili heteroaril supstituiran sa C1-C4alkilom, C1-C4alkoksi, C1-C4haloalkilom, halogenom, nitro, cijano, C1-C4alkiltio, C1-C4alkilsulfinilom, C1-C4alkilsulfonilom ili C1-C4alkilkarbonilom;
Y je O, C=O, S(O)m ili S(O)nNR8; pod uvjetom da kada Y je C=O, R6 i R7 su različiti od vodika kada bilo koji R4 ili R5 je vodik, i R4 i R5 su različiti od vodika kada bilo koji R6 ili R7 je vodik;
m je 0 ili 1 ili 2 i n je 0 ili 1;
R8 je vodik, C1-C6alkil, C3-C6cikloalkil, C1-C6alkoksikarbonil, tri(C1-C6alkil)sililetiloksikarbonil, C1-C6haloalkoksikarbonil, cijano, C1-C6haloalkil, C1-C6hidroksialkil, C2-C6alkenil, C2-C6alkinil, C2-C6haloalkenil, C1-C6alkilkarbonil, C1-C6haloalkilkarbonil, C1-C6cikloalkilkarbonil, fenilkarbonil ili fenilkarbonil supstituiran sa R9; benzilkarbonil ili benzilkarbonil supstituiran sa R9; piridilkarbonil ili piridilkarbonil supstituiran sa R9; fenoksikarbonil ili fenoksikarbonil supstituiran sa R9; benziloksikarbonil ili benziloksikarbonil supstituiran sa R9;
R9 je C1-C6haloalkil, C1-C6alkoksikarbonil, nitro, cijano, formil, karboksil ili halogen; i
G je vodik, poljoprivredno prihvatljiv kation ili latencijska skupina;
pri čemu, u G, poljoprivredno prihvatljiva je odabrana iz skupina C1-C8alkil, C2-C8haloalkil, fenilC1-C8alkil (pri čemu fenil je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili sa nitro), heteroarilC1-C8alkil (pri čemu heteroaril je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili sa nitro), C3-C8 alkenil, C3-C8 haloalkenil, C3-C8 alkinil, C(Xa)-Ra, C(Xb)-Xc-Rb, C(Xd)-N(Rc)-Rd, -SO2-Re, -P(Xe)(Rf)-R9 i CH2-Xf-Rh;
pri čemu Xa, Xb, Xc, Xd, Xe i Xf su neovisno jedan od drugoga kisik ili sumpor;
i pri čemu Ra je H, C1-C16alkil, C2-C18alkenil, C2-C18alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, di(C2-C8alkil)aminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C6alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, di(C2-C8alkil)aminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C6alkilaminoC1-C5alkil, tri(C3-C6alkil)sililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), heteroarilC1-C5alkil (pri čemu heteroaril je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, ili heteroaril ili heteroaril supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro;
Rb je C1-C18alkil, C3-C18alkenil, C3-C18alkinil, C2-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C2-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, di(C2-C8alkil)aminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C6alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C6alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C6alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, di(C2-C5alkil)aminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C6alkilaminoC1-C5alkil, tri(C3-C6alkil)sililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), heteroarilC1-C5alkil (pri čemu heteroaril je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), C3-C6haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, ili heteroaril ili heteroaril supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro;
Rc i Rd su svaki neovisno jedan od drugoga vodik, C1-C10alkil, C3-C10alkenil, C3-C10alkinil, C2-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, di(C2-C8alkil)aminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, di(C2-C8alkil)aminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C2-C5alkilaminoalkil, C3-C6trialkilsililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), heteroarilC1-C5alkil (pri čemu heteroaril je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroarilom ili heteroarilom supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroarilamino ili heteroarilamino supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, diheteroarilamino ili diheteroarilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, fenilamino ili fenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, difenilamino ili difenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, amino, C1-C3alkilamino, di(C1-C3alkil)amino, C1-C3alkoksi ili C3-C7cikloalkilamino, di(C3-C7cikloalkil)amino ili C3-C7cikloalkoksi; ili Rc i Rd spojeni su zajedno da tvore 3-7 člani prsten, koji proizvoljno sadrži jedan heteroatom koji je odabran od O ili S i proizvoljno supstituiran sa 1 ili 2 C1-C3alkilne skupine;
Re je C1-C10alkil, C2-C10alkenil, C2-C10alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, di(C2-C8alkil)aminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, di(C2-C8alkil)aminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, tri(C3-C6alkil)sililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), heteroarilC1-C5alkil (pri čemu heteroaril je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), C2-C5haloalkenil, C3-C6cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano, amino ili sa nitro, heteroarilamino ili heteroarilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, diheteroarilamino ili diheteroarilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, fenilamino ili fenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, amino, difenilamino, ili difenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, ili C3-C7cikloalkilamino, di(C3-C7cikloalkil)amino ili C3-C7cikloalkoksi, C1-C10alkoksi, C1-C10haloalkoksi, C1-C5alkilamino ili di(C2-C8alkil)amino;
Rf i R9 su svaki neovisno jedan od drugoga C1-C10alkil, C2-C10alkenil, C2-C10alkinil, C1-C10alkoksi, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C1-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, di(C2-C8alkil)aminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C6alkoksiC1-C6alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, di(C2-C8alkil)aminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C2-C5alkilaminoalkil, tri(C3-C6alkil)sililC1-C5alkil, fenilC1-C5alkil (pri čemu fenil je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), heteroarilC1-C5alkil (pri čemu heteroaril je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3alkilsulfonilom, halogenom, cijano, ili sa nitro), C2-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, heteroaril ili heteroaril supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, heteroarilamino ili heteroarilamino supstituiran sa C1-C3 alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro, diheteroarilamino ili diheteroarilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, fenilamino ili fenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, amino, hidroksil, difenilamino, ili difenilamino supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro, ili C3-C7cikloalkilamino, di(C3-C7cikloalkil)amino ili C3-C7cikloalkoksi, C1-C10haloalkoksi, C1-C5alkilamino ili di(C2-C8alkil)amino, ili benziloksi ili fenoksi, pri čemu benzil i fenilna skupina mogu naizmjenično biti supstituirane sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili nitro; i
Rh je C1-C10alkil, C3-C10alkenil, C3-C10alkinil, C1-C10haloalkil, C1-C10cijanoalkil, C1-C10nitroalkil, C2-C10aminoalkil, C1-C5alkilaminoC1-C5alkil, di(C2-C8alkil)aminoC1-C5alkil, C3-C7cikloalkilC1-C5alkil, C1-C5alkoksiC1-C5alkil, C3-C5alkeniloksiC1-C5alkil, C3-C5alkiniloksiC1-C5alkil, C1-C5alkiltioC1-C5alkil, C1-C5alkilsulfinilC1-C5alkil, C1-C5alkilsulfonilC1-C5alkil, C2-C8alkilidenaminoksiC1-C5alkil, C1-C5alkilkarbonilC1-C5alkil, C1-C5alkoksikarbonilC1-C5alkil, aminokarbonilC1-C5alkil, C1-C5alkilaminokarbonilC1-C5alkil, di(C2-C8alkil)aminokarbonilC1-C5alkil, C1-C5alkilkarbonilaminoC1-C5alkil, N-C1-C5alkilkarbonil-N-C1-C5alkilaminoC1-C5alkil, tri(C3-C6alkil)sililC1-C6alkil, fenilC1-C5alkil (pri čemu fenil je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili sa nitro), heteroarilC1-C5alkil (pri čemu heteroaril je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili sa nitro), fenoksiC1-C5alkil (pri čemu fenil je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili sa nitro), heteroariloksiC1-C5alkil (pri čemu heteroaril je proizvoljno supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, C1-C3alkiltio, C1-C3alkilsulfinilom, C1-C3 alkilsulfonilom, halogenom, cijano ili sa nitro), C3-C5haloalkenil, C3-C8cikloalkil, fenil ili fenil supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom ili sa nitro, ili heteroaril, ili heteroaril supstituiran sa C1-C3alkilom, C1-C3haloalkilom, C1-C3alkoksi, C1-C3haloalkoksi, halogenom, cijano ili sa nitro;
i pri čemu, u spoju sa formulom I, "aril" znači fenil ili naftil;
i pri čemu, u spoju sa formulom I, "heteroaril" znači tienil, furil, pirolil, izoksazolil, oksazolil, izotiazolil, tiazolil, pirazolil, imidazolil, triazolil, tetrazolil, piridil, pirimidinil, pirazinil, triazinil, oksadiazolil, tiadiazolil ili piridazinil, ili, gdje je prikladno, N-oksid ili njegova sol.
2. Spoj prema zahtjevu 1, naznačen time da R1 je halogen, C1-C4alkil, C1-C4haloalkil, C2-C4alkenil ili C2-C4 alkinil.
3. Spoj prema zahtjevu 1 ili 2, naznačen time da R2 je fenil, tienil, furil, pirolil, izoksazolil, oksazolil, izotiazolil, tiazolil, pirazolil, imidazolil, triazolil, tetrazolil, piridil, pirimidinil, pirazinil, triazinil, piridazinil, oksadiazolil ili tiadiazolil, ili N-oksid ili njegova sol, gdje su navedeni prsteni nesupstituirani ili supstituirani sa halogenom, C1-C4alkilom, C1-C4haloalkilom, C2-C4alkenilom, C2-C4haloalkenilom, C2-C4alkinilom, C1-C4alkoksi, C1-C4haloalkoksi, C1-C4alkiltio, C1-C4alkilsulfinilom, C1-C4alkilsulfonilom, C1-C4haloalkiltio, C1-C4haloalkilsulfinilom, C1-C4haloalkilsulfonilom, nitro ili cijano.
4. Spoj prema zahtjevu 1 ili 2, naznačen time da R2 je fenil ili piridil; ili fenil ili piridil gdje su oba supstituirana sa halogenom, nitro, cijano, C1-C2alkilom, C1-C2haloalkilom, C1-C2alkoksi ili C1-C2haloalkoksi.
5. Spoj prema zahtjevu 1 ili 2, naznačen time da R2 je fenil supstituiran na para-položaju sa halogenom, te je proizvoljno dodatno supstituiran sa halogenom, nitro, C1-C2alkilom, C1-C2haloalkilom, C1-C2alkoksi ili C1-C2haloalkoksi.
6. Spoj prema bilo kojem od zahtjeva 1 do 5, naznačen time da R3 je vodik (tj. r je 0), ili R3 je halogen ili C1-C6alkil.
7. Spoj prema zahtjevu 6, naznačen time da R3 je vodik (r je 0).
8. Spoj prema zahtjevu 6, naznačen time da r je 1, i R3 je halogen ili C1-C3alkil.
9. Spoj prema bilo kojem od zahtjeva 1 do 8, naznačen time da:
R4, R5, R6 i R7, neovisno jedan od drugoga, su vodik, C1-C4alkil, C1-C4haloalkil, C1-C4alkoksiC1-C4 alkil, C1-C4alkiltioC1-C4alkil, C1-C4alkilsulfinilC1-C4alkil, C1-C4alkilsulfonilC1-C4alkil; C6-C7cikloalkil ili C5-C7cikloalkil supstituiran sa C1- ili C2alkilom ili C1- ili C2haloalkilom u kojem metilen skupina je proizvoljno zamijenjena sa atomom kisika ili sumpora ili sulfinil ili sulfonil skupinom; ili C5-C7cikloalkilC1-C5alkil ili C5-C7cikloalkilC1-C5alkil supstituiran sa C1-C2alkilom ili C1- ili C2haloalkilom i u kojem metilen skupina je proizvoljno zamijenjena sa atomom kisika ili sumpora ili sulfinil ili sulfonil skupinom; ili
R4 i R7 su spojeni da tvore 4-8 člani zasićeni ili nezasićeni prsten koji je nesupstituiran ili supstituiran sa C1-C2alkilom, C1-C2alkoksi ili C1-C2alkoksiC1-C2alkilom, dok R5 i R6 neovisno jedan od drugoga su vodik ili C1-C2alkil.
10. Spoj prema bilo kojem od zahtjeva 1 do 8, naznačen time da R4, R5, R6 i R7, neovisno jedan od drugoga, su vodik, C1-C2alkil, C1-C2haloalkil ili C1-C2alkoksi-C1-C2alkil.
11. Spoj prema bilo kojem od zahtjeva 1 do 10, naznačen time da Y je O, S ili C=O.
12. Spoj prema zahtjevu 11, naznačen time da Y je O.
13. Spoj prema bilo kojem od zahtjeva 1 do 12, naznačen time da G označava C(Xa)-Ra ili C(Xb)-Xc-Rb, a značenja za Xa, Ra, Xb, Xc i Rb su kako je definirano u zahtjevu 1.
14. Spoj prema bilo kojem od zahtjeva 1 do 12, naznačen time da, u G, latencijska skupina je odabrana iz skupina C(Xa)-Ra i C(Xb)-Xc-Rb, pri čemu Xa, Xb i Xc su kisik, Ra je C1-C6alkil, C2-C6alkenil, C2-C6alkinil, C3-C6cikloalkil ili C1-C4alkoksiC1-C4alkil, i Rb je C1-C6alkil, C3-C6alkenil, C3-C6alkinil, C3-C6cikloalkil ili C1-C4alkoksiC1-C4alkil.
15. Spoj prema bilo kojem od zahtjeva 1 do 12, naznačen time da G je vodik.
16. Spoj prema zahtjevu 1, naznačen time da:
R1 je C1-C4alkil, R2 je fenil ili fenil supstituiran sa halogenom ili C1-C2alkilom, R3 je vodik (tj. r je 0), R4, R5, R6 i R7, neovisno jedan od drugoga, su C1-C2alkil, Y je O i G je vodik; ili R1 je C1-C4alkil, R2 je fenil ili fenil supstituiran sa halogenom ili C1-C2alkilom, R3 je vodik (tj. r je 0), R5 i R6, neovisno jedan od drugoga, su vodik ili C1-C2alkil, R4 i R7 su vezani da tvore 4-8 člani zasićeni ili nezasićeni prsten koji je nesupstituiran ili supstituiran sa C1-C2alkilom, C1-C2alkoksi ili C1-C2alkoksiC1-C2alkilom, Y je O i G je vodik.
17. Postupak za dobivanje spoja sa formulom I prema zahtjevu 1, naznačen time da sadrži reakciju spoja sa formulom (H)
[image]
pri čemu R1, R3, R4, R5, R6, R7, Y i r imaju značenja dodijeljena u zahtjevu 1 i Hal je klor, brom, jod ili trifluorometansulfoniloksi, sa arilnom- ili heteroarilnom boronskom kiselinom sa formulom R2B(OH)2, pri čemu R2 ima značenje dodijeljeno u zahtjevu 1, ili sol ili njegov ester, u prisutnosti pogodnog paladijevog katalizatora, liganda i baze, te u pogodnom otapalu.
18. Postupak za dobivanje spoja sa formulom I prema zahtjevu 1, gdje je navedeni spoj sa formulom (A)
[image]
naznačen time da sadrži reakciju spoja sa formulom (AA)
[image]
sa Lewisovom ili Brönstedovom kiselinom, proizvoljno u prisutnosti otapala, gdje su supstituenti u spojevima sa formulama (A) i (AA) kako je definirano u zahtjevu 1, i pri čemu Y je O.
19. Spoj sa formulom (H)
[image]
naznačen time da R1, R4, R5, R6, R7 i Y imaju značenja dodijeljena u zahtjevu 1; Hal je klor, brom, jod ili trifluorometansulfoniloksi;
r je 0, 1, 2 ili 3;
R3 je vodik (tj. r je 0), ili R3 je halogen ili C1-C6alkil;
i pri čemu ako r je 1, R3 je halogen ili C1-C3alkil.
20. Spoj sa formulom (AA)
[image]
naznačen time da supstituenti su kako je definirano u zahtjevu 1.
21. Postupak za kontrolu trava i korova u usjevima korisnih biljaka, naznačen time da sadrži primjenu herbicidno učinkovite količine spoja sa formulom I kako je definirano u bilo kojem zahtjevu od 1 do 16, ili pripravka koji sadrži takav spoj, na biljke ili na njihov lokus.
22. Herbicidni pripravak, naznačen time da pored toga što sadrži formulacijske adjuvante, sadrži herbicidno učinkovitu količinu spoja sa formulom I kako je definirano u bilo kojem zahtjevu od 1 do 16.
23. Pripravak prema zahtjevu 22, naznačen time da pored toga što sadrži spoj sa formulom I, sadrži dodatni herbicid u kao partner za miješanje i proizvoljno zaštitnu tvar.
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AR081768A1 (es) | 2010-05-31 | 2012-10-17 | Syngenta Participations Ag | Composiciones pesticidas |
TW201208572A (en) | 2010-05-31 | 2012-03-01 | Syngenta Participations Ag | Pesticidal compositions |
CN103002741A (zh) | 2010-05-31 | 2013-03-27 | 先正达参股股份有限公司 | 作物增强的方法 |
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PL3222144T3 (pl) | 2012-01-17 | 2019-12-31 | Syngenta Participations Ag | Mieszaniny pestycydowe zawierające spiroheterocykliczne pirolidynodiony |
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GB201310047D0 (en) | 2013-06-05 | 2013-07-17 | Syngenta Ltd | Compounds |
JP6267795B2 (ja) | 2013-08-20 | 2018-01-24 | ボストン サイエンティフィック サイムド,インコーポレイテッドBoston Scientific Scimed,Inc. | 医療用挿入デバイス |
GB201507497D0 (en) * | 2015-04-30 | 2015-06-17 | Syngenta Participations Ag | Herbicidal compounds |
CN106106568A (zh) * | 2016-06-20 | 2016-11-16 | 河南中天恒信生物化学科技有限公司 | 一种微生物农药及其制备方法 |
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JP2011506369A (ja) | 2011-03-03 |
AU2008334887B2 (en) | 2014-02-06 |
MA31907B1 (fr) | 2010-12-01 |
AU2008334887A1 (en) | 2009-06-18 |
SV2010003593A (es) | 2011-03-23 |
ES2395595T3 (es) | 2013-02-13 |
TN2010000269A1 (en) | 2011-11-11 |
TW200942173A (en) | 2009-10-16 |
EA020918B1 (ru) | 2015-02-27 |
IL206162A0 (en) | 2010-12-30 |
AR069678A1 (es) | 2010-02-10 |
PL2222657T3 (pl) | 2013-03-29 |
AP2010005287A0 (en) | 2010-06-30 |
KR20100100965A (ko) | 2010-09-15 |
MX2010006279A (es) | 2010-06-23 |
CR11488A (es) | 2010-09-13 |
EP2222657A1 (en) | 2010-09-01 |
NI201000098A (es) | 2011-03-15 |
EA201000888A1 (ru) | 2010-12-30 |
UA101346C2 (ru) | 2013-03-25 |
EP2222657B1 (en) | 2012-09-12 |
WO2009074314A1 (en) | 2009-06-18 |
NZ585790A (en) | 2012-02-24 |
JP5607537B2 (ja) | 2014-10-15 |
CA2707598A1 (en) | 2009-06-18 |
CU20100122A7 (es) | 2011-10-14 |
US20100279872A1 (en) | 2010-11-04 |
CO6170061A1 (es) | 2010-06-18 |
CN101918386B (zh) | 2013-11-13 |
US8895761B2 (en) | 2014-11-25 |
CN101918386A (zh) | 2010-12-15 |
ECSP088961A (es) | 2009-07-31 |
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