GR20050100569A - Advanced catalysts for the large scale production of high purity carbon nanotubes with chemical vapor deposition - Google Patents
Advanced catalysts for the large scale production of high purity carbon nanotubes with chemical vapor depositionInfo
- Publication number
- GR20050100569A GR20050100569A GR20050100569A GR20050100569A GR20050100569A GR 20050100569 A GR20050100569 A GR 20050100569A GR 20050100569 A GR20050100569 A GR 20050100569A GR 20050100569 A GR20050100569 A GR 20050100569A GR 20050100569 A GR20050100569 A GR 20050100569A
- Authority
- GR
- Greece
- Prior art keywords
- production
- catalysts
- carbon nanotubes
- vapor deposition
- chemical vapor
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/881—Molybdenum and iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1271—Alkanes or cycloalkanes
- D01F9/1272—Methane
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
- D01F9/1273—Alkenes, alkynes
Abstract
In the present invention, advanced catalysts for the production of high purity and high quality carbon nanotubes with the technique of chemical vapor deposition are described. The catalyst or the catalytic substrate on which carbon is deposited and grows in the form of nanotubes consists of the carrier or the substrate, which is aluminum oxide (alumina, Al2O3) or anyone of the other metal oxides that are usually employed as catalytic media, the active phase which is iron oxide (preferably hematite (Fe2O3)) and a promoter, such as molybdenum oxide (MoO3). The ratio of these three components plays a very important role in the yield of the catalyst. The use of these catalysts allows the production of carbon nanotubes at high rates and with yields per mass unit of catalytic material, which are much higher than those achieved with other methods of carbon nanotube production and other catalysts. The high yields, the high production rates and the very low cost of the catalysts that are employed in the developed method lead to the production of materials that cost much less than commercially available materials of similar or lower quality.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GR20050100569A GR1005879B (en) | 2005-11-16 | 2005-11-16 | Advanced catalysts for the large scale production of high purity carbon nanotubes with chemical vapor deposition. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GR20050100569A GR1005879B (en) | 2005-11-16 | 2005-11-16 | Advanced catalysts for the large scale production of high purity carbon nanotubes with chemical vapor deposition. |
Publications (2)
Publication Number | Publication Date |
---|---|
GR20050100569A true GR20050100569A (en) | 2007-06-21 |
GR1005879B GR1005879B (en) | 2008-04-18 |
Family
ID=38440080
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GR20050100569A GR1005879B (en) | 2005-11-16 | 2005-11-16 | Advanced catalysts for the large scale production of high purity carbon nanotubes with chemical vapor deposition. |
Country Status (1)
Country | Link |
---|---|
GR (1) | GR1005879B (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993024687A1 (en) * | 1992-05-22 | 1993-12-09 | Hyperion Catalysis International, Inc. | Improved methods and catalysts for the manufacture of carbon fibrils |
US5707916A (en) * | 1984-12-06 | 1998-01-13 | Hyperion Catalysis International, Inc. | Carbon fibrils |
WO2002081371A2 (en) * | 2001-04-05 | 2002-10-17 | Honda Giken Kogyo Kabushiki Kaisha | Chemical vapor deposition growth of single-wall carbon nanotubes |
-
2005
- 2005-11-16 GR GR20050100569A patent/GR1005879B/en not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5707916A (en) * | 1984-12-06 | 1998-01-13 | Hyperion Catalysis International, Inc. | Carbon fibrils |
WO1993024687A1 (en) * | 1992-05-22 | 1993-12-09 | Hyperion Catalysis International, Inc. | Improved methods and catalysts for the manufacture of carbon fibrils |
WO2002081371A2 (en) * | 2001-04-05 | 2002-10-17 | Honda Giken Kogyo Kabushiki Kaisha | Chemical vapor deposition growth of single-wall carbon nanotubes |
Also Published As
Publication number | Publication date |
---|---|
GR1005879B (en) | 2008-04-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PG | Patent granted | ||
ML | Lapse due to non-payment of fees |
Effective date: 20130604 |