GB649445A - Manufacture of hydrazine derivatives and triazole derivatives - Google Patents

Manufacture of hydrazine derivatives and triazole derivatives

Info

Publication number
GB649445A
GB649445A GB472148A GB472148A GB649445A GB 649445 A GB649445 A GB 649445A GB 472148 A GB472148 A GB 472148A GB 472148 A GB472148 A GB 472148A GB 649445 A GB649445 A GB 649445A
Authority
GB
United Kingdom
Prior art keywords
hydrazine
derivatives
amino
triazole
semicarbazide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB472148A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB472148A priority Critical patent/GB649445A/en
Publication of GB649445A publication Critical patent/GB649445A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D249/00Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/081,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C07D249/101,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D249/14Nitrogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for the manufacture of hydrazine derivatives and triazole derivatives comprises reacting hydrazine or its derivatives having the -NH.NH- structure with carbon monoxide at a pressure above 100 atmospheres and a temperature above 30 DEG C. Semicarbazide and cyclic compounds such as 4 - amino - 1,2,4-triazol-3-one and 4-aminotriazole may be produced. Derivatives of hydrazine may be used as starting materials including hydrazine hydrate semicarbazide, carbohydrazide and hydrazine dicarbonamide. The reaction may be carried out under anhydrous conditions or with water or other liquid media present. The process may be operated continuously. In examples by heating under pressure with carbon monoxide (1) 4-amino-1,2,4-triazol-3-one and (2) 4-amino-1,2,4-triazole are prepared from aqueous hydrazine hydrate; 4-amino-1,2,4-triazol-3-one is prepared from an aqueous solution containing semicarbazide and hydrazine hydrate; (4) semicarbazide from hydrazine hydrate and (5) 4-amino-1,2,4-triazole from aqueous hydrazine hydrate and hydrazine dicarbonamide. Specification 583,172, [Group III], is referred to.
GB472148A 1948-02-18 1948-02-18 Manufacture of hydrazine derivatives and triazole derivatives Expired GB649445A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB472148A GB649445A (en) 1948-02-18 1948-02-18 Manufacture of hydrazine derivatives and triazole derivatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB472148A GB649445A (en) 1948-02-18 1948-02-18 Manufacture of hydrazine derivatives and triazole derivatives

Publications (1)

Publication Number Publication Date
GB649445A true GB649445A (en) 1951-01-24

Family

ID=9782536

Family Applications (1)

Application Number Title Priority Date Filing Date
GB472148A Expired GB649445A (en) 1948-02-18 1948-02-18 Manufacture of hydrazine derivatives and triazole derivatives

Country Status (1)

Country Link
GB (1) GB649445A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113480486A (en) * 2021-07-30 2021-10-08 赣南师范大学 3-amido-1, 2,4-triazole derivative and preparation method and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113480486A (en) * 2021-07-30 2021-10-08 赣南师范大学 3-amido-1, 2,4-triazole derivative and preparation method and application thereof
CN113480486B (en) * 2021-07-30 2022-05-24 赣南师范大学 3-amido-1, 2,4-triazole derivative and preparation method and application thereof

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