GB2154476A - Process for production of steel bar or steel wire having an improved spheroidal cementite structure - Google Patents
Process for production of steel bar or steel wire having an improved spheroidal cementite structure Download PDFInfo
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- GB2154476A GB2154476A GB08418577A GB8418577A GB2154476A GB 2154476 A GB2154476 A GB 2154476A GB 08418577 A GB08418577 A GB 08418577A GB 8418577 A GB8418577 A GB 8418577A GB 2154476 A GB2154476 A GB 2154476A
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
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Description
2 GB 2 154 476 A 2 According to the present invention, the rough-rolled
steel is cooled before the finish-rolling. The cooling rate of this cooling should be chosen according to the hardenability of the steel in the following manner:
When the steel is a plain carbon steel containing not higher than 0.15% of C or a low alloy steel having a hardenability not higher than that of 0.15% C plain carbon steel, it is preferable to cool the rough-worked 5 steel at a cooling rate higher than 250'Clsec. to a temperature between Ar, and Ar, When the steel is a plain carbon steel containing 0.15 to 0.4% of C or a low alloy steel having a hardenability between those of 0.15% to 0.4% C plain carbon steel, it is preferable to cool the rough-worked steel at a cooling rate higherthan 10'C/sec. to a temperature between Ar, and Ar3.
When the steel is a plain carbon steel containing not lower than 0.4% of C or a low alloy steel having a 10 hardenability not lower than that of 0.4% C plain carbon steel, it is preferable to cool the rough-worked steel at a cooling rate higher than 2'Clsec. to a temperature between Ar, and Ar3 or Arcm.
According to a preferred embodiment of the invention, the annealing treatment is conducted on the same line as that of the hot working of the steel or on the secondary working line of the steel product.
According to a preferred embodiment of the invention, said annealing treatment comprises the step of:15 immediately after the finish-working, isothermally maintaining the finish- worked steel at a temperature between (Ael minus 1 00'C) and Ael point of at least 10 minutes.
According to another embodiment of the invention, the annealing treatment comprises the step of:
slowly cooling the finish-worked steel to 5000C at a cooling rate lower than 1 00'C, preferably lower than 60'C per minute.
According to a further embodiment of the invention, the annealing treatment includes the steps of:
cooling the finish-worked steel to a temperature between Ael and Arl; working the cooled steel with a reduction of at least 15%, thereby to induce the pearlitic or bainitic transformation of the steel and simultaneously to raise the temperature of the steel by the heat of mechanical deformation to a temperature between Ac, and AC3 orAccm; and, repeating said cooling and working steps.
The finish-worked steel may be cooled down to room temperature and the annealing treatment may be conducted by the usual method of spheroidization.
According to the present invention, the steel may be pretreated, before the finish-working, by working the steel with a reduction ratio of at least ten in a temperature range between Ar3 or Arcm and (Ar3 PIUS 30 100OC) or (Arem plus 100'C) thereby to make the austenitic grain smaller than 25 lim.
The present invention will be described, by way of example, with reference to the accompanying drawings, wherein; Fig. 1 is a graph representing the effect of the pre-treatment according to an embodiment of the present invention, Fig. 2 is a diagrammatic elevation of a hot rolling line for steel wire which is preferably employed in conducting the process according to the present invention, Fig. 3 is a diagrammatic elevation of a secondary working line for steel wire which is preferably employed for conducting the process according to the prsent invention, Fig. 4 is a diagrammatic elevation of a hot-rolling line for steel wire which is preferably employed for 40 conducting a preferred embodiment of the present invention, Fig. 5 is a diagrammatic elevation of a secondary working line for steel wire which is preferably employed for conducting a preferred embodiment of the present invention, Figs. 6 to 10 are graphs which show respectively the results of Examples of a Group 11.
Fig. 11 is a diagram showing a heat pattern of the spheroidizing treatment conducted in an example of 45 the present invention, Figs. 12 to 15 are graphs showing respectively the results of Examples of a Group Ill, and Fig. 16 is a graph showing the spheroidizing ratio of Examples of a Group IV.
Each step of the process according to the present invention will be explained in detail in the following:
(1) Reason for the Restriction of the Carbon Content.
In the case of a steel containing more than 2% of c, the austenite range in the transformation chart of the steel is very narrow, and then the amount of the pre-eutectoid cementite or free cementite precipitated in the crystalline boundaries in the course of the hot-working is increased, thus causing cracking of the hot-worked product.
The steel to which the process of the present invention is applied may contain Si, Mn, Cr, Mo, etc. as alloying element to provide a desired strength and ductility. The steel may further contain deoxidizing elements, such as Sol.Al and impurities, such as P and S, in a restricted amount depending upon the desired mechanical properties and the employed melting method.
As a steel to which the process of the present invention is preferably applied, there are steels S1 2C, S20C, S45C, Scr435, SCM435, SUJ2 of the JIS. However, the chemical composition of the steel is not an 60 essential part of the present invention, and an explanation thereof will not be given.
(2) The Reason for Heating the Steel Above the Ac, Point.
The heating temperature is chosen to be higher than Ac, point following the restriction of the 3 GB 2 154 476 A 3 temperature range of the finish-working which will be explained hereinafter. Further, with heating of the steel below the Ac, point, efficient hot-working cannot be attained because of the high resistance to deformation of the steel.
(3) The Restriction of the Temperature Range of the Finish-working.
In the temperature range of the finish-rolling, according to the invention, that is, the temperature range 5 between Ar, and Ar3 or Arcm point, the metallurgical structure of the steel consists of dual phases of metastable austenite and ferrite (pro-eutectoid cementite in the case of a hyper-eutectoid steel). When this metallurgical structure is subjected to a hot-working in that temperature range, much of fine ferrite (pro-eutectoid cementite in the case of hyper-eutectoid steel) may be generated in the crystalline boundaries or in the grains of the metastable austenite due to the mechanically induced transformation of 10 the austenite. Thus, the austenitic grains are separated from one another by the ferrites which have been precipited by the mechanical ly-induced transformation and the grain size thereof becomes finer.
After experiment it has been found that the cementite precipitated from the fine austenitic grain is easier to spheroidize than the cementite precipitated from the gross austenitic grain. From this technical viewpoint, the finish-working of the steel in the temperature range described above, is very effective for the 15 spheroidization of cementite.
If the steel is cooled to a temperature lowerthan the Ar, point, a lamellar cementite is precipitated in the metastable austenite before the finish-working. Therefore, with a finish-working at temperatures lower than Arl, the annealed steel exhibits a high tensile strength and a uniform metallurical structure cannot be obtained. Further, the deformed structure remains in the annealed steel and it increases the tensile strength 20 of the steel. Accordingly the finish-working should be conducted at temperatures higher than the Ar, point.
On the other hand, if the finish-working is conducted at temperatures higher than Ar3 or Arcm, the mechanically-induced transformation to ferrite or pro-eutectoid cementite would not sufficiently occur and the austenitic grain does not become so fine that the subsequent annealing treatment would not be so effective for the spheroidization of cementite.
In the case of the eutectoid steel, a pro-eutectoid cementite, which has been precipitated before the finish working, is mechanically deformed and fragmented in the course of the finish-working and the dispersed cementite grains would separately agglomerate with each other in the subsequent spheroidizing treatment to become spheroidal cementite. Dislocations introduced in the crystalline boundaries of meta-stable austenitic structure become the nuclei for generating the spheroidal cementite. 30 That is, finish-working at temperatures lower than the Ar, point is ineffective due to the precipitated lamellar cementite, and on the other hand, with a finish working attemperatures higherthan Ar3 or Arcm point, the recovery of the mechanically-worked metastable austenitic structure immediately occurs and the dislocations introduced by the hot-working disappear.
For the two reasons explained above, the finish-working would be conducted in the temperature range 35 between Ar, and Ar3 or Arcm.
Further, even if the finish-rolling is conducted within the above temperature range, it is found that the mechanical properties of the resulting steel product vary depending upon the cooling rate of the rough-rolled steel, that is, the cooling rate of the steel just before the finish-rolling. If the cooling rate is lower than a certain value, the deformability of the resulting steel is lowered acutely. This critical cooling 40 rate varies depending upon the kind of steel. The higher is the hardenability of the steel, the lower is the critical cooling rate.
Accordingly, the hardenability of the steel should be considered to decide the cooling rate of the steel before the finish-rolling as described in the above. The metallurgical reason for this restriction of the cooling rate is as follows:
As explained above, the finish-rolling within the temperature between Ar, and Ar3 or Arcm is generally effective for the spheroidization of cementite. However, even within that temperature range, the higher is the finish-rolling temperature, the less is the precipitation amount of the ferrite due to the mechanically induced transformation and the easier becomes the recovery of the dislocations which otherwise would be nuclei for the spheroidal cementite. The amount of the mechanically- induced ferrite and the recovery of the 50 dislocations depend upon.the hardenability of the steel. The lower is the hardenability of the steel, the higher is the cooling rate which should be used.
Accordingly, in order to obtain a uniform dispersion of cementite and then to improve the deformability of the resulting steel product, the cooling rate should be chosen in conformity with the hardenability of the steel.
Further, it should be noted that, in the present invention, the temperature range is defined in terms of the transformation temperatures under the cooling condition. To the contrary, in the prior art disclosed in
Japanese patent laid-open No. 27926/1983, it is defined in the terms of the temperatures in the equilibrium condition, which makes the process impractical or very difficult to conduct precisely.
In the process disclosed in Japanese patent laid-open No. 27926/1984r the working is conducted in a 60 temperature range between (Ae3 minus 20oQ and (Ael minus 30'C). For the steels preferably applicable to the present invention such as S1 2C, S20C, S45C, SCr435, SCM435 and SUJ2 of the JIS, this temperature range is situated above the Ar3 point of the steel. Therefore, according to the process disclosed in this Japanese patent laid-open, one cannot obtain a steel having a good spheroidal structure of cementite.
4 GB 2 154 476 A 4 (4) Reason for Restriction of the Reduction Ratio in the Finish-working.
According to the present invention, the hot-working of at least 20% should be made in the above-mentioned temperature range.
The higher is the reduction ratio in the finish-rolling within that temperature range, the more effective is the spheroidization of cementite in the subsequent annealing treatment. That is, with a hot-working of the steel in thattemperature range, the refinement of the metastable austenite and the introduction of dislocations are promoted, which renders the spheroidizing treatment easier and more effective. To the contrary, with a reduction of less than 20%, the above effect cannot be attained sufficiently and the lamellar cementite tends to precipitate readily.
Meanwhile, the temperature of the steel product is raised due to the heat of mechanical deformation. 10 Butthe temperature of the steel should be preferably maintained lower than the AC3 point also during the finish-rolling.
The term "reduction ratio" used herein means the ratio of reduction in cross-sectional area. In the case of multi path rolling, the reduction means the total reduction ratio of all the paths. The cooling of the rough-rol led steel to the starting temperature of the finish-rol ling maybe conducted by water cooling, mist 15 cooling, air cooling (i.e. forced air cooling), natural air cooling (i.e. by leaving the steel to cool down by the natural air) and by laying the steel on the laying zone to cool down naturally.
(5) The Pretreatment.
According to an embodiment of the present invention, the steel to be finish-worked is subjected to a pre-treatment, which comprises; working the steel with a reduction of at least 10% within a temperature range between Ar3 or Arcm and (Ar3 plus 1 00'Q or (Arcm plus 1 00'Q, thereby making the grain size lower than 25 pm, in which ferrite or pro- eutectoid cementite will be precipitated in the course of the subsequent finish-working of the steel.
This pre-treatment has the following two technical effects:
The first effect is that, as shown in Fig. 1, the CCT curve of the steel is shifted to the side in which the 25 transformation will occur for a shorter time, that is, to the left side in Fig. 1. This shift of the CCT curve is due to a mechanical ly-induced transformation of A3 or Acm (of austenite to ferrite or cementite), and it is effective for promoting the A, transformation, that is, for the precipitation of spheroidal cementite in the course of the subsequent annealing treatment such as isothermal treatment, slow-cooling treatment, etc. In Fig. 1, the solid line indicates the CCT curve in the case wherein the pre-treatment is not conducted and the 30 broken line indicates the shifted curve owing to the pre-treatment of the present invention.
The second effect is that the pre-treatment induces the recrystallization of austenite which is effective also for the improvement of the spheroidization in the subsequent annealing step.
If the pre-treatment is conducted with a reduction of less than 10%, the grain size of the austenitic structure will not become lower than 25 lim, and then the desired improvement in spheroidization in the 35 subsequent annealing treatment is not attained.
If the pre-treatment is conducted at temperatures below Ar3 or Arcm, the metallurgical structure of the steel is not maintained at a single phase of austenite. On the other hand, if the pre-treatment is conducted at temperatures higher than (Ar3 plus 1OWC) or (Arcm plus 1OWC), the grain size of the austenite of the steel does not become lower than 25 lim.
(6) The Annealing Treatment.
Subsequent to the finish-working of the steel described above, the steel is annealed by any one of the following treatments:
(a) The Isothermal Treatment.
The finish-worked steel may be annealed by isothermally maintaining the same within a temperature 45 range between (Ael minus 1OWC) and Ael for at least 10 minutes.
If the isothermal treatment is conducted at temperatures above the Ael point, the transformation A,, that is, the transformation of austenite to cementite does not occur. Thus, the treatment should be conducted below Ael point. However, the lower is the temperature at which the isothermal treatment is conducted, the more difficult does the spheroidization of cementite become. Particularly, if the treatment is 50 conducted at a temperature below (AE, minus 1OWC), cementite would be precipitated in a lamellar form. Accordingly, the isothermal treatment should be conducted within a temperature range between (Ael minus 1 OWC) and Ael. If the time duration of the isothermal treatment is shorter than 10 minutes, the spheroidization of the cementite is not completed. Thus, it is carried out for at least 10 minutes.
(b) The Slow-cooling Treatment. 55 The finish-worked steel may be annealed by slowly cooling the steel to 50WC at a cooling rate lower than 1OWC per minute, preferably lower than WC per minute.
If the slow-cooling is conducted at a cooling rate higherthan 1OWC per minute, lamellar cementite tends to precipitate. A cooling rate lower than WC per minute is preferable for obtaining an elevated spheroidization ratio of cementite.
GB 2 154 476 A 5 The slow cooling of the steel should beconductedto lower than 500'C at which precipitation ofthe spheroidal cementite is completed. When it is desired to shorten the time duration of the slow-cooling treatment, the slow cooling of the steel may be stopped at 600'C at which most of the precipitation of cementite is finished.
(c) The Repeating Treatment.
The finish-rolled steel may be annealed by the repeating treatment as mentioned above.
This treatment utilizes the heat of mechanical deformation for raising the temperature of the steel. In this treatment, an elevated spheroidizing ratio of cementite is obtained by the effect of the repetition of the cooling and heating of the steel and by the effect of mechanical deformation of the carbides.
The repeating treatment of the present invention is different from the prior art disclosed in the 10
Japanese patent iaid-open No. 858611983 in that the cooling is conducted to a temperature between Ar, and Ael. In the repeating treatment of the present invention, the cooling temperature is relatively high, and therefore the steel presents a metallurgical structure of a single phase of austenite or mixed phase of austenite and ferrite or cementite when the hot working is started. The resistance to deformation of the steel in such metallurgical structure is relatively low, and the working of the steel can be conducted smoothly. 15 In this embodiment of the invention the conditions of the repeating treatment are settled by the following reasons:
(1) The Cooling Temperature of the Steel.
As described above, it is well known that the mechanical deformation of the carbides is very effective for performing the spheroidization of cementite. The repeating treatment of the present invention utilizes 20 also the effect of the mechanical deformation of the carbides.
That is, while the mechanical deformation was conducted in the cold condition in the prior art, in the repeating treatment of the present invention, it is conducted by the hot working at that temperature range.
In order to attain the effect of the mechanical deformation, the carbides should be precipitated already when the pre-treatment is started. On the other hand, if the bainite transformation or pearlite transformation is completed at the time of hot working, the resistance to deformation of the steel is so high that the load applied to the working machine, such as rolling mill, becomes too high. Accordingly, the temperature range of the cooling step of the repeating treatment of the present invention is chosen so that the steel presents a metallurgical structure of the single phase of austenite or of the mixed phase of austenite and ferrite or cementite at the start of the hot working of the pre-treatment. In this case, the 30 austenite is a super-cooled austenite in which carbides would be precipitated by the mechanical ly-induced transformation in the course of the hot working. Therefore, in the pre- treatment of the invention, the hot working is conducted with the carbides being precipitated, thereby attaining sufficiently the mechanical deformation of the carbides.
Accordingly, the temperature of the cooling is chosen to be between Ael and Ar, which corresponds to 35 the super-cooled austenite range.
(2) Reduction Ratio in Section in the Hot Working. The hot working should be conducted with a reduction ratio of 15% for the following reasons: Firstly it is necessary to raise the temperature of the steel to higher than the Ac, point by the heat of mechanical deformation.
Secondly, it is necessary to perform a sufficient mechanical deformation of the carbides.
In this hot working also, the working may be conducted by only one path through the working machine or multiple paths therethrough.
(3) Reason for the Repetition of the Cooling and the Hot Working.
As described above, a repetitious treatment for the spheroidization of cementite is well known. The 45 principle of this method is that the steel is cooled down to lower than A, point to precipitate the carbides, and then the steel is heated to higher than A, point to dissolve a portion of the carbides, thus dividing the carbides. The repetition of such cooling and heating results in a complete spheroidal cementite.
If the temperature of the steel is raised to higherthan AC3 orAccm, the carbides tend to dissolve completely. Accordingly, the hot working of the steel should be controlled so that the temperature of the 50 steel is raised to between Ac, and AC3 or Accm.
This cooling-and heating must be repeated at least twice for substantially attaining the effect thereof.
(d) The Usual Annealing Treatment in Another Process Line.
When the finish-worked steel is left to cool down naturally to room temperature, the cementite is partially spheroidized. Such cooled steel maybe treated by the usual annealing method on a separate line. 55 In this case, the necessary time for annealing treatment is shorter than that in the prior art.
An apparatus employed for conducting the process of the invention will now be described with reference to the accompanying drawings.
Referring to Fig. 2, a rough rolling mill 2 is connected to a heating furnace 1. The production line further comprises a water-, mist- or air-cooling means 3 and a laying zone 4 downstream of the rough-rolling mill 2. 60 6 GB 2 154 476 A 6 As shown in Fig. 2, the cooling means 3 and the laying zone 4 are arranged parallel to each other.
The production line further comprises a finish-rolling mill 5, downstream of which cooling means 61 and 62 are disposed parallel to each other. The coiling means 61 supplies steel wire in the form of a coil to a continuous furnace 7, in which the coil of the steel wire is transferred by means of a conveyor 8. The 5 continuous furnace maybe an isothermal- heating furnace of a slow-cooling furnace.
In the case wherein the annealing treatment is conducted on a separate line, the steel wire is coiled by the coiler 62 and transferred to the other line.
Fig. 3 shows a secondary working line on which the process of the present invention is conducted.
The secondary working line comprises a pay-off reel 9 for uncoiling a steel wire, a high-frequency heating means 10 for heating the wire to a desired temperature and a die 11 through which the wire is drawn by a pinch-roller 12. The production line further comprises coilers 131 and 132 which are arranged parallel to each other.
The coiler 131 is disposed in a furnace 14 which may be an isothermal furnace or a slow-cooling furnace. In the case wherein the isothermal treatment or slow cooling treatment is conducted on the secondary production line, the coiler 131 is employed.
In the case wherein the annealing treatment is conducted on a separate line by a usual spheroidizing annealing treatment, the wire is coiled by the coiler 132 and then transferred to the other line.
Figs. 4 and 5 show respectively a production line for steel bar and a secondary production line for steel wire which are preferably employed for conducting a preferred embodiment of the present invention.
In Figs. 4 and 5, the means corresponding to those shown in Figs. 2 and 3 are indicated by the same 20 reference numerals, and only the portions which are different from those shown in Figs. 2 and 3 will be explained in the following.
The production line shown in Fig. 4further comprises an intermediate rolling mill 2' downstream of the cooling means 3 and the laying zone 4, and a second group of water-, mist- or air-cooling means 3'and the laying zone 4'which are arranged parallel to each other.
In this production line, the steel heated bythe furnace 1 is rough rolled by the rough-rolling mill 2, and then air-, mist- orwater-cooled by the means 3 to a temperature range between Ar3 orArcm and (Ar3 plus 100'C) or (Arcm plus 100'C). The rough-rolled steel may be laid on the laying zone 4to cool down naturally to said temperature range. Within this temperature range, the rough-rolled steel is rolled with a reduction of at least 10% by means of the intermediate rolling mill 2' thereby to make the grain size of austenite to smaller than 25 pm before the precipitation of cementite to pre-eutectoid ferrite. Subsequently, the steel is air-, mistor water-cooled by cooling means 3'or left to be laid in the laying zone 4'to cool down naturally to a temperature range between Ar, and Ar3 (Arcm). The cooled steel is then finish rolled by the finish-rolling mill 5 with a reduction of at least 20%. The finish-rolled steel is subjected to an annealing treatment as already explained above with reference to Fig. 2.
In the secondary working line shown in Fig. 5, there is disposed a water-, mist- or air-cooling means 15 downstream of the die 11 and further a drawing die 11' upstream of the pinch-roller 12. In this working line, the steel heated by the heating means 10 is drawn through the die 11 within a temperature range between Ar3 or Arcm and (Ar3 plus 100'C) or (Arcm plus 100'C) thereby to make the grain size of the austenite smaller than 25 pim. The steel is then water-, mist- or air-cooled by the cooling means 15 to a temperature range 40 between Ar, and Ar, (Arcm) and drawn through the die 1 Vwithin this temperature range.
The present invention will be explained with reference to the Examples, which are simple illustrations of the invention but do not restrict the scope of the invention.
Group I of Examples EXAMPLE 1
Steel bars of 60 mm diameter, each having a chemical composition shown in Table 1 were rolled to a diameter of 35 q) mm and then cooled respectively at a cooling rate shown in Table 2 to a temperature between 660 and 670'C. Subsequently, the steel bars were finish rolled to a diameter of 20 q) mm (with a reduction ratio of 67%) and immediately coiled in a continuous furnace. In the furnace, the coils of the rolled steel bars were isothermally maintained at 700'C for 30 minutes.
The mechanical and metallurgical properties, such as the tensile strength, reduction of area, threshold limit compressibility and spheroidizing ratio of the resulting steel are shown in Table 2. Particularly, the spheroidizing ratio was measured by counting the numbers of the cementites which have a ratio of larger diameter to smaller diameter higher than 3.0 and calculating its percentage to the cementites observed in the microscopic structure of a specimen.
The transformation temperatures Ael, Ae, or Aecm were measured by means of a Formaster test machine for thermal expansion. The transformation temperatures Arl, Ar3 or Arcm were measured by heating a steel bar of 35 (P mm diameter of 900'C. and cooling them at various cooling rates. That is, the steels of S1 2C and S20C were respectively water-cooled and forcibly air-cooled, and the other steels were left to cool down naturally. These transformation temperatures are indicated also in Table 1.
From the results shown in Table 2, it is understood that a cooling rate higher than 250'C/sec (water cooling) for the steel S1 2C, a cooling rate higher than 15'C/sec (forcible air cooling) for the steel S20C and a cooling rate higher than 3'C/sec (natural cooling) for the steel S45C are effective for improving the spheroidizing property and the deformability of the resulting steels.
TABLE 1
Steel Indication Chemical composition M3 or Ar3 or No. of JIS c si Mn p SCr mo Sol. AI Ael Aecm Ar, Arcm (OC) (OC) (OC) CC) A S20C 0.21 0.25 0.70 0.018 0.012 - - 0.028 731 815 645 701 B S45C 0.44 0.23 0.65 0.013 0.011 - 0.033 727 776 639 696 c SCr435 0.35 0.30 0.72 0.015 0.012 1.02 - 0.025 740 793 610 685 D SCM435 0.36 0.28 0.75 0.010 0.011 0.99 0.18 0.037 742 790 603 675 E SUJ2 1.00 0.27 0.36 0.013 0.008 1.34 - 0.035 745 814 610 681 F S12C 0.12 0.22 0.59 0.012 0.008 - - 0.020 732 880 620 684 c) CD N) 00 TABLE 2
Starting temperature Properties of finish Specimen Indication Cooling rate working T.S. R.A. L.C. S.R.
No. of JIS CC/Sec) (OC) kgflmm' (%) (%) (%) Note 1 3 660 45 70 76 82 2 15 660 44 75 72 84 S12C 3 40 660 42 76 75 86 4 250 660 42 82 84 93 Invention 3 670 49 72 70 76 6 15 670 45 78 84 92 Invention S20C 7 40 670 44 79 85 90 Invention 8 250 670 44 78 85 90 Invention 9 3 670 53 65 70 94 Invention 15 670 53 65 69 95 Invention S45C 11 40 670 53 64 69 94 Invention 12 250 670 54 66 70 94 Invention T.S.: Tensile Strength R.A.: Reduction of Area L.C.: Threshold Limit Compressibility S.R.: Spheroidizing Ratio a) cj CO 9 GB 2 154 476 A 9 Group 11 of Examples In this group of examples, steel specimens each having a chemical composition shown in Table 1 and a diameter 60 q) mm were processed on a production line as shown in Fig. 2. That is, the steel specimens were heated to 900'C and then rough rolled and cooled to a predetermined temperature. More specifically, the specimens of S12C and S20C were cooled respectively by water cooling and forceable air cooling and 5 the other specimens were left to cool down naturally to the respective starting temperature of the finish rolling.
The cooled steels were then finish rolled within a predetermined temperature range. The finish-rolled steels were subjected to the various annealing treatments.
The mechanical properties and metallurgical properties, such as the tensile strength, reduction of area, 10 threshold limit compressibility and the spheroiclizing ratio of cementite were measured.
EXAMPLE 2
The steels shown in Table 1 were rough rolled to 35 (p mm and cooled respectively to the starting temperature of the finish rolling indicated in Table 3. The cooled steels were then finish rolled to a diameter of 20 1) mm (with a reduction ratio of 67%) and immediately coiled in a furnace maintained at 70WC and 15 isothermally maintained for 30 minutes. The properties of the resulting steels are indicated in Table 3. Further, an experiment was conducted with steel S45C by varying the starting temperature of the finish rolling. The results are shown in Fig. 6. 20 It is to be understood from the results shown in Table 3 and Fig. 6 that the steels finish-rolled within the 20 temperature range of the present invention exhibit improved mechanical and metallurgical properties.
TABLE 30)
1 Tensile Test A Starting temperature Specimen indication of finish T.S. R.A. L.C. S.R.
No. of JIS working CC) kgflmm' (%) (%) (%) Note 13 720 50 65 62 54 14 690 48 78 78 89 Invention S20C 670 45 78 84 92 Invention 16 650 46 77 80 85 Invention 17 620 58 60 53 71 18 720 58 53 57 49 19 690 53 62 69 90 Invention S45C 670 53 65 70 94 Invention 21 650 55 64 70 92 Invention 22 620 67 49 50 84 23 700 58 50 60 63 24 670 55 68 68 88 Invention SCr435 650 52 70 72 98 Invention 26 620 56 68 70 94 Invention 27 590 70 47 48 78 28 700 62 59 49 70 29 670 54 72 65 91 Invention GB 2 154 476 A 10 TABLE 3(2)
Starting Tensile test temperature Specimen Indication of finish T.S. R.A. L.C. S.R.
No. of JIS working CC) kgUmM2 (%) (%) (%) Note SCM435 650 54 75 70 97 1 Invention 31 620 55 74 68 94 Invention 32 590 73 54 45 79 33 700 70 51 50 72 34 670 64 62 59 97 Invention SUJ 2 650 63 65 60 99 Invention 36 620 66 62 58 98 Invention 37 590 83 39 37 90 38 710 47 72 69 47 39 680 43 78 80 85 Invention S12C 660 42 82 84 93 Invention 41 630 43 80 83 89 Invention 42 610 49 70 62 78 EXAMPLE 3
The steel specimen S45C was rough rolled to 35 q) mm and naturally cooled to the starting temperature 5 indicated in Table 3. The finish rolling was conducted by varying the reduction ratio, that is, with 11 %(to 33 (p mm), with 27% (30 (p mm), with 49% (to 25 (p mm), with 67% (20 (P mm) and with 82% (15 (p mm). These finish-rolled steels and the steel as rough- rolled (without finish rolling) were coiled in the furnace and isothermally maintainted at 70WC. for 30 minutes.
The mechanical and metallurgical properties of the resulting steel are shown in Fig. 7. It is to be understood from Fig. 7 that the annealed steel which have been finished rolled according to the present 10 invention exhibits a lower tensile strength and improved reduction of area, threshold limit compressibility and spheroidizing ratio. It should be noted that the threshold limit compressibility and the spheroidizing ratio were acutely degraded when the finish rolling was conducted outside the scope of the present invention.
EXAMPLE4
The steels S45C and SCM435 were rolled respectively under the same condition as specimen No. 20 (the starting temperature of the finish rolling being 67WC) and specimen No. 30 (the starting temperature of the finish rolling being (650'C) to a diameter 20 (p mm, and then isothermally maintained by varying the time duration of the isothermal treatment from 0 to 40 minutes. The tensile strength and the spheroidizing ratio of the resulting steels are shown in Fig. 8.
Furtherthe finish-roiled steel of the specimen S45C was isothermally treated for 30 minutes by varying the isothermal temperature from 550'Cto 750'C. The tensile strength and the spheroidizing ratio of the resulting steels are shown in Fig. 9.
It is to be understood from Figs. 8 and 9 thatthe steels isothermally treated within the temperature range and for the time duration according to the present invention exhibit a lower tensile strength and an 25 elevated spheroidizing ratio of cementite.
EXAMPLE 5
The steels S45C and SCM435 were rolled respectively underthe same condition as specimen No. 20 (the starting temperature of the finish rolling being 67WC) and specimen No. 30 (the starting temperature of 11 G B 2 154 476 A 11 the finish rolling being 65WC) to a diameter of 20 (p mm, and then subjected to the slow cooling treatment by slowly cooling the same to 5000C. at various cooling rates from 150C/min. to 100'Clmin., while transferring or transporting the same in the continuous furnace. The tensile strength and the spheroidizing ratio of the resulting specimens are shown in Fig. 10.
It is to be understood from Fig. 10 that, if the finish-rolled steels were cooled at a cooling rate lower than 5 60'Clmin., steels having a lower tensile strength and an improved spheroidizing ratio of cementite are obtained.
EXAMPLE 6
The steels S45C and SCM435 were rolled respectively under the same conditions as specimen No. 20 (the starting temperature of the finish rolling being 67WC) and specimen No. 30 (the starting temperature 10 being 65WC) to a diameter of 20 mm, and then coiled and left to cool down to room temperature. At the same time, steels of S45C and SCM435 were hot worked according to the prior art process and left to cool down naturally to room temperature for comparison.
These specimens were subjected to a spheroidizing annealing treatment whose heat pattern is shown in Fig. 11. That is, the spheroidizing annealing treatment was conducted by heating the steels to 7WC. and 15 maintaining the same at 75WC for 1 hour, and then slowly cooling them up to 60WC by varying the cooling rate R from 0.5 to 20C/min.
The mechanical and metallurgical properties of the resulting steels are shown in Table 4. It is to be understood from Table 4 that the specimens hot worked according to the present invention exhibit an 20. improved spheroidizing property even by the usual spheroidizing annealing treatment.
TABLE 4
Cooling Tensile test rate in annealing Indication treatment T.S. R.A. L.C. S.R.
of JIS CC/min.) kgflmm' (%) (%) (%) Note 0.5 51 64 75 90 Invention 1.0 53 65 75 93 Invention 1.5 55 62 71 89 Invention 2.0 56 60 69 84 Invention S45C 0.5 58 54 58 65 Comparison 1.0 62 52 55 60 Comparison 1.5 64 52 55 60 Comparison 2,0 64 50 53 53 Comparison 0.5 55 74 73 98 Invention 1.0 55 72 70 96 Invention 1.5 57 69 71 92 Invention 2.0 58 70 66 88 Invention SCM435 0.5 62 68 55 85 Comparison 1.0 65 65 51 84 Comparison 1.5 65 64 50 80 Comparison 2.0 67 59 50 75 Comparison 12 GB 2 154 476 A 12 Group III of Examples In this group of examples, the effect of the pretreatment of the invention is examined.
In each example of this group, steel specimens shown in Table 1 were processed on the production line shown in Fig. 4. That is, each specimen was heated to 900'C and rough rolled by rough-rolling mill 2 from 60 q) mm to 35 (p mm. The roug h-rol led steels were left to cool down to a predetermined temperature and rolled by the intermediate mill 2'to 30 (p mm. The steels were then water cooled, to a predetermined temperature and finish rolled. The finish-rolled steel was subjected to any one of the annealing treatments according to the embodiment of the present invention.
The tensile strength, reduction of area, threshold limit compressibility and spheroidizing ratio of the 10 resulting steels were measured in the same manner as that of the Examples of Group 1.
EXAMPLE 7
With respect to the steels of S45C and SCM435 shown in Table 1, the intermediate rolling was conducted from 35 q) mm to 30 (p mm (the reduction ratio being 27%), and the water cooling was conducted up to 6700C for the steel of S45C and up to 650'C for the steel SCM435. Then, the finish rolling was 16 conducted up to a diameter of 20 q) mm. The finish-rolled steels were coiled in a furnace in which the steels 15 were maintained for 20 minutes at 700'C. As shown in Table 5, the starting temperature of the intermediate rolling was varied between 850'C and 71 OOC for the steel of S45C and between 850'C and 690'C for the steel of SCM435 in order to examine the effect of the temperature range of the intermediate rolling.
The mechanical and metallurgical properties, such as the tensile strength, reduction of area, threshold limit compressibility and the spheroidizing ratio of cementite were measured.
The intermediate rolling was conducted under the same conditions as the above and then the steel specimens were water quenched to measure the austenitic grain size at the time of completion of the intermediate rolling.
The determined values of the above measurements are shown in Table 5.
It is to be understood that, with an intermediate rolling at temperatures outside the range of the 25 invention, the grain size of the austenite would be largerthan 25 lim and that the mechanical and metallurgical properties would be degraded.
TABLE 5
Starting Tensile test temperature Specimen of intermediate T.S. R.A. L.C. S.R.
No. rolling CC) 1 kgflm M2 (%) (%) (%) Note 850 40 56 55 65 82 810 33 55 59 66 85 S45C 770 23 52 68 74 97 Invention 740 20 50 69 74 98 Invention 710 18 50 69 73 98 Invention 850 43 57 67 59 85 810 35 55 69 63 90 SCM435 770 25 52 75 73 98 Invention 730 20 51 79 75 99 Invention 690 20 50 78 75 100 Invention 1: Grain size of austenite after Intermediate rolling EXAMPLE 8
With respeetto the steel shown in Table 1, the intermediate rolling was conducted at 7000C from 35 ( mm to 30 (p mm. The rolled steels were water cooled to the starting temperature of the finish rolling shown in Table 6 and the finish rolling was conducted up to a diameter 20 0 mm. The finishrolled steels 35 were coiled and isothermally maintained for 20 minutes in a continuous furnace.
The tensile strength, reduction of area, threshold limit compressibility and the spheroidizing ratio of 13 GB 2 154 476 A 13 cementite were measured and are shown in Table 6. It is to be understood from the results shown in Table 6 that steel wires which have been pre- treated and finish rolled within the temperature range between Arl and Ar3 or between Arl and Arcm exhibit a lower tensile strength and elevated reduction of area, threshold limit compressibility and spheroidizing ratio.
TABLE 60) 5
Starting Tensile test temperature Specimen Indication of finish T.S. R.A. L.C. S.R.
No. of JIS working CC) kgflmm' (%) (%) (%) Note 43 720 53 63 61 50 44 690 46 79 80 92 Invention S20C 670 46 83 81 95 Invention 46 650 45 80 80 93 Invention 47 620 56 64 55 70 48 720 57 53 58 50 49 690 52 63 70 95 Invention S45C 670 52 68 74 97 Invention 51 650 51 65 73 97 Invention 52 620 68 52 53 85 53 700 58 50 61 63 54 670 53 72 70 93 Invention SCr435 650 51 75 75 100 Invention 56 620 52 73 72 98 Invention 57 590 71 51 52 80 58 700 60 64 54 78 59 670 52 76 68 90 Invention SCM435 650 52 75 73 98 Invention 61 620 53 73 69 97 Invention 62 590 70 55 45 83 63 700 69 54 55 80 64 670 62 64 60 99 Invention SUJ2 650 60 68 62 100 Invention 66 620 62 64 60 100 Invention 67 590 83 40 41 93 14 GB 2 154 476 A 14 TABLE 6(2)
Starting Tensile test Specimen Indication temperature T.S. R.A. L.C. S.R.
of finish No. of JIS working ('C) kgflmm' (%) (%) (%) Note 68 710 46 73 72 46 69 680 42 80 83 89 Invention S12C 660 40 82 86 93 Invention 71 630 41 82 86 92 Invention 72 610 49 71 65 78 EXAMPLE 9
With respect to the steel S45C, the intermediate rolling was conducted under the same conditions as that of Example 8. Then, the steel was finish rolled at 670'C by varying the reduction ratio from 0% to 75%, 5 and immediately coiled and isothermally maintained at 700'C for 20 minutes. Here, reduction ratio of 0% means that the steel intermediately rolled was directly (without finish rolling) coiled in the isothermal furnace.
The tensile strength, reduction of area, threshold limit compressibility and the spheroiclizing ratio of cementite of the resulting steel are shown in Fig. 12. It is to be understood that the steels finish-rolled with a 10 reduction ratio of more than 20% have a lower tensile strength and improved reduction of area, threshold limit compressibility and spheroiclizing ratio of cementite. It should be noted that the threshold limit compressibility and the spheroidizing ratio were acutely degraded if the finish rolling was conducted outside the scope of the present invention.
EXAMPLE 10
With respectto the steels of S45C and SCM435, the rolling was conducted respectively under the same conditions as specimen No. 50 (the starting temperature of the finish rolling being 670'C and specimen No.
(the starting temperature of the finish rolling being 650'C) of Example 8. After the finish rolling, the steels were isothermally maintained for various time durations from 0 minute to 20 minutes. Further, the finish-rolled specimen of S45C was isothermally maintained for 20 minutes by varying the temperature 20 from 550'C to 750'C.
The tensile strength and the spheroiclizing ratio of these steels are shown in Figs. 13 and 14. It is to be understood f rorn these results that only the steels annealed within the scope of the present invention exhibit excellent properties.
EXAMPLE11
With respect to the steels S45C and SCM435, the rolling was conducted respectively under the same conditions as specimen No. 50 (the starting temperature of the finish rolling being 670'C) and specimen No. 60 (the starting temperature of the finish rolling being 650'C) of Example 8. After the finish rolling, the steels were immediately coiled in a continuous slow cooling furnace. While transferring them in the furnace, the steels were slowly cooled to 500'C by varying the cooling rate from 20'Clminute to 200'Clminute.
The tensile strength and the spheroidizing ratio of these steels are shown in Fig. 15. It is to be understood from these results that a lower tensile strength and an improved spheroidizing ratio of cementite are obtainable when the slow cooling is conducted at a cooling rate within the scope of the present invention.
EXAMPLE 12
With respectto steels S45C and SCM435, the rolling was conducted respectively underthe same conditions as specimen No. 50 (starting temperature of the finish rolling being 670'C) and specimen No. 60 (the starting temperature of the finish rolling being 650'C) of Example 8. Afterthe finish rolling, the steels were left to cool down naturally to room temperature. On the other hand, each steel specimen S45C and SCM435 was subjected to a usual hot working and left to cool down naturally to room temperature for comparison.
These steels of the invention and for comparison were subjected to a spheroidizing annealing treatment according to the heat pattern shown in Fig. 11, in which the slow cooling rate R was varied from 0.5 to 2'C[minute.
The tensile strength, reduction of area, threshold limit compressibility and spheroidizing ratio of 45 cementite of the resulting steel are shown in Table 7. It is to be understood from Table 7 that the steels GB 2 154 476 A 15 processed according to the present invention exhibit improved properties with regard to the spheroidizingannealed condition.
TABLE 7
Cooling rate in Tensile test annealing Indication treatment T.S. R.A. L.C. S.R.
of JIS CC/min.) kgUmmI Note 0.5 50 67 75 96 Invention 1.0 51 65 75 93 Invention 1.5 54 64 73 91 Invention 2.0 56 60 70 88 Invention S45C 0.5 58 54 58 65 Comparison 1.0 62 52 55 60 Comparison 1.5 64 52 55 60 Comparison 2.0 64 50 53 53 Comparison 0.5 52 74 74 98 Invention 1.0 54 72 72 96 Invention 1.5 56 70 71 90 Invention 2.0 57 69 67 87 Invention SCM435 0.5 62 68 55 85 Comparison 1.0 65 65 51 84 Comparison 1.5 65 64 50 80 Comparison 2.0 67 59 50 85 Comparison Group Wof Examples EXAMPLE 13 The steels having the chemical composition shown in Table 1 were prepared by a usual melting method and steel bars each having a diameter of from 15.4 to 164.0 (p mm were produced therefrom. These steel bars were heated for 4 hours and rolled to a bar of 11.0 (p mm by means of rolling stands Nos. 1 to 9.
The rolling by Nos. 1 to 3, by Nos. 4 to 6 and by Nos. 7 to 9 respectively was conducted continuously. The 10 controlled cooling was conducted by the forcible cooling between No. 3 and No. 4, and between No. 6 and No. 7. The heating temperature of each steel, the starting and final temperatures and the reduction ratio of each rolling, and the transformation temperatures in equilibrium conditions are indicated in Table 8.
On the other hand, identical rolling was conducted but the steels were water quenched immediately before and immediately after the mill stands No. 1, 4 and 7 to observe the metallurgical structure thereof. It15 was observed that, just before the rolling in stands Nos. 1, 4 and 7, the metallurgical structure of the steel consists of austenite, and just after the rolling in stands Nos. 1, 4 and 7, the bainite or pearlite was already formed.
From the above observation, it is to be understood that the rolling was conducted according to an embodiment of the present invention.
Next, after the above continuous rolling, the steels were left to cool down or slowly cooled at a cooling rate of 20'C/min. the spheroidizing ratios of the resulting steels are shown in Table 8.
C3) TABLE8
No. 1 to No. 3 rolling No. 4 to No. 6 rolling No. 7. to No. 9 rolling Spheroidizing ratio (%) Steel Ael 'C Ae3 'C Heating Starting Final Reduction Starting Final Reduction Starting Final Reduction 20TImin Natural No. temp. temp. 'C temp. ratio % temp. 'C temp. ratio % temp. 'C temp. ratio % cooling cooling PC C OC oc A 731 815 1050 690 730 75 690 750 50 705 740 25 88 72 800 670 710 75 695 790 75 695 780 75 99 87 B 727 776 900 690 720 25 710 745 20 710 740 15 80 70 750 670 710 60 695 755 60 695 760 60 94 81 C 740 793 950 670 700 25 700 755 30 710 790 70 85 72 750 650 710 70 700 790 70 695 790 70 98 85 D 742 790 1000 670 715 30 700 760 60 705 755 30 84 75 780 650 740 90 665 780 85 650 755 80 100 85 E 745 814 1100 670 700 20 690 775 40 715 780 60 89 77 780 650 735 70 680 775 70 715 805 70 95 83 F 732 880 1050 680 730 75 700 760 50 710 750 25 84 70 800 660 710 75 670 780 75 680 790 75 98 - 88 C) m a) 17 GB 2 154 476 A 17 When the steels shown in Table 1 were processed by a usual method, for example by heating at 10500C, and the rolling being conducted from 9500C to 11040'C. with a reduction 60% and by being left to cool down naturally, the carbides were precipitated in the lamellarform in the case of steel specimens A, B, E and F. (The steel specimens C and D present bainitic structure and thus the measurement of the spheroidizing ratio was not possible).
Contrary to this, the steels processed according to the present embodiment of this invention exhibit always a spheroidizing ratio of higher than 70%, and, if the slow cooling is conducted after rolling, they exhibit a spheroidizing ratio as high as 85% or more.
With respect to the specimens A (heated at 800'C), B (heated at 900OC), C (heated at 750OC) and D (heated at 1000OC), F (heated at800OC), the spheroidizing ratio of the steels which were naturally cooled after 10 rolling in stands Nos. 1 to 3, Nos. 1 to 6 and Nos. 1 to 9 and of the steel naturally cooled afterthe usual hot rolling, are shown in Fig. 16. In Fig. 16, hollow circles indicate the spheroidizing ratio of steel A, hollow triangles indicate that of Steel B, the solid circles do that of the steel C, the solid triangles do that of steel D, and hollow squares do that of steel F.
From the results shown in Fig. 16, it is to be understood that the steels cooled after rolling in stands Nos. 1 to 6 and after rolling in Nos. 1 to 9 exhibit a spheroidizing ratio of more than 60%. But the steel naturally cooled down only after rolling in Nos. 1 to 3 exhibit a spheroidizing ratio as low as 20%. These results mean that the cooling and the hot working must be repeated at least 2 times in order to exert the effect.
As explained in detail hereinbefore, the steel bar or steel wire produced according to the present 20 invention as an improved spheroidizing ratio of cementite and excellent mechanical properties.
Claims (10)
- CLAIMS 1. Process for producing a steel bar or steel wire, whichcomprises; heating a steel containing less than 2% of C at a temperature higher than Ac, point of the steel; 25 rough working the heated steel; finish working the rough-worked steel within a temperature range between Ar, and Ar3 orArcm with a reduction ratio of at least 20%; and subjecting the finish-worked steel to an annealing treatment; whereby to provide a steel bar or steel wire having an improved spheroidal structure of cementite.
- 2. Process as claimed in claim 1, wherein the steel is a plain carbon steel containing not higher than 30 0.15% of C or a low alloy steel having a hardenability not higher than that of 01.5% C plain carbon steel, and wherein the rough-worked steel is cooled at a cooling rate higherthan 2500C/sec. to a temperature between Ar, and Ar3.
- 3. Process as claimed in Claim 1, wherein the steel is a plain carbon steel containing 0.15to 0.4% of C or 35 a low alloy steel having a hardenability between those of 0.15% to 0.4% C plain carbon steel, and wherein the rough-worked steel is cooled at a cooling rate higher than 1 O'Clsec. to a temperature between Ar, and Ar
- 4. Process as claimed in claim 1, wherein the steel is a plain carbon steel containing not lower than 0.4% of C or a low alloy steel having a hardenability not lower than that of 0. 4% C plain carbon steel, and wherein 40 the rough-worked steel is cooled at a cooling rate higher than 2'Clsec. to a temperature between Ar, and Ar3 or Arcm.
- 5. Process as claimed in any of claims 1 to 4, wherein the annealing treatment includes, immediately after the finish working, isothermally maintaining the finish-worked steel for at least 10 minutes at a temperature between (Ael minus 100'C) and Ael.
- 6. Process as claimed in any of claims 1 to 4, wherein the annealing treatment includes, immediately after the finish working, cooling the finish-worked steel at a cooling rate of lower than 1 OOOC/minute, preferably lower than 60'Clminute, to a temperature lower than 500'C.
- 7. Process as claimed in any of claims 1 to 4, wherein the annealing treatment includes cooling the finish-worked steel to a temperature between Ael and Arl; working the cooled steel with a reduction of at least 15%, thereby to induce the pearlite or bainitic transformation of the steel and simultaneously to raise the temperature of the steel by the heat of mechanical deformation to a temperature between Ac, and AC3 or Accm; and, repeating said cooling and working steps.
- 8. Process as claimed in any of claims 1 to 4, wherein the annealing treatment includes cooling the finish-worked steel to room temperature, and, subjecting the cooled steel to a usual spheroidizing annealing treatment.
- 9. Process as claimed in any of claims 1 to 8, which further comprises, before the finish working, working the steel with a reduction of at least 10% within a temperature range 18 GB 2 154 476 A 18 of between Ar3 orArcm and (Ar3plus 1OWC) or(Arcm plus 10OT), thereby refining the austenitic grain size of the steel to lower than 25 pm.
- 10. Processes for producing steel bar or steel wire as claimed inclaim 1 and substantially as herein described.Printed for Her Majesty's Stationery Office by Courier Press, Leamington Spa. 911985. Demand No. 8817443. Published by the Patent Office, 25 Southampton Buildings, London, WC2A lAY, from which copies may be obtained.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP461584A JPS60149724A (en) | 1984-01-13 | 1984-01-13 | Manufacture of steel bar or wire rod having spheroidized structure |
JP461484A JPS60149723A (en) | 1984-01-13 | 1984-01-13 | Manufacture of steel bar or wire rod having spheroidized structure |
JP950084A JPS60155621A (en) | 1984-01-24 | 1984-01-24 | Production of steel bar and wire rod having spheroidized structure |
Publications (3)
Publication Number | Publication Date |
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GB8418577D0 GB8418577D0 (en) | 1984-08-22 |
GB2154476A true GB2154476A (en) | 1985-09-11 |
GB2154476B GB2154476B (en) | 1987-06-03 |
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GB08418577A Expired GB2154476B (en) | 1984-01-13 | 1984-07-20 | Process for production of steel bar or steel wire having an improved spheroidal cementite structure |
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Country | Link |
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US (1) | US4604145A (en) |
CA (1) | CA1222678A (en) |
ES (1) | ES8505413A1 (en) |
FR (1) | FR2558174B1 (en) |
GB (1) | GB2154476B (en) |
Cited By (1)
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DE10061461A1 (en) * | 2000-12-08 | 2002-06-20 | Heinz Oelpmann | Bit holder |
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CA1243200A (en) * | 1984-03-28 | 1988-10-18 | Susumu Kanbara | Process and apparatus for direct softening heat treatment of rolled wire rods |
JPH03240919A (en) * | 1990-02-15 | 1991-10-28 | Sumitomo Metal Ind Ltd | Production of steel wire for wiredrawing |
JP3215891B2 (en) * | 1991-06-14 | 2001-10-09 | 新日本製鐵株式会社 | Manufacturing method of steel rod for cold working |
JP4018905B2 (en) * | 2000-04-04 | 2007-12-05 | 新日本製鐵株式会社 | Hot rolled wire rod and bar for machine structure and manufacturing method thereof |
JP3737952B2 (en) * | 2001-02-16 | 2006-01-25 | 本田技研工業株式会社 | CVT belt push block and manufacturing method thereof |
EP1371737A1 (en) * | 2002-06-10 | 2003-12-17 | Von Moos Stahl AG | Process and device for manufacturing steel wire or rod |
KR100469671B1 (en) * | 2002-07-11 | 2005-02-02 | 삼화강봉주식회사 | Quenched and tempered steel wire with superior characteristics of cold forging |
JP2006193790A (en) * | 2005-01-14 | 2006-07-27 | Daido Steel Co Ltd | Cold working tool steel |
EP2089552B1 (en) * | 2006-11-17 | 2017-01-25 | Swiss Steel AG | Method for the continuous production of steel wire or bar |
TWI450975B (en) * | 2011-04-11 | 2014-09-01 | China Steel Corp | Process for making cementite grains in pearlite of steel cylindrical or spherical |
CN103555913B (en) * | 2013-11-07 | 2015-03-25 | 首钢总公司 | Control method for improving plasticity of bearing steel wire rod |
Family Cites Families (15)
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US3762964A (en) * | 1972-04-10 | 1973-10-02 | Bethlehem Steel Corp | Method for producing cold workable hypoeutectoid steel |
JPS5420931B2 (en) * | 1973-09-10 | 1979-07-26 | ||
IT1090143B (en) * | 1975-01-29 | 1985-06-18 | Centre Rech Metallurgique | PROCESS FOR MANUFACTURING LAMINATED STEEL PRODUCTS |
JPS5356121A (en) * | 1976-11-02 | 1978-05-22 | Nippon Steel Corp | Production of steel bar and wire rod for cold forging |
SU850698A1 (en) * | 1979-07-19 | 1981-07-30 | Днепропетровский Ордена Трудовогокрасного Знамени Металлургическийинститут | Method of spheroidizing treatment of steel |
FR2488278A1 (en) * | 1980-08-05 | 1982-02-12 | Siderurgie Fse Inst Rech | Spheroidisation annealing steel to improve cold formability - preceded by quenching from rolling temp. to reduce annealing time |
JPS5741322A (en) * | 1980-08-25 | 1982-03-08 | Sumitomo Metal Ind Ltd | Spheroidizing method for carbide in steel |
JPS5798631A (en) * | 1980-12-06 | 1982-06-18 | Nisshin Steel Co Ltd | Manufacture of steel belt containing spherical carbide |
JPS601930B2 (en) * | 1981-01-13 | 1985-01-18 | 株式会社神戸製鋼所 | Manufacturing method of high carbon alloy steel wire rod |
JPS58235A (en) * | 1981-06-25 | 1983-01-05 | Daido Steel Co Ltd | Granulating device for radioactive waste or the like |
JPS583919A (en) * | 1981-07-01 | 1983-01-10 | Daido Steel Co Ltd | Manufacture of steel wire rod |
JPS5827926A (en) * | 1981-08-12 | 1983-02-18 | Nippon Steel Corp | Manufacture of wire rod having spheroidal structure |
JPS58107416A (en) * | 1981-12-21 | 1983-06-27 | Kawasaki Steel Corp | Method of directly softening steel wire or rod steel useful for mechanical construction |
US4448613A (en) * | 1982-05-24 | 1984-05-15 | Board Of Trustees, Leland Stanford, Jr. University | Divorced eutectoid transformation process and product of ultrahigh carbon steels |
JPS58207325A (en) * | 1982-05-28 | 1983-12-02 | Sumitomo Metal Ind Ltd | Spheroidizing treatment of wire rod |
-
1984
- 1984-07-19 US US06/632,234 patent/US4604145A/en not_active Expired - Lifetime
- 1984-07-19 ES ES534456A patent/ES8505413A1/en not_active Expired
- 1984-07-20 CA CA000459371A patent/CA1222678A/en not_active Expired
- 1984-07-20 GB GB08418577A patent/GB2154476B/en not_active Expired
- 1984-07-20 FR FR848411634A patent/FR2558174B1/en not_active Expired - Lifetime
Cited By (1)
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DE10061461A1 (en) * | 2000-12-08 | 2002-06-20 | Heinz Oelpmann | Bit holder |
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GB8418577D0 (en) | 1984-08-22 |
ES534456A0 (en) | 1985-05-16 |
FR2558174A1 (en) | 1985-07-19 |
CA1222678A (en) | 1987-06-09 |
ES8505413A1 (en) | 1985-05-16 |
US4604145A (en) | 1986-08-05 |
GB2154476B (en) | 1987-06-03 |
FR2558174B1 (en) | 1992-02-14 |
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