GB1407610A - Hydrocarbon conversion process - Google Patents

Hydrocarbon conversion process

Info

Publication number
GB1407610A
GB1407610A GB4729972A GB4729972A GB1407610A GB 1407610 A GB1407610 A GB 1407610A GB 4729972 A GB4729972 A GB 4729972A GB 4729972 A GB4729972 A GB 4729972A GB 1407610 A GB1407610 A GB 1407610A
Authority
GB
United Kingdom
Prior art keywords
diameter
pore volume
pores
less
pore
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4729972A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB4729972A priority Critical patent/GB1407610A/en
Priority to CA177,438A priority patent/CA1012478A/en
Priority to BE1005388A priority patent/BE805370A/en
Priority to JP48113339A priority patent/JPS5947719B2/en
Priority to NL7313986A priority patent/NL7313986A/xx
Priority to ZA737909*A priority patent/ZA737909B/en
Priority to SE7313850A priority patent/SE400784B/en
Priority to DE2351136A priority patent/DE2351136C2/en
Priority to FI3145/73A priority patent/FI59118C/en
Priority to FR7336334A priority patent/FR2202931B1/fr
Priority to NO3944/73A priority patent/NO139002C/en
Priority to AU61292/73A priority patent/AU479237B2/en
Priority to IT30015/73A priority patent/IT995791B/en
Publication of GB1407610A publication Critical patent/GB1407610A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1407610 Hydrodesulphurizing residual oils SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 13 Oct 1972 47299/72 Heading C5E The catalytic hydrodesulphurization without catalyst replenishment of residual hydrocarbon oils having a total vanadium + nickel content above 120 p.p.m. wt. is carried out using a catalyst which is either (i) in the form of particles having a specific average pore diameter (p, in nm) and a specific average particle diameter (d, in mm) such that in which P H2 is the hydrogen partial pressure in bars, a pore volume above 0À45 ml./g., at least 0À4 ml./g. pore volume in pores with a diameter of at least 0À7 Î p and at most 1À7 Î p, and a pore diameter distribution such that (a) less than 20% of the pore volume is in pores of diameter smaller than 0À7 x p, (b) less than 20% of the pore volume is in pores of diameter larger than 1À7 x p and (c) less than 10% of the pore volume is in pores of diameter larger than 100 nm., or (ii) in the form of agglomerates formed from such particles and having more than 10% of their pore volume in pores with a diameter above 100 nm. The oil can be an atmospheric or vacuum residue which can be first subjected to a catalytic demetallization. The hydrodesulphurization can be carried out at 300-475‹ C. and a hydrogen partial pressure of 50-200 bar. The catalyst suitably comprises nickel and/or cobalt together with molybdenum and/or tungsten on an alumina carrier can can be in the metallic, oxidic or sulphided form.
GB4729972A 1972-10-13 1972-10-13 Hydrocarbon conversion process Expired GB1407610A (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
GB4729972A GB1407610A (en) 1972-10-13 1972-10-13 Hydrocarbon conversion process
CA177,438A CA1012478A (en) 1972-10-13 1973-07-26 Hydrocarbon conversion process
BE1005388A BE805370A (en) 1972-10-13 1973-09-27 PROCESS FOR CONVERSION OF HYDROCARBONS
JP48113339A JPS5947719B2 (en) 1972-10-13 1973-10-11 Hydrocarbon conversion method
NL7313986A NL7313986A (en) 1972-10-13 1973-10-11
ZA737909*A ZA737909B (en) 1972-10-13 1973-10-11 Hydrocarbon conversion process
SE7313850A SE400784B (en) 1972-10-13 1973-10-11 PROCEDURE FOR CATALYTIC HYDRO DEFULRATION WITHOUT CATALYST FILLING OF CARBOHYDRATE STARTERS WITH A TOTAL VANADIN AND NICKEL CONTENT OVER 120 PER WEIGHT
DE2351136A DE2351136C2 (en) 1972-10-13 1973-10-11 Process for the catalytic hydrogenating desulphurization of residual hydrocarbon oils
FI3145/73A FI59118C (en) 1972-10-13 1973-10-11 FOERFARANDE FOER KATALYTISK HYDROAVSVAVLING AV RESTKOLVAETEOLJOR
FR7336334A FR2202931B1 (en) 1972-10-13 1973-10-11
NO3944/73A NO139002C (en) 1972-10-13 1973-10-11 PROCEDURE FOR CATALYTIC HYDROGEN SULFURING OF HYDROCARBON RESIDUES
AU61292/73A AU479237B2 (en) 1972-10-13 1973-10-11 Hydrocarbon conversion process
IT30015/73A IT995791B (en) 1972-10-13 1973-10-11 PROCESS FOR THE CONVERSION OF HYDROCARBONS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4729972A GB1407610A (en) 1972-10-13 1972-10-13 Hydrocarbon conversion process

Publications (1)

Publication Number Publication Date
GB1407610A true GB1407610A (en) 1975-09-24

Family

ID=10444455

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4729972A Expired GB1407610A (en) 1972-10-13 1972-10-13 Hydrocarbon conversion process

Country Status (12)

Country Link
JP (1) JPS5947719B2 (en)
BE (1) BE805370A (en)
CA (1) CA1012478A (en)
DE (1) DE2351136C2 (en)
FI (1) FI59118C (en)
FR (1) FR2202931B1 (en)
GB (1) GB1407610A (en)
IT (1) IT995791B (en)
NL (1) NL7313986A (en)
NO (1) NO139002C (en)
SE (1) SE400784B (en)
ZA (1) ZA737909B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4677093A (en) * 1984-09-14 1987-06-30 Compagnie Francaise De Raffinage Catalyst for the hydrotreatment of hydrocarbon feedstocks

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7607551A (en) * 1976-07-08 1978-01-10 Shell Int Research METHOD FOR THE METALIZATION OF HYDROCARBON OILS.
JPH0519371Y2 (en) * 1986-03-31 1993-05-21
FR2598632B1 (en) * 1986-05-14 1988-11-10 Total France HYDROCARBON HYDROTREATMENT CATALYSTS AND APPLICATIONS THEREOF

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1408759A (en) * 1971-12-07 1975-10-01 Shell Int Research Catalytic hydrodesulphurisation process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4677093A (en) * 1984-09-14 1987-06-30 Compagnie Francaise De Raffinage Catalyst for the hydrotreatment of hydrocarbon feedstocks

Also Published As

Publication number Publication date
NO139002B (en) 1978-09-11
ZA737909B (en) 1974-08-28
FR2202931B1 (en) 1977-03-11
NL7313986A (en) 1974-04-16
IT995791B (en) 1975-11-20
FR2202931A1 (en) 1974-05-10
SE400784B (en) 1978-04-10
CA1012478A (en) 1977-06-21
AU6129273A (en) 1975-04-17
DE2351136A1 (en) 1974-04-25
JPS4974204A (en) 1974-07-17
BE805370A (en) 1974-03-27
JPS5947719B2 (en) 1984-11-21
FI59118B (en) 1981-02-27
DE2351136C2 (en) 1984-11-22
NO139002C (en) 1978-12-20
FI59118C (en) 1981-06-10

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee