GB1305568A - - Google Patents

Info

Publication number
GB1305568A
GB1305568A GB6255369A GB1305568DA GB1305568A GB 1305568 A GB1305568 A GB 1305568A GB 6255369 A GB6255369 A GB 6255369A GB 1305568D A GB1305568D A GB 1305568DA GB 1305568 A GB1305568 A GB 1305568A
Authority
GB
United Kingdom
Prior art keywords
steam
hydrocarbon feed
hexane
dec
zirconium oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6255369A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1305568A publication Critical patent/GB1305568A/en
Priority claimed from US00389646A external-priority patent/US3839485A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1305568 Steam cracking FLUOR CORP and H F A TOPSOE 16 Dec 1970 [23 Dec 1969] 62553/69 Heading C5E [Also in Division B1] Unsaturated hydrocarbons are produced by contacting a saturated hydrocarbon feed in the presence of steam with a catalyst comprising an alkali metal comound and zirconium oxide at least part of which is amorphous prepared from amorphous zirconium oxide or a precursor thereof (see Division B1). The process is carried out at a temperature below 1100‹ C. and a pressure of 0À1-50 atm. abs. A minor proportion of unsaturated hydrocarbons may be added to the saturated hydrocarbon feed. The steam/hydrocarbon feed ratio should be 0À1 : 1 to 10 : 1. In the examples the hydrocarbon feeds treated are (i) a light naphtha comprising 24À1% isopentane; 53À6% n-pentane, 13À5% iso-hexane, 5À6% n-hexane and 3À2% aromatics; and (ii) pure n-heptane. The products specified include C 2 H 4 , C 3 H 6 , C 4 H 8 , C 4 H 6 , CH 4 , C 2 H 6 , CO 2 , H 2 and C 4 + saturated hydrocarbons.
GB6255369A 1969-12-23 1969-12-23 Expired GB1305568A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB6255369 1969-12-23
US9923770A 1970-12-17 1970-12-17
US00389646A US3839485A (en) 1969-12-23 1973-08-21 Catalytic steam cracking of hydrocarbons and catalysts therefor

Publications (1)

Publication Number Publication Date
GB1305568A true GB1305568A (en) 1973-02-07

Family

ID=27260550

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6255369A Expired GB1305568A (en) 1969-12-23 1969-12-23

Country Status (5)

Country Link
CA (1) CA973151A (en)
DE (1) DE2063174A1 (en)
FR (1) FR2116331B1 (en)
GB (1) GB1305568A (en)
NL (1) NL7018389A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2738579C3 (en) * 1977-08-26 1981-07-30 Aron Lejbovič Leningrad Šapiro Process for the production of styrene, vinyl toluenes or vinyl xylenes
JP2853720B2 (en) * 1992-06-22 1999-02-03 三菱瓦斯化学株式会社 Method for producing monoalkenylbenzenes

Also Published As

Publication number Publication date
CA973151A (en) 1975-08-19
FR2116331B1 (en) 1975-01-10
NL7018389A (en) 1971-06-25
DE2063174A1 (en) 1971-07-01
FR2116331A1 (en) 1972-07-13

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee