GB1286970A - Low temperature methanol synthesis catalyst precursor - Google Patents
Low temperature methanol synthesis catalyst precursorInfo
- Publication number
- GB1286970A GB1286970A GB63063/69A GB6306369A GB1286970A GB 1286970 A GB1286970 A GB 1286970A GB 63063/69 A GB63063/69 A GB 63063/69A GB 6306369 A GB6306369 A GB 6306369A GB 1286970 A GB1286970 A GB 1286970A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alumina
- oxides
- copper
- zinc
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract 6
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 239000012018 catalyst precursor Substances 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 239000005751 Copper oxide Substances 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910000431 copper oxide Inorganic materials 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 239000011787 zinc oxide Substances 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1286970 Catalyst precursor composition CATALYSTS & CHEMICALS Inc 29 Dec 1969 [26 Dec 1968] 63063/69 Heading B1E [Also in Division C2] A precursor composition which on reduction is a catalyst for the synthesis of methanol from carbon monoxide, carbon dioxide and hydrogen comprises zinc oxide, copper oxide and alumina prepared from a homogeneous aqueous dispersion of the oxides by drying, wherein the zinc oxide to copper oxide weight ratio, based on the metals is from 0.5:1 to 3:1, wherein the quantity of alumina in the composition is 5 to 45 weight percent, wherein the zinc and copper oxides are derived from zinc and copper basis carbonates, and wherein the homogenous aqueous dispersion is formed by the subjection to a shearing force of an aqueous suspension containing not more than 20 weight percent of the oxides. Several suitable forms of alumina are specified, e.g. alpha, beta, gamma, delta, eta, theta, kappa, chi, rho or amorphous forms, hydrated aluminas being preferred to non-hydrated forms. Preferably the alumina is activated by calcining or by heating in steam to raise the surface area to above 59 m<SP>2</SP>/g. Small amounts of chromium may also be included in the composition.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78723468A | 1968-12-26 | 1968-12-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1286970A true GB1286970A (en) | 1972-08-31 |
Family
ID=25140825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB63063/69A Expired GB1286970A (en) | 1968-12-26 | 1969-12-29 | Low temperature methanol synthesis catalyst precursor |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS4823263B1 (en) |
| BE (1) | BE743652A (en) |
| DE (1) | DE1965007A1 (en) |
| FR (1) | FR2027162A1 (en) |
| GB (1) | GB1286970A (en) |
| NL (1) | NL6919506A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2469205A1 (en) * | 1979-11-12 | 1981-05-22 | Mitsubishi Gas Chemical Co | PROCESS FOR THE PREPARATION OF A CATALYTIC COMPOSITION BASED ON COPPER, ZINC AND ALUMINUM OXIDES, USE THEREOF FOR VARIOUS REACTIONS, AND PROCESS FOR THE SYNTHESIS OF METHANOL FROM CARBON OXIDES AND HYDROGEN WITH THIS COMPOSITION AS CATALYST |
| US4305842A (en) | 1979-02-10 | 1981-12-15 | Mitsubishi Gas Chemical Company, Inc. | Preparation of improved catalyst composition |
| US4529738A (en) * | 1980-11-25 | 1985-07-16 | Institut Francais Du Petrole | Process for operating highly exothermic reactions |
| US7754651B2 (en) | 2001-12-08 | 2010-07-13 | Süd -Chemie AG | Cu/Zn/Al catalyst for methanol synthesis |
| US7820128B2 (en) | 2005-05-03 | 2010-10-26 | Sud-Chemie Ag | Production of Cu/Zn/A1 catalysts via the formate route |
| CN113929560A (en) * | 2021-11-22 | 2022-01-14 | 中国华能集团清洁能源技术研究院有限公司 | Method for preparing methanol by carbon dioxide hydrogenation and application thereof |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS555888Y2 (en) * | 1973-05-26 | 1980-02-09 | ||
| JPS51156545U (en) * | 1975-06-06 | 1976-12-13 | ||
| JPS5241037U (en) * | 1975-09-17 | 1977-03-23 | ||
| JPS5729156Y2 (en) * | 1978-04-20 | 1982-06-25 | ||
| JPS6238122Y2 (en) * | 1979-10-02 | 1987-09-29 | ||
| CA1327812C (en) * | 1987-12-23 | 1994-03-15 | Thomas G. Attig | Vapor-phase hydrogenation of maleic anhydride to tetrahydrofuran and gamma-butyrolactone |
| BRPI0714401A2 (en) * | 2006-07-17 | 2013-02-26 | Basf Se | process for hydrogenating unsaturated hydrocarbons over catalysts containing copper and zinc |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1159035A (en) * | 1965-08-18 | 1969-07-23 | Ici Ltd | Methanol Synthesis. |
-
1969
- 1969-12-24 BE BE743652D patent/BE743652A/xx unknown
- 1969-12-26 JP JP44104752A patent/JPS4823263B1/ja active Pending
- 1969-12-26 FR FR6945146A patent/FR2027162A1/fr not_active Withdrawn
- 1969-12-27 DE DE19691965007 patent/DE1965007A1/en active Pending
- 1969-12-29 NL NL6919506A patent/NL6919506A/xx unknown
- 1969-12-29 GB GB63063/69A patent/GB1286970A/en not_active Expired
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4305842A (en) | 1979-02-10 | 1981-12-15 | Mitsubishi Gas Chemical Company, Inc. | Preparation of improved catalyst composition |
| FR2469205A1 (en) * | 1979-11-12 | 1981-05-22 | Mitsubishi Gas Chemical Co | PROCESS FOR THE PREPARATION OF A CATALYTIC COMPOSITION BASED ON COPPER, ZINC AND ALUMINUM OXIDES, USE THEREOF FOR VARIOUS REACTIONS, AND PROCESS FOR THE SYNTHESIS OF METHANOL FROM CARBON OXIDES AND HYDROGEN WITH THIS COMPOSITION AS CATALYST |
| US4386017A (en) | 1979-11-12 | 1983-05-31 | Mitsubishi Gas Chemical Company | Preparation of improved catalyst composition |
| US4529738A (en) * | 1980-11-25 | 1985-07-16 | Institut Francais Du Petrole | Process for operating highly exothermic reactions |
| US7754651B2 (en) | 2001-12-08 | 2010-07-13 | Süd -Chemie AG | Cu/Zn/Al catalyst for methanol synthesis |
| US7820128B2 (en) | 2005-05-03 | 2010-10-26 | Sud-Chemie Ag | Production of Cu/Zn/A1 catalysts via the formate route |
| CN113929560A (en) * | 2021-11-22 | 2022-01-14 | 中国华能集团清洁能源技术研究院有限公司 | Method for preparing methanol by carbon dioxide hydrogenation and application thereof |
| CN113929560B (en) * | 2021-11-22 | 2023-02-24 | 中国华能集团清洁能源技术研究院有限公司 | Method for preparing methanol by carbon dioxide hydrogenation and application thereof |
| WO2023087686A1 (en) * | 2021-11-22 | 2023-05-25 | 中国华能集团清洁能源技术研究院有限公司 | Method for preparing methanol by means of hydrogenation of carbon dioxide and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| BE743652A (en) | 1970-05-28 |
| NL6919506A (en) | 1970-06-30 |
| FR2027162A1 (en) | 1970-09-25 |
| DE1965007A1 (en) | 1970-10-15 |
| JPS4823263B1 (en) | 1973-07-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |