GB1131631A - Catalysts of high activity at low temperature - Google Patents

Catalysts of high activity at low temperature

Info

Publication number
GB1131631A
GB1131631A GB428/65A GB42865A GB1131631A GB 1131631 A GB1131631 A GB 1131631A GB 428/65 A GB428/65 A GB 428/65A GB 42865 A GB42865 A GB 42865A GB 1131631 A GB1131631 A GB 1131631A
Authority
GB
United Kingdom
Prior art keywords
catalyst
catalysts
manganese
zinc
copper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB428/65A
Inventor
Phineas Davies
Alan James Hall
Dennis Albert Dowden
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB428/65A priority Critical patent/GB1131631A/en
Priority to NO65160945A priority patent/NO122755B/no
Priority to DE1965J0029635 priority patent/DE1542222B2/en
Priority to NL656516883A priority patent/NL153099B/en
Priority to BE674365A priority patent/BE674365A/xx
Priority to SE54/66A priority patent/SE343042B/xx
Priority to ES0321501A priority patent/ES321501A1/en
Priority to AT10966A priority patent/AT285524B/en
Priority to FR44881A priority patent/FR1462839A/en
Publication of GB1131631A publication Critical patent/GB1131631A/en
Priority to MY1969211A priority patent/MY6900211A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

1,131,631. Shift reaction catalysts. IMPERIAL CHEMICAL INDUSTRIES Ltd. 3 Dec., 1965 [5 Jan., 1965; 25 Aug., 1965], Nos. 428/65 and 36478/65. Heading B1E. A catalyst composition comprises the products of reducing partly coprecipitated oxides of copper and zinc and at least one further metal selected from manganese and the metals of groups II to V whose oxides are differently reducible. The composition is partly reduced to produce a catalyst for use in the carbon monoxide steam reaction. The further metal may be aluminium or magnesium, also mentioned are titanium, zirconium, thiourea. Preferred atomic proportions are:- copper at least 10%, for example 10% to 70%; zinc at least 20% for example 20% to 800/0; manganese or other metal 4% to 20%. The catalyst may also contain catalyst support material for example alumina not introduced by coprecipitation.
GB428/65A 1965-01-05 1965-01-05 Catalysts of high activity at low temperature Expired GB1131631A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
GB428/65A GB1131631A (en) 1965-01-05 1965-01-05 Catalysts of high activity at low temperature
NO65160945A NO122755B (en) 1965-01-05 1965-12-16
DE1965J0029635 DE1542222B2 (en) 1965-01-05 1965-12-17 USE OF A CATALYST CONTAINING COPPER, ZINC AND ALUMINUM TO REACT CARBON OXYDE WITH STEAM
NL656516883A NL153099B (en) 1965-01-05 1965-12-24 PROCESS FOR CONVERTING CARBON MONOXIDE WITH STEAM AND FOR PREPARATION OF COPPER-ZINC CATALYSTS FOR USE IN THIS CONVERSION.
BE674365A BE674365A (en) 1965-01-05 1965-12-27
SE54/66A SE343042B (en) 1965-01-05 1966-01-03
ES0321501A ES321501A1 (en) 1965-01-05 1966-01-05 Catalytic procedure for the reaction of carbon monoxide and water vapor. (Machine-translation by Google Translate, not legally binding)
AT10966A AT285524B (en) 1965-01-05 1966-01-05 Catalyst composition for the conversion of carbon monoxide with steam in the gas phase
FR44881A FR1462839A (en) 1965-01-05 1966-01-05 Catalysts with high activity at low temperatures
MY1969211A MY6900211A (en) 1965-01-05 1969-12-31 Catalysis of high activity at low temperature

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB428/65A GB1131631A (en) 1965-01-05 1965-01-05 Catalysts of high activity at low temperature
GB3647865 1965-08-25

Publications (1)

Publication Number Publication Date
GB1131631A true GB1131631A (en) 1968-10-23

Family

ID=26235915

Family Applications (1)

Application Number Title Priority Date Filing Date
GB428/65A Expired GB1131631A (en) 1965-01-05 1965-01-05 Catalysts of high activity at low temperature

Country Status (9)

Country Link
AT (1) AT285524B (en)
BE (1) BE674365A (en)
DE (1) DE1542222B2 (en)
ES (1) ES321501A1 (en)
FR (1) FR1462839A (en)
GB (1) GB1131631A (en)
NL (1) NL153099B (en)
NO (1) NO122755B (en)
SE (1) SE343042B (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4199479A (en) 1978-02-24 1980-04-22 Chevron Research Company Hydrogenation catalyst
US4308176A (en) * 1980-03-28 1981-12-29 Norsk Hydro A.S. Catalyst and method for producing said catalyst
FR2560531A1 (en) * 1984-03-02 1985-09-06 Inst Francais Du Petrole METHOD FOR MANUFACTURING CATALYSTS CONTAINING COPPER, ZINC, ALUMINUM AND AT LEAST ONE RARE EARTH GROUP METAL AND ZIRCONIUM AND USE OF THE CATALYSTS OBTAINED FOR THE REACTIONS INVOLVING A SYNTHESIS GAS
US5128307A (en) * 1988-11-03 1992-07-07 Basf Aktiengesellschaft Copper-containing catalyst for low temperature shift conversion
EP0721799A1 (en) 1995-01-11 1996-07-17 United Catalysts, Inc. Promoted and stabilized copper oxide and zinc oxide catalyst and preparation method
US6693057B1 (en) 2002-03-22 2004-02-17 Sud-Chemie Inc. Water gas shift catalyst
US6903050B2 (en) 2002-10-28 2005-06-07 Engelhard Corporation Method of preparation of non-pyrophoric copper-alumina catalysts
EP1818095A3 (en) * 2006-02-10 2009-12-02 Samsung SDI Co., Ltd. Water gas shift catalyst and fuel cell system including the same
EP3007806B1 (en) 2013-06-13 2018-10-03 Clariant Corporation Method for reducing halide concentration in gas streams
US10494255B2 (en) 2015-10-29 2019-12-03 Johnson Matthey Public Limited Company Water gas shift process
US10807866B2 (en) 2015-10-29 2020-10-20 Johnson Matthey Public Limited Company Water-gas shift catalyst
US11014811B2 (en) 2015-10-29 2021-05-25 Johnson Matthey Public Limited Company Water gas shift process
US11045793B1 (en) * 2020-07-24 2021-06-29 Qatar University Controlled on-pot design of mixed copper/zinc oxides supported aluminum oxide as an efficient catalyst for conversion of syngas to heavy liquid hydrocarbons and alcohols under ambient conditions feasible for the Fischer-Tropsch synthesis
CN114669191A (en) * 2022-03-31 2022-06-28 中国科学院生态环境研究中心 Manganese copper ore material and application thereof in removing carbon monoxide at room temperature
RU2781406C1 (en) * 2021-10-29 2022-10-11 Федеральное государственное автономное образовательное учреждение высшего образования «Национальный исследовательский Томский государственный университет» Method for preparation of oxide catalysts

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4565803A (en) * 1983-12-16 1986-01-21 Shell Oil Company Methanol synthesis catalyst
FR2558738B1 (en) * 1984-01-27 1987-11-13 Inst Francais Du Petrole PROCESS FOR THE MANUFACTURE OF CATALYSTS CONTAINING COPPER, ZINC AND ALUMINUM FOR USE IN THE PRODUCTION OF METHANOL FROM SYNTHESIS GAS

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4199479A (en) 1978-02-24 1980-04-22 Chevron Research Company Hydrogenation catalyst
US4308176A (en) * 1980-03-28 1981-12-29 Norsk Hydro A.S. Catalyst and method for producing said catalyst
FR2560531A1 (en) * 1984-03-02 1985-09-06 Inst Francais Du Petrole METHOD FOR MANUFACTURING CATALYSTS CONTAINING COPPER, ZINC, ALUMINUM AND AT LEAST ONE RARE EARTH GROUP METAL AND ZIRCONIUM AND USE OF THE CATALYSTS OBTAINED FOR THE REACTIONS INVOLVING A SYNTHESIS GAS
EP0155868A1 (en) * 1984-03-02 1985-09-25 Institut Français du Pétrole Process for the preparation of catalysts comprising copper, zinc, aluminium and at least one other metal selected from the group formed by rare earth metals and zirconium, and use of such catalysts in reactions of a synthesis gas
US5128307A (en) * 1988-11-03 1992-07-07 Basf Aktiengesellschaft Copper-containing catalyst for low temperature shift conversion
EP0721799A1 (en) 1995-01-11 1996-07-17 United Catalysts, Inc. Promoted and stabilized copper oxide and zinc oxide catalyst and preparation method
US7064097B1 (en) 2002-03-22 2006-06-20 Sud-Chemie Inc. Process for production of a water gas shift catalyst
US6693057B1 (en) 2002-03-22 2004-02-17 Sud-Chemie Inc. Water gas shift catalyst
US6903050B2 (en) 2002-10-28 2005-06-07 Engelhard Corporation Method of preparation of non-pyrophoric copper-alumina catalysts
EP1818095A3 (en) * 2006-02-10 2009-12-02 Samsung SDI Co., Ltd. Water gas shift catalyst and fuel cell system including the same
EP3007806B1 (en) 2013-06-13 2018-10-03 Clariant Corporation Method for reducing halide concentration in gas streams
US10494255B2 (en) 2015-10-29 2019-12-03 Johnson Matthey Public Limited Company Water gas shift process
US10807866B2 (en) 2015-10-29 2020-10-20 Johnson Matthey Public Limited Company Water-gas shift catalyst
US11014811B2 (en) 2015-10-29 2021-05-25 Johnson Matthey Public Limited Company Water gas shift process
US11045793B1 (en) * 2020-07-24 2021-06-29 Qatar University Controlled on-pot design of mixed copper/zinc oxides supported aluminum oxide as an efficient catalyst for conversion of syngas to heavy liquid hydrocarbons and alcohols under ambient conditions feasible for the Fischer-Tropsch synthesis
RU2781406C1 (en) * 2021-10-29 2022-10-11 Федеральное государственное автономное образовательное учреждение высшего образования «Национальный исследовательский Томский государственный университет» Method for preparation of oxide catalysts
CN114669191A (en) * 2022-03-31 2022-06-28 中国科学院生态环境研究中心 Manganese copper ore material and application thereof in removing carbon monoxide at room temperature
CN114669191B (en) * 2022-03-31 2023-05-19 中国科学院生态环境研究中心 Manganese copper ore material and application thereof in room temperature carbon monoxide removal

Also Published As

Publication number Publication date
DE1542222A1 (en) 1969-12-18
NO122755B (en) 1971-08-09
SE343042B (en) 1972-02-28
NL153099B (en) 1977-05-16
DE1542222B2 (en) 1976-12-16
FR1462839A (en) 1966-12-16
NL6516883A (en) 1966-07-06
ES321501A1 (en) 1967-01-01
BE674365A (en) 1966-06-27
AT285524B (en) 1970-10-27

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