GB1085892A - Oxidation of organic compounds with gases containing molecular oxygen - Google Patents

Oxidation of organic compounds with gases containing molecular oxygen

Info

Publication number
GB1085892A
GB1085892A GB1519864A GB1519864A GB1085892A GB 1085892 A GB1085892 A GB 1085892A GB 1519864 A GB1519864 A GB 1519864A GB 1519864 A GB1519864 A GB 1519864A GB 1085892 A GB1085892 A GB 1085892A
Authority
GB
United Kingdom
Prior art keywords
oxidation
organic compounds
cyclohexane
molecular oxygen
gases containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1519864A
Inventor
Raymond Leslie Day
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB1519864A priority Critical patent/GB1085892A/en
Priority to NL6504478A priority patent/NL6504478A/xx
Priority to BE662611A priority patent/BE662461A/xx
Priority to FR13111A priority patent/FR1431459A/en
Publication of GB1085892A publication Critical patent/GB1085892A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/36—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in compounds containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Cyclohexanol, cyclohexanone, cyclohexyl hydroperoxide and adipic acid are produced by the continuous liquid phase oxidation of cyclohexane, wherein a gas containing O2 is dissolved in cyclohexane in a first zone, at a temperature at which negligible oxidation occurs, the solution then being passed into a second zone in which it is heated to a higher temperature to effect the reaction. In Example 2, the mixed product, after removing cyclohexane, is oxidized with HNO3 to adipic acid. The process is claimed for the liquid phase oxidation of organic compounds generally, and a number of other such compounds are mentioned.
GB1519864A 1964-04-13 1964-04-13 Oxidation of organic compounds with gases containing molecular oxygen Expired GB1085892A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB1519864A GB1085892A (en) 1964-04-13 1964-04-13 Oxidation of organic compounds with gases containing molecular oxygen
NL6504478A NL6504478A (en) 1964-04-13 1965-04-08
BE662611A BE662461A (en) 1964-04-13 1965-04-13
FR13111A FR1431459A (en) 1964-04-13 1965-04-13 Process for the liquid phase oxidation of an organic compound

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1519864A GB1085892A (en) 1964-04-13 1964-04-13 Oxidation of organic compounds with gases containing molecular oxygen

Publications (1)

Publication Number Publication Date
GB1085892A true GB1085892A (en) 1967-10-04

Family

ID=10054763

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1519864A Expired GB1085892A (en) 1964-04-13 1964-04-13 Oxidation of organic compounds with gases containing molecular oxygen

Country Status (3)

Country Link
BE (1) BE662461A (en)
GB (1) GB1085892A (en)
NL (1) NL6504478A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2142553A (en) * 1983-06-03 1985-01-23 Boc Group Plc Liquid phase oxidation
EP0150821A2 (en) * 1984-02-01 1985-08-07 BASF Aktiengesellschaft Process for the continuous preparation of mixtures containing cyclohydroperoxyde and also cyclohexanol and cyclohexanone

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2142553A (en) * 1983-06-03 1985-01-23 Boc Group Plc Liquid phase oxidation
AU572150B2 (en) * 1983-06-03 1988-05-05 Boc Group Plc, The Liquid phase oxidation
EP0150821A2 (en) * 1984-02-01 1985-08-07 BASF Aktiengesellschaft Process for the continuous preparation of mixtures containing cyclohydroperoxyde and also cyclohexanol and cyclohexanone
EP0150821A3 (en) * 1984-02-01 1985-12-18 Basf Aktiengesellschaft Process for the continuous preparation of mixtures containing cyclohydroperoxyde and also cyclohexanol and cyclohexanone

Also Published As

Publication number Publication date
BE662461A (en) 1965-10-13
NL6504478A (en) 1965-10-14

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