PL414234A1 - Sposób wytwarzania kompleksów rutenu i związków pośrednich oraz ich zastosowanie w metatezie olefin - Google Patents

Sposób wytwarzania kompleksów rutenu i związków pośrednich oraz ich zastosowanie w metatezie olefin

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Publication number
PL414234A1
PL414234A1 PL414234A PL41423415A PL414234A1 PL 414234 A1 PL414234 A1 PL 414234A1 PL 414234 A PL414234 A PL 414234A PL 41423415 A PL41423415 A PL 41423415A PL 414234 A1 PL414234 A1 PL 414234A1
Authority
PL
Poland
Prior art keywords
application
ruthenium
metathesis
olefins
intermediate compounds
Prior art date
Application number
PL414234A
Other languages
English (en)
Other versions
PL238806B1 (pl
Inventor
Krzysztof Skowerski
Rafał Gawin
Original Assignee
Apeiron Synthesis Spółka Akcyjna
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=57045229&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=PL414234(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Apeiron Synthesis Spółka Akcyjna filed Critical Apeiron Synthesis Spółka Akcyjna
Priority to PL414234A priority Critical patent/PL238806B1/pl
Priority to AU2016330158A priority patent/AU2016330158B2/en
Priority to EP16774982.9A priority patent/EP3356379B1/en
Priority to KR1020187010104A priority patent/KR102637889B1/ko
Priority to CA2999412A priority patent/CA2999412A1/en
Priority to JP2018516190A priority patent/JP6905978B2/ja
Priority to US15/764,123 priority patent/US11192911B2/en
Priority to CN201680056336.7A priority patent/CN108137631B/zh
Priority to PCT/IB2016/054486 priority patent/WO2017055945A1/en
Priority to RU2018113805A priority patent/RU2735724C1/ru
Priority to EP21161627.1A priority patent/EP3868769A1/en
Publication of PL414234A1 publication Critical patent/PL414234A1/pl
Priority to IL258354A priority patent/IL258354B/en
Publication of PL238806B1 publication Critical patent/PL238806B1/pl
Priority to US17/513,752 priority patent/US11976085B2/en
Priority to US18/234,753 priority patent/US20240076308A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/40—Non-coordinating groups comprising nitrogen
    • B01J2540/44—Non-coordinating groups comprising nitrogen being derivatives of carboxylic or carbonic acids, e.g. amide (RC(=O)-NR2, RC(=O)-NR-C(=O)R), nitrile, urea (R2N-C(=O)-NR2), guanidino (R2N-C(=NR)-NR2) groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]

Abstract

Przedmiotem zgłoszenia jest nowy sposób wytwarzania kompleksów rutenu o wzorze (1) i związków pośrednich. Zgłoszenie dotyczy także zastosowania kompleksów rutenu o wzorze 1, jako prekatalizatorów i/lub katalizatorów w reakcjach metatezy olefin.
PL414234A 2015-09-30 2015-09-30 Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin PL238806B1 (pl)

Priority Applications (14)

Application Number Priority Date Filing Date Title
PL414234A PL238806B1 (pl) 2015-09-30 2015-09-30 Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
EP21161627.1A EP3868769A1 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
US15/764,123 US11192911B2 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
PCT/IB2016/054486 WO2017055945A1 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
KR1020187010104A KR102637889B1 (ko) 2015-09-30 2016-07-27 루테늄 복합체 및 그의 중간체를 제조하는 방법 및 올레핀 복분해에서 그의 사용방법
CA2999412A CA2999412A1 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
JP2018516190A JP6905978B2 (ja) 2015-09-30 2016-07-27 ルテニウム錯体およびその中間体の製造方法並びにオレフィンメタセシスにおけるその使用方法
AU2016330158A AU2016330158B2 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
CN201680056336.7A CN108137631B (zh) 2015-09-30 2016-07-27 制备钌配位化合物及其中间体的方法和它们在烯烃复分解中的用途
EP16774982.9A EP3356379B1 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
RU2018113805A RU2735724C1 (ru) 2015-09-30 2016-07-27 Способ получения комплексов рутения и их промежуточных соединений и их применение в метатезисе олефинов
IL258354A IL258354B (en) 2015-09-30 2018-03-26 A process for creating complexes of ruthenium and their intermediates and their use in the metathesis of olefins
US17/513,752 US11976085B2 (en) 2015-09-30 2021-10-28 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
US18/234,753 US20240076308A1 (en) 2015-09-30 2023-08-16 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL414234A PL238806B1 (pl) 2015-09-30 2015-09-30 Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin

Publications (2)

Publication Number Publication Date
PL414234A1 true PL414234A1 (pl) 2017-04-10
PL238806B1 PL238806B1 (pl) 2021-10-04

Family

ID=57045229

Family Applications (1)

Application Number Title Priority Date Filing Date
PL414234A PL238806B1 (pl) 2015-09-30 2015-09-30 Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin

Country Status (11)

Country Link
US (3) US11192911B2 (pl)
EP (2) EP3356379B1 (pl)
JP (1) JP6905978B2 (pl)
KR (1) KR102637889B1 (pl)
CN (1) CN108137631B (pl)
AU (1) AU2016330158B2 (pl)
CA (1) CA2999412A1 (pl)
IL (1) IL258354B (pl)
PL (1) PL238806B1 (pl)
RU (1) RU2735724C1 (pl)
WO (1) WO2017055945A1 (pl)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015157736A1 (en) 2014-04-10 2015-10-15 California Institute Of Technology Reactions in the presence of ruthenium complexes
PL238806B1 (pl) 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
HUE054859T2 (hu) 2016-11-09 2021-10-28 Verbio Ver Bioenergie Ag Cserebomlási reakcióhoz alkalmazható ruténium komplexek
PL241085B1 (pl) * 2016-11-10 2022-08-01 Apeiron Synthesis Spolka Akcyjna Zastosowanie kompleksów rutenu w reakcji metatezy olefin
PL243369B1 (pl) * 2018-04-16 2023-08-14 Apeiron Synthesis Spolka Akcyjna Nowe kompleksy rutenu oraz ich zastosowanie w reakcjach metatezy olefin
US11203679B2 (en) 2018-04-27 2021-12-21 Arlanxeo Deutschland Gmbh Use of ruthenium and osmium catalysts for the metathesis of nitrile rubber
PL426318A1 (pl) * 2018-07-12 2020-01-13 Apeiron Synthesis Spółka Akcyjna Zastosowanie N-chelatujących kompleksów rutenu w reakcji metatezy
EP3650436A1 (en) * 2018-11-06 2020-05-13 Skotan S.A. Method of preparing a mixture of 9-decenoic acid ethyl and 1-decene in an ethenolysis reaction from a raw material of technical purity
WO2020109217A2 (en) * 2018-11-29 2020-06-04 Umicore Ag & Co. Kg Metal organic compounds
PL242934B1 (pl) * 2019-12-23 2023-05-22 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i zastosowanie kompleksu rutenu jako katalizatora
PL434983A1 (pl) 2020-08-17 2022-02-21 Apeiron Synthesis Spółka Akcyjna Nowe kompleksy rutenu, sposoby ich wytwarzania i ich zastosowanie w reakcji krzyżowej metatezy olefin
PL439977A1 (pl) * 2021-12-23 2023-06-26 Apeiron Synthesis Spółka Akcyjna Nowe sterycznie aktywowane chelatujące kompleksy rutenu, sposób ich otrzymywania oraz ich zastosowanie w reakcjach metatezy olefin
CN114634436B (zh) * 2022-04-08 2022-12-02 安徽泽升科技有限公司 一种含钌催化剂及其制备方法与用途
PL442226A1 (pl) * 2022-09-08 2024-03-11 Uniwersytet Warszawski Nowe kompleksy rutenu, sposób ich otrzymywania, związki pośrednie stosowane w tym sposobie, sposób ich wytwarzania oraz zastosowanie nowych kompleksów rutenu w reakcjach metatezy olefin

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002079208A2 (en) 2001-04-02 2002-10-10 California Institute Of Technology One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts
US6818586B2 (en) * 2001-08-01 2004-11-16 Cymetech, Llp Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
JP5406525B2 (ja) 2005-07-04 2014-02-05 ツァナン・サイテック・カンパニー・リミテッド ルテニウム錯体配位子、ルテニウム錯体、固定化ルテニウム錯体触媒及びその調製方法と用途
WO2008010961A2 (en) 2006-07-13 2008-01-24 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
CN102123979A (zh) 2006-10-13 2011-07-13 埃莱文斯可更新科学公司 通过烯烃复分解由内烯烃合成末端烯烃的方法
FR2934178B1 (fr) * 2008-07-25 2010-09-10 Rhodia Operations Compositions catalytiques pour la metathese de corps gras insatures avec des olefines et procedes de metathese les mettant en oeuvre
FR2947189B1 (fr) 2009-06-29 2011-07-29 Rhodia Operations Procede de peparation d'une composition catalytique pour la metathese de corps gras insatures
WO2011056881A2 (en) * 2009-11-09 2011-05-12 Exxonmobil Chemical Patents Inc. Metathesis catalyst and process for use thereof
KR20180077335A (ko) 2010-01-08 2018-07-06 엘켐 실리콘즈 프랑스 에스에이에스 용액 형태의 카르벤의 제조 방법, 특히 상기 방법을 이용하여 수득되는 신규한 안정적 형태의 카르벤, 및 촉매작용에 있어서의 그의 용도
PL400162A1 (pl) 2012-07-27 2014-02-03 Apeiron Synthesis Spólka Z Ograniczona Odpowiedzialnoscia Nowe kompleksy rutenu, ich zastosowanie w reakcjach metatezy oraz sposób prowadzenia reakcji metatezy
FR2999184B1 (fr) 2012-12-12 2015-01-09 Ecole Nationale Superieure De Chimie De Rennes Complexes de ruthenium comprenant un diaminocarbene n-heterocyclique insature dissymetrique
US9249170B2 (en) * 2013-04-11 2016-02-02 California Institute Of Technology Cyclic alkyl amino carbene (CAAC) ruthenium complexes as improved catalysts for ethenolysis reactions
WO2015157736A1 (en) 2014-04-10 2015-10-15 California Institute Of Technology Reactions in the presence of ruthenium complexes
PL238806B1 (pl) 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin

Also Published As

Publication number Publication date
US11192911B2 (en) 2021-12-07
IL258354A (en) 2018-05-31
JP6905978B2 (ja) 2021-07-21
US20220073549A1 (en) 2022-03-10
US20240076308A1 (en) 2024-03-07
IL258354B (en) 2022-03-01
AU2016330158B2 (en) 2021-05-13
US11976085B2 (en) 2024-05-07
RU2735724C1 (ru) 2020-11-06
WO2017055945A1 (en) 2017-04-06
JP2018535194A (ja) 2018-11-29
EP3356379B1 (en) 2021-03-10
CA2999412A1 (en) 2017-04-06
CN108137631A (zh) 2018-06-08
KR20180059822A (ko) 2018-06-05
PL238806B1 (pl) 2021-10-04
CN108137631B (zh) 2021-04-16
EP3868769A1 (en) 2021-08-25
AU2016330158A1 (en) 2018-04-12
US20180298046A1 (en) 2018-10-18
KR102637889B1 (ko) 2024-02-19
EP3356379A1 (en) 2018-08-08

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