FR2388781A1 - PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM GAS MIXTURES OF LOW HYDROGEN CONTENT - Google Patents

PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM GAS MIXTURES OF LOW HYDROGEN CONTENT

Info

Publication number
FR2388781A1
FR2388781A1 FR7812391A FR7812391A FR2388781A1 FR 2388781 A1 FR2388781 A1 FR 2388781A1 FR 7812391 A FR7812391 A FR 7812391A FR 7812391 A FR7812391 A FR 7812391A FR 2388781 A1 FR2388781 A1 FR 2388781A1
Authority
FR
France
Prior art keywords
hydrocarbons
preparation
gas mixtures
hydrogen content
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7812391A
Other languages
French (fr)
Other versions
FR2388781B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2388781A1 publication Critical patent/FR2388781A1/en
Application granted granted Critical
Publication of FR2388781B1 publication Critical patent/FR2388781B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8953—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/045—Regeneration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Procédé pour la préparation d'hydrocarbures. Un mélange d'oxyde de carbone et d'hydrogène, dont le rapport molaire H2 /CO est inférieur à 1,0 est mis en contact avec un catalyseur contenant de 5 à 50 % en poids d'un ou plusieurs métaux du groupe du fer et/ou de 0,1 à 5 % en poids de ruthénium et de 5 à 50 % en poids de cuivre et/ou de zinc Dans ce catalyseur, le rapport en poids entre la quantité totale de cuivre et de zinc et la quantité totale de métaux du groupe du fer, augmentée de dix fois la quantité de ruthénium, est compris entre 0,5 et 5. Application à la préparation d'hydrocarbures à partir de mélanges de gaz d'une faible teneur en hydrogène.Process for the preparation of hydrocarbons. A mixture of carbon monoxide and hydrogen with a H2 / CO molar ratio of less than 1.0 is contacted with a catalyst containing 5 to 50% by weight of one or more metals from the iron group and / or from 0.1 to 5% by weight of ruthenium and from 5 to 50% by weight of copper and / or zinc In this catalyst, the ratio by weight between the total quantity of copper and zinc and the total quantity of metals of the iron group, increased by ten times the amount of ruthenium, is between 0.5 and 5. Application to the preparation of hydrocarbons from gas mixtures with a low hydrogen content.

FR7812391A 1977-04-28 1978-04-26 PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM GAS MIXTURES OF LOW HYDROGEN CONTENT Granted FR2388781A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7704658A NL7704658A (en) 1977-04-28 1977-04-28 PROCESS FOR THE PREPARATION OF HYDROCARBONS.

Publications (2)

Publication Number Publication Date
FR2388781A1 true FR2388781A1 (en) 1978-11-24
FR2388781B1 FR2388781B1 (en) 1981-08-07

Family

ID=19828451

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7812391A Granted FR2388781A1 (en) 1977-04-28 1978-04-26 PROCESS FOR THE PREPARATION OF HYDROCARBONS FROM GAS MIXTURES OF LOW HYDROGEN CONTENT

Country Status (11)

Country Link
JP (1) JPS53135906A (en)
AU (1) AU515324B2 (en)
BE (1) BE866072A (en)
CA (1) CA1095536A (en)
DE (1) DE2818308A1 (en)
FR (1) FR2388781A1 (en)
GB (1) GB1553959A (en)
IN (1) IN148281B (en)
IT (1) IT1094560B (en)
NL (1) NL7704658A (en)
ZA (1) ZA782399B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2483400A1 (en) * 1980-06-03 1981-12-04 Shell Int Research PROCESS FOR THE PREPARATION OF HYDROCARBONS
EP0055512A1 (en) * 1980-12-22 1982-07-07 The Standard Oil Company Process for the manufacture of 1-4-butanediol and tetrahydrofuran
EP0082692A2 (en) * 1981-12-21 1983-06-29 The Standard Oil Company Process for upgrading synthesis gas and catalysts therefor
US4654321A (en) * 1981-12-21 1987-03-31 The Standard Oil Company Upgrading synthesis gas catalyst
FR2694013A1 (en) * 1992-07-27 1994-01-28 Inst Francais Du Petrole Cobalt-based catalyst and process for converting synthesis gas to hydrocarbons.

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7704656A (en) * 1977-04-28 1978-10-31 Shell Int Research PROCESS FOR THE PREPARATION OF HYDROCARBONS.
US4617283A (en) * 1984-06-27 1986-10-14 Union Carbide Corporation Catalyst for converting synthesis gas to liquid motor fuels
DE3578384D1 (en) * 1984-11-02 1990-08-02 Shell Int Research CATALYST PRODUCTION.
GB2169614A (en) * 1984-12-31 1986-07-16 Mobil Oil Corp Producing alpha-olefins and their conversion into lubricants

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1011662A (en) * 1949-02-26 1952-06-25 Ruhrchemie Ag Process for obtaining carbon monoxide hydrogenation products with a high content of oxygen compounds
GB681648A (en) * 1950-03-08 1952-10-29 Du Pont Process for preparing high molecular weight hydrocarbons

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7704656A (en) * 1977-04-28 1978-10-31 Shell Int Research PROCESS FOR THE PREPARATION OF HYDROCARBONS.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1011662A (en) * 1949-02-26 1952-06-25 Ruhrchemie Ag Process for obtaining carbon monoxide hydrogenation products with a high content of oxygen compounds
GB681648A (en) * 1950-03-08 1952-10-29 Du Pont Process for preparing high molecular weight hydrocarbons

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2483400A1 (en) * 1980-06-03 1981-12-04 Shell Int Research PROCESS FOR THE PREPARATION OF HYDROCARBONS
EP0055512A1 (en) * 1980-12-22 1982-07-07 The Standard Oil Company Process for the manufacture of 1-4-butanediol and tetrahydrofuran
EP0082692A2 (en) * 1981-12-21 1983-06-29 The Standard Oil Company Process for upgrading synthesis gas and catalysts therefor
EP0082692A3 (en) * 1981-12-21 1984-09-12 The Standard Oil Company Process for upgrading synthesis gas and catalysts therefor
US4654321A (en) * 1981-12-21 1987-03-31 The Standard Oil Company Upgrading synthesis gas catalyst
FR2694013A1 (en) * 1992-07-27 1994-01-28 Inst Francais Du Petrole Cobalt-based catalyst and process for converting synthesis gas to hydrocarbons.
EP0581619A1 (en) * 1992-07-27 1994-02-02 Institut Francais Du Petrole Cobalt based catalyst and process for the commution of synthesis gas into hydrocarbons
US5302622A (en) * 1992-07-27 1994-04-12 Institut Francais Du Petrole Cobalt-based catalyst and process for converting synthesis gas into hydrocarbons

Also Published As

Publication number Publication date
IN148281B (en) 1981-01-03
DE2818308C2 (en) 1988-09-01
IT1094560B (en) 1985-08-02
BE866072A (en) 1978-10-18
FR2388781B1 (en) 1981-08-07
IT7822723A0 (en) 1978-04-26
AU3538178A (en) 1979-11-01
GB1553959A (en) 1979-10-17
DE2818308A1 (en) 1978-11-02
AU515324B2 (en) 1981-03-26
JPS53135906A (en) 1978-11-28
ZA782399B (en) 1979-04-25
CA1095536A (en) 1981-02-10
NL7704658A (en) 1978-10-31

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