FR2370712A1 - - Google Patents

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Publication number
FR2370712A1
FR2370712A1 FR7733600A FR7733600A FR2370712A1 FR 2370712 A1 FR2370712 A1 FR 2370712A1 FR 7733600 A FR7733600 A FR 7733600A FR 7733600 A FR7733600 A FR 7733600A FR 2370712 A1 FR2370712 A1 FR 2370712A1
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FR
France
Prior art keywords
catalyst
metals
weight
parts
iron group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7733600A
Other languages
French (fr)
Other versions
FR2370712B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2370712A1 publication Critical patent/FR2370712A1/fr
Application granted granted Critical
Publication of FR2370712B1 publication Critical patent/FR2370712B1/fr
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/045—Regeneration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procédé pour la préparation d'hydrocarbures à partir d'oxyde de carbone et d'hydrogène. On utilise un catalyseur comprenant de 10 à 17 parties en poids d'un ou plusieurs métaux du groupe du fer pour 100 parties en poids de support et un ou plusieurs promoteurs dans une proportion de 1 à 50 % par rapport à la quantité de métaux du groupe du fer présents sur le catalyseur. Le catalyseur est préparé par imprégnation. Le catalyseur a un diamètre moyen spécifique des pores (p) d'au maximum 10 000 nm et un diamètre moyen spécifique des particules (d) d'au maximum 5 mm. Le quotient p/d est supérieur à 2 (p en nm et d en mm). Application à la synthèse de Fischer-Tropsch.Process for the preparation of hydrocarbons from carbon monoxide and hydrogen. A catalyst is used comprising 10 to 17 parts by weight of one or more metals from the iron group per 100 parts by weight of support and one or more promoters in a proportion of 1 to 50% relative to the amount of metals of the carrier. iron group present on the catalyst. The catalyst is prepared by impregnation. The catalyst has a specific mean pore diameter (p) of at most 10,000 nm and a specific mean particle diameter (d) of at most 5 mm. The quotient p / d is greater than 2 (p in nm and d in mm). Application to the Fischer-Tropsch synthesis.

FR7733600A 1976-11-10 1977-11-08 Expired FR2370712B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7612460A NL7612460A (en) 1976-11-10 1976-11-10 PROCESS FOR THE PREPARATION OF HYDROCARBONS.

Publications (2)

Publication Number Publication Date
FR2370712A1 true FR2370712A1 (en) 1978-06-09
FR2370712B1 FR2370712B1 (en) 1980-10-10

Family

ID=19827203

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7733600A Expired FR2370712B1 (en) 1976-11-10 1977-11-08

Country Status (11)

Country Link
JP (1) JPS5359604A (en)
AU (1) AU513157B2 (en)
BE (1) BE860395A (en)
CA (1) CA1089495A (en)
DE (1) DE2750007A1 (en)
FR (1) FR2370712B1 (en)
GB (1) GB1548468A (en)
IN (1) IN147159B (en)
IT (1) IT1087492B (en)
NL (1) NL7612460A (en)
ZA (1) ZA776649B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2460712A1 (en) * 1979-07-13 1981-01-30 Shell Int Research PROCESS FOR PREPARING FISCHER-TROPSCH CATALYSTS AND APPLYING THESE CATALYSTS TO THE PREPARATION OF HYDROCARBONS
FR2483911A1 (en) * 1980-06-06 1981-12-11 Shell Int Research PROCESS FOR THE PREPARATION OF MEDIUM DISTILLATES FROM A MIXTURE OF CARBON OXIDE AND HYDROGEN
EP0131924A1 (en) * 1983-07-15 1985-01-23 Daido Sanso K.K. Method for producing hydrocarbons
EP0455308A2 (en) * 1990-05-04 1991-11-06 Shell Internationale Researchmaatschappij B.V. Process for the conversion of methanol into liquid hydrocarbons

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL190574C (en) * 1979-07-13 1994-05-02 Shell Int Research Process for the preparation of iron magnesium catalysts and their use in the preparation of hydrocarbons.
DK144602C (en) * 1979-12-18 1982-09-27 Haldor Topsoe As PROCEDURE FOR PREPARING A GAS MIXTURE WITH HIGH CONTENT OF C2 CARBON
US4613624A (en) * 1981-10-13 1986-09-23 Chevron Research Company Conversion of synthesis gas to diesel fuel and catalyst therefor
US4605676A (en) * 1981-10-13 1986-08-12 Chevron Research Company Synthesis gas conversion using ROR-activated catalyst
US4605679A (en) * 1981-10-13 1986-08-12 Chevron Research Company Activated cobalt catalyst and synthesis gas conversion using same
EP0110449B1 (en) * 1982-11-22 1986-08-13 Shell Internationale Researchmaatschappij B.V. Process for the preparation of a fischer-tropsch catalyst, a catalyst so prepared and use of this catalyst in the preparation of hydrocarbons
CA1234158A (en) * 1983-11-15 1988-03-15 Johannes K. Minderhoud Process for the preparation of hydrocarbons
CA1240708A (en) * 1983-11-15 1988-08-16 Johannes K. Minderhoud Process for the preparation of hydrocarbons
GB2169614A (en) * 1984-12-31 1986-07-16 Mobil Oil Corp Producing alpha-olefins and their conversion into lubricants
IN166813B (en) * 1985-01-18 1990-07-21 Shell Int Research
US4717702A (en) * 1985-04-26 1988-01-05 Shell Internationale Research Maatschappij Bv Catalyst for conversion of synthesis gas to diesel fuel and process for preparation of such catalyst
GB8515222D0 (en) * 1985-06-15 1985-07-17 British Nuclear Fuels Plc Synthesis gas conversion catalyst
GB8623233D0 (en) * 1986-09-26 1986-10-29 British Petroleum Co Plc Syngas conversion catalyst
FR2694013B1 (en) * 1992-07-27 1994-09-30 Inst Francais Du Petrole Cobalt-based catalyst and process for converting synthesis gas to hydrocarbons.
JP2007181755A (en) * 2006-01-05 2007-07-19 Nippon Gas Gosei Kk Catalyst for producing liquefied petroleum gas and method for producing liquefied petroleum gas by using the same
JP2010116328A (en) * 2008-11-11 2010-05-27 Nippon Oil Corp Method for producing unsaturated hydrocarbon and oxygen-containing compound, catalyst and method for producing the same
TWI473652B (en) 2008-12-26 2015-02-21 Nippon Oil Corp Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
CN103949262A (en) * 2014-04-21 2014-07-30 武汉凯迪工程技术研究总院有限公司 Structured iron-based catalyst for preparing alpha-alkene by synthesis gas as well as preparation method and application of structured iron-based catalyst

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE919288C (en) * 1949-09-13 1954-10-18 Ruhrchemie Ag Process for the production of iron catalysts which are suitable for the catalytic hydrogenation of carbons, which is carried out in particular under high gas loads
DE881497C (en) * 1951-10-09 1953-06-29 Ruhrchemie Ag Iron catalyst for the hydrogenation of carbohydrates with a high content of petrol-like hydrocarbons

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2460712A1 (en) * 1979-07-13 1981-01-30 Shell Int Research PROCESS FOR PREPARING FISCHER-TROPSCH CATALYSTS AND APPLYING THESE CATALYSTS TO THE PREPARATION OF HYDROCARBONS
FR2483911A1 (en) * 1980-06-06 1981-12-11 Shell Int Research PROCESS FOR THE PREPARATION OF MEDIUM DISTILLATES FROM A MIXTURE OF CARBON OXIDE AND HYDROGEN
EP0131924A1 (en) * 1983-07-15 1985-01-23 Daido Sanso K.K. Method for producing hydrocarbons
EP0455308A2 (en) * 1990-05-04 1991-11-06 Shell Internationale Researchmaatschappij B.V. Process for the conversion of methanol into liquid hydrocarbons
EP0455308A3 (en) * 1990-05-04 1992-01-08 Shell Internationale Research Maatschappij B.V. Process for the conversion of methanol into liquid hydrocarbons

Also Published As

Publication number Publication date
CA1089495A (en) 1980-11-11
JPS6337090B2 (en) 1988-07-22
JPS5359604A (en) 1978-05-29
IN147159B (en) 1979-12-01
DE2750007C2 (en) 1987-08-27
IT1087492B (en) 1985-06-04
GB1548468A (en) 1979-07-18
BE860395A (en) 1978-05-03
DE2750007A1 (en) 1978-05-18
NL7612460A (en) 1978-05-12
FR2370712B1 (en) 1980-10-10
AU513157B2 (en) 1980-11-20
ZA776649B (en) 1978-08-30
AU2970877A (en) 1979-04-26

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