FR2051493A1 - 2-cyanobenzimidazole derivs - Google Patents
2-cyanobenzimidazole derivsInfo
- Publication number
- FR2051493A1 FR2051493A1 FR7010871A FR7010871A FR2051493A1 FR 2051493 A1 FR2051493 A1 FR 2051493A1 FR 7010871 A FR7010871 A FR 7010871A FR 7010871 A FR7010871 A FR 7010871A FR 2051493 A1 FR2051493 A1 FR 2051493A1
- Authority
- FR
- France
- Prior art keywords
- alkyl
- parts
- cyanobenzimidazole
- derivs
- carbonamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
- C07D235/24—Benzimidazoles; Hydrogenated benzimidazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
2-Cyanobenzimidazole derivs. New cpds. of formula (I) (where R= =Hal, alkyl, or CO2 alkyl, and R2-R5 = H, hal, NO2, or opt. subst. alkyl,) and their salts, are of use as parasiticides (esp. anthelmintics), fungicides, insecticides, and herbicides. (I) are prepd.:-(a) by reaction of the 2-trichloromethyl deriv. with NH3, (b) by dehydration of the 2-alkoxime or carbonamide, (c) by alkylation or alkoxycarbonylation of I (R' = H). Thus refluxing benzimidazole-2-carbonamide (40 parts), with POCl3 (1200 parts) for 6 hr. gave 2-cyano-benzimidazole (25.5 parts), m.p. 294-5 degrees (from EtOH).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1658269 | 1969-03-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2051493A1 true FR2051493A1 (en) | 1971-04-09 |
Family
ID=10079918
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7010871A Withdrawn FR2051493A1 (en) | 1969-03-29 | 1970-03-26 | 2-cyanobenzimidazole derivs |
Country Status (5)
Country | Link |
---|---|
AU (1) | AU1310970A (en) |
BE (1) | BE748168A (en) |
DE (1) | DE2014293A1 (en) |
FR (1) | FR2051493A1 (en) |
NL (1) | NL7004376A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2521141A1 (en) * | 1982-02-09 | 1983-08-12 | Rhone Poulenc Agrochimie | NOVEL DERIVATIVES OF CYANO-2 BENZIMIDAZOLE, THEIR PREPARATION AND THEIR USE AS FUNGICIDES |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0000574B1 (en) * | 1977-08-01 | 1982-08-04 | Ciba-Geigy Ag | Benzimidazole-2 derivatives, their preparation and their use for the preparation of medicaments |
DE4237567A1 (en) * | 1992-11-06 | 1994-05-11 | Bayer Ag | Pesticides |
DE4242183A1 (en) * | 1992-12-15 | 1994-06-16 | Bayer Ag | Use of CN-substituted benzimidazoles |
DE4416116A1 (en) * | 1994-05-06 | 1995-11-09 | Bayer Ag | Substituted benzimidazoles |
-
1970
- 1970-03-25 DE DE19702014293 patent/DE2014293A1/en active Pending
- 1970-03-26 FR FR7010871A patent/FR2051493A1/en not_active Withdrawn
- 1970-03-26 AU AU13109/70A patent/AU1310970A/en not_active Expired
- 1970-03-26 NL NL7004376A patent/NL7004376A/xx unknown
- 1970-03-27 BE BE748168D patent/BE748168A/en unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2521141A1 (en) * | 1982-02-09 | 1983-08-12 | Rhone Poulenc Agrochimie | NOVEL DERIVATIVES OF CYANO-2 BENZIMIDAZOLE, THEIR PREPARATION AND THEIR USE AS FUNGICIDES |
EP0087375A1 (en) * | 1982-02-09 | 1983-08-31 | Rhone-Poulenc Agrochimie | Cyano-2-benzimidazole derivatives, their preparation and their utilisation as fungicides and acaricides |
US4536502A (en) * | 1982-02-09 | 1985-08-20 | Rhone-Poulenc Agrochimie | Fungicidal 2-cyanobenzimidazole derivatives, compositions, and method of use |
Also Published As
Publication number | Publication date |
---|---|
BE748168A (en) | 1970-09-28 |
DE2014293A1 (en) | 1970-10-08 |
AU1310970A (en) | 1971-09-30 |
NL7004376A (en) | 1970-10-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |