FI112233B - Katalysator för polymerisering av olefiner, förfarande för framställning av denna och användning av denna - Google Patents

Katalysator för polymerisering av olefiner, förfarande för framställning av denna och användning av denna Download PDF

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Publication number
FI112233B
FI112233B FI931423A FI931423A FI112233B FI 112233 B FI112233 B FI 112233B FI 931423 A FI931423 A FI 931423A FI 931423 A FI931423 A FI 931423A FI 112233 B FI112233 B FI 112233B
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Finland
Prior art keywords
catalyst
polymerization
formula
carrier
polymer
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FI931423A
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English (en)
Finnish (fi)
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FI931423A (fi
FI931423A0 (fi
Inventor
Bernd Bachmann
Walter Spaleck
Hans-Friedrich Herrmann
Bernhard Hierholzer
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Basell Polyolefine Gmbh
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Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (8)

1. Pä en bärare uppburen polymerisationskatalysa-tor, som kan framställas genom omsättning av reaktionspro- 5 dukten av ett aluminiumoxan och ätminstone ett metallocen med en mikroporös polymerbärare, varvid den mikroporösa polymerbärarens porvolym är ätminstone 50 volym-% av bä-rarmaterialets totalvolym.
2. Katalysator enligt patentkrav 1, känneteck-10 nad av att som den porösa polymerbäraren används ett termoplastiskt material.
3. Katalysator enligt patentkrav 1 eller 2, kän-netecknad av att som polymerbäraren används polyeten, polypropen, polystyren, polyvinylklorid, akrylnitrilbuta- 15 dien-styren-kopolymer, polyamid, polymetyl-metakrylat eller polykarbonat.
4. Katalysator enligt ett eller flera av patent-kraven 1 - 3, kännetecknad av att som aluminiumoxan används en förening enligt formel (II) 20 I 1 t • > .·; ·.; R ^R AI—0--AI 0 AI (II) ***** S\s^
25 RX R • · • I * * I • I · • * · för den lineära typen och/eller en förening enligt formel (III) * * * » » 30 Γ-. Γ , Ί :· --0-AI--, (Ml) • I I t | • · » • » • · 35 112 2 3 3 för den cykliska typen, varvid grupperna R i formlerna (II) och (III) kan vara lika eller oi ikä och ange en Ci-6-alkylgrupp, C6-i8-arylgrupp, bensyl eller väteatom, och p anger ett heltal 2-50.
5. Katalysator enligt ett eller flera av patent- kraven 1 - 4, kännetecknad av att som metallocen an-vänds z irkonocen.
6. Förfarande för framställning av en katalysator enligt ett eller flera av patentkraven 1-5, kanne- 10 tecknat av att reaktionsprodukten av ett aluminiumoxan och ätminstone ett metallocen omsätts med en mikroporös polymerbärare.
7. Förfarande för framställning av en olefinpoly-mer genom polymerisation eller kopolymerisation av ett 15 olefin med formeln Ra-CH=CH-Rb, där Ra och Rb är lika eller oiikä och anger en väteatom eller kolvätegrupp med 1-14 C-atomer, eller Ra och Rb kan med vid dessa bundna atomer bilda en ring, vid en temperatur pä -60 - 200 °C vid ett tryck pä 0,5 - 100 bar i en lösning, suspension eller gas- 2. fas i närvaro av en katalysator, kännetecknat av att man använder en katalysator enligt ett eller flera av pa- » i a ·' tentkraven 1-5.
) · •. *: 8. Förfarande enligt patentkrav 7, känneteck- ;* n a t av att propen eller eten polymeriseras eller kopoly- *: 25 meriseras. • · • | f * i * · » » • * * > a t a
FI931423A 1992-04-01 1993-03-30 Katalysator för polymerisering av olefiner, förfarande för framställning av denna och användning av denna FI112233B (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4210780 1992-04-01
DE4210780 1992-04-01

Publications (3)

Publication Number Publication Date
FI931423A0 FI931423A0 (fi) 1993-03-30
FI931423A FI931423A (fi) 1993-10-02
FI112233B true FI112233B (sv) 2003-11-14

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ID=6455689

Family Applications (1)

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FI931423A FI112233B (sv) 1992-04-01 1993-03-30 Katalysator för polymerisering av olefiner, förfarande för framställning av denna och användning av denna

Country Status (13)

Country Link
US (2) US20020013217A1 (sv)
EP (1) EP0563917B1 (sv)
JP (1) JP3944247B2 (sv)
KR (1) KR100269057B1 (sv)
AT (1) ATE167198T1 (sv)
AU (1) AU665811B2 (sv)
CA (1) CA2093056A1 (sv)
DE (1) DE59308657D1 (sv)
ES (1) ES2117065T3 (sv)
FI (1) FI112233B (sv)
NO (1) NO302237B1 (sv)
RU (1) RU2111219C1 (sv)
ZA (1) ZA932305B (sv)

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Also Published As

Publication number Publication date
NO302237B1 (no) 1998-02-09
AU665811B2 (en) 1996-01-18
KR930021658A (ko) 1993-11-22
ES2117065T3 (es) 1998-08-01
AU3559893A (en) 1993-10-07
DE59308657D1 (de) 1998-07-16
FI931423A (fi) 1993-10-02
NO931243L (no) 1993-10-04
US5942586A (en) 1999-08-24
JPH0625348A (ja) 1994-02-01
JP3944247B2 (ja) 2007-07-11
EP0563917A1 (de) 1993-10-06
US20020013217A1 (en) 2002-01-31
FI931423A0 (fi) 1993-03-30
CA2093056A1 (en) 1993-10-02
NO931243D0 (no) 1993-03-31
RU2111219C1 (ru) 1998-05-20
KR100269057B1 (ko) 2000-10-16
ATE167198T1 (de) 1998-06-15
ZA932305B (en) 1993-10-18
EP0563917B1 (de) 1998-06-10

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