FI109812B - Stabiloitu polyamidisäie, seos ja menetelmä säikeiden stabiloimiseksi sekä stabiloitu seos - Google Patents
Stabiloitu polyamidisäie, seos ja menetelmä säikeiden stabiloimiseksi sekä stabiloitu seos Download PDFInfo
- Publication number
- FI109812B FI109812B FI952356A FI952356A FI109812B FI 109812 B FI109812 B FI 109812B FI 952356 A FI952356 A FI 952356A FI 952356 A FI952356 A FI 952356A FI 109812 B FI109812 B FI 109812B
- Authority
- FI
- Finland
- Prior art keywords
- functionalized
- synergist
- stabilizer
- copper
- stabilized
- Prior art date
Links
- 239000004952 Polyamide Substances 0.000 title claims description 34
- 229920002647 polyamide Polymers 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 17
- 230000000087 stabilizing effect Effects 0.000 title claims description 13
- 239000000956 alloy Substances 0.000 title claims description 8
- 229910045601 alloy Inorganic materials 0.000 title claims description 8
- 239000003381 stabilizer Substances 0.000 claims description 52
- -1 copper (I) halide Chemical class 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 35
- 239000010949 copper Substances 0.000 claims description 34
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical class [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 34
- 239000004954 Polyphthalamide Substances 0.000 claims description 32
- 239000000835 fiber Substances 0.000 claims description 32
- 229920006375 polyphtalamide Polymers 0.000 claims description 32
- 229910052802 copper Inorganic materials 0.000 claims description 31
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 29
- 229920000098 polyolefin Polymers 0.000 claims description 27
- 238000004519 manufacturing process Methods 0.000 claims description 18
- 239000004698 Polyethylene Substances 0.000 claims description 13
- 229920000573 polyethylene Polymers 0.000 claims description 13
- 239000004743 Polypropylene Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 12
- 229920002943 EPDM rubber Polymers 0.000 claims description 11
- 235000007715 potassium iodide Nutrition 0.000 claims description 11
- 229910001508 alkali metal halide Inorganic materials 0.000 claims description 9
- 150000008045 alkali metal halides Chemical class 0.000 claims description 9
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 9
- 150000001408 amides Chemical class 0.000 claims description 8
- 238000002074 melt spinning Methods 0.000 claims description 7
- 229920001897 terpolymer Polymers 0.000 claims description 7
- 230000006641 stabilisation Effects 0.000 claims description 6
- 238000011105 stabilization Methods 0.000 claims description 6
- 239000005749 Copper compound Substances 0.000 claims description 5
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 claims description 5
- 150000001880 copper compounds Chemical class 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 238000009950 felting Methods 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229910021595 Copper(I) iodide Inorganic materials 0.000 claims 7
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 claims 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 2
- 150000004694 iodide salts Chemical class 0.000 claims 2
- 238000010276 construction Methods 0.000 claims 1
- WCCJDBZJUYKDBF-UHFFFAOYSA-N copper silicon Chemical compound [Si].[Cu] WCCJDBZJUYKDBF-UHFFFAOYSA-N 0.000 claims 1
- 239000003517 fume Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 210000000653 nervous system Anatomy 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 claims 1
- 230000002463 transducing effect Effects 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 13
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000003623 enhancer Substances 0.000 description 5
- 238000009987 spinning Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- 229920003231 aliphatic polyamide Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000004953 Aliphatic polyamide Substances 0.000 description 3
- 229920002633 Kraton (polymer) Polymers 0.000 description 3
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 3
- 229920003182 Surlyn® Polymers 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- PZRHRDRVRGEVNW-UHFFFAOYSA-N milrinone Chemical compound N1C(=O)C(C#N)=CC(C=2C=CN=CC=2)=C1C PZRHRDRVRGEVNW-UHFFFAOYSA-N 0.000 description 3
- 229960003574 milrinone Drugs 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 3
- 229950011008 tetrachloroethylene Drugs 0.000 description 3
- FQLAJSQGBDYBAL-UHFFFAOYSA-N 3-(azepane-1-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2CCCCCC2)=C1 FQLAJSQGBDYBAL-UHFFFAOYSA-N 0.000 description 2
- PGGROMGHWHXWJL-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide Chemical group C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 PGGROMGHWHXWJL-UHFFFAOYSA-N 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 229920003233 aromatic nylon Polymers 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000012925 reference material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical group NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- CYMRPDYINXWJFU-UHFFFAOYSA-N 2-carbamoylbenzoic acid Chemical class NC(=O)C1=CC=CC=C1C(O)=O CYMRPDYINXWJFU-UHFFFAOYSA-N 0.000 description 1
- DARJESXGWBVEBK-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide;benzene-1,3-dicarboxamide;hexanediamide Chemical compound NC(=O)CCCCC(N)=O.NC(=O)C1=CC=CC(C(N)=O)=C1.C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 DARJESXGWBVEBK-UHFFFAOYSA-N 0.000 description 1
- LJAQBTOSXLZLBM-UHFFFAOYSA-N 4-(piperidine-1-carbonyl)benzamide Chemical group C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCC1 LJAQBTOSXLZLBM-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
- 239000004956 Amodel Substances 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- ODWXUNBKCRECNW-UHFFFAOYSA-M bromocopper(1+) Chemical compound Br[Cu+] ODWXUNBKCRECNW-UHFFFAOYSA-M 0.000 description 1
- PUEVFCCOBZIVDO-FJOGWHKWSA-N buta-1,3-diene (Z)-but-2-enedioic acid styrene Chemical compound C=CC=C.C=Cc1ccccc1.OC(=O)\C=C/C(O)=O PUEVFCCOBZIVDO-FJOGWHKWSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- ZKXWKVVCCTZOLD-UHFFFAOYSA-N copper;4-hydroxypent-3-en-2-one Chemical compound [Cu].CC(O)=CC(C)=O.CC(O)=CC(C)=O ZKXWKVVCCTZOLD-UHFFFAOYSA-N 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- VDBXLXRWMYNMHL-UHFFFAOYSA-N decanediamide Chemical compound NC(=O)CCCCCCCCC(N)=O VDBXLXRWMYNMHL-UHFFFAOYSA-N 0.000 description 1
- 230000000911 decarboxylating effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 125000004427 diamine group Chemical group 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000010035 extrusion spinning Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QZUPTXGVPYNUIT-UHFFFAOYSA-N isophthalamide Chemical compound NC(=O)C1=CC=CC(C(N)=O)=C1 QZUPTXGVPYNUIT-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JXRWDHUZHAWOLC-UHFFFAOYSA-N naphthalene-1,2-dicarboxamide Chemical compound C1=CC=CC2=C(C(N)=O)C(C(=O)N)=CC=C21 JXRWDHUZHAWOLC-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- NAYYNDKKHOIIOD-UHFFFAOYSA-N phthalamide Chemical compound NC(=O)C1=CC=CC=C1C(N)=O NAYYNDKKHOIIOD-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical class [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920006345 thermoplastic polyamide Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12236793 | 1993-09-16 | ||
US08/122,367 US5447980A (en) | 1993-09-16 | 1993-09-16 | Stabilized polyamide fiber |
US9409596 | 1994-08-18 | ||
PCT/US1994/009596 WO1995008011A1 (en) | 1993-09-16 | 1994-08-18 | Stabilized polyamide fiber |
Publications (3)
Publication Number | Publication Date |
---|---|
FI952356A0 FI952356A0 (fi) | 1995-05-15 |
FI952356A FI952356A (fi) | 1995-05-15 |
FI109812B true FI109812B (fi) | 2002-10-15 |
Family
ID=22402286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI952356A FI109812B (fi) | 1993-09-16 | 1995-05-15 | Stabiloitu polyamidisäie, seos ja menetelmä säikeiden stabiloimiseksi sekä stabiloitu seos |
Country Status (10)
Country | Link |
---|---|
US (1) | US5447980A (no) |
EP (1) | EP0668943B1 (no) |
JP (1) | JP3456483B2 (no) |
BR (1) | BR9405594A (no) |
CA (1) | CA2148487C (no) |
DE (1) | DE69415493T2 (no) |
FI (1) | FI109812B (no) |
NO (1) | NO310935B1 (no) |
SG (1) | SG79914A1 (no) |
WO (1) | WO1995008011A1 (no) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5585429A (en) * | 1995-03-27 | 1996-12-17 | Amoco Corporation | Polyphthalamide resin formulations |
US5763561A (en) * | 1996-09-06 | 1998-06-09 | Amoco Corporation | Polyamide compositions having improved thermal stability |
JP2000319508A (ja) * | 1999-05-13 | 2000-11-21 | Toyobo Co Ltd | ポリアミド樹脂組成物 |
DE60006968T2 (de) * | 1999-06-18 | 2004-10-21 | Solvay Advanced Polymers Llc | Verfahren zur verringerung der bildung von formablagerungen während des formens von polyamiden und deren zusammensetzungen |
EP1554762B2 (en) * | 2002-10-15 | 2014-04-30 | Solvay Specialty Polymers USA, LLC. | Anti-yellowing polycondensation polymer compositions and articles |
CA2535344C (en) * | 2003-08-19 | 2015-10-06 | Solvay Advanced Polymers, L.L.C. | Impact-modified polyamide hollow body |
US20050197452A1 (en) * | 2004-02-27 | 2005-09-08 | Solvay Advanced Polymers, Llc | Safety equipment comprising an aromatic polyamide composition, and aromatic polyamide composition |
DE102004022963A1 (de) * | 2004-05-10 | 2005-12-08 | Ems-Chemie Ag | Thermoplastische Polyamid-Formmassen |
US20070245924A1 (en) * | 2006-04-20 | 2007-10-25 | Hofmann Michael A | Reduced abrasion of titanium dioxide pigments produced from the chloride process |
DE102007038578A1 (de) | 2007-08-16 | 2009-02-19 | Evonik Degussa Gmbh | Verfahren zur Dekorierung von Oberflächen |
DE102010030212A1 (de) * | 2010-06-17 | 2011-12-22 | Robert Bosch Gmbh | Stabilisatorzusammensetzung für Polyamide |
DE102010042131A1 (de) | 2010-10-07 | 2012-04-12 | Evonik Degussa Gmbh | Mit Polyphthalamid-Fasern verstärkter Gummikörper |
DE102010051310A1 (de) | 2010-11-16 | 2012-05-16 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Verfahren zur Herstellung von Polyamidzusammensetzungen mit verbesserten thermooxidativen, antibakteriellen, licht- oder energieaktiven Eigenschaften |
DE102011007196A1 (de) | 2011-04-12 | 2012-10-18 | Evonik Degussa Gmbh | Verfahren zur Herstellung eines Verbundes aus einem Polyamidformteil und einem Methacrylatcopolymer-Formteil |
CN104039878A (zh) | 2011-11-08 | 2014-09-10 | 索尔维特殊聚合物美国有限责任公司 | 用于井下原油部件的高耐热性聚酰胺 |
CN105849325B (zh) * | 2014-01-08 | 2018-07-06 | 旭化成株式会社 | 聚酰胺复丝纤维和包含该纤维的轮胎帘线 |
JP6282903B2 (ja) * | 2014-03-14 | 2018-02-21 | ユニチカ株式会社 | モノフィラメント |
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WO2017144279A1 (en) | 2016-02-24 | 2017-08-31 | Solvay Specialty Polymers Usa, Llc | Impact-modified polymer compositions and articles made therefrom |
CN110283311B (zh) * | 2019-06-26 | 2021-09-24 | 平顶山神马帘子布发展有限公司 | 一种尼龙66工业丝生产中减少铜析出的生产***及生产方法 |
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US3457325A (en) * | 1965-03-08 | 1969-07-22 | Du Pont | Polyamide fibers stabilized with inorganic iodides and copper phthalates |
DE1595603A1 (de) * | 1966-03-12 | 1970-05-14 | Bayer Ag | Stabilisierte Polyamide |
NL139548B (nl) * | 1969-03-06 | 1973-08-15 | Snia Viscosa | Werkwijze voor het bereiden van gestabiliseerde polyamiden. |
US3639335A (en) * | 1970-06-12 | 1972-02-01 | Toray Industries | Thermally-stable polyamide compositions |
US3917561A (en) * | 1974-03-29 | 1975-11-04 | Monsanto Co | Process for preparing melt-stable poly(dodecamethyleneterephthalamide |
DE2862021D1 (en) * | 1977-12-29 | 1982-10-28 | Bayer Ag | Impact resistant polyamide moulding blends |
US4346194A (en) * | 1980-01-22 | 1982-08-24 | E. I. Du Pont De Nemours And Company | Toughened polyamide blends |
US4594386A (en) * | 1983-08-15 | 1986-06-10 | Copolymer Rubber & Chemical Corporation | Polyamide grafted EPM blend |
US4537929A (en) * | 1984-01-20 | 1985-08-27 | Plastic Specialties And Technologies, Inc. | High impact nylon composition |
CA1289686C (en) * | 1985-07-31 | 1991-09-24 | Richard Gelles | Impact resistant polymeric compositions |
US5006601A (en) * | 1986-09-25 | 1991-04-09 | Shell Oil Company | Impact resistant blends of thermoplastic polyamides, polyolefins and elastomers |
DE3717218A1 (de) * | 1987-05-22 | 1989-03-23 | Bayer Ag | Glasfaserverstaerkte stabilisierte polyamidformmasse |
CA2013049A1 (en) * | 1989-03-28 | 1990-09-28 | Pieter Gijsman | Polyamide 4.6 composition |
US5106946A (en) * | 1989-10-20 | 1992-04-21 | E. I. Du Pont De Nemours And Company | High tenacity, high modulus polyamide yarn and process for making same |
CA2051767C (en) * | 1990-09-20 | 2003-05-13 | Ruth A. Montag | Polyphthalamide composition |
-
1993
- 1993-09-16 US US08/122,367 patent/US5447980A/en not_active Expired - Lifetime
-
1994
- 1994-08-18 SG SG9608658A patent/SG79914A1/en unknown
- 1994-08-18 WO PCT/US1994/009596 patent/WO1995008011A1/en active IP Right Grant
- 1994-08-18 EP EP94927951A patent/EP0668943B1/en not_active Expired - Lifetime
- 1994-08-18 DE DE69415493T patent/DE69415493T2/de not_active Expired - Lifetime
- 1994-08-18 CA CA002148487A patent/CA2148487C/en not_active Expired - Fee Related
- 1994-08-18 JP JP50919695A patent/JP3456483B2/ja not_active Expired - Lifetime
- 1994-08-18 BR BR9405594-7A patent/BR9405594A/pt not_active IP Right Cessation
-
1995
- 1995-05-15 FI FI952356A patent/FI109812B/fi not_active IP Right Cessation
- 1995-05-16 NO NO19951935A patent/NO310935B1/no unknown
Also Published As
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---|---|
NO951935L (no) | 1995-05-16 |
FI952356A0 (fi) | 1995-05-15 |
EP0668943A1 (en) | 1995-08-30 |
NO951935D0 (no) | 1995-05-16 |
FI952356A (fi) | 1995-05-15 |
SG79914A1 (en) | 2001-04-17 |
DE69415493D1 (de) | 1999-02-04 |
CA2148487C (en) | 2006-08-15 |
WO1995008011A1 (en) | 1995-03-23 |
EP0668943B1 (en) | 1998-12-23 |
BR9405594A (pt) | 1999-09-08 |
NO310935B1 (no) | 2001-09-17 |
DE69415493T2 (de) | 1999-09-02 |
JPH08503274A (ja) | 1996-04-09 |
US5447980A (en) | 1995-09-05 |
JP3456483B2 (ja) | 2003-10-14 |
CA2148487A1 (en) | 1995-03-23 |
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