FI109812B - Stabiloitu polyamidisäie, seos ja menetelmä säikeiden stabiloimiseksi sekä stabiloitu seos - Google Patents

Stabiloitu polyamidisäie, seos ja menetelmä säikeiden stabiloimiseksi sekä stabiloitu seos Download PDF

Info

Publication number: FI109812B
Authority: FI; Finland
Prior art keywords: functionalized; synergist; stabilizer; copper; stabilized
Prior art date: 1993-09-16

Application number

FI952356A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI952356A0 (fi

FI952356A (fi

Inventor

Mark G Reichmann

Original Assignee

Solvay Advanced Polymers Llc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-09-16

Filing date

1995-05-15

Publication date

2002-10-15

1995-05-15 Application filed by Solvay Advanced Polymers Llc filed Critical Solvay Advanced Polymers Llc

1995-05-15 Publication of FI952356A0 publication Critical patent/FI952356A0/fi

1995-05-15 Publication of FI952356A publication Critical patent/FI952356A/fi

2002-10-15 Application granted granted Critical

2002-10-15 Publication of FI109812B publication Critical patent/FI109812B/fi

Links

239000004952 Polyamide Substances 0.000 title claims description 34
229920002647 polyamide Polymers 0.000 title claims description 34
238000000034 method Methods 0.000 title claims description 17
230000000087 stabilizing effect Effects 0.000 title claims description 13
239000000956 alloy Substances 0.000 title claims description 8
229910045601 alloy Inorganic materials 0.000 title claims description 8
239000003381 stabilizer Substances 0.000 claims description 52
-1 copper (I) halide Chemical class 0.000 claims description 45
239000000203 mixture Substances 0.000 claims description 35
239000010949 copper Substances 0.000 claims description 34
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical class [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 34
239000004954 Polyphthalamide Substances 0.000 claims description 32
239000000835 fiber Substances 0.000 claims description 32
229920006375 polyphtalamide Polymers 0.000 claims description 32
229910052802 copper Inorganic materials 0.000 claims description 31
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 29
229920000098 polyolefin Polymers 0.000 claims description 27
238000004519 manufacturing process Methods 0.000 claims description 18
239000004698 Polyethylene Substances 0.000 claims description 13
229920000573 polyethylene Polymers 0.000 claims description 13
239000004743 Polypropylene Substances 0.000 claims description 12
229920000642 polymer Polymers 0.000 claims description 12
229920001155 polypropylene Polymers 0.000 claims description 12
229920002943 EPDM rubber Polymers 0.000 claims description 11
235000007715 potassium iodide Nutrition 0.000 claims description 11
229910001508 alkali metal halide Inorganic materials 0.000 claims description 9
150000008045 alkali metal halides Chemical class 0.000 claims description 9
229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 9
150000001408 amides Chemical class 0.000 claims description 8
238000002074 melt spinning Methods 0.000 claims description 7
229920001897 terpolymer Polymers 0.000 claims description 7
230000006641 stabilisation Effects 0.000 claims description 6
238000011105 stabilization Methods 0.000 claims description 6
239000005749 Copper compound Substances 0.000 claims description 5
VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 claims description 5
150000001880 copper compounds Chemical class 0.000 claims description 5
229910052783 alkali metal Inorganic materials 0.000 claims description 3
150000001336 alkenes Chemical class 0.000 claims description 3
238000009950 felting Methods 0.000 claims description 3
150000004820 halides Chemical class 0.000 claims description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
239000005977 Ethylene Substances 0.000 claims description 2
150000001340 alkali metals Chemical class 0.000 claims description 2
150000001993 dienes Chemical class 0.000 claims description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
229910021595 Copper(I) iodide Inorganic materials 0.000 claims 7
LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 claims 3
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 2
150000004694 iodide salts Chemical class 0.000 claims 2
238000010276 construction Methods 0.000 claims 1
WCCJDBZJUYKDBF-UHFFFAOYSA-N copper silicon Chemical compound [Si].[Cu] WCCJDBZJUYKDBF-UHFFFAOYSA-N 0.000 claims 1
239000003517 fume Substances 0.000 claims 1
239000000178 monomer Substances 0.000 claims 1
210000000653 nervous system Anatomy 0.000 claims 1
230000002195 synergetic effect Effects 0.000 claims 1
230000002463 transducing effect Effects 0.000 claims 1
230000000052 comparative effect Effects 0.000 description 13
229920005989 resin Polymers 0.000 description 11
239000011347 resin Substances 0.000 description 11
239000000126 substance Substances 0.000 description 8
238000001125 extrusion Methods 0.000 description 7
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
239000010408 film Substances 0.000 description 6
239000000654 additive Substances 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
239000003623 enhancer Substances 0.000 description 5
238000009987 spinning Methods 0.000 description 5
238000012360 testing method Methods 0.000 description 5
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
229920003231 aliphatic polyamide Polymers 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
230000000694 effects Effects 0.000 description 4
230000014759 maintenance of location Effects 0.000 description 4
238000002844 melting Methods 0.000 description 4
230000008018 melting Effects 0.000 description 4
239000004953 Aliphatic polyamide Substances 0.000 description 3
229920002633 Kraton (polymer) Polymers 0.000 description 3
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 3
229920003182 Surlyn® Polymers 0.000 description 3
230000015556 catabolic process Effects 0.000 description 3
238000006731 degradation reaction Methods 0.000 description 3
150000004985 diamines Chemical class 0.000 description 3
PZRHRDRVRGEVNW-UHFFFAOYSA-N milrinone Chemical compound N1C(=O)C(C#N)=CC(C=2C=CN=CC=2)=C1C PZRHRDRVRGEVNW-UHFFFAOYSA-N 0.000 description 3
229960003574 milrinone Drugs 0.000 description 3
229920001778 nylon Polymers 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 3
229950011008 tetrachloroethylene Drugs 0.000 description 3
FQLAJSQGBDYBAL-UHFFFAOYSA-N 3-(azepane-1-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2CCCCCC2)=C1 FQLAJSQGBDYBAL-UHFFFAOYSA-N 0.000 description 2
PGGROMGHWHXWJL-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide Chemical group C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 PGGROMGHWHXWJL-UHFFFAOYSA-N 0.000 description 2
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
230000032683 aging Effects 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
229920003233 aromatic nylon Polymers 0.000 description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 2
230000007547 defect Effects 0.000 description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
239000000155 melt Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000000465 moulding Methods 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
239000008188 pellet Substances 0.000 description 2
230000002035 prolonged effect Effects 0.000 description 2
239000012925 reference material Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
230000035882 stress Effects 0.000 description 2
DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical group NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
CYMRPDYINXWJFU-UHFFFAOYSA-N 2-carbamoylbenzoic acid Chemical class NC(=O)C1=CC=CC=C1C(O)=O CYMRPDYINXWJFU-UHFFFAOYSA-N 0.000 description 1
DARJESXGWBVEBK-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide;benzene-1,3-dicarboxamide;hexanediamide Chemical compound NC(=O)CCCCC(N)=O.NC(=O)C1=CC=CC(C(N)=O)=C1.C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 DARJESXGWBVEBK-UHFFFAOYSA-N 0.000 description 1
LJAQBTOSXLZLBM-UHFFFAOYSA-N 4-(piperidine-1-carbonyl)benzamide Chemical group C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCC1 LJAQBTOSXLZLBM-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
239000004956 Amodel Substances 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
229910000881 Cu alloy Inorganic materials 0.000 description 1
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
238000003723 Smelting Methods 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
230000002159 abnormal effect Effects 0.000 description 1
125000002015 acyclic group Chemical group 0.000 description 1
230000002411 adverse Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
239000003513 alkali Substances 0.000 description 1
239000004760 aramid Substances 0.000 description 1
229920003235 aromatic polyamide Polymers 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
150000001649 bromium compounds Chemical class 0.000 description 1
ODWXUNBKCRECNW-UHFFFAOYSA-M bromocopper(1+) Chemical compound Br[Cu+] ODWXUNBKCRECNW-UHFFFAOYSA-M 0.000 description 1
PUEVFCCOBZIVDO-FJOGWHKWSA-N buta-1,3-diene (Z)-but-2-enedioic acid styrene Chemical compound C=CC=C.C=Cc1ccccc1.OC(=O)\C=C/C(O)=O PUEVFCCOBZIVDO-FJOGWHKWSA-N 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000003776 cleavage reaction Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
ZKXWKVVCCTZOLD-UHFFFAOYSA-N copper;4-hydroxypent-3-en-2-one Chemical compound [Cu].CC(O)=CC(C)=O.CC(O)=CC(C)=O ZKXWKVVCCTZOLD-UHFFFAOYSA-N 0.000 description 1
229930003836 cresol Natural products 0.000 description 1
QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
VDBXLXRWMYNMHL-UHFFFAOYSA-N decanediamide Chemical compound NC(=O)CCCCCCCCC(N)=O VDBXLXRWMYNMHL-UHFFFAOYSA-N 0.000 description 1
230000000911 decarboxylating effect Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
125000004427 diamine group Chemical group 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000010035 extrusion spinning Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000012760 heat stabilizer Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
150000002430 hydrocarbons Chemical group 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
QZUPTXGVPYNUIT-UHFFFAOYSA-N isophthalamide Chemical compound NC(=O)C1=CC=CC(C(N)=O)=C1 QZUPTXGVPYNUIT-UHFFFAOYSA-N 0.000 description 1
239000004571 lime Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
JXRWDHUZHAWOLC-UHFFFAOYSA-N naphthalene-1,2-dicarboxamide Chemical compound C1=CC=CC2=C(C(N)=O)C(C(=O)N)=CC=C21 JXRWDHUZHAWOLC-UHFFFAOYSA-N 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
NAYYNDKKHOIIOD-UHFFFAOYSA-N phthalamide Chemical compound NC(=O)C1=CC=CC=C1C(N)=O NAYYNDKKHOIIOD-UHFFFAOYSA-N 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
239000011342 resin composition Substances 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
230000007017 scission Effects 0.000 description 1
FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical class [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 1
235000009518 sodium iodide Nutrition 0.000 description 1
229940014800 succinic anhydride Drugs 0.000 description 1
238000009864 tensile test Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000004753 textile Substances 0.000 description 1
229920006345 thermoplastic polyamide Polymers 0.000 description 1
239000010409 thin film Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Artificial Filaments (AREA)
Compositions Of Macromolecular Compounds (AREA)

FI952356A 1993-09-16 1995-05-15 Stabiloitu polyamidisäie, seos ja menetelmä säikeiden stabiloimiseksi sekä stabiloitu seos FI109812B (fi)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US12236793		1993-09-16
US08/122,367 US5447980A (en)	1993-09-16	1993-09-16	Stabilized polyamide fiber
US9409596		1994-08-18
PCT/US1994/009596 WO1995008011A1 (en)	1993-09-16	1994-08-18	Stabilized polyamide fiber

Publications (3)

Publication Number	Publication Date
FI952356A0 FI952356A0 (fi)	1995-05-15
FI952356A FI952356A (fi)	1995-05-15
FI109812B true FI109812B (fi)	2002-10-15

Family

ID=22402286

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI952356A FI109812B (fi)	1993-09-16	1995-05-15	Stabiloitu polyamidisäie, seos ja menetelmä säikeiden stabiloimiseksi sekä stabiloitu seos

Country Status (10)

Country	Link
US (1)	US5447980A (no)
EP (1)	EP0668943B1 (no)
JP (1)	JP3456483B2 (no)
BR (1)	BR9405594A (no)
CA (1)	CA2148487C (no)
DE (1)	DE69415493T2 (no)
FI (1)	FI109812B (no)
NO (1)	NO310935B1 (no)
SG (1)	SG79914A1 (no)
WO (1)	WO1995008011A1 (no)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5585429A (en) *	1995-03-27	1996-12-17	Amoco Corporation	Polyphthalamide resin formulations
US5763561A (en) *	1996-09-06	1998-06-09	Amoco Corporation	Polyamide compositions having improved thermal stability
JP2000319508A (ja) *	1999-05-13	2000-11-21	Toyobo Co Ltd	ポリアミド樹脂組成物
DE60006968T2 (de) *	1999-06-18	2004-10-21	Solvay Advanced Polymers Llc	Verfahren zur verringerung der bildung von formablagerungen während des formens von polyamiden und deren zusammensetzungen
EP1554762B2 (en) *	2002-10-15	2014-04-30	Solvay Specialty Polymers USA, LLC.	Anti-yellowing polycondensation polymer compositions and articles
CA2535344C (en) *	2003-08-19	2015-10-06	Solvay Advanced Polymers, L.L.C.	Impact-modified polyamide hollow body
US20050197452A1 (en) *	2004-02-27	2005-09-08	Solvay Advanced Polymers, Llc	Safety equipment comprising an aromatic polyamide composition, and aromatic polyamide composition
DE102004022963A1 (de) *	2004-05-10	2005-12-08	Ems-Chemie Ag	Thermoplastische Polyamid-Formmassen
US20070245924A1 (en) *	2006-04-20	2007-10-25	Hofmann Michael A	Reduced abrasion of titanium dioxide pigments produced from the chloride process
DE102007038578A1 (de)	2007-08-16	2009-02-19	Evonik Degussa Gmbh	Verfahren zur Dekorierung von Oberflächen
DE102010030212A1 (de) *	2010-06-17	2011-12-22	Robert Bosch Gmbh	Stabilisatorzusammensetzung für Polyamide
DE102010042131A1 (de)	2010-10-07	2012-04-12	Evonik Degussa Gmbh	Mit Polyphthalamid-Fasern verstärkter Gummikörper
DE102010051310A1 (de)	2010-11-16	2012-05-16	Thüringisches Institut für Textil- und Kunststoff-Forschung e.V.	Verfahren zur Herstellung von Polyamidzusammensetzungen mit verbesserten thermooxidativen, antibakteriellen, licht- oder energieaktiven Eigenschaften
DE102011007196A1 (de)	2011-04-12	2012-10-18	Evonik Degussa Gmbh	Verfahren zur Herstellung eines Verbundes aus einem Polyamidformteil und einem Methacrylatcopolymer-Formteil
CN104039878A (zh)	2011-11-08	2014-09-10	索尔维特殊聚合物美国有限责任公司	用于井下原油部件的高耐热性聚酰胺
CN105849325B (zh) *	2014-01-08	2018-07-06	旭化成株式会社	聚酰胺复丝纤维和包含该纤维的轮胎帘线
JP6282903B2 (ja) *	2014-03-14	2018-02-21	ユニチカ株式会社	モノフィラメント
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1993
- 1993-09-16 US US08/122,367 patent/US5447980A/en not_active Expired - Lifetime
1994
- 1994-08-18 SG SG9608658A patent/SG79914A1/en unknown
- 1994-08-18 WO PCT/US1994/009596 patent/WO1995008011A1/en active IP Right Grant
- 1994-08-18 EP EP94927951A patent/EP0668943B1/en not_active Expired - Lifetime
- 1994-08-18 DE DE69415493T patent/DE69415493T2/de not_active Expired - Lifetime
- 1994-08-18 CA CA002148487A patent/CA2148487C/en not_active Expired - Fee Related
- 1994-08-18 JP JP50919695A patent/JP3456483B2/ja not_active Expired - Lifetime
- 1994-08-18 BR BR9405594-7A patent/BR9405594A/pt not_active IP Right Cessation
1995
- 1995-05-15 FI FI952356A patent/FI109812B/fi not_active IP Right Cessation
- 1995-05-16 NO NO19951935A patent/NO310935B1/no unknown

Also Published As

Publication number	Publication date
NO951935L (no)	1995-05-16
FI952356A0 (fi)	1995-05-15
EP0668943A1 (en)	1995-08-30
NO951935D0 (no)	1995-05-16
FI952356A (fi)	1995-05-15
SG79914A1 (en)	2001-04-17
DE69415493D1 (de)	1999-02-04
CA2148487C (en)	2006-08-15
WO1995008011A1 (en)	1995-03-23
EP0668943B1 (en)	1998-12-23
BR9405594A (pt)	1999-09-08
NO310935B1 (no)	2001-09-17
DE69415493T2 (de)	1999-09-02
JPH08503274A (ja)	1996-04-09
US5447980A (en)	1995-09-05
JP3456483B2 (ja)	2003-10-14
CA2148487A1 (en)	1995-03-23

Legal Events

Date	Code	Title	Description
2008-02-29	MA	Patent expired

Publication	Publication Date	Title
FI109812B (fi)	2002-10-15	Stabiloitu polyamidisäie, seos ja menetelmä säikeiden stabiloimiseksi sekä stabiloitu seos
EP0839862B1 (en)	2001-09-05	Heat-aging-resistant polyamide resin composition and fiber comprising the same
JPS6224456B2 (no)	1987-05-28
EP0572267B1 (en)	1997-09-17	Polypropylene-copolyphthalamide blends
EP0934979A2 (en)	1999-08-11	Partly aromatic polyamide resins compositions
US20040087734A1 (en)	2004-05-06	Polyamide compositions with improved antistatic and hydrophilic properties
US3554980A (en)	1971-01-12	Method for preventing stickiness of fibres consisting of or comprising copolyamide
CA1297216C (en)	1992-03-10	Fibres and yarns from a blend of aromatic polyamides
JP2002053761A (ja)	2002-02-19	熱可塑性樹脂組成物
US4801633A (en)	1989-01-31	Salt resistant polyamide composition
US3669917A (en)	1972-06-13	Copolyamide fibers of reduced stickiness containing a normal paraffin
JPH06207099A (ja)	1994-07-26	熱可塑性成形材料
EP0735082B1 (en)	2004-05-26	Polyphthalamide resin compositions
WO1993000404A1 (en)	1993-01-07	Flexible polyamide film
JPS6364469B2 (no)	1988-12-12
JPS5853953A (ja)	1983-03-30	炭化水素系重合体組成物
JPH04370130A (ja)	1992-12-22	エチレン−酢酸ビニル共重合体ケン化物系組成物の製造法
JPH0770822A (ja)	1995-03-14	ポリアミド系ポリマーアロイ繊維
JPH05209311A (ja)	1993-08-20	ポリプロピレン系繊維
JPS584738B2 (ja)	1983-01-27	ポリアミドジユシソセイブツ
JPS6365709B2 (no)	1988-12-16
JPS58173155A (ja)	1983-10-12	ポリアミド樹脂組成物
JP2976859B2 (ja)	1999-11-10	難燃性ナイロン樹脂組成物
JPH1060268A (ja)	1998-03-03	ポリアミド樹脂組成物
JP4725144B2 (ja)	2011-07-13	抄紙プレスフェルト基布