ES8206411A1 - Procedimiento de preparacion de derivados 11-dodecen-1-ilos - Google Patents
Procedimiento de preparacion de derivados 11-dodecen-1-ilosInfo
- Publication number
- ES8206411A1 ES8206411A1 ES506524A ES506524A ES8206411A1 ES 8206411 A1 ES8206411 A1 ES 8206411A1 ES 506524 A ES506524 A ES 506524A ES 506524 A ES506524 A ES 506524A ES 8206411 A1 ES8206411 A1 ES 8206411A1
- Authority
- ES
- Spain
- Prior art keywords
- compound
- formula
- ester
- dodecen
- acetoxyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- QNXYZQSFDTZEBK-UHFFFAOYSA-N dodec-11-en-1-ol Chemical compound OCCCCCCCCCCC=C QNXYZQSFDTZEBK-UHFFFAOYSA-N 0.000 title 2
- 150000001875 compounds Chemical class 0.000 abstract 4
- 238000006243 chemical reaction Methods 0.000 abstract 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 229960003328 benzoyl peroxide Drugs 0.000 abstract 2
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical group [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/313—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of doubly bound oxygen containing functional groups, e.g. carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION DE DERIVADOS 11-DODECEN-1-ILOS DE FORMULA CH2=CH-(CH2)9-CH2-R, EN LA QUE R ES HIDROXILO O ACETOXILO. CONSISTE EN LA REACCION DE UN ACIDO DE FORMULA HAL-CH2-(CH2)9-COCH, EN LA QUE HAL ES HALOGENO CON UNA BASE, SEGUIDA DE LA REACCION CON UN ALCOHOL C1-4, EN PRESENCIA DE UN ACIDO COMO CATALIZADOR; OXIDACION DEL ESTER FORMADO AL ESTER DE FORMULA OCH-(CH2)9-COOR1, EN LA QUE R1 ES UN ALQUILO C1-4; CONVERSION DE ESTE EN EL COMPUESTO CH2=CH-(CH2)9COOR1 Y REDUCCION DEL ESTER SIGUIENDO METODOS CONVENCIONALES, CON LO QUE SE OBTIENE EL COMPUESTO EN EL QUE R ES HIDROXILO. POR ACILACION DE ESTE SE OBTIENE EL COMPUESTO EN QUE R ES ACETOXILO. ESTOS COMPUESTOS TIENE APLICACIONES EN AGRICULTURA, EN LA PROTECCION VEGETAL INTEGRADA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HU80802575A HU180386B (en) | 1980-10-24 | 1980-10-24 | Process for producing 11-dodecen-1-ol and 11-dodecen-1-yl-acetate of insect-feromone activity |
Publications (2)
Publication Number | Publication Date |
---|---|
ES506524A0 ES506524A0 (es) | 1982-08-16 |
ES8206411A1 true ES8206411A1 (es) | 1982-08-16 |
Family
ID=10960083
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES506524A Expired ES8206411A1 (es) | 1980-10-24 | 1981-10-23 | Procedimiento de preparacion de derivados 11-dodecen-1-ilos |
Country Status (11)
Country | Link |
---|---|
BE (1) | BE890748A (es) |
DE (1) | DE3142114A1 (es) |
ES (1) | ES8206411A1 (es) |
FR (1) | FR2492816A1 (es) |
GB (1) | GB2085881A (es) |
GR (1) | GR74694B (es) |
HU (1) | HU180386B (es) |
IT (1) | IT1139272B (es) |
PT (1) | PT73870B (es) |
RO (1) | RO82277A (es) |
YU (1) | YU252981A (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4560792A (en) * | 1982-07-20 | 1985-12-24 | Phillips Petroleum Company | Disproportionation of functional olefins |
DE3815044A1 (de) * | 1988-05-04 | 1989-11-16 | Basf Ag | 1-tert.-butoxy-(omega)-alkene und deren verwendung als riechstoffe |
DK2967033T3 (da) | 2013-03-13 | 2019-11-18 | Stepan Co | Overfladeaktive midler baseret på monoumættede fedtalkoholderivater |
HUE063333T2 (hu) * | 2015-11-18 | 2024-01-28 | Provivi Inc | Zsíros olefinszármazékok elõállítása olefin-metatézisen keresztül |
WO2018150379A2 (en) | 2017-02-17 | 2018-08-23 | Provivi, Inc. | Synthesis of pheromones and related materials via olefin metathesis |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1096345B (de) * | 1959-02-28 | 1961-01-05 | Bayer Ag | Verfahren zur Herstellung von Hexadecadien-(10, 12)-ol-(1) |
CA961862A (en) * | 1971-04-23 | 1975-01-28 | Andre Comeau | Trans-8-trans-10-dodecadien-1-o1 |
-
1980
- 1980-10-24 HU HU80802575A patent/HU180386B/hu unknown
-
1981
- 1981-10-16 BE BE1/10334A patent/BE890748A/fr not_active IP Right Cessation
- 1981-10-22 IT IT24627/81A patent/IT1139272B/it active
- 1981-10-23 GR GR66339A patent/GR74694B/el unknown
- 1981-10-23 GB GB8132023A patent/GB2085881A/en not_active Withdrawn
- 1981-10-23 PT PT73870A patent/PT73870B/pt unknown
- 1981-10-23 ES ES506524A patent/ES8206411A1/es not_active Expired
- 1981-10-23 YU YU02529/81A patent/YU252981A/xx unknown
- 1981-10-23 DE DE19813142114 patent/DE3142114A1/de not_active Withdrawn
- 1981-10-23 FR FR8119930A patent/FR2492816A1/fr active Pending
- 1981-11-19 RO RO81105823A patent/RO82277A/ro unknown
Also Published As
Publication number | Publication date |
---|---|
PT73870B (en) | 1983-01-25 |
IT8124627A0 (it) | 1981-10-22 |
RO82277A (ro) | 1983-09-26 |
GR74694B (es) | 1984-07-04 |
HU180386B (en) | 1983-02-28 |
DE3142114A1 (de) | 1982-06-16 |
ES506524A0 (es) | 1982-08-16 |
BE890748A (fr) | 1982-04-16 |
PT73870A (en) | 1981-11-01 |
FR2492816A1 (fr) | 1982-04-30 |
YU252981A (en) | 1983-10-31 |
RO82277B (ro) | 1983-08-30 |
GB2085881A (en) | 1982-05-06 |
IT1139272B (it) | 1986-09-24 |
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