ES2422382T3 - Un procedimiento para la preparación de ácido metacrílico o ésteres del ácido metacrílico - Google Patents
Un procedimiento para la preparación de ácido metacrílico o ésteres del ácido metacrílicoInfo
- Publication number
- ES2422382T3 ES2422382T3 ES08760294T ES08760294T ES2422382T3 ES 2422382 T3 ES2422382 T3 ES 2422382T3 ES 08760294 T ES08760294 T ES 08760294T ES 08760294 T ES08760294 T ES 08760294T ES 2422382 T3 ES2422382 T3 ES 2422382T3
- Authority
- ES
- Spain
- Prior art keywords
- acid
- hydroxyisobutyric acid
- methacrylic acid
- hydroxyisobutyric
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/42—Hydroxy-carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/04—Acids; Metal salts or ammonium salts thereof
- C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/0004—Oxidoreductases (1.)
- C12N9/0008—Oxidoreductases (1.) acting on the aldehyde or oxo group of donors (1.2)
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/0004—Oxidoreductases (1.)
- C12N9/001—Oxidoreductases (1.) acting on the CH-CH group of donors (1.3)
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/10—Transferases (2.)
- C12N9/1096—Transferases (2.) transferring nitrogenous groups (2.6)
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/14—Hydrolases (3)
- C12N9/16—Hydrolases (3) acting on ester bonds (3.1)
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/88—Lyases (4.)
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/52—Propionic acid; Butyric acids
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/62—Carboxylic acid esters
- C12P7/625—Polyesters of hydroxy carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12Y—ENZYMES
- C12Y102/00—Oxidoreductases acting on the aldehyde or oxo group of donors (1.2)
- C12Y102/04—Oxidoreductases acting on the aldehyde or oxo group of donors (1.2) with a disulfide as acceptor (1.2.4)
- C12Y102/04004—3-Methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring) (1.2.4.4), i.e. branched-chain-alpha-ketoacid dehydrogenase
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12Y—ENZYMES
- C12Y103/00—Oxidoreductases acting on the CH-CH group of donors (1.3)
- C12Y103/99—Oxidoreductases acting on the CH-CH group of donors (1.3) with other acceptors (1.3.99)
- C12Y103/99012—2-Methylacyl-CoA dehydrogenase (1.3.99.12)
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12Y—ENZYMES
- C12Y206/00—Transferases transferring nitrogenous groups (2.6)
- C12Y206/01—Transaminases (2.6.1)
- C12Y206/01042—Branched-chain-amino-acid transaminase (2.6.1.42)
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12Y—ENZYMES
- C12Y301/00—Hydrolases acting on ester bonds (3.1)
- C12Y301/02—Thioester hydrolases (3.1.2)
- C12Y301/02004—3-Hydroxyisobutyryl-CoA hydrolase (3.1.2.4)
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12Y—ENZYMES
- C12Y402/00—Carbon-oxygen lyases (4.2)
- C12Y402/01—Hydro-lyases (4.2.1)
- C12Y402/01017—Enoyl-CoA hydratase (4.2.1.17), i.e. crotonase
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Genetics & Genomics (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Molecular Biology (AREA)
- Biomedical Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un procedimiento para la preparación de ácido metacrílico o ésteres del ácido metacrílico, que comprende lasetapas de procedimiento IA) preparación de ácido 3-hidroxiisobutírico mediante un procedimiento que comprende la etapa deprocedimiento de la puesta en contacto de una célula que fue modificada por tecnología genética conrespecto a su tipo salvaje, de modo que, en comparación con su tipo salvaje, es capaz de formar más ácido3-hidroxiisobutírico o polihidroxialcanoatos basados en ácido 3-hidroxiisobutírico, con un medio nutricio quecontiene como fuente de carbono hidratos de carbono, glicerol, dióxido de carbono, metano, metanol, Lvalinao L-glutamato, bajo condiciones en las que a partir de la fuente de carbono se forman ácido 3-hidroxiisobutírico o polihidroxialcanoatos basados en ácido 3-hidroxiisobutírico, eventual purificación delácido 3-hidroxiisobutírico a partir del medio nutricio, así como, eventualmente, neutralización del ácido 3-hidroxiisobutírico, IB) deshidratación del ácido 3-hidroxiisobutírico bajo formación de ácido metacrílico, así como, eventualmente,esterificación del ácido metacrílico, en el que 1) la formación de ácido 3-hidroxiisobutírico o polihidroxialcanoatos basados enácido 3-hidroxiisobutírico tiene lugar a través de metilmalonato-semiladehídoen calidad de producto previo.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006025821A DE102006025821A1 (de) | 2006-06-02 | 2006-06-02 | Ein Enzym zur Herstellung von Mehylmalonatsemialdehyd oder Malonatsemialdehyd |
PCT/EP2007/055394 WO2007141208A2 (de) | 2006-06-02 | 2007-06-01 | Mikrobiologische herstellung von 3-hydroxyisobuttersäure |
PCT/EP2008/056707 WO2008145737A1 (de) | 2007-06-01 | 2008-05-30 | Ein verfahren zur herstellung von methacrylsäure oder methacrylsäureestern |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2422382T3 true ES2422382T3 (es) | 2013-09-11 |
Family
ID=38650473
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES08760294T Active ES2422382T3 (es) | 2006-06-02 | 2008-05-30 | Un procedimiento para la preparación de ácido metacrílico o ésteres del ácido metacrílico |
Country Status (11)
Country | Link |
---|---|
US (3) | US20100068773A1 (es) |
CN (1) | CN101563465B (es) |
AU (1) | AU2007255500A1 (es) |
BR (2) | BRPI0713092A2 (es) |
CA (1) | CA2654133A1 (es) |
DE (2) | DE102006025821A1 (es) |
ES (1) | ES2422382T3 (es) |
HK (1) | HK1137486A1 (es) |
RU (1) | RU2008151951A (es) |
WO (1) | WO2007141208A2 (es) |
ZA (1) | ZA200810206B (es) |
Families Citing this family (94)
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DE102006017760A1 (de) * | 2006-03-24 | 2007-09-27 | Ufz-Umweltforschungszentrum Leipzig-Halle Gmbh | Verfahren zur enzymatischen Herstellung von 2-Hydroxy-2-methylcarbonsäuren |
WO2008115840A2 (en) | 2007-03-16 | 2008-09-25 | Genomatica, Inc. | Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors |
DE102007015583A1 (de) * | 2007-03-29 | 2008-10-02 | Albert-Ludwigs-Universität Freiburg | Ein Enzym zur Herstellung von Methylmalonyl-Coenzym A oder Ethylmalonyl-Coenzym A sowie dessen Verwendung |
DE102007052463A1 (de) * | 2007-11-02 | 2009-05-07 | Evonik Degussa Gmbh | Fermentative Gewinnung von Aceton aus erneuerbaren Rohstoffen mittels neuen Stoffwechselweges |
DE102007060705A1 (de) * | 2007-12-17 | 2009-06-18 | Evonik Degussa Gmbh | ω-Aminocarbonsäuren oder ihre Lactame, herstellende, rekombinante Zellen |
CN101978042B (zh) | 2008-01-22 | 2017-03-08 | 基因组股份公司 | 利用合成气或其它气态碳源和甲醇的方法和有机体 |
US7977084B2 (en) | 2008-03-05 | 2011-07-12 | Genomatica, Inc. | Primary alcohol producing organisms |
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DE102008002715A1 (de) * | 2008-06-27 | 2009-12-31 | Evonik Röhm Gmbh | 2-Hydroxyisobuttersäure produzierende rekombinante Zelle |
DE102008040193A1 (de) | 2008-07-04 | 2010-01-07 | Evonik Röhm Gmbh | Verfahren zur Herstellung freier Carbonsäuren |
DE102008040415A1 (de) | 2008-07-15 | 2010-01-21 | Evonik Röhm Gmbh | Thermisches Salzspalten von Ammoniumcarboxylaten |
WO2010030711A2 (en) | 2008-09-10 | 2010-03-18 | Genomatica, Inc. | Microorganisms for the production of 1,4-butanediol |
DE102009009580A1 (de) | 2009-02-19 | 2010-08-26 | Evonik Degussa Gmbh | Verfahren zur Herstellung freier Säuren aus ihren Salzen |
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KR102036265B1 (ko) | 2009-05-07 | 2019-10-24 | 게노마티카 인코포레이티드 | 아디페이트, 헥사메틸렌디아민 및 6-아미노카프로산의 생합성을 위한 미생물 및 방법 |
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CN102625845A (zh) | 2009-09-09 | 2012-08-01 | 基因组股份公司 | 协同产生异丙醇与伯醇,二元醇和酸的微生物和方法 |
DE102009029651A1 (de) | 2009-09-22 | 2011-03-24 | Evonik Röhm Gmbh | Verfahren zur Herstellung freier Carbonsäuren |
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DE102009046626A1 (de) | 2009-11-11 | 2011-05-12 | Evonik Degussa Gmbh | Candida tropicalis Zellen und deren Verwendung |
DE102009046623A1 (de) | 2009-11-11 | 2011-05-12 | Evonik Röhm Gmbh | Verwendung eines zu einem MeaB-Protein homologen Proteins zur Erhöhung der enzymatischen Aktivität einer 3-Hydroxycarbonsäure-CoA-Mutase |
DE102010014680A1 (de) | 2009-11-18 | 2011-08-18 | Evonik Degussa GmbH, 45128 | Zellen, Nukleinsäuren, Enzyme und deren Verwendung sowie Verfahren zur Herstellung von Sophorolipiden |
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-
2006
- 2006-06-02 DE DE102006025821A patent/DE102006025821A1/de not_active Withdrawn
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2007
- 2007-06-01 WO PCT/EP2007/055394 patent/WO2007141208A2/de active Application Filing
- 2007-06-01 US US12/303,161 patent/US20100068773A1/en not_active Abandoned
- 2007-06-01 BR BRPI0713092-9A patent/BRPI0713092A2/pt not_active IP Right Cessation
- 2007-06-01 AU AU2007255500A patent/AU2007255500A1/en not_active Abandoned
- 2007-06-01 DE DE112007001307T patent/DE112007001307A5/de not_active Withdrawn
- 2007-06-01 RU RU2008151951/10A patent/RU2008151951A/ru not_active Application Discontinuation
- 2007-06-01 CA CA002654133A patent/CA2654133A1/en not_active Abandoned
- 2007-06-01 CN CN2007800279107A patent/CN101563465B/zh not_active Expired - Fee Related
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2008
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2015
- 2015-02-18 US US14/624,713 patent/US20150218601A1/en not_active Abandoned
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DE102006025821A1 (de) | 2007-12-06 |
US20100068773A1 (en) | 2010-03-18 |
US20100291644A1 (en) | 2010-11-18 |
US20150218601A1 (en) | 2015-08-06 |
RU2008151951A (ru) | 2010-07-20 |
WO2007141208A3 (de) | 2008-03-20 |
BRPI0812487A2 (pt) | 2019-07-16 |
ZA200810206B (en) | 2009-09-30 |
CN101563465A (zh) | 2009-10-21 |
BRPI0713092A2 (pt) | 2012-10-16 |
HK1137486A1 (en) | 2010-07-30 |
DE112007001307A5 (de) | 2009-04-30 |
CA2654133A1 (en) | 2007-12-13 |
AU2007255500A1 (en) | 2007-12-13 |
CN101563465B (zh) | 2013-09-18 |
WO2007141208A2 (de) | 2007-12-13 |
US9234218B2 (en) | 2016-01-12 |
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