ES2154990B1 - Nuevos colorantes de quinolinio y boratos en composiciones fotopolimerizables. - Google Patents
Nuevos colorantes de quinolinio y boratos en composiciones fotopolimerizables.Info
- Publication number
- ES2154990B1 ES2154990B1 ES009802256A ES9802256A ES2154990B1 ES 2154990 B1 ES2154990 B1 ES 2154990B1 ES 009802256 A ES009802256 A ES 009802256A ES 9802256 A ES9802256 A ES 9802256A ES 2154990 B1 ES2154990 B1 ES 2154990B1
- Authority
- ES
- Spain
- Prior art keywords
- sub
- compositions
- boratos
- photopolimerizable
- quinolinio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 QUINOLINIO Chemical class 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- 239000003086 colorant Substances 0.000 title 1
- 239000000975 dye Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/06—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
- C07D215/58—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems with hetero atoms directly attached to the ring nitrogen atom
- C07D215/60—N-oxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/36—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems
- C07D241/50—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems with hetero atoms directly attached to ring nitrogen atoms
- C07D241/52—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/52—Radicals substituted by nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
- C07D307/79—Benzo [b] furans; Hydrogenated benzo [b] furans with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/0091—Methine or polymethine dyes, e.g. cyanine dyes having only one heterocyclic ring at one end of the methine chain, e.g. hemicyamines, hemioxonol
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/10—The polymethine chain containing an even number of >CH- groups
- C09B23/105—The polymethine chain containing an even number of >CH- groups two >CH- groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/14—Styryl dyes
- C09B23/145—Styryl dyes the ethylene chain carrying an heterocyclic residue, e.g. heterocycle-CH=CH-C6H5
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/02—Dyestuff salts, e.g. salts of acid dyes with basic dyes
- C09B69/06—Dyestuff salts, e.g. salts of acid dyes with basic dyes of cationic dyes with organic acids or with inorganic complex acids
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/031—Organic compounds not covered by group G03F7/029
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Optical Filters (AREA)
- Quinoline Compounds (AREA)
Abstract
Estos colorantes corresponden a la fórmula (1), en la que X es, por ejemplo, CH, C-CH{sub, 3} o +NORL-; R es, entre otros, alquilo C{sub, 1}-C{sub, 6}; R{sub, l} es, por ejemplo, alcoxi C{sub, 1}-C{sub, 6} o alquilo C{sub, 1}C{sub, 12}; s es un número de 0 a 4; R{sub, 2} es, por ejemplo, hidrógeno; Ar es, por ejemplo, un grupo (A), (B), (D) o (E); Y es, entre otros, alquilo C{sub, l}-C{sub, 6} o alcoxi C{sub, 1}-C{sub, 6}; en la fórmula (A), r es un número de 0 a 5; en las fórmulas (B) y (E) es un número de 0 a 9, y en la fórmula (D) es un número de 0 a 7; y L es un anión. Los colorantes de la fórmula (I), en combinación con un compuesto dador de electrones, en especial un compuesto borato, son idóneos como fotoiniciadores de la fotopolimerización de composiciones polimerizables por radicales.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97810820 | 1997-11-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2154990A1 ES2154990A1 (es) | 2001-04-16 |
ES2154990B1 true ES2154990B1 (es) | 2001-12-01 |
Family
ID=8230453
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES009802256A Expired - Lifetime ES2154990B1 (es) | 1997-11-03 | 1998-10-28 | Nuevos colorantes de quinolinio y boratos en composiciones fotopolimerizables. |
Country Status (13)
Country | Link |
---|---|
US (1) | US6096794A (es) |
JP (1) | JPH11269210A (es) |
KR (1) | KR19990044967A (es) |
BE (1) | BE1013014A3 (es) |
BR (1) | BR9804736A (es) |
CA (1) | CA2252277A1 (es) |
DE (1) | DE19850139A1 (es) |
ES (1) | ES2154990B1 (es) |
FR (1) | FR2770525B1 (es) |
GB (1) | GB2333777A (es) |
IT (1) | IT1303691B1 (es) |
NL (1) | NL1010465C2 (es) |
TW (1) | TW455616B (es) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000319283A (ja) * | 1999-03-08 | 2000-11-21 | Fuji Photo Film Co Ltd | ボレート化合物、それを含む光重合性組成物及び記録材料 |
US20030092788A1 (en) * | 1999-09-17 | 2003-05-15 | Tigran Galstian | Near infrared sensitive photopolymerizable composition |
JP4188578B2 (ja) * | 2000-06-30 | 2008-11-26 | 富士フイルム株式会社 | 光重合性組成物並びにそれを用いた記録材料及び記録方法 |
JP4156784B2 (ja) | 2000-07-25 | 2008-09-24 | 富士フイルム株式会社 | ネガ型画像記録材料及び画像形成方法 |
JP2002082429A (ja) * | 2000-09-08 | 2002-03-22 | Fuji Photo Film Co Ltd | ネガ型画像記録材料 |
DE10053264A1 (de) * | 2000-10-26 | 2002-05-08 | Orga Kartensysteme Gmbh | Verfahren zum Einschreiben von Daten auf/in Datenträger mittels Laserstrahlung und damit hergestellte Datenträger |
JP4244274B2 (ja) * | 2001-09-27 | 2009-03-25 | 富士フイルム株式会社 | 光重合性組成物及び記録材料 |
TWI246525B (en) * | 2001-11-06 | 2006-01-01 | Wako Pure Chem Ind Ltd | Hybrid onium salt |
DE10160524A1 (de) * | 2001-12-05 | 2003-06-26 | Dyomics Gmbh | Neue Fluoreszenzmarker mit großem Stokes-Shift |
DE10356130A1 (de) | 2003-11-28 | 2005-06-23 | Dyomics Gmbh | Neue Polymethinfarbstoffe auf Cumarin-Basis mit einstellbarem Stokes-Shift |
JP4459091B2 (ja) * | 2004-05-07 | 2010-04-28 | 富士フイルム株式会社 | 染料含有ネガ型硬化性組成物、カラーフィルタおよびその製造方法 |
JP4471101B2 (ja) * | 2004-07-30 | 2010-06-02 | 富士フイルム株式会社 | 平版印刷版原版 |
US7198834B2 (en) * | 2005-03-22 | 2007-04-03 | Hewlett-Packard Development Company, L.P. | Imaging media including interference layer for generating human-readable marking on optical media |
US7270944B2 (en) * | 2005-03-29 | 2007-09-18 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
US20070065623A1 (en) * | 2005-09-21 | 2007-03-22 | Vladek Kasperchik | Laser-imageable coating based on exothermic decomposition |
US20070065749A1 (en) * | 2005-09-21 | 2007-03-22 | Vladek Kasperchik | Radiation-markable coatings for printing and imaging |
US20070086308A1 (en) * | 2005-10-13 | 2007-04-19 | Gore Makarand P | Systems and methods for imaging |
JP2008201913A (ja) * | 2007-02-20 | 2008-09-04 | Fujifilm Corp | 光重合性組成物 |
GB0710331D0 (en) * | 2007-05-30 | 2007-07-11 | Bioquell Uk Ltd | Improved in or relating to methods of decontaminating enclosed spaces |
JP2009079150A (ja) * | 2007-09-26 | 2009-04-16 | Fujifilm Corp | 新規な光重合開始剤、それを用いた顔料分散組成物、着色光硬化性組成物、およびカラーフィルタ |
WO2009097619A1 (en) * | 2008-01-31 | 2009-08-06 | Rohrbacker David A | Molding composition and method using same to form displacements for use in a metal casting process |
JP5452942B2 (ja) * | 2009-01-29 | 2014-03-26 | 東海染工株式会社 | マーキング用インク |
JP5573724B2 (ja) * | 2011-02-18 | 2014-08-20 | Jsr株式会社 | 着色組成物、カラーフィルタ及び表示素子 |
CN107223121B (zh) * | 2014-12-19 | 2020-10-27 | 科思创德国股份有限公司 | 湿稳定的全息介质 |
JP6568218B2 (ja) | 2014-12-23 | 2019-08-28 | ブリヂストン アメリカズ タイヤ オペレーションズ、 エルエルシー | 化学線硬化型高分子混合物、硬化高分子混合物、及び関連するプロセス |
WO2017051182A1 (en) * | 2015-09-25 | 2017-03-30 | Photocentric Limited | Methods for making an object and formulations for use in said methods |
US11097531B2 (en) | 2015-12-17 | 2021-08-24 | Bridgestone Americas Tire Operations, Llc | Additive manufacturing cartridges and processes for producing cured polymeric products by additive manufacturing |
EP3532267B1 (en) | 2016-10-27 | 2023-03-01 | Bridgestone Americas Tire Operations, LLC | Processes for producing cured polymeric products by additive manufacturing |
EP3541793B1 (de) | 2016-11-09 | 2021-03-31 | Covestro Intellectual Property GmbH & Co. KG | Verfahren zur herstellung von triaryl-organoboraten |
CN110177797B (zh) | 2016-11-09 | 2022-09-23 | 科思创德国股份有限公司 | 制备三芳基有机硼酸盐的方法 |
EP3538532B1 (en) | 2016-11-09 | 2020-09-16 | Covestro Intellectual Property GmbH & Co. KG | Process for the manufacturing of triarvl-organo borates |
WO2019113602A1 (en) * | 2017-12-08 | 2019-06-13 | The Regents Of The University Of Colorado | Highly efficient free radical photopolymerizations through enabled dark cure |
WO2020122954A1 (en) * | 2018-12-14 | 2020-06-18 | Hewlett-Packard Development Company, L.P. | Textile printing |
CN111689995B (zh) * | 2020-06-15 | 2023-09-19 | 万华化学集团股份有限公司 | 一种高溶解度的三芳基碳硼酸盐及其制备方法和应用 |
ES2969163T3 (es) * | 2021-02-11 | 2024-05-16 | Xetos Ag | Composición HOE fotopolimerizable |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2850585A1 (de) * | 1978-11-22 | 1980-06-04 | Hoechst Ag | Photopolymerisierbares gemisch |
CA1216998A (en) * | 1980-09-10 | 1987-01-20 | Donald P. Specht | Photopolymerization compositions comprising amine- substituted photosensitizers and n-heterocyclic compounds bearing an n-oxy substituent |
US5057393A (en) * | 1989-07-10 | 1991-10-15 | The Mead Corporation | Dye branched-alkyl borate photoinitiators |
EP0441232A3 (en) * | 1990-02-09 | 1992-10-14 | Basf Aktiengesellschaft | Cationic photopolymerisation process |
DE4103906A1 (de) * | 1991-02-08 | 1992-08-13 | Basf Ag | Verfahren zur kationischen photopolymerisation |
EP0555058B1 (en) * | 1992-02-07 | 1997-05-07 | Toyo Ink Manufacturing Co., Ltd. | (Oxo)sulfonium complex, polymerizable composition containing the complex, and method of polymerizing composition |
US5631307A (en) * | 1994-06-28 | 1997-05-20 | Toyo Ink Manufacturing Co., Ltd. | Photopolymerization initiator composition and photopolymerizable composition |
US5912257A (en) * | 1995-09-06 | 1999-06-15 | The Research Foundation Of State University Of New York | Two-photon upconverting dyes and applications |
TW466256B (en) * | 1995-11-24 | 2001-12-01 | Ciba Sc Holding Ag | Borate photoinitiator compounds and compositions comprising the same |
AU717137B2 (en) * | 1995-11-24 | 2000-03-16 | Ciba Specialty Chemicals Holding Inc. | Borate coinitiators for photopolymerization |
GB9609439D0 (en) * | 1996-05-04 | 1996-07-10 | Zeneca Ltd | Polymerisable composition |
JP2001527565A (ja) * | 1997-05-23 | 2001-12-25 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 光重合のためのポリボラート共開始剤 |
-
1998
- 1998-10-06 TW TW087116591A patent/TW455616B/zh not_active IP Right Cessation
- 1998-10-21 GB GB9822858A patent/GB2333777A/en not_active Withdrawn
- 1998-10-26 US US09/179,170 patent/US6096794A/en not_active Expired - Fee Related
- 1998-10-28 ES ES009802256A patent/ES2154990B1/es not_active Expired - Lifetime
- 1998-10-29 FR FR9813568A patent/FR2770525B1/fr not_active Expired - Fee Related
- 1998-10-30 CA CA002252277A patent/CA2252277A1/en not_active Abandoned
- 1998-10-30 DE DE19850139A patent/DE19850139A1/de not_active Withdrawn
- 1998-10-30 BE BE9800784A patent/BE1013014A3/fr not_active IP Right Cessation
- 1998-10-30 BR BR9804736-1A patent/BR9804736A/pt not_active IP Right Cessation
- 1998-11-02 JP JP32746498A patent/JPH11269210A/ja active Pending
- 1998-11-03 IT IT1998MI002363A patent/IT1303691B1/it active
- 1998-11-03 KR KR1019980046911A patent/KR19990044967A/ko not_active Application Discontinuation
- 1998-11-03 NL NL1010465A patent/NL1010465C2/nl not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
FR2770525A1 (fr) | 1999-05-07 |
TW455616B (en) | 2001-09-21 |
GB2333777A (en) | 1999-08-04 |
IT1303691B1 (it) | 2001-02-23 |
BR9804736A (pt) | 1999-12-07 |
BE1013014A3 (fr) | 2001-07-03 |
ITMI982363A1 (it) | 2000-05-03 |
KR19990044967A (ko) | 1999-06-25 |
JPH11269210A (ja) | 1999-10-05 |
NL1010465C2 (nl) | 1999-07-06 |
DE19850139A1 (de) | 1999-05-12 |
US6096794A (en) | 2000-08-01 |
CA2252277A1 (en) | 1999-05-03 |
GB9822858D0 (en) | 1998-12-16 |
FR2770525B1 (fr) | 2000-03-31 |
ES2154990A1 (es) | 2001-04-16 |
NL1010465A1 (nl) | 1999-05-07 |
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