ES2154006T3 - Procedimiento para la preparacion de un catalizador util para la hidrogenizacion de copolimeros de estireno-butadieno. - Google Patents

Procedimiento para la preparacion de un catalizador util para la hidrogenizacion de copolimeros de estireno-butadieno.

Info

Publication number
ES2154006T3
ES2154006T3 ES97110260T ES97110260T ES2154006T3 ES 2154006 T3 ES2154006 T3 ES 2154006T3 ES 97110260 T ES97110260 T ES 97110260T ES 97110260 T ES97110260 T ES 97110260T ES 2154006 T3 ES2154006 T3 ES 2154006T3
Authority
ES
Spain
Prior art keywords
sub
hydrogenization
styrene
procedure
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97110260T
Other languages
English (en)
Inventor
Andrea Vallieri
Claudio Cavallo
Gian Tommaso Viola
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enichem SpA
Original Assignee
Enichem SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem SpA filed Critical Enichem SpA
Application granted granted Critical
Publication of ES2154006T3 publication Critical patent/ES2154006T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/94—Hydrogenation of a polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

COMPOSICION CATALITICA EFECTIVA EN LA HIDROGENACION SELECTIVA DE DOBLES ENLACES OLEFINICOS PREPARADA POR LA REACCION ENTRE: (A) POR LO MENOS UN DERIVADO DE BIS(CICLOPENTADIENIL)TITANIO DE FORMULA GENERAL (I) (C{SUB,5}H{SUB,5}){SUB,2}TI(R)(R{SUB,1}) EN DONDE R Y R{SUB,1}, IGUALES O DIFERENTES, SON HALOGENOS; EL COMPUESTO ANTERIOR (I) ES UN SOLIDO O ESTA DISPERSADO EN UNO O MAS DILUYENTES NO-DISOLVENTES; (B) POR LO MENOS UN DERIVADO ORGANICO DE FORMULA GENERAL (II) M(R{SUB,2})(R{SUB,3}), EN DONDE M SE SELECCIONA ENTRE ZINC Y MAGNESIO, Y R{SUB,2} Y R{SUB,3}, IGUALES O DIFERENTES, SE SELECCIONAN ENTRE ALQUILOS C{SUB,1}
ES97110260T 1996-07-04 1997-06-24 Procedimiento para la preparacion de un catalizador util para la hidrogenizacion de copolimeros de estireno-butadieno. Expired - Lifetime ES2154006T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT96MI001368A IT1284105B1 (it) 1996-07-04 1996-07-04 Procedimento per la preparazione di un catalizzatore utile per la idrogenazione di copolimeri stirene-butadiene

Publications (1)

Publication Number Publication Date
ES2154006T3 true ES2154006T3 (es) 2001-03-16

Family

ID=11374529

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97110260T Expired - Lifetime ES2154006T3 (es) 1996-07-04 1997-06-24 Procedimiento para la preparacion de un catalizador util para la hidrogenizacion de copolimeros de estireno-butadieno.

Country Status (12)

Country Link
US (1) US5948869A (es)
EP (1) EP0816382B1 (es)
JP (1) JP4121586B2 (es)
KR (1) KR100244045B1 (es)
CN (1) CN1107079C (es)
BR (1) BR9703827A (es)
CA (1) CA2209428C (es)
DE (1) DE69703765T2 (es)
ES (1) ES2154006T3 (es)
IT (1) IT1284105B1 (es)
RU (1) RU2194718C2 (es)
TW (1) TW426689B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19703478A1 (de) * 1997-01-31 1998-08-06 Hoechst Ag Verfahren zur Herstellung eines Matallocen-Katalysatorsystems
US6187873B1 (en) * 1997-08-07 2001-02-13 Shell Oil Company Increased throughput in the manufacture of block copolymers by reduction in polymer cement viscosity through the addition of polar solvents
IT1296066B1 (it) 1997-11-06 1999-06-09 Enichem Spa Procedimento per la idrogenazione di (co) polimeri dienici
TW583027B (en) * 1998-10-30 2004-04-11 Shell Int Research A method for preparing a hydrogenation catalyst system
US6479424B1 (en) 1998-12-14 2002-11-12 Bp Corporation North America Inc. Fluxional catalysts and related ligands containing bulky substituents
US6313230B1 (en) * 1999-09-21 2001-11-06 Industrial Technology Research Institute Catalyst composition for hydrogenation of conjugated diene based synthetic rubbers
TW546307B (en) * 2002-10-25 2003-08-11 Tsrc Corp Method for hydrogenating conjugated diene polymer
TWI256399B (en) * 2004-08-19 2006-06-11 Tsrc Corp Hydrogenation catalyst composition and process for hydrogenation of conjugated diene polymer
CN1844178B (zh) * 2005-04-08 2012-02-29 中国石油化工集团公司 一种苯乙烯-共轭二烯烃嵌段聚合物选择氢化的方法
ITMI20050860A1 (it) 2005-05-13 2006-11-14 Polimeri Europa Spa Procedimento per la idrogenazione selettiva di copolimeri stirene-butadiene
US7700694B2 (en) 2006-04-28 2010-04-20 Tsrc Corporation Catalyst composition and method for hydrogenating a polymer having a conjugated diene
FR2900352B1 (fr) * 2006-04-28 2008-07-04 Tsrc Corp Composition de catalyseur et procede pour hydrogener un polymere ayant un diene conjugue
JP4921849B2 (ja) * 2006-05-09 2012-04-25 台橡股▲ふん▼有限公司 共役ジエン重合体の水素化方法
CN101205268B (zh) * 2006-12-19 2010-09-29 台橡股份有限公司 氢化共轭二烯聚合物的方法及氢化触媒组合物
ITMI20070626A1 (it) * 2007-03-29 2008-09-30 Polimeri Europa Spa Mescola vulcanizzabile comprendente copolineri ramificati vinilarene-diene coniugato parzialmente idrogenati
ITMI20071210A1 (it) * 2007-06-15 2008-12-16 Polimeri Europa Spa Procedimento per la idrogenazione parziale di copolimeri random vinil arene-diene coniugato
US8549401B1 (en) * 2009-03-30 2013-10-01 Symantec Corporation Systems and methods for automatically generating computer-assistance videos
TWI415681B (zh) * 2009-07-24 2013-11-21 Ind Tech Res Inst 觸媒系統及選擇性氫化製程
TWI472544B (zh) 2009-10-30 2015-02-11 Tsrc Corp 氫化觸媒組合物及其氫化方法
US8999905B2 (en) 2010-10-25 2015-04-07 Afton Chemical Corporation Lubricant additive
IT1403084B1 (it) 2010-10-25 2013-10-04 Polimeri Europa Spa Copolimeri stirene-butadiene idrogenati e processo per la loro preparazione.
SG11201501536TA (en) * 2012-09-21 2015-05-28 Asahi Kasei Chemicals Corp Catalyst composition for hydrogenation and method for hydrogenation using the same
SG11201501532YA (en) * 2012-09-21 2015-05-28 Asahi Kasei Chemicals Corp Catalyst composition for hydrogenation and method for hydrogenation using the same
EP3327041B1 (en) * 2016-11-29 2024-04-10 TSRC Corporation Process and catalyst composition for producing selectively hydrogenated conjugated diene polymer
US20180171258A1 (en) 2016-12-16 2018-06-21 Afton Chemical Corporation Multi-Functional Olefin Copolymers and Lubricating Compositions Containing Same
US11098262B2 (en) 2018-04-25 2021-08-24 Afton Chemical Corporation Multifunctional branched polymers with improved low-temperature performance

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6220122A (ja) * 1985-07-19 1987-01-28 Hitachi Ltd 磁気ヘツド
JP2718059B2 (ja) * 1988-04-28 1998-02-25 日本合成ゴム株式会社 重合体の水素添加方法および触媒
US5270274A (en) * 1991-11-28 1993-12-14 Japan Synthetic Rubber Co., Ltd. Catalyst composition for hydrogenating olefinically unsaturated polymers
JP3326773B2 (ja) * 1993-01-26 2002-09-24 ジェイエスアール株式会社 オレフィン性不飽和結合を含有する重合体の水素化方法および水素添加触媒
JP3617553B2 (ja) * 1994-05-18 2005-02-09 旭化成ケミカルズ株式会社 オレフィン水添複合触媒及び水添共役ジエン系重合体の製造方法
JP3454922B2 (ja) * 1994-07-15 2003-10-06 旭化成株式会社 イソプレン系重合体の水添方法

Also Published As

Publication number Publication date
JP4121586B2 (ja) 2008-07-23
RU2194718C2 (ru) 2002-12-20
EP0816382A1 (en) 1998-01-07
ITMI961368A0 (es) 1996-07-04
CN1177599A (zh) 1998-04-01
KR100244045B1 (ko) 2000-02-01
IT1284105B1 (it) 1998-05-08
CN1107079C (zh) 2003-04-30
TW426689B (en) 2001-03-21
DE69703765T2 (de) 2001-08-02
MX9705031A (es) 1998-07-31
DE69703765D1 (de) 2001-02-01
CA2209428A1 (en) 1998-01-04
KR980009294A (ko) 1998-04-30
US5948869A (en) 1999-09-07
CA2209428C (en) 2006-03-28
EP0816382B1 (en) 2000-12-27
ITMI961368A1 (it) 1998-01-04
BR9703827A (pt) 1998-08-11
JPH11563A (ja) 1999-01-06

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