ES2146985T3 - Formacion de copolimero de bloque in situ durante la polimerizacion de un monomero de vinilo aromatico - Google Patents

Formacion de copolimero de bloque in situ durante la polimerizacion de un monomero de vinilo aromatico

Info

Publication number
ES2146985T3
ES2146985T3 ES97907863T ES97907863T ES2146985T3 ES 2146985 T3 ES2146985 T3 ES 2146985T3 ES 97907863 T ES97907863 T ES 97907863T ES 97907863 T ES97907863 T ES 97907863T ES 2146985 T3 ES2146985 T3 ES 2146985T3
Authority
ES
Spain
Prior art keywords
vinyl monomer
aromatic vinyl
block copolymer
during polymerization
formation during
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97907863T
Other languages
English (en)
Inventor
Duane B Priddy
Irene Q Li
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2146985T3 publication Critical patent/ES2146985T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
    • C07D295/24—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/46—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with hetero atoms directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

LA PRESENTE INVENCION SE REFIERE A UN PROCESO DE POLIMERIZACION RADICALAR A GRANEL, PARA PRODUCIR UN POLIMERO MODIFICADO CON CAUCHO, A PARTIR DE UN MONOMERO DE VINILO AROMATICO. DICHO PROCEDIMIENTO CONSISTE EN: POLIMERIZAR EL MONOMERO DE VINILO AROMATICO, EN PRESENCIA DE UN CAUCHO DIENICO, CON AL MENOS UN GRUPO RADICAL LIBRE ESTABLE, BAJO CONDICIONES DE POLIMERIZACION TALES QUE SE FORMA UN CAUCHO DE COPOLIMERO INJERTADO Y/O DE BLOQUE DIENICO - VINIL AROMATICO.
ES97907863T 1996-03-29 1997-02-26 Formacion de copolimero de bloque in situ durante la polimerizacion de un monomero de vinilo aromatico Expired - Lifetime ES2146985T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US1461696P 1996-03-29 1996-03-29

Publications (1)

Publication Number Publication Date
ES2146985T3 true ES2146985T3 (es) 2000-08-16

Family

ID=21766567

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97907863T Expired - Lifetime ES2146985T3 (es) 1996-03-29 1997-02-26 Formacion de copolimero de bloque in situ durante la polimerizacion de un monomero de vinilo aromatico

Country Status (19)

Country Link
US (1) US5721320A (es)
EP (2) EP0889918B1 (es)
JP (2) JP3673525B2 (es)
KR (1) KR20000005048A (es)
CN (2) CN1130403C (es)
AR (1) AR006423A1 (es)
AU (2) AU712769B2 (es)
BR (2) BR9708300A (es)
CA (1) CA2245686C (es)
CO (1) CO4820409A1 (es)
DE (1) DE69701517T2 (es)
ES (1) ES2146985T3 (es)
HK (1) HK1017900A1 (es)
HU (1) HU220138B (es)
ID (1) ID16412A (es)
MY (1) MY132457A (es)
PL (2) PL329115A1 (es)
TW (1) TW354324B (es)
WO (2) WO1997036944A1 (es)

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FR2768738A1 (fr) * 1997-09-19 1999-03-26 Atochem Elf Sa Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable
MXPA97008152A (es) 1997-10-23 2003-12-11 Ct De Investigacion En Quimica Metodo para la preparacion de nanocompositos compuestos de elastomeros dienicos y termoplasticos.
DE19752394A1 (de) * 1997-11-19 1999-05-20 Basf Ag Verfahren zur Herstellung von Pfropfpolymerisaten
US5880230A (en) * 1997-12-31 1999-03-09 Nalco/Exxon Energy Chemicals, L.P. Shortstop agents for vinyl polymerizations
CH693416A5 (de) 1998-03-09 2003-07-31 Ciba Sc Holding Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler.
TW495515B (en) * 1998-03-09 2002-07-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives, a polymerizable composition containing the same and a process for polymerization
CA2265345A1 (en) 1998-03-25 1999-09-25 The Lubrizol Corporation Vinyl aromatic-(vinyl aromatic-co-acrylic) block copolymers prepared by stabilized free radical polymerization
FR2779437B1 (fr) 1998-06-03 2004-10-15 Atochem Elf Sa Polymere vinylaromatique choc par polymerisation d'un monomere vinylaromatique en presence d'un radical libre stable et d'un amorceur de polymerisation
US6864313B2 (en) 1998-06-25 2005-03-08 Ciba Specialty Chemicals Corp. Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
TWI246519B (en) 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
CA2340689A1 (en) * 1998-09-03 2000-03-16 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
DE69941028D1 (de) * 1998-09-03 2009-08-06 Ciba Holding Inc Propfung von äthylenisch ungesättigten monomeren auf polymeren
FR2784111B1 (fr) * 1998-10-06 2003-08-01 Atochem Elf Sa Polymerisatin radicalaire en presence de plusieurs radicaux libres stables
EP1040147B1 (en) 1998-10-26 2003-07-02 The Lubrizol Corporation Radial polymers prepared by stabilized free radical polymerization
FR2787462B1 (fr) * 1998-12-22 2003-09-05 Corning Sa Capteurs de radicaux libres immobilises, preparation et utilisation
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
FR2791060A1 (fr) * 1999-03-18 2000-09-22 Atochem Elf Sa Procede de preparation d'un caoutchouc porteur de radical libre stable et utilisation dudit caoutchouc porteur pour la preparation d'un polymere vinylaromatique choc
US6355756B1 (en) 1999-05-18 2002-03-12 International Business Machines Corporation Dual purpose electroactive copolymers, preparation thereof, and use in opto-electronic devices
DE60012738T2 (de) * 1999-07-02 2005-08-04 Ciba Specialty Chemicals Holding Inc. Mono- und multifunktionelle alkoxyamine zur herstellung von funktionalisierten makromeren
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
EP1203054B1 (en) 1999-08-12 2004-11-03 Ciba SC Holding AG Polymer blends with improved impact resistance
US6569968B1 (en) * 1999-08-19 2003-05-27 Kurita Water Industries Ltd. Polymer of a water-soluble radical-polymerizable monomer, process for producing the polymer and flocculant comprising the polymer
US7034079B2 (en) * 1999-10-20 2006-04-25 The Lubrizol Corporation Radial polymers prepared by stabilized free radical polymerization
TWI225492B (en) 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
TWI274053B (en) 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
JP2002348340A (ja) * 2001-05-28 2002-12-04 Denki Kagaku Kogyo Kk ブロック共重合体及びその製造方法
KR100445073B1 (ko) 2001-08-21 2004-08-21 삼성전자주식회사 듀얼 다이 패키지
US7868171B2 (en) 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
CN1795218A (zh) * 2003-02-05 2006-06-28 陶氏环球技术公司 橡胶改性单亚乙烯基芳族聚合物中的粒度和形态控制
JP2007525544A (ja) * 2003-02-05 2007-09-06 ダウ グローバル テクノロジーズ インコーポレーテッド 塊状重合プロセスによって製造される高光沢ゴム変性モノビニリデン芳香族ポリマー
KR20050099526A (ko) * 2003-02-05 2005-10-13 다우 글로벌 테크놀로지스 인크. 비닐 방향족 단량체로부터 제조된 고무 개질 중합체
US7528194B2 (en) * 2003-02-10 2009-05-05 Ciba Specialty Chemicals Corp. Comb copolymers with defined side chains and process for their manufacture
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Also Published As

Publication number Publication date
EP0889890A1 (en) 1999-01-13
JP2001508398A (ja) 2001-06-26
EP0889918B1 (en) 2000-03-22
EP0889918A1 (en) 1999-01-13
AR006423A1 (es) 1999-08-25
PL329115A1 (en) 1999-03-15
CN1215402A (zh) 1999-04-28
AU1975697A (en) 1997-10-22
HUP9902432A2 (hu) 1999-11-29
CN1130403C (zh) 2003-12-10
AU711277B2 (en) 1999-10-07
HUP9902432A3 (en) 2000-05-29
PL329114A1 (en) 1999-03-15
WO1997036944A1 (en) 1997-10-09
WO1997036894A1 (en) 1997-10-09
HK1017900A1 (en) 1999-12-03
BR9708300A (pt) 1999-08-03
CN1214705A (zh) 1999-04-21
ID16412A (id) 1997-09-25
MY132457A (en) 2007-10-31
BR9708575A (pt) 1999-08-03
KR20000005048A (ko) 2000-01-25
DE69701517D1 (de) 2000-04-27
US5721320A (en) 1998-02-24
DE69701517T2 (de) 2000-11-09
CA2245686C (en) 2005-04-05
JP2000507623A (ja) 2000-06-20
AU712769B2 (en) 1999-11-18
TW354324B (en) 1999-03-11
CA2245686A1 (en) 1997-10-09
CO4820409A1 (es) 1999-07-28
JP3673525B2 (ja) 2005-07-20
AU2594697A (en) 1997-10-22
HU220138B (hu) 2001-11-28

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