ES2142237B1 - Mezclas estabilizantes. - Google Patents
Mezclas estabilizantes.Info
- Publication number
- ES2142237B1 ES2142237B1 ES009701536A ES9701536A ES2142237B1 ES 2142237 B1 ES2142237 B1 ES 2142237B1 ES 009701536 A ES009701536 A ES 009701536A ES 9701536 A ES9701536 A ES 9701536A ES 2142237 B1 ES2142237 B1 ES 2142237B1
- Authority
- ES
- Spain
- Prior art keywords
- sub
- magnesium
- alkyl
- formula
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 230000000087 stabilizing effect Effects 0.000 title abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000006096 absorbing agent Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229960001545 hydrotalcite Drugs 0.000 abstract 2
- 229910001701 hydrotalcite Inorganic materials 0.000 abstract 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 abstract 2
- 239000000347 magnesium hydroxide Substances 0.000 abstract 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract 2
- 239000000395 magnesium oxide Substances 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- 159000000003 magnesium salts Chemical class 0.000 abstract 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 2
- 239000000049 pigment Substances 0.000 abstract 2
- 229920000768 polyamine Polymers 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 abstract 1
- 229940007718 zinc hydroxide Drugs 0.000 abstract 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
- C08K5/5477—Silicon-containing compounds containing nitrogen containing nitrogen in a heterocyclic ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Mezclas estabilizantes. Una mezcla estabilizante que contiene (A) o bien (Al) por lo menos un compuesto de la fórmula (I);en donde R{sub,1 es, por ejemplo C{sub,1 -C{sub,10 , alquilo; R{sub,2 es C{sub,3 -C{sub,10 alquileno; R {sub,3 es por ejemplo hidrógeno o C{sub,1 -C{sub,8 alquilo; y n{sub,1 es un numero de 2 a 50; o (A2) un producto obtenible haciendo reaccionar un producto - obtenido mediante reacción de una poliamina de la fórmula H{sub,2 N-(CH{sub,2 ){sub,n"''2 -NH-(CH{sub,2 ){sub,n"''"''2 -NH-(CH{sub,2 ){sub,n"''"''"''2 -NH{sub,2 en donde n{sub,2 "'', n{sub,2 "''"'' y n{sub,2 "''"''"'' son un número entre 2 y 12 con cloruro cianúrico - con un compuesto de la fórmula (IIb) ; en donde R{sub,4 es por ejemplo hidrógeno o C{sub,1 C{sub,12 alquilo; y R{sub,5 es como se ha definido para R{sub,3 ; B) óxido de magnesio, hidróxido de magnesio, óxido de zinc, hidróxido de zinc o una sal orgánica de zinc o magnesio, o una hidrotalcita; y C) o bien (C1) un absorbedor de UV o (.C2) y un pigmento o (C3) un absorbebor de UV y un pigmento; con la salvedad de que, cuando el componente A) es un producto obtenible haciendo reaccionar un producto -obtenido mediante reacción de la poliamina anterior con cloruro cianúrico -con la 2,2,6,6-tetrametil-4-piperidilamina, el componente B) es óxido de magnesio, hidróxido de magnesio o una sal orgánica de zinc o magnesio, o una hidrotalcita. Esta mezcla estabilizadora es útil para estabilizar poliolefinas contra degradación inducida por luz.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96810461 | 1996-07-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2142237A1 ES2142237A1 (es) | 2000-04-01 |
ES2142237B1 true ES2142237B1 (es) | 2000-11-16 |
Family
ID=8225650
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES009701536A Expired - Lifetime ES2142237B1 (es) | 1996-07-12 | 1997-07-10 | Mezclas estabilizantes. |
Country Status (12)
Country | Link |
---|---|
US (1) | US6328912B1 (es) |
JP (1) | JPH10168321A (es) |
KR (1) | KR100463815B1 (es) |
BE (1) | BE1012528A3 (es) |
CA (1) | CA2210049C (es) |
DE (1) | DE19729399A1 (es) |
ES (1) | ES2142237B1 (es) |
FR (1) | FR2750993B1 (es) |
GB (2) | GB2315271B (es) |
IT (1) | IT1293320B1 (es) |
NL (1) | NL1006564C2 (es) |
TW (1) | TW357175B (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6828364B2 (en) * | 2000-07-14 | 2004-12-07 | Ciba Specialty Chemicals Corporation | Stabilizer mixtures |
CN1330693C (zh) * | 2002-05-30 | 2007-08-08 | 西巴特殊化学品控股有限公司 | 稳定的制品 |
ATE469959T1 (de) * | 2005-06-24 | 2010-06-15 | Basf Se | Zusammensetzungen mit einem polyorganosiloxan mit einer oder mehrerer piperidinylfunktionen als oberflächenschutzmittel |
KR100853088B1 (ko) * | 2006-03-14 | 2008-08-19 | 주식회사 엘지화학 | 광색성 염료의 나노 캡슐화 방법 |
IT1393333B1 (it) | 2009-02-09 | 2012-04-20 | 3V Sigma Spa | Nuove ammine stericamente impedite e loro uso come stabilizzanti per polimeri |
JP6859660B2 (ja) * | 2016-10-28 | 2021-04-14 | Toto株式会社 | 樹脂材料および成形体 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1152192B (it) | 1982-05-19 | 1986-12-31 | Apital Prod Ind | Composti per stabilizzare i polimeri |
US4929652A (en) * | 1987-05-05 | 1990-05-29 | Ciba-Geigy Corporation | Polyolefins stabilized against damage caused by light |
IT1215455B (it) | 1987-05-05 | 1990-02-14 | Ciba Geigy Spa | Composizione stabilizzante per polietilene comprendente composti contenenti gruppi piperidinici e composti metallici |
EP0290386B1 (de) * | 1987-05-05 | 1992-06-10 | Ciba-Geigy Ag | Stabilisierung von organischen Polymeren gegen Lichtabbau |
DE3724223A1 (de) * | 1987-07-22 | 1989-02-02 | Huels Chemische Werke Ag | Stabilisatorsystem |
JPH083006B2 (ja) * | 1987-07-31 | 1996-01-17 | 旭電化工業株式会社 | 安定化されたポリプロピレン系樹脂組成物 |
DE3739765A1 (de) * | 1987-11-24 | 1989-06-08 | Bayer Ag | Beschichtete formkoerper und ein verfahren zu ihrer herstellung |
IT1218004B (it) | 1988-05-27 | 1990-03-30 | Enichem Sintesi | Stabilizzanti uv per poli eri organici |
IT1219701B (it) | 1988-05-31 | 1990-05-24 | Ciba Geigy Spa | Poliammine parzialmente sostituite con 4,6 bis (n,n bis(2,2,6,6 tetrametil 4 piperdil) ammino) 1,3,5-triazin-2-il |
IT1246170B (it) | 1990-07-24 | 1994-11-16 | Ciba Geigy Spa | Composizione stabilizzante per polipropilene comprendente composti triazinici contenenti gruppi piperidinici e composti metallici |
IT1270870B (it) | 1993-03-11 | 1997-05-13 | Ciba Geigy Ag | Composti polimetilipeperidinici contenenti gruppi silanici atti all'impiego come stabilizzanti per materiali organici |
CH686519A5 (de) * | 1993-05-24 | 1996-04-15 | Sandoz Ag | Stabilisatoren fuer polymere Materialien. |
IT1269197B (it) | 1994-01-24 | 1997-03-21 | Ciba Geigy Spa | Composti 1-idrocarbilossi piperidinici contenenti gruppi silanici atti all'impiego come stabilizzanti per materiali organici |
IT1269953B (it) * | 1994-06-27 | 1997-04-16 | Ciba Geigy Spa | Films di poliolefine o copolimeri di olefine con migliorata stabilita' alla luce e resistenza agli insetticidi |
FR2725451B1 (fr) | 1994-10-06 | 1998-04-17 | Sandoz Sa | Nouvelle composition stabilisante pour les matieres polymeres |
TW401437B (en) * | 1995-02-10 | 2000-08-11 | Ciba Sc Holding Ag | Synergistic stabilizer mixture |
IT1275584B1 (it) | 1995-07-21 | 1997-08-06 | 3V Sigma Spa | Composizioni per la stabilizzazione di polimeri sintetici |
JP3375617B2 (ja) * | 1996-10-11 | 2003-02-10 | 株式会社東北総合研究社 | 養殖帆立貝の掛止具 |
JP3466606B1 (ja) * | 2002-12-27 | 2003-11-17 | 弘昭 杉山 | 連結貝係止具とロール状連結貝係止具 |
JP3694522B1 (ja) * | 2004-12-27 | 2005-09-14 | 弘昭 杉山 | 貝係止具と、集合貝係止具と、連続貝係止具と、ロール状連続貝係止具 |
-
1997
- 1997-06-03 TW TW086107586A patent/TW357175B/zh not_active IP Right Cessation
- 1997-06-26 KR KR1019970027682A patent/KR100463815B1/ko not_active IP Right Cessation
- 1997-06-30 BE BE9700562A patent/BE1012528A3/fr active
- 1997-07-08 GB GB9714272A patent/GB2315271B/en not_active Expired - Fee Related
- 1997-07-08 GB GB0015949A patent/GB2349642B/en not_active Expired - Fee Related
- 1997-07-09 DE DE19729399A patent/DE19729399A1/de not_active Ceased
- 1997-07-10 IT IT97MI001646A patent/IT1293320B1/it active IP Right Grant
- 1997-07-10 FR FR9708777A patent/FR2750993B1/fr not_active Expired - Fee Related
- 1997-07-10 US US08/889,989 patent/US6328912B1/en not_active Expired - Lifetime
- 1997-07-10 ES ES009701536A patent/ES2142237B1/es not_active Expired - Lifetime
- 1997-07-10 JP JP9200903A patent/JPH10168321A/ja active Pending
- 1997-07-10 CA CA002210049A patent/CA2210049C/en not_active Expired - Fee Related
- 1997-07-11 NL NL1006564A patent/NL1006564C2/nl not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
GB9714272D0 (en) | 1997-09-10 |
CA2210049C (en) | 2006-06-06 |
JPH10168321A (ja) | 1998-06-23 |
TW357175B (en) | 1999-05-01 |
GB0015949D0 (en) | 2000-08-23 |
GB2349642A (en) | 2000-11-08 |
FR2750993B1 (fr) | 2001-06-29 |
GB2315271B (en) | 2000-11-08 |
DE19729399A1 (de) | 1998-01-15 |
FR2750993A1 (fr) | 1998-01-16 |
US6328912B1 (en) | 2001-12-11 |
GB2349642B (en) | 2001-01-17 |
KR100463815B1 (ko) | 2005-06-22 |
CA2210049A1 (en) | 1998-01-12 |
ES2142237A1 (es) | 2000-04-01 |
NL1006564C2 (nl) | 2000-07-13 |
NL1006564A1 (nl) | 1998-01-15 |
GB2315271A (en) | 1998-01-28 |
KR980009352A (ko) | 1998-04-30 |
BE1012528A3 (fr) | 2000-12-05 |
IT1293320B1 (it) | 1999-02-16 |
ITMI971646A1 (it) | 1999-01-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EC2A | Search report published |
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