ES2123506T3 - Reactivo y procedimiento de perfluoroalquilacion de sustratos nucleofilos por perfluoroalcanosulfinatos de sodio en medio oxidante. - Google Patents

Reactivo y procedimiento de perfluoroalquilacion de sustratos nucleofilos por perfluoroalcanosulfinatos de sodio en medio oxidante.

Info

Publication number
ES2123506T3
ES2123506T3 ES91401278T ES91401278T ES2123506T3 ES 2123506 T3 ES2123506 T3 ES 2123506T3 ES 91401278 T ES91401278 T ES 91401278T ES 91401278 T ES91401278 T ES 91401278T ES 2123506 T3 ES2123506 T3 ES 2123506T3
Authority
ES
Spain
Prior art keywords
perfluoro
substrates
perfluoroalcanosulfinates
nucleophil
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91401278T
Other languages
English (en)
Inventor
Jean-Louis Clavel
Eliane Laurent
Bernard Langlois
Nathalie Roidot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Application granted granted Critical
Publication of ES2123506T3 publication Critical patent/ES2123506T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/04—Substitution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C07B45/06—Formation or introduction of functional groups containing sulfur of mercapto or sulfide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/74—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by halogenation, hydrohalogenation, dehalogenation, or dehydrohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/16—Saturated compounds containing keto groups bound to acyclic carbon atoms containing halogen
    • C07C49/167—Saturated compounds containing keto groups bound to acyclic carbon atoms containing halogen containing only fluorine as halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/34—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D309/36—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyrane Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

LA PRESENTE INVENCION COMPRENDE UN REACTIVO DE PERFLUOROALQUILACION Y SU PROCESO DE UTILIZACION SOBRE SUSTRATOS NUCLEOFILOS. EL REACTIVO DE PERFLUOROALQUILACION COMPRENDE: A) UN ION PERFLUOROALCANOSULFINATO; B) UN SISTEMA OXIDANTE MONOELECTRONICO CUYO POTENCIAL REDOX ES SUPERIOR O IGUAL A 1,20 V RESPECTO DEL ELECTRODO DE REFERENCIA LLAMANDO DE COLOMEL SATURADO (ECS : HG/HGCL SUB 2). APLICACION EN LA SINTESIS ORGANICA.
ES91401278T 1990-05-23 1991-05-17 Reactivo y procedimiento de perfluoroalquilacion de sustratos nucleofilos por perfluoroalcanosulfinatos de sodio en medio oxidante. Expired - Lifetime ES2123506T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9006426A FR2662439B1 (fr) 1990-05-23 1990-05-23 Reactif et procede de perfluoroalkylation de substrats nucleophiles par les perfluoroalcanesulfinates de sodium en milieu oxydant.

Publications (1)

Publication Number Publication Date
ES2123506T3 true ES2123506T3 (es) 1999-01-16

Family

ID=9396875

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91401278T Expired - Lifetime ES2123506T3 (es) 1990-05-23 1991-05-17 Reactivo y procedimiento de perfluoroalquilacion de sustratos nucleofilos por perfluoroalcanosulfinatos de sodio en medio oxidante.

Country Status (8)

Country Link
US (1) US5565689A (es)
EP (1) EP0458684B1 (es)
JP (2) JP2542129B2 (es)
AT (1) ATE173241T1 (es)
DE (1) DE69130462T2 (es)
DK (1) DK0458684T3 (es)
ES (1) ES2123506T3 (es)
FR (1) FR2662439B1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2738814B1 (fr) * 1995-09-15 1997-11-14 Rhone Poulenc Chimie Reactif, compose et procede pour la perfluoroalc(o)ylation de nucleophile, ainsi que les derives obtenus
JPH11504619A (ja) * 1995-02-24 1999-04-27 ローヌ−プラン シミ 求核性物質のペルフルオロアルキル化のための反応体、化合物および方法、および得られた誘導体
FR2730992B1 (fr) * 1995-02-24 1997-04-04 Rhone Poulenc Chimie Procede d'obtention de composes perhalogenoalkyles et/ou acyles et agents de perhalogenoalkylation et/ou acylation susceptibles d'etre mis en oeuvre dans ce procede
WO2003078366A1 (en) * 2002-03-13 2003-09-25 University Of Florida Process for trifluoromethylation of sulfates
EP1814837B1 (en) * 2004-10-18 2010-02-24 Central Glass Co., Ltd. A method for producing 4,4,4-trifluorobutane-2-one
JP5106048B2 (ja) * 2006-11-06 2012-12-26 東ソー株式会社 パーフルオロアルキル基を有するベンゼン類の製造方法
JP2009292777A (ja) * 2008-06-06 2009-12-17 Univ Meijo パーフルオロ炭化水素基導入方法
JP5655633B2 (ja) 2010-03-04 2015-01-21 セントラル硝子株式会社 パーフルオロアルカンスルフィン酸塩の製造方法
CN103553857B (zh) * 2013-10-29 2016-01-20 南京大学 一种制备邻三氟甲基苯胺或其衍生物的方法
CN104072324B (zh) * 2014-06-19 2016-06-08 华东理工大学 制备2-三氟甲基-4-取代苯胺类化合物的方法
JP6435207B2 (ja) * 2015-02-10 2018-12-05 公益財団法人相模中央化学研究所 （２，２，２−トリフルオロエチル）ケトンの製造方法
DE112016002460T5 (de) 2015-06-04 2018-02-15 Sumitomo Chemical Company, Limited Verfahren zur Herstellung von Perfluoralkansulfonylphenol-Verbindungen
CN105693464B (zh) * 2016-02-25 2019-11-15 上海杰视医疗科技有限公司 一种含氟烷烃化合物的制备方法
AU2020378491B2 (en) * 2019-11-08 2024-05-23 Board Of Trustees Of Michigan State University Nano-reactor system for decomposition of per- and polyfluoroalkyl substances
CN113636918A (zh) * 2021-08-13 2021-11-12 上海兆维科技发展有限公司 一种全氟烷基化芳基化合物的制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4304614A (en) * 1975-09-04 1981-12-08 Walker Franklin E Zirconium hydride containing explosive composition
US4605432A (en) * 1980-03-07 1986-08-12 E. I. Du Pont De Nemours And Company Pyridyl sulfone herbicides
US4505929A (en) * 1980-06-12 1985-03-19 The Dow Chemical Company Sulfur-substituted diphenyl ethers having antiviral activity
DE3533672A1 (de) * 1985-09-19 1987-03-26 Schering Ag Neue 12- und 13-substituierte ergolinderivate
US4935440A (en) * 1986-11-25 1990-06-19 Syntex (U.S.A.) Inc. 3-[ω-(3,5-Di-t-butyl-4-hydroxyphenyl)alkyl]pyrroles, and anti-inflammatory uses thereof
US4990699A (en) * 1988-10-17 1991-02-05 Ethyl Corporation Perfluoroalkylation process
US5041509A (en) * 1990-02-07 1991-08-20 Cherylyn Lee Side chain copolymers exhibiting nonlinear optical response
US5153192A (en) * 1990-04-09 1992-10-06 Alcon Laboratories, Inc. Thiophene sulfonamides useful as carbonic anhydrase inhibitors
US5095136A (en) * 1990-08-27 1992-03-10 E. R. Squibb & Sons, Inc. Method for preparing isoprenoid cyclopropane 1,1-dicarboxylates and derivatives thereof and novel intermediates
US5117041A (en) * 1990-11-13 1992-05-26 E. I. Du Pont De Nemours And Company Sulfonation process

Also Published As

Publication number Publication date
EP0458684A1 (fr) 1991-11-27
JP2542129B2 (ja) 1996-10-09
JPH09263548A (ja) 1997-10-07
FR2662439A1 (fr) 1991-11-29
EP0458684B1 (fr) 1998-11-11
DK0458684T3 (da) 1999-07-26
DE69130462D1 (de) 1998-12-17
JPH06234665A (ja) 1994-08-23
ATE173241T1 (de) 1998-11-15
DE69130462T2 (de) 1999-07-08
FR2662439B1 (fr) 1993-11-19
US5565689A (en) 1996-10-15

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